38238
当前位置: 首页   >  成果及论文
成果及论文

2022


28. "Catalytic Diastereoselective Construction of Multiple Contiguous Quaternary Carbon Stereocenters via [2 + 2] Cycloaddition and Mechanistic Insight." 

        Xi Wang, Fujie Liu and  Tao Xu*Chin. Chem. Lett., 2022, in Press.[doi]


Invited contribution to <Comprehensive Organometallic Chemistry IV>

27. Book Chapter "70019. Synthetic applications of C-C bond activation reactions" 

       Tao Xu* <Comprehensive Organometallic Chemistry IV> 2021, <DOI:10.1016/B978-0-12-820206-7.00130-X>.



2021

Invited contribution to themed collection: Total synthesis in OBC

26. "Total Synthesis of Bioactive Tetracyclic Norditerpene Dilactones." 

        Yuna Zhang, Xinxin Li and  Tao Xu*, Org. Biomol. Chem., 2021, 19, 9138-9147.[doi]


25. "Rh-Catalyzed Cascade C‒C/Colefin‒H Activations and Mechanistic Insight." 

        Yuxi Wang, Bo Qiu, Lingfei Hu, Gang Lu* and Tao Xu* ACS Catal. 2021, 11, 9136-9142. [doi]


Invited review for Special Issue in honor of Guangbin Dong 's 2021 Tetrahedron Young Investigator Award in Organic Synthesis.

24. "Isolation and total synthesis of penicimutans- and aranorosin-type natural products – a summary." 

        Haiyong Yu,  Xiaotong Li, Yuping Jia, Daizhou Zhang, Tao Xu* Tetrahedron, 202191, 132240. [doi]



23. "Regioselective Activation of Benzocyclobutenones and Dienamides Lead to anti-Bredt Bridged-Ring Systems by a [4+4] Cycloaddition." 

        Jianyu Zhang, Xi Wang, Tao Xu* Nat. Commun. 2021 12, 3022. [doi]

 * Highlighted by CBG and X-Mol [doi

 * Highlighted by Synform 2021/09, A153–A155  <DOI: 10.1055/s-0040-1720534> [doi]


22. "Remote Methylene C(sp3)-H Functionalization Enabled by an Organophosphine Catalyzed Alkyne Isomerization." 

        De Wang,  Zefeng Song, Jianyu Zhang, Tao Xu* Org. Chem. Front. 2021 8. 1125-1131[doi].

 

 * Selected as inside front cover. [doi]

2020

21. "Chemoselective Perfluoromethylation of Thio- and Selenoamides." 

        Xianhong Xu,  Jianyu Zhang, Tao Xu* Org. Lett. 2020,  22, 8638-8642. [doi]

 

   * Highlighted by ChemBeanGo [doi]

20. Inivited contribution to the special issue <The Catalysis of Ring Synthesis>

       "Pd-Catalyzed Regio- and Diastereoselective Heck Cyclization to Access Bicyclo[3.2.1]octanone Ring Systems." 

        Bo Li, Guiming Zhang,  Tao Xu* ChemCatChem. 2020, 12, 5058–5061. [doi]

 

 

19. "Total Synthesis and Structural Reassignment of Aranorosinol A, Aranorosinol B and EI-2128-1." 

        Haiyong Yu, Yingyuan Tian, Yan Zong, Jianyu Zhang, Tao Xu* J. Org. Chem. 2020, 85, 4335-4343. [doi]

 

 * Hightlighted by Org. Chem. Highlights 2021, Juanary 18. [doi]


18. "Total Synthesis of Galanthamine and Lycoramine Featuring an Early-Stage C‒C and a Late-Stage Dehydrogenation via C‒H Activation." 

        Yuna Zhang, Shuna Shen, Hua Fang, Tao Xu* Org. Lett. 202022, 1244-1248 . [doi]

 

 * Selected and featured as supplementery cover.[doi]


17. "Total Synthesis of (‒)-Penicimutanin A and the Related Congeners." haiyong Yu, Yan Zong, Tao Xu* Chem. Sci. 2020, 11, 656-660.[doi]

 

  * Highlighted by Chemistry Views - News 25 November 2019.[doi]

  * Highlighted by Synfacts 2020, 16(02), 0122.[doi]

 * Featured as Front Inside Cover.[doi]


16. "Highly Regio- and Enantioselective Dienylation of p-Quinone Methides Enabled by an Organocatalyzed Isomerization/Addition Cascade of Allenoates." De Wang,*; Zefeng Song, Weijia Wang, Tao Xu* Org. Lett. 2019, 21, 3963-3967.[doi]

 

 

15. "Total Synthesis of penta-Me Amurensin H and Diptoindonesin G Featuring a Rh-catalyzed Carboacylation/Aromatization Cascade Enabled by C-C Activation." Yuting Qin, Junling Zhan, Tiantian Shan, Tao Xu* Tetrahedron Lett. 2019, 60, 925-927.[doi]

2018

14. “Catalytic Enantioselective Synthesis of 3,4-Polyfused Oxindoles with Quaternary All-Carbon Stereocenters: A Rh-Catalyzed C−C Activation Approach” Bo Qiu, Xiaotong Li, Jianyu Zhang, Junling Zhan, Shuangping Huang, Tao Xu* Org. Lett. 2018, 20, 7689.[doi]

13. Total Synthesis of Bioactive Marine Meroterpenoids: The Cases of Liphagal and Frondosin B.” Yan Zong, Weijia Wang, Tao Xu* Marine Drugs 2018, 16, 115.[doi]

12. “RhI-Catalyzed Carboacylation/Aromatization Cascade Initiated by Regioselective C−C Activation of Benzocyclobutenones”  Tianwen Sun, Yuna Zhang, Bo, Qiu, Yafei Wang, Yuting Qin, Guangbin Dong,* Tao Xu* Angew. Chem. Int. Ed. 2018, 57, 2859-2863.[doi]

 

 

11. Isolation, Synthesis, and Radical-Scavenging Activity of Rhodomelin A, a Ureidobromophenol from the Marine Red Alga Rhodomela confervoides” Li, K.; Wang, Y.-F.; Li, X.-M.; Wang, W.-J.; Ai, X.-Z.; Li, X.; Yang, S.-Q.; Gloer, J.; Wang, B.-G*; Xu, T.* Org. Lett. 2018, 20, 417.[doi]

 

2016

10. Enantioselective Rh-catalyzed Carboacylation of C=N Bonds via C−C Activation of Benzocyclobutenones.” Deng, L.; Xu, T.*; Li, H.; Dong, G.* J. Am. Chem. Soc. 2016, 138, 369-374.[doi]

*Highlighted by Synfacts 2016; 12(3): 0288.

 

Before independent

2015

9. “Computational Study of Rh-Catalyzed Carboacylation of Olefins: Ligand-Promoted Rhodacycle Isomerization Enables Regioselective C-C Bond Functionalization of Benzocyclobutenones.” Lu, G.; Fang, C.; Xu, T.; Dong, G.; Liu, P.* J. Am. Chem. Soc. 2015, 137, 8274-8283.[doi]

2014

8. “Coupling Sterically Hindered Trisubstituted Olefin and Benzocyclobutenones via C-C Activation: Total Synthesis and Structural Revision of Cycloinumakiol.” Xu, T.; Dong, G.* Angew. Chem. Int. Ed. 2014, 53, 10733-10736.[doi]

                                            

*Highlighted by Synfacts 2014, 10(12), 1235.

Invited Review

7. “Transition-Metal-Catalyzed C-C Bond Activation of Four-membered cyclic ketones.” Xu, T.; Dermenci, A.; Dong, G.* Top. Curr. Chem. 2014, 346, 233-257.[doi]

                                                                              

 

6. “RhI-Catalyzed Decarbonylative Coupling of Olefins and Benzocyclobutenones via C-C Activation: An Efficient Approach To Access Functionalized Spirocycles.” Xu, T.; Savage, N. A.; Dong, G.* Angew. Chem. Int. Ed. 2014, 53, 1891-1895.[doi]

VIP in Angewandte Chemie

5. Divergent Synthesis of Fused -Naphthol & Indene Rings via Rh-Catalyzed Alkyne insertion into Bezocyclobutenones.” Chen, P.; Xu, T.; Dong, G.* Angew. Chem. Int. Ed. 2014, 53, 1674-1678.[doi]

*This paper was chosen as VIP paper.

*Highlighted by Synfacts 2014, 10(5), 469.

 

2012

4. “Highly Enantioselective Rh-Catalyzed Carboacylation of Olefins: Efficient Synthesis of Chiral Poly-Fused Rings.” Xu, T.; Ko, H. M.; Savage, N. A.; Dong, G.* J. Am. Chem. Soc. 2012, 134, 20005-20008.[doi]

*Highlighted by ChemInform 2013 44(22).

*Hightlighted by T. H. Lambert, Org. Chem. Highlights 2013, September 23.

 

3. “Rh-Catalyzed Regioselective Carboacylation of Olefins: A C-C Activation Approach to Access Fused-Ring Systems.” Xu, T.; Dong, G.* Angew. Chem. Int. Ed. 2012, 51, 7567.[doi]

 *Highlighted by Chemical & Engineering News, 90(27), July 02, 2012.

 *Highlighted by Synlett, 2013, 24, 1.

 *Highlighted by Annu. Rep. Sect. A (Inorg. Chem,) 2013, 109, 153.

 *Highlighted by ChemInform 2013, 44, 98.

 

2011&before

2. “A Concise Approach to the Total Synthesis of Pseudolaric acid A.” Xu, T.; Li, C.-C.*; Yang, Z.* Org. Lett. 2011, 13, 2630-2633.[doi]

 *Highlighted Synthesis in Annu. Rep. Prog. Chem., Sect. B: Org. Chem,, 2012.

1. A Selective Fluorescent Sensor for Imaging Cd2+ in Living Cells.” Peng, X.*; Du, J.; Fan, J.; Wang, J.; Wu, Y.; Zhao, J.; Sun, S.; Xu, T. J. Am. Chem. Soc. 2007, 129, 1500-1501.