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Huiwen Yang, Yanhua Hu, Yashi Zou, Zhenfeng Zhang,* and Wanbin Zhang*. Cobalt-Catalyzed Efficient Asymmetric Hydrogenation of α-Primary Amino Ketones, JACS Au 2023, accepted. DOI: 10.1021/jacsau.3c00524.
Yicong Luo, Yuqi Ma, Guanlin Li, Xiaohong Huo,* and Wanbin Zhang*. Desymmetrization of Geminal Difluoromethylenes using a Palladium/Copper/Lithium Ternary System for the Stereodivergent Synthesis of Fluorinated Amino Acids, Angew. Chem. Int. Ed. 2023, 62, e202313838. DOI: 10.1002/anie.202313838
Fei Li, Yicong Luo, Jinbao Ren, Qianjia Yuan,* Deyue Yan, and Wanbin Zhang*. Iridium-Catalyzed Remote Site-Switchable Hydroarylation of Alkenes Controlled by Ligands, Angew. Chem. Int. Ed. 2023, 62, e202309859. DOI: 10.1002/anie.202309859.
Yunnan Xu, Yicong Luo, Jianxun Ye, Delong Liu, and Wanbin Zhang*. Rh-Catalyzed Enantioselective Desymmetric Hydrogenation of α-Acetamido-1,3-indanediones Using Ether-Bridged Biphenyl Diphosphine Ligands. J. Am. Chem. Soc. 2023, accepted. DOI: 10.1021/jacs.3c07509.
Jing Guan, Jianzhong Chen, Yicong Luo, Lisen Guo, and Wanbin Zhang*, Copper-Catalyzed Chemoselective Asymmetric Hydrogenation of C=O Bonds of Exocyclic α,β-Unsaturated Pentanones. Angew. Chem. Int. Ed. 2023, accepted. DOI: 10.1002/anie.202306380.
Cheng Sheng, Zheng Ling, Junzhe Xiao, Kai Yang, Fang Xie, Shengming Ma*, and Wanbin Zhang*, Enantio- and Diastereoselective Synthesis of Chiral Tetrasubstituted α-Amino Allenoates Bearing a Vicinal All-Carbon Quaternary Stereocenter with Dual-Copper-Catalysis. Angew. Chem. Int. Ed. 2023, accepted. DOI: 10.1002/anie.202305680.
Zhengxing Wu, Jingjie Meng, Huikang Liu, Yunyi Li, Xiao Zhang, and Wanbin Zhang*, “Multisite programmable functionalization of alkenes via controllable alkene isomerization". Nat. Chem. 2023, DOI: 10.1038/s41557-023-01209-x.
"Cu-Catalyzed Asymmetric Kinetic Boron Conjugate Addition of γ-Substituted α,β-Unsaturated γ-Lactams." Liang Tang, Yicong Luo, Cheng Sheng, Fang Xie*, and Wanbin Zhang*, Angew. Chem. Int. Ed. 2023, e202304640. DOI: 10.1002/anie.202304640.
"Synergistic Li/Li Bimetallic System for the Asymmetric Synthesis of Anti-tuberculosis Drug TBAJ-587." Tanveer Ahmad,+ Feng Gao,+ Jing Li,+ Zhenfeng Zhang,+ Tao Song, Qianjia Yuan and Wanbin Zhang*, J. Org. Chem., 2023, accepted (+ co-first authors).
“Cobalt-Catalyzed Efficient Convergent Asymmetric Hydrogenation of E/Z-Enamides”, Tiantian Chen, Yashi Zou, Yanhua Hu, Zhenfeng Zhang, Hao Wei, Liangming Wei, and Wanbin Zhang*, Angew. Chem. Int. Ed. 2023, e202303488. DOI: 10.1002/anie.202303488.
Jiayu Zhou, Jianxun Ye, Yang Zhang, Zhaodi Li, Jingjing Li, Delong Liu,* and Wanbin Zhang, Synthesis of Chiral Diaryl Methanols via RuPHOX-Ru Catalyzed Asymmetric Hydrogenation, Adv. Synth. Catal. 2023, 365, 1275-1286. DOI: 10.1002/adsc.202300213.
Tao Song, Yicong Luo, Kuiyang Wang, Bingyi Wang, Qianjia Yuan,* Wanbin Zhang*, Nickel-Catalyzed Remote C(sp3)-N/O Bond Formation of Alkenes with Unactivated Amines and Alcohols. ACS Catal. 2023,13, 4409–4420. accepted. DOI: 10.1021/acscatal.3c00238
Siqi Dong, Shaofeng Xu, Yashi Zou, Zhaodi Li, Kai Xu, Daxu Fu,* Delong Liu,* and Wanbin Zhang, The Construction of Chiral 3-Acyl Bicyclolactams via a RuPHOX/Pd Catalyzed Asymmetric Allylic Substitution Cascade of α-Carbonylamides, Org. Chem. Front., 2023, accepted. DOI: 10.1039/D3QO00055A
“Synergistic Catalysis for Stereocontrol of Prochiral Nucleophiles in Palladium-Catalyzed Asymmetric Allylic Substitution”, Xi Wang, Youbin Peng, Ling Zhao, Xiaohong Huo,* and Wanbin Zhang*, Sci. China Chem., 2023, 66, accepted. DOI: 10.1007/s11426-022-1547-0.
“Precise Synthesis of Chiral Z-Allylamides by Cobalt-Catalyzed Asymmetric Sequential Hydrogenations”, Yanhua Hu,+ Yashi Zou,+ Huiwen Yang, Haotian Ji, Yue Jin, Zhenfeng Zhang,* Yangang Liu, and Wanbin Zhang*, Angew. Chem. Int. Ed. 2023, e202217871. DOI: 10.1002/anie.202217871. (+ co-first authors)
Invited paper: "Asymmetric Hydrogenation of Tetrasubstituted α,β-Unsaturated Ketones: Access to Chiral 2-Substituted Cyclopentyl Aryl Ketones", Zhengdong Ding, Feng Gao, Yining Lu, Qianjia Yuan,* Wei-Ping Deng*, and Wanbin Zhang*, Precis. Chem. 2023, 1, accepted. DOI: 10.1021/prechem.2c00010.
“Asymmetric Synthesis of Anti-tuberculosis-specific Drug TBAJ-876 through Synergistic Li/Li Catalysis” Jing Li,+ Feng Gao,+ Tanveer Ahmad,+ Yicong Luo,+ Zhenfeng Zhang,+ Qianjia Yuan and Wanbin Zhang* Chin. J. Chem. 2023, accepted. (+ co-first authors)
“Iridium-Catalyzed 1,3-Rearrangement of Allylic Alcohols” Fei Li, Yicong Luo, Xuejie Zhu, Yong Ye, Qianjia Yuan,* and Wanbin Zhang*, Chem. Eur. J. 2023, e202300027. DOI: 10.1002/chem.202300027.
Hot paper: "Stereodivergent Synthesis of Allenes with α,β-Adjacent Central Chiralities Empowered by Synergistic Pd/Cu Catalysis" Ling Zhao, Yicong Luo, Junzhe Xiao, Xiaohong Huo, Shengming Ma,* and Wanbin Zhang*, Angew. Chem. Int. Ed. 2023, 62, e202218146. DOI: 10.1002/anie.202218146.
"Nickel-Catalyzed Asymmetric Hydrogenation of α-Substituted Vinylphosphonates and Diarylvinylphosphine Oxides" Hanlin Wei, Hao Chen, Jianzhong Chen*, Ilya. D. Gridnev* and Wanbin Zhang*, Angew. Chem. Int. Ed. 2022, accepted. DOI: 10.1002/anie.202214990.
Invited Perspective: "Dual Catalysis in Organic Synthesis: Current Challenges and New Trends" Chandi C. Malakar,* Luca Dell’Amico,* and Wanbin Zhang*, Eur. J. Org. Chem. 2022, 2022, e202201114. DOI: 10.1002/ejoc.202201114.
"Lewis base catalyzed asymmetric C-acylation" Mo Wang, Zhenfeng Zhang, Wanbin Zhang*, Sci. Sin. Chim., 2022, accepted article. DOI: 10.1360/SSC-2022-0209
"Iridium-Catalyzed Double Asymmetric Hydrogenation of 2,5-Dialkylienecyclopentanones for the Synthesis of Chiral Cyclopentanones", Yu Nie, Qianjia Yuan, Feng Gao, Masahiro Terada, and Wanbin Zhang*, Org. Lett. 2022, 24, accepted article. DOI: org/10.1021/acs.orglett.2c02656.
"Rh-Catalyzed Sequential Asymmetric Hydrogenations of 3-Amino-4-Chromones via an Unusual Dynamic Kinetic Resolution Process", Yunnan Xu,§ Yicong Luo,§ Jianxun Ye, Yu Deng, Delong Liu and Wanbin Zhang*, J. Am. Chem. Soc., 2022, 144, accepted article. DOI：10.1021/jacs.2c09266 (§co-first author)
“Asymmetric synthesis of bedaquiline based on bimetallic activation and non-covalent interaction promotion strategies”,Feng Gao+, Jing Li+, Tanveer Ahmad+, Yicong Luo+, Zhenfeng Zhang+, Qianjia Yuan , Xiaohong Huo , Tao Song , Wanbin Zhang*, Sci. China Chem., 2022, 65, 1968-1977. DOI：10.1007/s11426-022-1387-7. (+ co-first author)
“Progress in Transition Metal-Catalyzed Asymmetric Ring-Opening Reactions of Epoxides and Aziridines”, Qingfeng Du+, Lu Zhang+, Feng Gao*, Le Wang*, Wanbin Zhang, Chin. J. Org. Chem., 2022, 42, 3240. DOI：10.6023/cjoc202207034. (+ co-first author)
“Pd-Catalyzed Aerobic Intermolecular 1,2-Diamination of Conjugated Dienes: Regio- and Chemoselective Synthesis of Piperazines and 2-Piperazinones”, Huikang Liu, Yunyi Li, Zehua Yang, Qianyi Ge, Zhengxing Wu,* and Wanbin Zhang*, Chem. Eur. J. 2022, 28, accepted. DOI: 10.1002.chem.202201808.
Hot paper: “Stereodivergent Desymmetrization of Simple Dicarboxylates via Branch-Selective Pd/Cu Catalyzed Allylic Substitution”, Guanlin Li, Ling Zhao, Yicong Luo, Youbin Peng, Kai Xu, Xiaohong Huo,* and Wanbin Zhang*, Chem. Eur. J. 2022, 28, e202200273. DOI: 10.1002/chem.202200273.
“Design, Synthesis and Application of Chiral Bicyclic Imidazole Catalysts”, Mo Wang,§ Zhenfeng Zhang,§ and Wanbin Zhang*, Acc. Chem. Res. 2022, 55, DOI: 10.1021/acs.accounts.2c00455. (§co-first author)
“Bimetallic Catalysis in Stereodivergent Synthesis”, XiaohongHuo, Guanlin Li, Xi Wang, and Wanbin Zhang*, Angew. Chem. Int. Ed. 2022, 61, accepted. DOI: 10.1002/anie.202210086.
“Palladium-catalyzed long-range isomerization of aryl olefins”, Qianyi Ge, Jingjie Meng, Huikang Liu, Zehua Yang,* Zhengxing Wu,* and Wanbin Zhang*, Chin. J. Chem. 2022, 40, accept. DOI: 10.1002/cjoc.202200254.
“Nickel-catalysed asymmetric hydrogenation of oximes”, Bowen Li, Jianzhong Chen, Dan Liu, Ilya D. Gridnev, and Wanbin Zhang*, Nat. Chem. 2022, 14, 920-927. (DOI: 10.1038/s41557-022-00971-8)
“Azole-Directed Cobalt-Catalyzed Asymmetric Hydrogenation of Alkenes”, Yue Jin, Yashi Zou, Yanhua Hu, Yunxi Han, Zhenfeng Zhang*, and Wanbin Zhang*, Chem. Eur. J. 2022, e202201517. DOI: 10.1002/chem.202201517
“Synthesis of Chiral 5-Aryl-2-oxazolidin- ones via an Ir-BiphPHOX Catalyzed Enantioselective Hydrogenation”, Tongli Zhang, Jun Yan, Jingli He, Xuezhen Kou, Jiefeng Shen, Delong Liu*, Wanbin Zhang, Chin. J. Org. Chem. 2022, 42, 1747-1758. DOI: 10.6023/cjoc202112040
“RuPHOX-Ru Catalyzed Asymmetric Hydrogenation of α-Substituted Tetralones via a Dynamic Kinetic Resolution”, Jingjing Li, Jianxun Ye, Jiayu Zhou, Jing Li, Delong Liu*, Wanbin Zhang, Chem. Commun. 2022, 58, 4905–4908. DOI: 10.1039/D2CC01193J
“Pd-Catalyzed Asymmetric Allylic Substitution Cascade of Substituted 4-Hydroxy-2H-pyrones with meso-Allyl Dicarbonates”, Yan Zheng, Siqi Dong, Kai Xu, Delong Liu*, Wanbin Zhang, Org. Lett. 2022, 24, 3440-3444. DOI: 10.1021/acs.orglett.2c00937
Hot paper: “Nickel/Copper-Cocatalyzed Asymmetric Benzylation of Aldimine Esters for the Enantioselective Synthesis of α-Quaternary Amino Acids”, Youbin Peng, Chongyu Han, Yicong Luo, Guanlin Li, XiaohongHuo, and Wanbin Zhang*, Angew. Chem. Int. Ed., 2022, 61, e202203448. DOI: 10.1002/anie.202203448
“Chiral Bicyclic Imidazole-Catalyzed Direct Enantioselective C-Acetylation of Indolones”, Muxing Zhou, Yashi Zou, Lu Zhang, Zhenfeng Zhang, and Wanbin Zhang*, CCS Chem., 2022, DOI: 10.31635/ccschem.022.202201782.
“Copper-Catalyzed Regioselective [3+3] Annulations of Alkynyl Ketimines with α-Cyano Ketones: the Synthesis of Polysubstituted 4H-Pyran Derivatives with a CF3-Containing Quaternary Center”,Cheng Sheng, Zheng Ling, Tanveer Ahmad, Fang Xie, and Wanbin Zhang*, Chem. Eur. J. 2022, 28, e202200128. DOI: 10.1002/chem.202200128
“Synthesis of Chiral Hydantoins and Thiazolidinediones via Iridium-Catalyzed Asymmetric Hydrogenation”,Yu Nie, Jing Li, Qianjia Yuan*, and Wanbin Zhang*, Chin. J. Chem. 2022, 40, 819-824. DOI: 10.1002/cjoc.202100809.
“Cu-catalyzed asymmetric addition of alcohols to β,γ-alkynyl-α-imino esters for the construction of linear chiral N,O-ketals”, Cheng Sheng, Zheng Ling, Yicong Luo, and Wanbin Zhang*, Nat. Commun. 2022, 13, 400. DOI: 10.1038/s41467-022-28002-7.
“Asymmetric Hydrogenation for the Synthesis of 2-Substituted Chiral Morpholines”, Mingxu Li, Jian Zhang, Yashi Zou, Fengfan Zhou, Zhenfeng Zhang*, and Wanbin Zhang, Chem. Sci. 2021, 12, 15061-15066. DOI: 10.1039/D1SC04288B.
“Pd(II)-Catalyzed Enantioselective Ring-Contraction for the Construction of 1,4-Benzoxazines”, Chenghao Ye, Feng Gao, Haipeng Wei, Jianzhong Chen, Guoqiang Yang, Qianjia Yuan*, and Wanbin Zhang*, J. Org. Chem. 2021, 86, 16573-16581. DOI: 10.1021/acs.joc.1c01874.
“Chemical Synthesis of the anti-COVID-19 Drug Remdesivir”, Mo Wang, Lu Zhang, Xiaohong Huo, Zhenfeng Zhang, and Wanbin Zhang*, Current Protocols 2021, 1, e303. DOI: 10.1002/cpz1.303.
“Kinetic Resolution of Azaflavanones via A RuPHOX-Ru Catalyzed Asymmetric Hydrogenation”, Yue Zhu, Jiayu Zhou, Jing Li, Kai Xu, Jianxun Ye, Yufei Lu, Delong Liu*, and Wanbin Zhang, Org. Chem. Front. 2021, 8, 6609-6615. DOI: 10.1039/D1QO01310F.
“Development of Earth-Abundant Transition Metals-Catalyzed Enantioselective Alkenylations using Alkenyl Metal Nucleophiles”, Liang Wu, Hanlin Wei, Jiefeng Shen*, Jianzhong Chen*, and Wanbin Zhang, Acta Chim. Sinica 2021, 79, 1331-1344. DOI: 10.6023/A21070338.
Hot paper: “Enantio- and Diastereodivergent Synthesis of Spirocycles through Dual-Metal-Catalyzed [3+2] Annulation of 2-Vinyloxiranes with Nucleophilic Dipoles”, Youbin Peng, Xiaohong Huo, Yicong Luo, Liang Wu, and Wanbin Zhang*, Angew. Chem. Int. Ed. 2021, 60, 24941-24949. DOI: 10.1002/anie.202111842.
Invited Highlight: “Stereodivergent Pd/Cu Catalysis for the Construction of Allenyl Axial Chirality and Central Chirality”, Xiaohong Huo and Wanbin Zhang*, Chin. J. Org. Chem. 2021, 41, 3337-3338. DOI: 10.6023/cjoc202100058.
“Rh-Catalyzed Asymmetric Hydrogenation of 3-Benzoylaminocoumarins for the Synthesis of Chiral 3-Amino Dihydrocoumarins”, Yunnan Xu, Delong Liu, Yu Deng, Yi Zhou, and Wanbin Zhang*, Angew. Chem. Int. Ed. 2021, 60, 23602-23607. DOI: 10.1002/anie.202110286.
“Enantio- and Diastereodivergent Construction of 1,3-Nonadjacent Stereocenters Bearing Axial and Central Chirality through Synergistic Pd/Cu Catalysis”, Jiacheng Zhang, Xiaohong Huo, Junzhe Xiao, Ling Zhao, Shengming Ma*, and Wanbin Zhang*, J. Am. Chem. Soc. 2021, 143, 12622-12632. DOI: 10.1021/jacs.1c05087.
Invited Paper: “Development of Nickel-Catalyzed Cross-Coupling of Alcohol Derivatives to Construct Carbon-Carbon Bonds”, Liang Wu, Hanlin Wei, Jianzhong Chen*, and Wanbin Zhang*, Chin. J. Org. Chem. 2021, 41, 4208-4239. DOI: 10.6023/cjoc202106021.
“Synthesis of Chiral 2-Substituted 1,4-Benzoxazin-3-ones via Iridium-Catalyzed Enantioselective Hydrogenation of Benzoxazinones”, Yu Nie, Jing Li, Jun Yan, Qianjia Yuan*, and Wanbin Zhang*, Org. Lett., 2021, 23, 5373-5377. DOI: 10.1021/acs.orglett.1c01701.
Cover Picture Paper: “Asymmetric Hydrogenation of γ-Branched Allylamines for the Efficient Synthesis of γ-Chirogenic Amines”, Jian Zhang, Tiantian Chen, Yuanhao Wang, Fengfan Zhou, Zhenfeng Zhang*, Ilya D. Gridnev*, and Wanbin Zhang*, Nat. Sci., 2021, e10021. DOI: 10.1002/ntls.10021.
“Nickel-Catalyzed Asymmetric Hydrogenation of Hydrazones”, Bowen Li, Dan Liu, Yanhua Hu, Jianzhong Chen, Zhenfeng Zhang*, and Wanbin Zhang*, Eur. J. Org. Chem., 2021, 3421-3425. DOI: 10.1002/ejoc.202100642.
“Cobalt-Catalyzed Chemo- and Enantioselective Hydrogenation of Conjugated Enynes”, Yanhua Hu, Zhenfeng Zhang, Yangang Liu, and Wanbin Zhang*, Angew. Chem. Int. Ed., 2021, 60, 16989-16993. DOI: 10.1002/anie.202106566.
“Stereodivergent Pd/Cu Catalysis for Asymmetric Desymmetric Alkylation of Allylic Geminal Dicarboxylates.”, Xiaohong Huo, Ling Zhao, Yicong Luo, Yue Wu, Yuwen Sun, Guanlin Li, Tatiana Gridneva, Jiacheng Zhang, Yong Ye and Wanbin Zhang*, CCS Chem., 2021, 3, 1933-1944. DOI: 10.31635/ccschem.021.202101044.
“Mechanistic Study of Ni and Cu Dual Catalyst for Asymmetric C—C Bond Formation; Asymmetric Coupling of 1,3-Dienes with C-nucleophiles to Construct Vicinal Stereocenters.”, Jingzhao Xia, Takahiro Hirai, Shoichiro Katayama, Haruki Nagae, Wanbin Zhang*, Kazushi Mashima*, ACS Catal., 2021, 11, 6643-6655. DOI: 10.1021/acscatal.1c01626.
“One Stone Two Birds – Enantioselective Bimetalic Catalysis for α‐Amino Acid Derivatives with An Allene Unit.”, Junzhe Xiao, Haibo Xu, Xiaohong Huo, Wanbin Zhang*, Shengming Ma*, Chin. J. Chem., 2021, 39, 1958-1964. DOI: 10.1002/cjoc.202100002.
Very Important Paper (VIP): “Synergistic Ir/Cu Catalysis for Asymmetric Allylic Alkylation of Oxindoles: Enantio- and Diastereoselective Construction of Quaternary and Tertiary Stereocenters”, Tianhong Wang, Youbin Peng, Guanlin Li, Yicong Luo, Yong Ye, Xiaohong Huo*, and Wanbin Zhang*, Chem. Eur. J., 2021, 27, 10255-10260. DOI: 10.1002/chem.202101267.
Invited Paper: “Stereodivergent Pd/Cu catalysis: asymmetric alkylation of racemic symmetrical 1,3-diphenyl allyl acetates”, Ling Zhao, Guanlin Li, Rui He, Penglin Liu, Feijun Wang, Xiaohong Huo*, Min Zhao*, and Wanbin Zhang*, Org. Biomol. Chem., 2021, 19, 1955-1959. DOI:10.1039/D0OB02499F.
“Synthesis and biological evaluation of naphthoquinone phenacylimidazolium derivatives”, Jing Yuan, Zhanxiong Liu, Zhenfeng Zhang*, Deyue Yan, and Wanbin Zhang, Bioorg. Med. Chem. Lett., 2021, 41, 127977. DOI: 10.1016/j.bmcl.2021.127977.
Invited Paper: “Ir-Catalyzed asymmetric hydrogenation of 3-arylindenones for the synthesis of chiral 3-arylindanones”, Jun Yan, Yu Nie, Feng Gao, Qianjia Yuan, Fang Xie*, and Wanbin Zhang*, Tetrahedron, 2021, 84, 132003. DOI:10.1016/j.tet.2021.132003.
Very Important Paper (VIP): “Asymmetric Hydroacylation Involving Alkene Isomerization for the Construction of C3-Chirogenic Center”, Chong Liu, Jing Yuan, Zhenfeng Zhang*, Ilya D. Gridnev, and Wanbin Zhang*, Angew. Chem. Int. Ed., 2021, 60, 8997-9002. DOI: 10.1002/anie.202017190.
Very Important Paper (VIP): “Chiral Bicyclic Imidazole-Catalyzed Acylative Dynamic Kinetic Resolution for the Synthesis of Chiral Phthalidyl Esters”, Muxing Zhou, Tatiana Gridneva, Zhenfeng Zhang, Ende He, Yangang Liu, and Wanbin Zhang*, Angew. Chem. Int. Ed., 2021, 60, 1641-1645. DOI: 10.1002/anie.202012445.
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