个人简介
Biography
Dr. Liu was born in Anhui, China. He obtained the B.S. degree from Anhui Normal University (AHNU) in 2001. After that, he continued his research experience in both Shanghai Institute of Organic Chemistry (SIOC), CAS and AHNU under the jointly supervision of Prof. Dr. Shizheng Zhu and Prof. Dr. Shaowu Wang and obtained his Master degree in 2004. After a one year’s stint in Prof. Gang Zhao’s laboratory in SIOC, he joined Prof. Dr. Chi-Ming Che’s group in The University of Hong Kong and earned his Ph.D. degree in 2010. His Ph.D. research focused on organic catalysis and organometallic chemistry. He continued postdoctoral study in Prof. Che’s group in the University of Hong Kong and in Prof. Dr. Carlos F. Barbas III’s group in The Scripps Research Institute. At the end of 2012, he began his independent academic career in Southern University of Science and Technology of China. Dr. Liu’s research interest is asymmetric radical reactions.
Academic Experience
Sept. 2012—present Associate Professor, Southern University of Science and Technology
Apr. 2010—Aug. 2012 Postdoctoral Fellow, the Scripps Research Institute
Apr. 2010—Aug. 2012 The University of Hong Kong
Jul. 2004—Aug. 2005 Research Assistant at Shanghai Institute of Organic Chemistry, CAS
Education Qualifications
Sept. 2005—Mar. 2010 Ph.D. The University of Hong Kong
Sept. 2001—Jun. 2004 MSc. Shanghai Institute of Organic Chemistry, CAS in Cooperation with
Anhui Normal University
Sept. 1997—Jun. 2001 BSc, Anhui Normal University
Honors and Awards
2017 Award for National Excellent Young Scholar (NSFC) (国家自然科学基金优秀青年项目)
2017 The Distinguished Lectureship Award (Chemical Society of Japan)
2016 SUSTech Outstanding Researcher Awards (SUSTech)
2013 Peacock Rewarding Plan (Type B) (Shenzhen Municipal Government)
2011 Award for Outstanding Research Postgraduate Student (HKU)
近期论文
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“Catalytic Asymmetric Radical Diamination of Alkenes.”
Chem. 2017, accepted.
Fu-Li Wang,Xiao-Yang Dong,Jin-Shun Lin,Yang Zeng, Guan-Yuan Jiao, Qiang-Shuai Gu, Xian-Qi Guo, Can-Liang Ma and Xin-Yuan Liu*
“A remote C–C bond cleavage–enabled skeletal reorganization: Access to medium-/large-sized cyclic alkenes.”
Science Advances 2017, 3, e1701487.
Lei Li, Zhong-Liang Li, Qiang-Shuai Gu, Na Wang and Xin-Yuan Liu*.
“Catalytic Radical Intramolecular Aminoperfluoroalkylation and Aminodifluoromethylation of Unactivated Alkenes with Fluoroalkylsulfonyl Chlorides”
Synthesis. 2017, 49, 4213.
Xue-Fei Li, Jin-Shun Lin and Xin-Yuan Liu*.
Published as part of the Special Topic Modern Cyclization Strategies in Synthesis
“Phosphine-catalyzed remote α-C–H bond activation of alcohols or amines triggered by the radical trifluoromethylation of alkenes: reaction development and mechanistic insights”
Org. Chem. Front. 2017, 4, 2139
Lei Li, Liu Ye, Shao-Fei Ni, Zhong-Liang Li, Su Chen, Yi-Meng Du, Xiao-Hua Li, Li Dang* and Xin-Yuan Liu*
Graphical abstract: Phosphine-catalyzed remote α-C–H bond activation of alcohols or amines triggered by the radical trifluoromethylation of alkenes: reaction development and mechanistic insights
“Catalytic Asymmetric Radical Aminoperfluoroalkylation and Aminodifluoromethylation of Alkenes: A Versatile Platform for Enantioenriched-Fluoroalkyl Amines”
Nat. Commun. 2017, 8, 14841.
Jin-Shun Lin, Fu-Li Wang, Xiao-Yang Dong, Wei-Wei He, Yue Yuan, Su Chen, and Xin-Yuan Liu,*
“Achiral Pyridine Ligand-Enabled Enantioselective Radical Oxytrifluoromethylation of Alkenes with Alcohols”
Angew. Chem., Int. Ed. 2017, 56, 8883.
Yong-Feng Cheng, Xiao-Yang Dong, Qiang-Shuai Gu, Zhang-Long Yu, and Xin-Yuan Liu*
Selected as Cover picture.
Highlighted by Chin. J. Org. Chem. 2017, 37, 2172
Highlighted by Synfacts 2017, 13(10), 1042. pdf
“Dual-Catalyzed Enantioselective Remote C−H Functionalization Triggered by Radical Trifluoromethylation of Alkenes: Highly Selective Formation of C−CF3 and C−C Bonds”
J. Fluorine Chem. 2017, 10.1016/j.jfluchem.2017.03.008
Taotao Li, Peng Yu, Yi-Meng Du, Jin-Shun Lin, Yonggang Zhi,* and Xin-Yuan Liu,*
invited paper for a special issue
“1,2-Difunctionalization-Type (Hetero)arylation of Unactivated Alkenes Triggered by Radical Addition/Remote (Hetero)aryl Migration”
Chem. Commun. 2017, 53, 4038.
Lei Li, Qiang-Shuai Gu, Na Wang, Ping Song, Zhong-Liang Li, Xiao-Hua Li, Fu-Li Wang, and Xin-Yuan Liu,*
“Transition-Metal-Free β C−H Bond Carbonylation of Enamides or Amides with a Trifluoromethyl Group as CO Surrogate for the Synthesis of 1,3-Oxazin-6-ones”
Org. Lett. 2017, 19, 1330.
Ping Song, Peng Yu, Jin-Shun Lin, Yiqun Li,* Ning-Yuan Yang, and Xin-Yuan Liu,*
Radical Aryl Migration Enables Diversity-Oriented Synthesis of Structurally Diverse Medium/Macro- or Bridged-Rings.
Nat. Commun. 2016, 7, 13852.
Lei Li, Zhong-Liang Li, Fu-Li Wang, Zhen Guo, Yong-Feng Cheng, Na Wang, Chao Fang, Jingjiang Liu, Chunhui Hou, Bin Tan, and Xin-Yuan Liu*
Radical-Mediated 1,2-Formyl/carbonyl-Functionalization of Alkenes and Application to Construction of Medium-Sized-, Fused-, and Bridged-Ring Systems.
Angew. Chem., Int. Ed. 2016, 55, 15100.
Zhong-Liang Li, Xiao-Hua Li, Na Wang, Ning-Yuan Yang, and Xin-Yuan Liu*
A Dual-Catalytic Strategy to Direct Asymmetric Radical Aminotrifluoromethylation of Alkenes”
J. Am. Chem. Soc. 2016, 138, 9357.
Jin-Shun Lin, Xiao-Yang Dong, Tao-Tao Li, Na-Chuan Jiang, Bin Tan, and Xin-Yuan Liu*
Highlighted by “Synfacts 2016, 1020”. Highlighted by “Chin. J. Org. Chem. 2016, 36, 2247”.
Stereoselective Radical Cyclization Cascades Triggered by Addition of Diverse Radicals to Alkynes to Construct 6(5)‐6‐5 Fused Rings.
Org. Lett., 2016, 18, 5284.
Lin Huang, Liu Ye, Xiao-Hua Li, Zhong-Liang Li, Jin-Shun Lin, and Xin-Yuan Liu*
Catalytic Diverse Radical-Mediated 1,2-Cyanofunctionalization of Unactivated Alkenes via Synergistic Remote Cyano Migration and Protected Strategies.
Org. Lett., 2016, 18, 6026.
Na Wang, Lei Li, ZhNa Wang, Lei Li, Zhong-Liang Li, Ning-Yuan Yang, Zhen Guo,* Hong-Xia Zhang, and Xin-Yuan Liu,*ong-Liang Li, Ning-Yuan Yang, Zhen Guo,* Hong-Xia Zhang, and Xin-Yuan Liu*
Organic base-catalysed solvent-tuned chemoselective carbotrifluoromethylation and oxytrifluoromethylation of unactivated alkenes.
Chem. Commun., 2016, 52, 9052.
Ning-Yuan Yang, Zhong-Liang Li, Liu Ye, Bin Tan, and Xin-Yuan Liu*
From themed collection 2016 Emerging Investigators by Chem. Commun.
Counteranion-Controlled Unprecedented Diastereo- and Enantioselective Tandem Povarov Reaction for Construction of Bioactive Octahydro-dipyrroloquinolines.
ACS Catal. 2016, 6, 6182.
Xiao-Long Yu, Liping Kuang, Su Chen, Xiao-Long Zhu, Zhong-Liang Li, Bin Tan, and Xin-Yuan Liu,*
Nickel(0)-Catalyzed Denitrogenative Transannulation of Triazoles with Alkynes: Mechanistic Insights of Chemical Reactivity, Regio- and Enantioselectivity from Density Functional Theory and Experiment.
ACS Catal. 2016, 6, 3496.
Na Wang, Sheng-Cai Zheng, Lin-Lin Zhang, Zhen Guo,* and Xin-Yuan Liu*
Copper-Catalyzed Redox-Triggered Remote C–H Functionalization: Highly Selective Formation of C–CF3 and C–O Bonds
Chin. J. Chem. 2016, 34, 490.
Taotao Li, Peng Yu, Jin-Shun Lin, Yonggang Zhi,* and Xin-Yuan Liu,*
Invited paper for the Special Issue of “Trifluoromethylation and Trifluoromethythiolation Reactions”
Gold-catalyzed tandem synthesis of bioactive spiro-dipyrroloquinolines and its application in the one-step synthesis of incargranine B aglycone and seneciobipyrrolidine (I).
Org. Chem. Front. 2016, 3, 324.
Can-Liang Ma, Xiao-Hua Li, Xiao-Long Yu, Xiao-Long Zhu, Yong-Zhou Hu, Xiao-Wu Dong,* Bin Tan,* and Xin-Yuan Liu*
From themed collection 2015 Emerging Investigators by OCF.
Discovery and Enantiocontrol of Axially Chiral Urazoles via Organocatalytic Tyrosine Click Reaction
Nat. Commun. 2016, 7, 10677.
Ji-Wei Zhang, Jin-Hui Xu, Dao-Juan Cheng, Chuan Shi, Xin-Yuan Liu,* and Bin Tan,*
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