Publication at UCAS (Since 2020):
20. Reactivity of an Iron Carbonyl Dianion Dictated by a Lewis Basic Appendant. Xiaohu Zhang and Jiaxiang Chu*
Submitted.
19. Team Profile: Elucidation of Organometallic Reaction Mechanisms by a China–Germany Team. Cuijuan Zhang, Fabian Dankert, Ziang Jiang, Baolu Wang, Dominik Munz,* and Jiaxiang Chu*
Angew. Chem. Int. Ed. 2023, e202314198 (team profile).
https://onlinelibrary.wiley.com/doi/10.1002/anie.202314198
18. Evidence for Carbene Intermediates in Isocyanide Homologation by Aluminium(I). Cuijuan Zhang, Fabian Dankert, Ziang Jiang, Baolu Wang, Dominik Munz,* and Jiaxiang Chu*
Angew. Chem. Int. Ed. 2023, e202307352.
https://onlinelibrary.wiley.com/doi/10.1002/anie.202307352
17.A Borane Lewis Acid in the Secondary Coordination Sphere of a Ni(II) Imido Imparts Distinct C-H Activation Selectivity. Baolu Wang,+ Chris S. G. Seo,+ Cuijuan Zhang, Jiaxiang Chu* and Nathaniel K. Szymczak*
J. Am. Chem. Soc. 2022, 144, 15793. (contribution equally)
https://pubs.acs.org/doi/10.1021/jacs.2c06662
highlighted by C&EN: "Functional group not directly on metal changes its behavior"
https://cen.acs.org/acs-news/acs-meeting-news/Functional-group-directly-metal-changes/100/web/2022/08
highlighted by Trends in Chemistry: "Remixing the secondary coordination sphere"
https://www.sciencedirect.com/science/article/abs/pii/S2589597423001181
Prior to UCAS (2011-2019):
16. Redox-Controlled Reactivity at Boron: Parallels to Frustrated Lewis/Radical Pair Chemistry. Anthony Wong+, Jiaxiang Chu+, Guang Wu, Joshua Telser, Roman Dobrovetsky, and Gabriel Ménard*
Inorg. Chem. 2020, 59, 10343. (contribution equally)
https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c01464
15. Neutral and Anionic Monomeric Zirconium Imides Prepared via Selective C=N Bond Cleavage of a Multidentate and Sterically Demanding b-Diketiminato Ligand.
Takashi Kurogi, Jiaxiang Chu, Yaofeng Chen,* and Daniel J. Mindiola*
Chem. Asia J. 2019, 14, 2629.
14. Probing hydrogen atom transfer at a phosphorus(V) oxide bond using a “bulky hydrogen atom” surrogate: analogies to PCET.
Jiaxiang Chu, Timothy G. Carroll, Guang Wu, Joshua Telser, Roman Dobrovetsky,* and Gabriel Ménard*
J. Am. Chem. Soc. 2018, 140, 15375.
https://pubs.acs.org/doi/10.1021/jacs.8b09063
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13. Scandium Terminal Imido Chemistry.
Erli Lu, Jiaxiang Chu, Yaofeng Chen.*
Acc. Chem. Res. 2018, 51, 557.
https://pubs.acs.org/doi/10.1021/acs.accounts.7b00605
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12. Reactivity of scandium terminal imido complex towards boranes: C(sp3)-H bond borylation and B–O bond cleavage.
Jiaxiang Chu, Chen Wang, Li Xiang, Xuebing Leng, Yaofeng Chen.*
Organometallics 2017, 36, 4620. (Invited for the themed issue entitled “Organometallic Actinide and Lanthanide Chemistry”)
11. NHC-CAAC heterodimers with three stable oxidation states.
Dominik Munz+, Jiaxiang Chu+, Mohand Melaimi, and Guy Bertrand.*
Angew. Chem. Int. Ed. 2016, 55, 12886. (contribution equally)
10. Synthesis of hemilabile cyclic (alkyl)(amino)carbenes (CAACs) and applications in organometallic chemistry.
Jiaxiang Chu, Dominik Munz, Rodolphe Jazzar, Mohand Melaimi, Guy Bertrand.*
J. Am. Chem. Soc. 2016, 138, 7884.
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9. Air-stable cyclic (alkyl)(amino)carbene copper complexes as catalysts for the hydrolytic dehydrogenation of BH3NH3: isolation of a CuBH4 complex supported by a single ligand.
Xingbang Hu; Michèle Soleihavoup; Mohand Melaimi; Jiaxiang Chu; Guy Bertrand.*
Angew. Chem., Int. Ed. 2015, 54, 6008.
8. Scandium terminal imido complex induced intramolecular C–N bond cleavage and transformation.
Jiaxiang Chu; Qinghai Zhou; Yuxue Li;* Xuebing Leng; Yaofeng Chen.*
Sci. China. Chem. 2014, 57, 1098.
7. Lewis acid triggered reactivity of a lewis base stabilized scandium terminal imido complex: C−H bond activation, cycloaddition, and dehydrofluorination.”
Jiaxiang Chu; Xianghao Han; Christos E. Kefalidis; Jiliang Zhou; Laurent Maron;* Xuebing Leng; Yaofeng Chen.*
J. Am. Chem. Soc. 2014, 136, 10894.
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6. Chameleon behavior of a newly synthesized scandium nitrilimine derivative.
Jiaxiang Chu; Christos E. Kefalidis; Laurent Maron;* Xuebing Leng; Yaofeng Chen.*
J. Am. Chem. Soc. 2013, 135, 8165.
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5. An yttrium hydride-silane complex as a structural model for a σ-bond metathesis transition state.
Jiliang Zhou; Jiaxiang Chu; Yanyan Zhang; Guang Yang; Xuebing Leng; Yaofeng Chen.*
Angew. Chem., Int. Ed. 2013, 52, 4243.
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4. Reversible addition of Si-H bond of phenylsilane to Sc=N bond of scandium terminal imido complex.
Jiaxiang Chu; Erli Lu; Yaofeng Chen;* Xuebing Leng.
Organometallics 2013, 32, 1137. (Invited for the themed issue entitled “Recent Advances in Organo-f-Element Chemistry”).
3. Reactivity of a scandium terminal imido complex towards inorganic and organometallic halides.
Erli Lu; Qinghai Zhou; Yuxue Li; Jiaxiang Chu; Yaofeng Chen;* Xuebing Leng; Jie Sun.
Chem. Commun. 2012, 48, 3403.
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2. Scandium terminal imido complex induced C-H bond selenation and formation of an Sc-Se bond.
Erli Lu; Jiaxiang Chu; Yaofeng Chen;* Maxim V. Borzov; Guangyu Li.
Chem. Commun. 2011, 47, 743.
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1. Reactivity of a scandium terminal imido complex towards unsaturated substrates.
Jiaxiang Chu; Erli Lu; Zhixiao Liu; Yaofeng Chen;* Xuebing Leng; Haibin Song.
Angew. Chem., Int. Ed. 2011, 50, 7677.
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https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201102267
