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成果及论文


部分代表性工作(完整论文列表参见英文主页):

回国后工作(2020年以后):


10. Transition-Metal-Free Carbonyl Redox: A Ketene in Three Oxidation States.

Liankun Ai, Xinyue Meng, Songyang Li, Cuijuan Zhang, Dominik Munz,* and Jiaxiang Chu* 

Angew. Chem. Int. Ed2025, 64, e202515888.

https://onlinelibrary.wiley.com/doi/10.1002/anie.202515888


X-MOL公众号的介绍(含链接):“【有机】国科大楚甲祥及合作者:首次稳定烯酮的三种不同氧化态

highlighted by Trends in Chemistry (will be online soon).


9. Room Temperature Ring Opening of Benzene by Four-electron Reduction and Carbonylation. 

Leiyang Zhang,‡ Ziang Jiang,‡ Cuijuan Zhang,‡ Kehang Cheng, Songyang Li, Yueze Gao, Xiaotai Wang,* and Jiaxiang Chu* 

J. Am. Chem. Soc2025147, 25017. (contribution equally)

https://pubs.acs.org/doi/10.1021/jacs.5c08414


highlighted by C&EN: "Metal complexes rip open benzene"

https://cen.acs.org/physical-chemistry/chemical-bonding/Metal-complexes-rip-open-benzene/103/web/2025/07

该工作入选美国化学会2025年度分子(含链接):Molecules of the year 2025


8. Evidence for Carbene Intermediates in Isocyanide Homologation by Aluminium(I). 

Cuijuan Zhang, Fabian Dankert, Ziang Jiang, Baolu Wang, Dominik Munz,* and Jiaxiang Chu* 

Angew. Chem. Int. Ed2023, 62, e202307352.

https://onlinelibrary.wiley.com/doi/10.1002/anie.202307352

Interviewed by Angew. Chem. as Team Profile: Elucidation of Organometallic Reaction Mechanisms by a China–Germany Team. 

Cuijuan Zhang, Fabian Dankert, Ziang Jiang, Baolu Wang, Dominik Munz,* and Jiaxiang Chu* 

Angew. Chem. Int. Ed2023, 62, e202314198.

https://onlinelibrary.wiley.com/doi/10.1002/anie.202314198


X-MOL公众号的介绍:“【有机】捕捉异腈偶联反应中的卡宾中间体

https://mp.weixin.qq.com/s/I3FW0f5hZ2rBwezOTPuyvQ


7. A Borane Lewis Acid in the Secondary Coordination Sphere of a Ni(II) Imido Imparts Distinct C-H Activation Selectivity. 

Baolu Wang,+ Chris S. G. Seo,+ Cuijuan Zhang, Jiaxiang Chu* and Nathaniel K. Szymczak* 

J. Am. Chem. Soc. 2022144, 15793(contribution equally) 

 https://pubs.acs.org/doi/10.1021/jacs.2c06662


highlighted by C&EN: "Functional group not directly on metal changes its behavior"

https://cen.acs.org/acs-news/acs-meeting-news/Functional-group-directly-metal-changes/100/web/2022/08

highlighted by Trends in Chemistry: "Remixing the secondary coordination sphere"

https://www.sciencedirect.com/science/article/abs/pii/S2589597423001181


本课题组公众号的介绍:  “JACS:次级配位环境调控下后过渡金属氮宾的反应性” 

https://mp.weixin.qq.com/s/YZJuZ7fyADdS2-QQRYqrzg


独立前的工作(2011-2019):


6. Probing hydrogen atom transfer at a phosphorus(V) oxide bond using a “bulky hydrogen atom” surrogate: analogies to PCET.  

Jiaxiang Chu, Timothy G. Carroll, Guang Wu, Joshua Telser, Roman Dobrovetsky,* and Gabriel Ménard*   

J. Am. Chem. Soc. 2018, 140, 15375.                                 

https://pubs.acs.org/doi/10.1021/jacs.8b09063


    5. NHC-CAAC heterodimers with three stable oxidation states.   
    Dominik Munz+, Jiaxiang Chu+, Mohand Melaimi, and Guy Bertrand.*   
     Angew. Chem. Int. Ed. 2016, 55, 12886. (contribution equally)   
         
      
      4. Synthesis of hemilabile cyclic (alkyl)(amino)carbenes (CAACs) and applications in organometallic chemistry.     
      Jiaxiang Chu, Dominik Munz, Rodolphe Jazzar, Mohand Melaimi, Guy Bertrand.*     
      J. Am. Chem. Soc. 2016138, 7884.       
          

    3. Lewis acid triggered reactivity of a lewis base stabilized scandium terminal imido complex: CH bond activation, cycloaddition, and dehydrofluorination.”   
    Jiaxiang Chu; Xianghao Han; Christos E. Kefalidis; Jiliang Zhou; Laurent Maron;* Xuebing Leng; Yaofeng Chen.*   
    J. Am. Chem. Soc. 2014, 136, 10894.    
         

  • 2. Chameleon behavior of a newly synthesized scandium nitrilimine derivative.   
  •  Jiaxiang Chu; Christos E. Kefalidis; Laurent Maron;* Xuebing Leng; Yaofeng Chen.*   
    J. Am. Chem. Soc. 2013, 135, 8165.  
                  

    1. Reactivity of a scandium terminal imido complex towards unsaturated substrates.   
    Jiaxiang Chu; Erli Lu; Zhixiao Liu; Yaofeng Chen;* Xuebing Leng; Haibin Song.   
    Angew. Chem., Int. Ed. 2011, 50, 7677.   
    https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201102267             

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