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个人简介

Haiping Xia obtained his B.S. in chemistry in 1983, M.S. in 1986, and Ph.D. in 2002 from Xiamen University. He started to work at Xiamen University in 1986 and was promoted to Associate Professor in 1991, and Professor in 1999. His research focuses on the synthesis, reactivity, and applications of metalla-aromatics. HONORS AND AWARDS The Huang Yao-Zeng organometallic chemistry award of the Chinese chemical society in 2016 (Organometallics 2017, 36, 245) Carbolong Complexes was elected as one of the “ten major scientific and technological progress of China's colleges and Universities” in 2013 “MinJiang Distinguished Professor” in 2010 Received the National Natural Science Funds for Distinguished Young Scholar of China in 2009 “New Century Excellent Talents in University” Program by the Ministry of Education in 2004 The 7th Fujian “Youth Science and Technology Award” in 2004 The “Young Chemist Award of Chinese Chemical Society at the 60th anniversary of the founding of Chinese Chemical Society” in 1992

研究领域

主要从事金属有机化学研究。创新性成果有:1)开拓了一系列构筑金属杂环的新方法--[5+1]、[4+2]和[3+3]关环法;2)将一些经典的有机反应(如SNAr等)拓展到金属有机体系。3)通过引入过渡金属到反芳香性的有机骨架,首次实现了物质从反芳香性到芳香性的一步转变,将芳香性的概念首次拓展到金属杂双五元环体系,同时也首次拓展到一个含三键的五元环体系。开辟了一个全新的芳香体系——金属杂戊搭炔和金属杂戊搭烯化学。

近期论文

Zhuo, Q.; Zhang, H.; Hua, Y.; Kang, H.; Zhou, X.; Lin, X.; Chen, Z.; Lin, J.; Zhuo, K.; Xia, H., Constraint of a ruthenium-carbon triple bond to a five-membered ring. Sci. Adv. 2018, 4 (6), eaat0336. Zhu, C.; Xia, H.,* Carbolong Chemistry: A Story of Carbon Chain Ligands and Transition Metals. Acc. Chem. Res. 2018, DOI: 10.1021/acs.accounts.8b00175. Zhou, X.; Li, Y.; Shao, Y.; Hua, Y.; Zhang, H.; Lin, Y. *; Xia, H. *, Reactions of Cyclic Osmacarbyne with Coinage Metal Complexes. Organometallics 2018, 37 (11), 1788-1794. Lin, Q.; Li, S.; Lin, J.; Chen, M.; Lu, Z.; Tang, C.; Chen, Z.; He, X.; Chen, J.;* Xia, H.;* Synthesis and Characterization of Photothermal Osmium Carbolong Complexes. Chem. Eur. J., 2018, DOI: 10.1002/chem.201800656. Zhou, X.; Huang, F.; Tang, C.; Zhuo, Q.; Chen, Z.; Zhang, H.;* Xia, H; A missing member of conjugated N-heterocycles: realizing pyrido[1,2-α]azepine by reacting ruthenium alkenylcarbene complex with alkyne. Chem. Commun., 2018, 54, 4009 - 4012. Wang, T.; Chen, Z.; Yu, S.; Sheng, T.; Ma, H.; Chen, L.; Muhammad Rauf, Xia, H.; Zhou, Z.;* and Sun, S.; Constructing canopy-shaped molecular architectures to create local Pt surface sites with high tolerance to H2S and CO for hydrogen electrooxidation. Energy Environ. Sci., 2018, 11, 166-171. Lu, Z.; Cai, Y.; Wei, Y; Lin, Q.; Chen, J.;* He, X.; Li, S.; Wu, W.; Xia, H.;* Photothermal Möbius aromatic metallapentalenofuran and its NIR-responsive copolymer. Polym. Chem. 2018, 9, 2092-2100. Chen, J.;* Lin, Q.; Li, S.; Lu, Z; Lin, J.; Chen, Z.; Xia, H.;* Synthesis and Characterization of an Osmapentalene Derivative Containing a β-Agostic Os···H–C(sp3) Interaction. Organometallics 2018 37, 4, 618-623. Zhu, C.; Zhu, J.; Zhou, X.; Zhu, Q.; Yang, Y.; Wen, T.; Xia, H.;* Isolation of an Eleven‐Atom Polydentate Carbon‐Chain Chelate Obtained by Cycloaddition of a Cyclic Osmium Carbyne with an Alkyne. Angew. Chem. Int. Ed. 2018, 57, 3154-3157. Zhou, X.; Zhang, H.; Reactions of Metal-Carbon Bonds within Six-Membered Metallaaromatic Rings. Chem. Eur. J. 10.1002/chem.201705679. Hua, Y.; Zhang, H.;* Xia, H.;* Aromaticity: History and Development. Chin. J. Org. Chem. 2018, 38(1), 11-28. Wang, H.; Zhou, X.; Xia, H. Metallaaromatics Containing Main‐group Heteroatoms. Chin. J. Chem. 2018, 36, 93-105. Zhou, X.; Wu, J.; Hao, Y.; Zhu, C.; Zhuo, Q.; Xia, H.;* Zhu, J.;* Rational Design and Synthesis of Unsaturated Se-Containing Osmacycles with σ-Aromaticity, Chem. Eur. J. 2018, 24, 2389-2395. Yang, C.; Lin, G.; Zhu, C.; Pang, X.; Zhang, Y.; Wang, X.; Li, X.; Wang, B.;* Xia, H.;* Liu, G.;* Metalla-aromatic loaded magnetic nanoparticles for MRI/photoacoustic imaging-guided cancer phototherapy, J. Mater. Chem. B, 2018, 6, 2528. Huang, J.; Zhou, X.; Zhao, Q.; Li, S.; Xia, H.;* Synthesis, Characterization and Electrochemical Properties of 4,5-Diazafluoren-9-yl or Fluoren-9-yl Terminated Homobimetallic Ruthenium and Osmium Allenylidene, Alkynyl-Allenylidene Complexes. Chin. J. Chem. 2017, 35, 420-428. Zhuo, Q.; Lin, J.; Hua, Y.; Zhou, X.; Shao, Y.; Chen, S.; Chen, Z.; Zhu, J.; Zhang,H.; Xia, H.;* Multiyne chains chelating osmium via three metalcarbon σ bonds, Nat. Commun. 2017, 8, 1912. Huang, Z.; Lan, Q.; Hua, Y.; Chen, Z.; Zhang, H.;* Lin, Z.;* Xia, H.;* Color-Tuning Strategy for Iridapolycycles [(N-N)Ir(C-C)ClPPh3]+ by the Synergistic Modifications on Both the C-C and N-N Units, Organometallics 2017, 36 (24), 4802–4809. Long, L.; Zhou, X.; Wang, T.; Chen, Z.; Zhang, H.;* Xia, H.;* Synthesis of Imidazopyridinium-Fused Metallacycloallene via One-Pot Reaction of η2-Alkynol-Coordinated Osmacycle with 2-Aminopyridine, Organometallics 2017, 36, 4184−4190. Li, R.; Lu, Z.; Cai, Y.; Jiang, F.; Tang, C.; Chen, Z.; Zheng, J.; Pi, J.; Zhang, R.; Liu, J.; Chen, Z.; Yang, Y.; Shi, J.; Hong, W.;* Xia,H.;* Switching of Charge Transport Pathways via Delocalization Changes in Single-Molecule Metallacycles Junctions, J. Am. Chem. Soc. 2017, 139, 14344-14347. He, X.;* He, X.; Li, S.; Zhuo, K.; Qin, W.; Dong, S.; Chen, J.; Ren, L.; Liu, G.; Xia, H.;* Amphipathic metal-containing macromolecules with photothermal properties, Polym. Chem., 2017, 8, 3674-3678. Zhu, C.; Wu, J.; Li, S.; Yang, Y.; Zhu, J.; Lu, X.; Xia, H.;* Synthesis and Characterization of a Metallacyclic Framework with Three Fused Five-membered Rings, Angew. Chem., Int. Ed. 2017, 56, 9067.

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