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研究领域

环境催化方向 能源与环境问题是当今世界聚焦的热点问题。本课题组专门从事于此方向的研究工作。第一,针对于火电厂及重型柴油车的烟气污染,主要针对NOx的污染,研发新型负载型稀土催化剂,克服现有催化剂有毒,高温稳定性差,低温活性低的缺陷。这不论在基础研究还是应用研究领域都具有十分重要的意义。第二,针对于目前国际热点能源问题——光水解制氢,展开研究工作。能源问题是人类目前面对的严峻问题,化石能源终将枯竭,人类开发替代能源刻不容缓。利用太阳光,在催化剂的作用下使水分解为氢气和氧气,这样,氢气可以成为人类取之不尽的燃料,若人类在此方向研究成功将具有划时代的意义。

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CZSun, J Zhu, Y Lv, L Qi, B Liu, F Gao, KQ Sun, L Dong*, Y Chen, Dispersion, reduction and catalytic performance of CuO supported on ZrO2-doped TiO2 for NO removal by CO, Appl. Catal. B: Environ., 103(1-2), 206, 2011. CZ Sun, LH Dong, WJ Yu, LC Liu, H Li, F Gao, L. Dong*, Y Chen, Promotion effect of tungsten oxide on SCR of NO with NH3 for the V2O5-WO3/Ti0.5Sn0.5O2 catalyst: experiments combined with DFT calculations, J. Mol. Catal. A: Chem., 346(1-2), 29, 2011. CZ Sun, LC Liu, L Qi, H Li, H Zhang, F Gao, L Dong*,Efficient fabrication ofZrO2-doped TiO2 hollow nanospheres with enhanced photocatalytic activity of rhodamine B degradation, J. Colloid and Interface Sci. 364(2), 288, 2011. CZ Sun, K Wang, HT Sun, N Sun, DZ Chen*, A DFT study on a muti-pathways, one product reaction: initially divergent radical reactions reconverge to form a single product, Inter. J. Quantum Chem., 114, 769, 2014. CZ Sun, MS Liu, HT Sun, Fang Huang, Nan Sun, DZ Sun, Theoretical Mechanism for Selective Catalysis of Ruthenium Complex Catalyzed Hydroboration of Terminal Alkynes to Z-Vinylboronates, Inter. J. Quantum Chem.,DOI: 10.1002/qua.24791, 2014 CZ Sun, XD He, WJ Wang, GH Chu, SX Zhang DZ Chen, Computational study on the mechanism of uncatalyzed and selenium-based catalyzed bromolactonization, Comput. Theor. Chem. 1046, 49, 2014 MS Liu, CZ Sun*, F Hang, N Sun, DZ Chen*, Theoretical mechanism for selective catalysis of double hydrophosphination of terminal arylacetylenes by an iron complex,Dalton Trans.,43, 4813, 2014. LL Cao, CZ Sun*, N Sun, L Meng, DZ Chen*, Theoretical mechanism studies on the electrocatalytic reduction of CO2 to formate by water-stable iridium dihydride pincer complex, Dalton Trans., 42, 5755, 2013. JF Zhao, CZ Sun*, N Sun, L Meng, DZ Chen*, Theoretical study on the mechanism of the reaction for alkene hydroaminations catalyzed by chiral aldehyde, Inter. J. Quantum Chem., 113, 2457, 2013. LC Liu, Q Fan, CZSun, XR Gu, H Li, F Gao, CY Feng, L Dong*, Synthesis of sandwich-like TiO2@C composite hollow spheres with high ratecapability and stability for lithium-ion batteries, J Power Sources,221, 141, 2013. LH Dong,CZ Sun, CJ Tang, B Zhang, J Zhu, B Liu, F Gao, Y Hu, L Dong*,Y Chen, Investigations of surface VOxspecies and their contributions to activities ofVOx/Ti0.5Sn0.5O2 catalysts toward selective catalytic reduction of NO by NH3, Appl. Catal. A: Gen., 431-432, 126, 2012. LC Liu, XR Gu,CZSun, H Li, Y Deng, F Gao, L Dong*, In situ loading of ultra-small Cu2O particles on TiO2 nanosheets to enhance the visible-light photoactivity, Nanoscale, 4, 6351, 2012. HL Zhang, CJ Tang, CZSun, L Qi, F Gao, L Dong*, Y Chen, Direct synthesis, characterization and catalytic performance of bimetallic Fe–Mo-SBA-15 materials in selective catalytic reduction of NO with NH3, Micro. Meso. Mater., 151, 44, 2012. CJ Tang, HL Zhang, CZ Sun, JC Li, L Qi, YJ Quan, F Gao, L Dong*, An efficient strategy for highly loaded, well dispersed and thermally stable metal oxide catalysts, Catal. Comm.12, 1075, 2011. LH Dong, L Zhang, CZ Sun, WJ Yu, J Zhu, LJ Liu, B Liu, Y Hu, F Gao, L Dong*, Y Chen, Study of the properties of CuO/VOx/Ti0.5Sn0.5O2 catalysts and their activities in NO+CO reaction, ACS Catal.1, 468, 2011.

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