个人简介

Fellow of the American Association for the Advancement of Science (2011). In Recognition of Outstanding Research Awards, Exxon Education Foundation

研究领域

Biophysical and Physical Chemistry

The Robinson group specializes in using a variety of Electron Paramagnetic Resonance (EPR) techniques, including continuous wave and pulsed Saturation Recovery (pSR) and pulsed Electron-Electron Double Resonance (pELDOR) EPR at 2 and 10 GHz. The research areas of interest include: dynamics of B-form duplex DNA and protein-DNA binding (as part of the process of DNA recognition); protein-RNA interactions; the interaction of interfacial signaling proteins and membranes; and the organization of organic chromophores in polymer matrices. The group collaborates with Professors Larry Dalton, Mickey Schurr, and Mike Gelb (all UW Chemistry) as well as Snorri Sigurdsson (University of Iceland), and Albert Beth and Eric Hustedt (Vanderbilt University). The Robinson laboratory contains a CW/pulsed 10 GHz and a CW/pulsed 2 GHz EPR spectrometers. In addition, the Robinson group is responsible for the shared EPR instrumentation (from NIH-IEHS), which is used by more than a dozen groups around the UW campus. The group also has a Beowulf cluster computer comprised of 40 Athlon 1.6 GHz processors as part of the NSF-funded Center on Materials and Devices for Information Technology Research (CMDITR). Professor Robinson teaches courses in Introductory Chemistry (CHEM 152) and Physical Chemistry (CHEM 455 and 456).

近期论文

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Sullivan, P.A, Rommel, H.L., Liao, Y. et al. "Theory Guided Design and Synthesis of Multichromophore Dendrimers: An Analysis of the Electro-Optic effect." J. Amer. Chem. Soc. In Press (2007). Rommel, H.L., and Robinson, B.H. "Orientation of electro-optic chromophores under poling conditions: A spheroidal model." J. Phys. Chemistry, B, (About to be Submitted) (2007). Isborn, C. M., A. LeClercq, et al. "Comparison of Hyperpolarizabilities Calculated with Various Quantum Mechanical Methods." J. Phys. Chem. A, 111, 1319 –1327 (2007). E. R. Davidson, B. E. Eichinger, B. H. Robinson,"Hyperpolarizability: Calibration of theoretical methods for chloroform, water, acetonitrile, and p-nitroaniline." Opt. Mater., 29; 360 (2006). Wallace, P. M., D. R. B. Sluss, et al. "Single-Molecule Microscopy Studies of Electric-Field Poling in Chromophore-Polymer Composite Materials." J. Phys. Chem. B. 110(1): 75-82 (2006). Nielsen, R., D. and B. H. Robinson. "The Spherical Tensor Formalism Applied to Relaxation in Magnetic Resonance." Concepts Magn. Reson., 28A, 270-290 (2006). Liao, Y., K. A. Firestone, et al. "Linear and Nonlinear Optical Properties of a Macrocyclic Trichromophore Bundle with Parallel-Aligned Dipole Moments." J. Phys. Chem. B, 110, 5434 (2006). Liao, Y., S. Bhattacharjee, et al. "Antiparallel-Aligned Neutral-Ground-State and Zwitterionic Chromophores as a Nonlinear Optical Material." JACS, 128, 6847 (2006). Kinnibrugh, T., S. Bhattacharjee, et al."Influence of Isomerization on Non-Linear Optical Properties of Molecules." J. Phys. Chem. B., 110; 13512 (2006). Isborn, C. M., E. R. Davidson, et al. "Ab Initio Diradical/Zwitterionic Polarizabilities and Hyperpolarizabilities in Twisted Double Bonds." J. Phys. Chem. A, 110, 7189 -7196 (2006). Davidson, E. R., B. E. Eichinger, et al. "Hyperpolarizability: Calibration of Theoretical Methods for Chloroform, Water, Acetonitrile, and p-Nitroaniline." Opt. Mater.; In Press (2006). Clark, R. H., R. D. Nielsen, et al. "Site-Directed Labeling Studies of Protein Orientation on Biomineral Crystals by EPR Spectroscopy." BioInterface; Submitted (2006). Nielsen, R. D., Che, K., Gelb, M. H. and Robinson, B. H. "A ruler for determining the position of proteins in membranes". J. Amer. Chem. Soc.; 127 (17): 6430-6442 (2005) Mailer, C., Nielsen, R. D. and Robinson, B. H. "Explanation of spin-lattice relaxation rates of spin labels obtained with Multi-frequency Saturation Recovery EPR". J. Phys. Chem. A.; 109 (18): 4049-4061 (2005). Liao, Y., Eichinger, B. E., Firestone, K. A., Haller, M., Luo, J., Kaminsky, W., Benedict, J. B., Reid, P. J., Jen, A. K.-Y., Dalton, L. R. and Robinson, B. H. "Systematic Study of the Structure-Property Relationship of a Series of Ferrocenyl Nonlinear Optical Chromophores". J. Amer. Chem. Soc.; 127 (8): 2758-2766 (2005). Edwards, T. E., Robinson, B. H. and Sigurdsson, S. T. "Identification of amino acids that promote specific and rigid TAR RNA-Tat protein complex formation". Chemistry and Biology; 12 (3): 329-337 (2005). Young, C. L., Dalton, L. R., Robinson, B. H. and Kwiram, A. L. "Proton ENDOR Studies of Soliton Wavefunctions and Dynamics in Polyacetylenes". J. Phys. Chem. B; 108: 8682-8688 (2004). Rosen, G. M., Beselman, A., Tsai, P., Pou, S., Mailer, C., Ichikawa, K., Robinson, B. H., Nielsen, R., Halpern, H. J. and MacKerell, A. D. "Influence of Conformation on the EPR Spectrum of 5-5-Dimethyl-1-hydroperoxy-1-pyrrolidinyloxyl: A Spin Trapped Adduct of Superoxide". J. Org. Chem.; 69: 1321-1330 (2004). Nielsen, R. D., Hustedt, E. J., Beth, A. H. and Robinson, B. H. "Formulation of Zeeman Modulation as a Signal Filter". J. Magn. Reson.; 170: 345-371 (2004). Nielsen, R. D. and Robinson, B. H. "The Effect of Field Modulation on a Simple Resonance Line Shape". Concepts Magn. Reson.; 223A: 38-48 (2004).