Engel, Paul S. - Rice University - Department of Chemistry

个人简介

B.S. Chemistry (1964) University of California, Los Angeles Ph.D. Chemistry (1968) Harvard University

研究领域

We are investigating the chemistry of free radical initiators and inhibitors of polymerization. A related area of research is the free radical of single walled carbon nanotubes with organic free radicals.

近期论文

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Watson, B.M.; Kasper, F.K.; Engel, P.S.; Mikos, A.G. "Synthesis and Characterization of Injectable, Biodegradable, Phosphate-Containing, Chemically Cross-Linkable, Thermoresponsive Macromers for Bone Tissue Engineering," Biomacromolecules, 2014, 15, 1788-1796. Engel, P. S.; Gudimetla, V. B.; Gancheff, J. S.; Denis, P. A. Solution Phase Photolysis of 1,2-Dithiane Alone and with Single-Walled Carbon Nanotubes. J. Phys. Chem. A, 116 2012: 8345-8351 Mukerjee, A.; Combs, R.; Chattopadhyay, J.; Abmayr, D. W.; Engel, P. S.; Billups, W. E.; Attachment of Nitrogen and Oxygen Centered Radicals to Single-Walled Carbon Nanotube Salts. Chem. Mater., 20 2008: 7339-7343 Alvarez, N. T.; Kittrell, C., Schmidt, H. K.; Hauge, R. H.; Engel, P. S.; Tour, J. M. Selective Photochemical Functionalization of Surfactant-Dispersed Single Wall Carbon Nanotubes in Water. J. Am. Chem. Soc., 130 2008: 14227-14233 Engel, P. S.; Billups, W. E.; Abmayr, D. W.; Tsvaygboym, K.; Wang, R. The Reaction of Carbon Nanotubes with Organic Peroxides. J. Phys. Chem. C, 112 2008: 695-700 Chattopadhyay, J.; Chakraborty, S.; Mukherjee, A.; Wang, R.; Engel, P. S.; Billups, W. E. SET Mechanism in the Functionalization of Single-Walled Carbon Nanotubes. J. Phys. Chem. C, 111(48) 2007: 17928-17932 Wang, R.; Cherukuri, P.; Duque, J. G.; Leeuw, T. K.; Lackey, M. K.; Moran. C. H.; Moore, V. C.; Conyers J. L; Smalley, R. E.; Schmidt, H. K; Weisman, R. B.; Engel, P. S SWNCT PEG-eggs: Single-Walled Carbon Nanotubes in Biocompatible Shell-Crosslinked Micelles. Carbon, 45 2007: 2388-2394 Engel, P. S.; Tsvaygboym, K.; Bachillo, S.; Smith W. B.; Jiang, J-J, Chignell, C. F.; Motten, A. G. Photorearrangement of alpha-Azoxy Ketones and Triplet Sensitizaion of Azoxy Compounds. J. Org. Chem, 70 2005: 2598 Engel, P.S.; Ying, Y-M.; He, S-L. An Aliphatic Bifunctional Free Radical Initiator. Synthesis of a Block Copolymer from an Azoperester by Sequential Thermal and Photochemical Initiation. Macromolecules, 36 2003: 3821-3825 Temenoff, J.S.; Shin,H.; Conway, D.E.; Engel, P.S.; Mikos, A. G. In Vitro Cytotoxicity of Redox Radical Initiators for Crosslinking of Oligo(Poly(Ethylene Glycol) Funarate) Macromers. Biomacromolecules, 4 2003: 1605-1613 Engel, P.S.; Duan, S.; He, S.-L.; Tsvaygboym, K.: Wang, C.; Wu, A.; Ying, Y.-M.; Smith, W.B. The Free Radical Chemistry of the Azoxy Group. Arkivoc 2003: 89-108 P.S. Engel, L. Pan, Y. Ying, and L.B. Alemany. Thermolysis of Free-Radical Initiators: tert-Butylazocumene and Its 1,3 and 1,4-Bisazo and 1,3,5-Trisazo Analogues. JACS, 123 2001: 3706-3715