个人简介
Education
1981-1983 Postdoctoral Fellow; The University of Wisconsin, Madison, WI (with C. P. Casey)
1981 Ph.D., Chemistry; Princeton University, Princeton, NJ (with J. R. Norton)
1975 B.A., High Honors; Chemistry, Rutgers University, Camden, NJ
Professional Experience
2015-present Paul Snowden Russell Distinguished Service Professor, The University of Chicago
1999-2015 Professor of Chemistry, The University of Chicago
1993-1999 Professor of Chemistry, The University of Iowa
1988-1992 Associate Professor of Chemistry, The University of Iowa
1988 Associate Professor of Chemistry, Washington State University
1983-1987 Assistant Professor of Chemistry, Washington State University
1975-1976 Research Chemist, ARCO Chemical Company, Glenolden, PA
Awards and Professional Activities
2016 Dow Lecturer, University of California, Berkeley
2015 Organizer, Symp. on Metal Catalyzed Olefin Polymerization; Fall Nat. ACS Mtg.
2014 Search Committee, Assoc. Lab Director, PSE Directorate, Argonne Nat. Lab.
2013 BASF Lecturer, The Scripps Research Institute, La Jolla, CA
2012 Fellow of the American Association for the Advancement of Science
2011 Advisory Committee, U Chicago Tech
2011 Plenary Lecturer, C&CF 2011
2011 Guest Professor, Zhejiang University, Hangzhou, China
2011 NSF Center for Enabling Transformations in Catalysis Review Panel
2010 Eastman Chemical Lecturer, Univ. of California, Berkeley
2009, 2010 Vice Chair and Chair, Gordon Conference on Organometallic Chemistry
2009-present Governing Board, Council for Chemical Research
2008 Lanxess-Therban Lecture, XXIII ICOMC, Rennes, France
2007 Invited Lecturer, Mitsui Symposium on Catalysis, Chiba, Japan
2006 Plenary Lecturer, 39th IDW, Carleton University, Ottawa, Ontario
2006 NSF Inorganic/Bioinorganic/Organometallics Career Proposal Review Panel
2005 Visiting Professor, University of Rennes, Rennes France
2002 Frontiers in Chemistry Lectureship, University of Iowa
2002 Humphrey Lecturer, University of Vermont
2002 Organizer, Symp. on Recent Adv. in Organometallic Chem., Fall Nat. ACS Mtg.
2002- Editorial Advisory Board, Journal of Organometallic Chemistry
2000 Frontiers Lecturer, Case Western University
1999 Organizer, Symp. on Advances in Polymer Synthesis, Fall Nat. ACS Mtg.
1998 Akron Polymer Group Lecturer
1998 British Petroleum Lecturer, UK
1997-1998 Chair-Elect and Chair, Organometallic Subdivision, Inorganic Division, ACS
1997- Editorial Advisory Board, Journal of Molecular Catalysis
1996-1998 University of Iowa Faculty Scholar Award
1995-1999 Board of Directors, The University of Iowa Research Foundation
1993-1995 Editorial Advisory Board, Organometallics
1993 Frontiers Lecturer, Case Western University
1992 Organizer, Symposium on Chemistry of Electrophilic Metal Centers, Nat. ACS Mtg.
1992 Program Planning Committee, Gordon Conference on Organometallic Chemistry
1992 Professeur Invité, University of Rennes, Rennes, France
1989-1991 Alfred P. Sloan Research Fellow
1989, 1990 Union Carbide Research Innovation Awards
1975 Athenaeum Honor Society, Rutgers University
1975 American Institute of Chemists Student Award, Rutgers Un
研究领域
Research in the Jordan group is focused on synthetic and mechanistic organometallic chemistry. The central theme of this work is the interplay between the structures and reactivity of organometallic compounds, especially in systems that are relevant to catalysis. We design reactive organometallic complexes for use as practical catalysts and synthetic reagents, and as probes of fundamental mechanistic issues in catalysis. We use a wide range of synthetic and spectroscopic methods for the manipulation and characterization of reactive materials, most notably anaerobic synthesis techniques, NMR spectroscopy, molecular modeling and X-ray crystallography. Our current efforts are focused on four major topics: (i) catalytic olefin polymerization, with an emphasis on the development of electronically unsymmetrical catalysts for the copolymerization of ethylene with polar CH2=CHX monomers, (ii) the self-assembly of multinuclear organometallics for olefin polymerization and small molecule activation, (iii) the conversion of CO2 to value-added products, and (iv) the influence of second-sphere functional groups on the behavior of organometallic catalysts.
近期论文
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(197)f "Synthesis of Borophosphonate Cage Compounds: Influence of Substituent and Concentration Effects on Product Distribution in Condensation Reactions of Aryl Phosphonic Acids and Boronic Acids" Liu Q.; Contrella N. D.; Filatov A. S.; Jordan, R. F. Organometallics, 2015, 34, 254-262.
"cis/trans Isomerization of o-Phosphino-Arenesulfonate Palladium Methyl Complexes" Zhou X.; Lau K.-C.; Petro B. J.; Jordan, R. F. Organometallics, 2014, 33, 7209–7214.
"Lewis Acid Modification and Ethylene Oligomerization Behavior of Palladium Catalysts That Contain a Phosphine-Sulfonate-Diethyl Phosphonate Ancillary Ligand" Contrella N. D.; Jordan, R. F. Organometallics, 2014, 33, 7199-7208.
"Hydrogen Bonding Behavior of Amide-Functionalized α-Diimine Palladium Complexes" Zhai F.; Jordan, R. F. Organometallics, 2014, 33, 7176-7192.
"Halogenolysis of a Nickelalactone Complex Produces β-Halo-Anhydrides" Zarkesh, R. A.; Hopkins, M. D.; Jordan, R. F. Eur. J. Inorg. Chem., 2014, 2014, 5491-5494.
"Differentiation between Chelate Ring Inversion and Aryl Rotation in a CF3-Substituted Phosphine-Sulfonate Palladium Methyl Complex" Feng, G.; Conley, M. P.; Jordan, R. F. Organometallics, 2014, 33, 4486-4496.
"Copolymerization of Ethylene and Methyl Acrylate by Cationic Palladium Catalysts That Contain Phosphine-Diethyl Phosphonate Ancillary Ligands" Contrella, N. D.; Sampson, J. R.; Jordan, R. F. Organometallics, 2014, 33, 3546-3555.
"Comparative Reactivity of Zr– and Pd–Alkyl Complexes with Carbon Dioxide" Lau, K.-C.; Petro, B. J.; Bontemps, S.; Jordan, R. F. Organometallics, 2013, 32, 6895-6898.
"Ortho-Phosphinobenzenesulfonate: A Superb Ligand for Palladium-Catalyzed Coordination–Insertion Copolymerization of Polar Vinyl Monomers" Nakamura, A.; Anselment, T. M. J.; Claverie, J.; Goodall, B.; Jordan, R. F.; Mecking, S.; Rieger, B.; Sen, A.; van Leeuwen, P. W. N. M.; Nozaki, K. Acc. Chem. Res., 2013, 7, 1438-1449.
"Enhancement of Chain Growth and Chain Transfer Rates in Ethylene Polymerization by (Phosphine-sulfonate)PdMe Catalysts by Binding of B(C6F5)3 to the Sulfonate Group" Cai, Z.; Shen, Z.; Zhou, X.; Jordan, R. F. ACS Catal., 2012, 2, 1187-1195.
"Synthesis, cis/trans Isomerization, and Reactivity of Palladium Alkyl Complexes That Contain a Chelating N-Heterocyclic-Carbene Sulfonate Ligand" Zhou, X.; Jordan, R. F. Organometallics, 2011, 30, 4632-4642.
"Synthesis, Structures, and Ethylene Dimerization Reactivity of Palladium Alkyl Complexes That Contain a Chelating Phosphine-Trifluoroborate Ligand" Kim, Y.; Jordan, R. F. Organometallics, 2011, 30, 4250-4256.
"cis/trans Isomerization of Phosphinesulfonate Palladium(II) Complexes." Conley, M. P.; Jordan, R. F. Angewandte Chemie International Edition, 2011, 50, 3744-3746.
"Copolymerization of Ethylene and Vinyl Fluoride by (Phosphine-bis(arenesulfonate))PdMe(pyridine) Catalysts: Insights into Inhibition Mechanisms." Shen, Z.; Jordan, R. F. Macromolecules, 2010, 43, 8706-8708.
"Synthesis and Ethylene Polymerization Behavior of {MeB(3-Ph-pyrazolyl)3}TiCl3." Chen, C.; Jordan, R. F. J. Organomet. Chem., 2010, 695, 2543-2547.
"Lewis Acid Catalyzed Synthesis of Poly(pyrazolyl)borate Ligands." Chen, C.; Jordan, R. F. Organometallics, 2010, 29, 3679-3682.
"Palladium Catalyzed Dimerization of Vinyl Ethers to Acetals." Chen, C.; Jordan, R. F. J. Am. Chem. Soc., 2010, 132, 10254-10255.
"Synthesis, Structures, and Ethylene Polymerization Behavior of Bis(pyrazolyl)borate Zirconium and Hafnium Benzyl Complexes." Chen, C.; Lee, H.; Jordan, R. F. Organometallics, 2010, 29, 5273-5381.
"Cationic Polymerization and Insertion Chemistry in the Reactions of Vinyl Ethers with (a-diimine)PdMe+ Species." Chen, C.; Luo, S.; Jordan, R. F. J. Am. Chem. Soc., 2010, 132, 5273-5284.
"Mechanism of the Reaction of Vinyl Chloride with (a-diimine)PdMe+ Species." Kilyanek, S. M.; Stoebenau, E. J. III, Vinayavekhin, N.; Jordan, R. F. Organometallics, 2010, 29, 1750-1760.
" Self-Assembled Tetranuclear Palladium Catalysts That Produce High Molecular Weight Linear Polyethylene." Shen, Z.; Jordan, R. F. J. Am. Chem. Soc., 2010, 132, 52-53.
"Comparison of Olefin Polymerization Behavior of Sterically Crowded Tris(Pyrazolyl)Borate Group 4 Metal Complexes." Michiue, K.; Jordan, R. F. J. Molecular Catalysts A:Chemical, 2008, 282, 107-116.
"Synthesis and Molecular Structures of Zirconium Complexes that Contain Bidentate Amido Ligands." Lococo, M. D.; Lee, H.; Jordan, R. F. J. Mol. Struc., 2009, 920, 363-368.
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