陆嘉星 - 华东师范大学 - 化学与分子工程学院

研究领域

应用电化学电化学催化电化学合成本课题组主要在有机电化学、电化学催化、导电聚合物膜的制备及其催化、电极过程动力学等方面进行了一定的应用基础研究。特别是近年来，以CO2为主要原料之一，在温和条件下进行有机碳酸酯、有机化合物电化学羧化反应、有机电化学不对称合成的研究，电化学还原CO2合成有机小分子化合物的研究等形成了一定的特色。

近期论文

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Heng-Pan Yang, Sen Qin, Huan Wang* andLu, J. X.* Organically doped palladium: a highly efficient catalyst for electroreduction of CO2 to methanol. Green Chem., 2015, 17, 5144–5148 Heng-Pan Yang, Ying-Na Yue, Qi-Long Sun, Qiu Feng, Huan Wang* and Lu, J. X.* Entrapment of a chiral cobalt complex within silver: a novel heterogeneous catalyst for asymmetric carboxylation of benzyl bromides with CO2. Chem. Commun., 2015, 51, 12216—12219. Heng-Pan Yang, HuanWang, Lu, J. X.* lkaloid-induced asymmetric hydrogenation on a Cu nanoparticle cathode by electrochemical conditions. Electrochem.Commun. 55 (2015) 18–21 Laxia Wu, Hengpan Yang, Huan Wangb andLu, J. X.*Electrosynthesis of cyclic carbonates from CO2 and epoxides on a reusable copper nanoparticle cathode. RSC Adv., 2015, 5, 23189–23192 Huan Wang, Li He, Guo-Jiao Sui and Lu, J. X.* Electrocatalytic reduction of PhCH2Br on a Ag–Y zeolite modified electrode. RSC Adv., 2015, 5, 42663–42665 Yang, H. P.; Chi, D. H.; Sun, Q. L.; Sun, W. W.; Wang, H.*;Lu, J. X.*, Entrapment of alkaloid within silver: from enantioselective hydrogenation to chiral recognition. Chem. Commun.2014, 50 (64), 8868-8870. Xiao, Y.; Chen, B. L.; Yang, H. P.; Wang, H.*; Lu, J. X.*, Electrosynthesis of enantiomerically pure cyclic carbonates from CO2 and chiral epoxides. Electrochem. Commun.2014, 43 (0), 71-74. Chen, B. L.; Zhu, H. W.; Xiao, Y.; Sun, Q. L.; Wang, H.*;Lu, J. X.*, Asymmetric electrocarboxylation of 1-phenylethyl chloride catalyzed by electrogenerated chiral [CoI(salen)]? complex. Electrochem. Commun.2014, 42 (0), 55-59. Chen, B. L.; Tu, Z. Y.; Zhu, H. W.; Sun, W. W.; Wang, H.*; Lu, J. X.*, CO2 as a C1-organic building block: Enantioselective electrocarboxylation of aromatic ketones with CO2catalyzed by cinchona alkaloids under mild conditions. Electrochim. Acta. 2014,116 (0), 475-483. Wang, H.; Xu, X. M.; Lan, Y. C.; Wang, H. M.;Lu, J. X.*, Electrocarboxylation of haloacetophenones at silver electrode. Tetrahedron2014, 70 (6), 1140-1143. Yang, H. P.; Lv, T.; Sun, W. W.; Du, Y. F.; Wang, H.*; Lu, J. X.*, Enantioselective hydrogenation of methyl benzoylformate on Ag electrode electrosorbed with cinchonine. RSC Adv.2014, 4 (58), 30584-30586. Chi, D. H.; Yang, H. P.; Du, Y. F.; Lv, T.; Sui, G. J.; Wang, H.*; Lu, J. X.*, Morphology-controlled CuO nanoparticles for electroreduction of CO2 to ethanol. RSC Adv.2014, 4, 37329-37332. Yangchun Lan,Chao Gai, Paul J.A. Kenis*, Jiaxing Lu*, Electrochemical Reduction of Carbon Dioxide on Cu/CuO Core/Shell Catalysts. ChemElectroChem. 2014, 1, 1577-1582. Chen, B. L.; Xiao, Y.; Xu, X. M.; Yang, H. P.; Wang, H.*; Lu, J. X.*, Alkaloid induced enantioselective electroreduction of acetophenone. Electrochim. Acta2013, 107 (0), 320-326. Zhang, G. R.; Ding, B. B.; Wu, L.; He, L.; Ni, B.; Lu, J. X.*, Possible tuning fabrication of nanoplatinum particles with the conducting copolymer films and their behavior toward the electrooxidation of methanol. J. Appl. Polym. Sci.2013, 129 (3), 1593-1606. Zhao, S. F.; Lu, J. X.*; Bond, A. M.*; Zhang, J.*, Remarkable Sensitivity of the Electrochemical Reduction of Benzophenone to Proton Availability in Ionic Liquids. Chem. Eur. J.2012, 18 (17), 5290-5301. Zhao, S. F.; Lu, J. X.*; Bond, A. M.*; Zhang, J.*, Voltammetric studies in “wet” 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid using electrodes with adhered microparticles. Electrochem. Commun.2012, 16 (1), 14-18. Wu, L. X.; Wang, H.; Xiao, Y.; Tu, Z. Y.; Ding, B. B.; Lu, J. X.*, Synthesis of dialkyl carbonates from CO2 and alcohols via electrogenerated N-heterocyclic carbenes. Electrochem. Commun.2012, 25 (0), 116-118. Wang, H.; Wu, L. X.; Zhao, J. Q.; Li, R. N.; Zhang, A. J.; Kajiura, H.; Li, Y. M.; Lu, J. X*., Synthesis of cyclic carbonates from CO2 and diols via electrogenerated cyanomethyl anion. Greenhouse Gases: Science and Technology2012, 2 (1), 59-65. Wu, L. X.; Wang, H.; He, L.; Wu, L.; Zhang, A. J.; Kajiura, H.; Li, Y. M.; Lu, J. X.*, Direct Electrosynthesis of Organic Carbonates from CO2 with Alcohols Under Mild Condition. Int. J. Electrochem. Sci.2012, 7 (6), 5616-5625. Zhao, S. F.; Wu, L. X.; Wang, H.; Lu, J. X.*; Bond, A. M.*; Zhang, J.*, A unique proton coupled electron transfer pathway for electrochemical reduction of acetophenone in the ionic liquid [BMIM][BF4] under a carbon dioxide atmosphere. Green Chem.2011, 13 (12), 3461-3468. Wang, H.; Zhang, K.; Chen, B. L.; Li, R. N.; Zhao, J. Q.; Lu, J. X.*, Study on Electrocarboxylation of [(4-Methoxy-Benzylidene)-Amino] - Acetic Acid Ester. Int. J. Electrochem. Sci.2011, 6 (5), 1720-1729. Wang, H.; Wu, L. X.; Lan, Y. C.; Zhao, J. Q.; Lu, J. X.*, Electrosynthesis of Cyclic Carbonates From CO2 and Diols in Ionic Liquids Under Mild Conditions. Int. J. Electrochem. Sci.2011, 6 (9), 4218-4227. Zhang, K.; Xiao, Y. J.; Lan, Y. C.; Zhu, M. X.; Wang, H.*; Lu, J. X.*, Electrochemical reduction of aliphatic conjugated dienes in the presence of carbon dioxide. Electrochem. Commun.2010, 12 (12), 1698-1702. Zhang, G. R.; Zhang, A. J.; Liu, X. L.; Zhao, S. F.; Zhang, J. B.; Lu, J. X.*, Investigation of the Electropolymerization of o-Toluldine and p-Phenylenediamine and Their Electrocopolymerization by In Situ Ultraviolet-Visible Spectro electrochemistry. J. Appl. Polym. Sci.2010, 115 (5), 2635-2647. Wang, H.; Zhao, C.; Bhatt, A. I.; MacFarlane, D. R.; Lu, J. X.*; Bond, A. M.*, Electrochemical Study of Dialcarb "Distillable" Room-Temperature Ionic Liquids. ChemPhysChem.2009, 10 (2), 455-461. Zhang, K.; Wang, H.; Zhao, S. F.; Niu, D. F.; Lu, J. X.*, Asymmetric electrochemical carboxylation of prochiral acetophenone: An efficient route to optically active atrolactic acid via selective fixation of carbon dioxide. J. Electroanal. Chem.2009, 630 (1-2), 35-41. Zhang, A. J.; Chen, J.; Niu, D. F.; Wallace, G. G.; Lu, J. X.*, Electrochemical polymerization of pyrrole in BMIMPF6 ionic liquid and its electrochemical response to dopamine in the presence of ascorbic acid. Synth. Met.2009, 159 (15-16), 1542-1545. Zhang, L.; Niu, D. F.; Zhang, K.; Zhang, G. R.; Luo, Y. W.; Lu, J. X.*, Electrochemical activation of CO2 in ionic liquid ( BMIMBF4): synthesis of organic carbonates under mild conditions. Green Chem.2008, 10 (2), 202-206. Niu, D. F.; Zhang, A. J.; Xue, T.; Zhang, J. B.; Zhao, S. F.; Lu, J. X.*, Electrocatalytic dimerisation of benzyl bromides and phenyl bromide at silver cathode in ionic liouid BMIMBF4. Electrochem. Commun.2008, 10 (10), 1498-1501. Wang, H.; Zhang, K.; Liu, Y. Z.; Lin, M. Y.; Lu, J. X.*, Electrochemical carboxylation of cinnamate esters in MeCN. Tetrahedron2008, 64 (2), 314-318. Niu, D. F.; Xiao, L. P.; Zhang, A. J.; Zhang, G. R.; Tan, Q. Y.; Lu, J. X.*, Electrocatalytic carboxylation of aliphatic halides at silver cathode in acetonitrile. Tetrahedron2008, 64 (46), 10517-10520. Wang, H.; Lin, M. Y.; Zhang, K.; Li, S. J.; Lu, J. X.*, Electrochemical reduction of cinnamonitrile in the presence of carbon dioxide: Synthesis of cyano- and phenyl-substituted propionic acids. Aust. J. Chem.2008, 61 (7), 526-530.

学术兼职

中国有机电化学和工业行业联合会副理事长《电化学》编委