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成果及论文

主要围绕有机磷化合物的绿色合成,惰性化学键活化,生物质的转化,药物与材料功能分子设计合成展开工作。目前承担国家自然科学基金(面上基金)1项(材料与化工学院历史上的第一个面上项目),国家自然科学基金(地区基金)1国家自然科学基金(青年基金)1项,海南省重点研发计划1项,海南省自然科学基金面上项目1项,湖南省自然科学基金(青年基金)1项。自2011年以来,以第一作者和通讯作者身份在J. Am. Chem. Soc. 4篇(2018年发表的JACS是以海南省科研机构为第一单位的第一篇),Angew. Chem. Int. Ed. 2篇等高水平国际期刊发表SCI论文80篇。论文总被引2800多次,H-index28。撰写Wiley和Thieme出版社书籍各1章。《中国学科发展战略-磷科学》撰写组成员。


一作或通讯作者论文列表

[1] Zuo D, Wang Q, Liu L, Huang T, Szostak M,* Chen T Q.* Highly Chemoselective Transamidation of Unactivated Tertiary Amides by Electrophilic N–C(O) Activation via Amide-to-Acyl Iodide Re-Routing. Angewandte Chemie International Edition, 2022, 61, e202202794.

[2] Chen T Q, Zhao C-Q, Han L-B.* Hydrophosphorylation of Alkynes Catalyzed by Palladium: Generality and Mechanism. Journal of the American Chemical Society, 2018, 140, 3139–3155.

[3] Zhu Y Y, Chen T Q,* Li S, Shimada S, Han L-B.* Efficient Pd-Catalyzed Dehydrogenative Coupling of P(O)H with RSH: a Precise Construction of P(O)-S Bonds. Journal of the American Chemical Society, 2016, 138, 5825–5828.

[4] Yang J, Chen T Q,* Han L-B.* C-P Bond-Forming Reactions via C-O/P-H Cross Coupling Catalyzed by Nickel. Journal of the American Chemical Society, 2015, 137, 1782-1785.

[5] Chen T Q,* Han L-B.* Nickel-Catalyzed C-O/C-H Cross-Coupling Reactions for C-C Bond Formation. Angewandte Chemie International Edition, 2015, 54, 8600-8602.

[6] Shen R W,b† Chen T Q,a Zhao Y L, Qiu R H, Zhou Y B, Yin S F,* Wang X B, Goto M, Han L-B.* Facile Regio- and Stereoselective Hydrometalation of Alkynes with a Combination of Carboxylic Acids and Group 10 Transition Metal Complexes: Selective Hydrogenation of Alkynes with Formic Acid. Journal of the American Chemical Society, 2011, 133, 17037-17044 (†:并列第一作者, 第一单位第一作者).

[7] Xue Liu, Xinyi Li, Long Liu, Tianzeng Huang, Wen-Hao Chen, Michal Szostak*, Tieqiao Chen*, Pd/Cu-Catalyzed Synthesis of Internal and Sila-Ynones by Direct Selective Acyl Sonogashira Cross-Coupling of Carboxylic Acids with Terminal Alkynes. ACS Catalysis, 2023, 13,5819-5827.

[8] Liguang Gan, Tianhao Xu, Qihang Tan, Mengjie Cen, Lingling Wang,  Jingwei Zhao, Kuang Liu, Long Liu, Wen-Hao Chen, Li-Biao Han,* Jacek E. Nycz,* and Tieqiao Chen*, Metal-Free Highly Chemo-Selective Bisphosphorylation and Deoxyphosphorylation of Carboxylic Acid. Chemical Science, 2023, 14,5519-5526.

[9] Zhang M-Z,* Liu L, Gou Q, Wang Q, Li Y, Li W-T, Luo F, Yuan M, Chen T Q,* He W-M.* Synthesis of Hydroxyl-Containing Oxindoles and 3,4-Dihydroquinolin-2-ones through Oxone-Mediated Cascade Arylhydroxylation of Activated Alkenes. Green Chemistry, 2020, 22, 8369-8374.

[10]  Zhang M-Z,* Wang P, Liu H-Y, Wang D,* Deng Y, Bai Y-H, Luo F, Wu W-Y, Chen T Q.* Metal-Catalyst-Free One-Pot Aqueous Synthesis of trans-1,2-Diols from Electron-Deficient α,β-Unsaturated Amides via Epoxidation Using Oxone as a Dual Role Reagent. ChemSusChem, 2023, accept.

[11] Zhang J-S, Liu L., Chen T Q,* Han L-B. Cross-Dehydrogenative Alkynylation: A Powerful Tool for the Synthesis of Internal Alkynes. ChemSusChem 2020, 13, 4776-4794.

[12] Liu X, Liu L, Huang T, Zhang J, Tang Z, Li C. Chen, T Q,* Trifluoromethylation of Benzoic Acids: An Access to Aryl Trifluoromethyl Ketones. Organic Letters, 2021, 23, 4930-4934.

[13] Li X, Liu L, Huang T, Tang Z, Li C, Li W, Zhang T, Li Z, Chen T Q.* Palladium-Catalyzed Decarbonylative Sonogashira Coupling of Terminal Alkynes with Carboxylic Acids. Organic Letters, 2021, 23, 3304-3309.

[14] Yu W Q, Liu L, Huang T Z, Zhou X B, Chen T Q,* Palladium-Catalyzed Decarbonylative Heck Coupling of Aromatic Carboxylic Acids with Terminal Alkenes. Organic Letters, 2020, 22, 7123-7128.

[15] Li Z, Liu L, Xu K, Huang T, Li X, Song B, Chen T Q.* Palladium-Catalyzed N-Acylation of Tertiary Amines by Carboxylic Acids: A Method for the Synthesis of Amides. Organic Letters, 2020, 22, 5517-5521.

[16] Liu L, Zhu D, Liu M, Zhou Y, Chen T Q,* Palladium-Catalyzed Decarbonylative Alkynylation of Amides. Organic Letters, 2018, 20, 2741-2744.

[17] Zhang J-S, Chen T Q,* Zhou Y, Yin S-F, Han L-B.* Catalytic sp3C-CN Bond Cleavage: Ni-Mediated Phosphorylation of Alkylnitriles. Organic Letters, 2018, 20, 6746-6749.

[18] Zhang J Q, Chen T Q,* Zhang J.-S., Han L.-B.* Silver-Free Direct Synthesis of Alkynylphosphine Oxides via spC-H/P(O)-H Dehydrogenative Coupling Catalyzed by Palladium. Organic Letters, 2017, 19, 4692-4695.

[19] Xiao J, Chen T Q,* Han L-B.* Nickel-Catalyzed Direct C-H/C-O Cross Couplings Generating Fluorobenzenes and Heteroarenes. Organic Letters, 2015, 17, 812–815.

[20] Zhao Y L, Chen T Q,* Han D Q, Zhao C-Q,* Han L-B.* Facile Base-Mediated Redox Transformation: An Efficient Strategy for the Synthesis of αAcyloxyphosphoryl Compounds. Organic Letters, 2014, 16, 6152-6155.

[21] Xi X X, Chen T Q,* Zhang J-S, Han L-B. Efficient and Selective Hydrogenation of C-O Bonds with a Simple Sodium Formate Catalyzed by Nickel. Chemical Communications, 2018, 54, 1521-1524.

[22] Xiao J, Yang J, Chen T Q,* Han L-B.* Nickel-Catalyzed Synthesis of (E)-Olefins from Benzylic Alcohol Derivatives and Arylacetonitriles via C-O Activation. Chemical Communications, 2016, 52, 2157-2160.

[23] Yang J, Xiao J, Chen T Q,* Yin S-F,* Han L-B.* Efficient Nickel-catalyzed Phosphinylation of C-S Bonds Forming C-P Bonds. Chemical Communications, 2016, 52, 12233-12236.

[24] Zhang J-S, Chen T Q,* Yang J, Han L-B.* Nickel-Catalysed P-C Bond Formation via P-H/C-CN Cross Couplings. Chemical Communications, 2015, 51, 7540-7542.

[25] Yang J, Chen T Q,* Zhou Y B, Yin S F, Han L-B.* Palladium-Catalyzed Dehydrogenative Coupling of Terminal Alkynes with Secondary Phosphine Oxides. Chemical Communications, 2015, 51, 3549-3551.

[26] Chen T Q, Guo C C,* Goto M, Han L -B.* A Brønsted acid-catalyzed generation of palladium complexes: efficient head-to-tail dimerization of alkynes. Chemical Communications, 2013, 49, 7498-7500.

[27] Xiao J, Yang J, Chen T Q,* Han L-B.* Nickel-Catalyzed α-Benzylation of Arylacetonitriles via C-O Activation. Advanced Synthesis & Catalysis, 2016, 358, 816-819.

[28] Chen H, Liu L, Huang T, Chen J,* Chen T Q.* Direct Dehydrogenation for the Synthesis of a,b-Unsaturated Carbonyl Compounds. Advanced Synthesis & Catalysis, 2020, 362, 3332-3346.

[29] Xiang K, Zhang S, Liu L, Huang T, Tang Z, Li C, Xu K, Chen T Q.* Tunable C-H Arylation and Acylation of Azoles with Carboxylic Acids by Pd/Cu Cooperative Catalysis. Organic Chemistry Frontiers, 2021, 8, 2543-2550.

[30] Zhang M-Z,* Tian J, Yuan M, Peng W-Q, Wang Y-Z, Wang P, Liu L, Gou Q, Huang H, Chen T Q.* Visible Light-Induced Aerobic Dioxygenation of α,β-unsaturated amides/Alkenes toward Selective Synthesis of β-Oxy Alcohols Using Rose Bengal as a Photosensitizer. Organic Chemistry Frontiers, 2021, 8, 2215-2223.

[31] Liu M, Chen T Q,* Yin S F.* Copper-Catalysed Aerobic Oxidative Esterification of N-Heteroaryl Methanes with Alcohols. Catalysis Science & Technology, 2016, 6, 690-693.

[32] Liu M, Chen T Q,* Zhou Y B, Yin S F.* Transition Metal-Free Oxidative ortho-Acylation of Phenols with N-Heteroarylmethanes via Double C-H Activation. Catalysis Science & Technology, 2016, 6, 5792-5796.

[33] Chen X L,† Chen T Q,† Ji F Y, Zhou Y B,* Yin S-F.* Iron-Catalyzed Aerobic Oxidative Functionalization of sp3C-H Bonds: a Versatile Strategy for the Construction of N-Heterocycles, Catalysis Science & Technology, 2015, 5, 2197-2202 (†:并列第一作者).

[34] Chen X L,† Chen T Q,† Li Q, Zhou Y B, Han L-B, Yin S-F.* Copper-Catalyzed Aerobic Oxidative Inert C-C and C-N Bond Cleavage: A New Strategy for the Synthesis of Tertiary Amides. Chemistry - A European Journal, 2014, 20, 12234-12238 (†:并列第一作者).

[35] Xu, T; Zhou, X; Xiao, X; Yuan, Y; Liu, L; Huang, T; Li, C; Tang, Z; Chen, T Q* Nickel-Catalyzed Decarbonylative Thioetherification of Carboxylic Acids with ThiolsThe Journal of Organic Chemistry, 2022, 87, 8672-8648.

[36] Xu T, Li W, Zhang K, Han Y, Liu L, Huang T, Li C, Tang Z, Chen T Q.* Palladium-Catalyzed Decarbonylative Cyanation of Carboxylic Acids with TMSCN. The Journal of Organic Chemistry, 2022, 87, 11871-11879.

[37] Tang Y, Liu K, Zhang J, Liu L,* Huang T, Li C, Tang Z, Chen T Q.* Palladium-Catalyzed Stereoselective Difunctionalization of Bicyclic Alkenes with Organoammonium Salts and Organoboronic Compounds. The Journal of Organic Chemistry, 2021, 86, 11937-11947.

[38] Zhang M,* Li W, Li Y, Wang Q, Li C, Liu Y, Yin J, Yang X, Huang H, Chen T Q.* Discovery of an Oxidative System for Radical Generation from Csp(3)- H Bonds: A Synthesis of Functionalized Oxindoles. The Journal of Organic Chemistry, 2021, 86, 15544-15557.

[39] Tian Z, Gong Q, Huang T, Liu L, Chen T Q.* Practical Electro-Oxidative Sulfonylation of Phenols with Sodium Arenesulfinates Generating Arylsulfonate Esters. The Journal of Organic Chemistry, 2021, 86, 15914-15926.

[40] Long Liu, Yuanyuan Tang, Kunyu Wang, Tianzeng Huang, Tieqiao Chen.* Transition-Metal-Free and Base-Promoted Carbon-Heteroatom Bonds Formation via C-N Cleavage of Benzyl Ammonium Salts. The Journal of Organic Chemistry, 2021, 86, 4159-4170.

[41] Xu K Q, Liu L, Li Z H, Huang T Z, Xiang K, Chen T Q.* Controllable Phosphorylation of Thioesters: Selective Synthesis of Aryl and Benzyl phosphoryl compounds. The Journal of Organic Chemistry, 2020, 85, 14653-14663.

[42] Huang T, Chen T Q,* Han L-B.* Oxidative Dephosphorylation of Benzylic Phosphonates with Dioxygen Generating Symmetrical trans-Stilbenes. The Journal of Organic Chemistry, 2018, 83, 2959-2965.

[43] Zhang M-Z,* Luo N, Long, R-Y, Gou X-T, Shi W-B, He S-H, Jiang Y, Chen J-Y, Chen, T Q.* Transition-Metal-Free Oxidative Aminooxyarylation of Alkenes: Annulations toward Aminooxylated Oxindoles. The Journal of Organic Chemistry, 2018, 83, 2369-2375.

[44] Yang J, Xiao J, Chen T Q,* Han L-B.* Nickel-Catalyzed Phosphorylation of Phenol Derivatives via C-O/P-H Cross Coupling. The Journal of Organic Chemistry, 2016, 81, 3911-3916. 

[45] Liu K, Song B, Dang Q, Liu L,* Tang J, Huang T, Li C, Tang Z, Chen T Q*. Walking Cations: Transition-Metal Free Benzyl Cation-Triggered sp2C-H Phosphorylation and Etherification. Chinese Journal of Chemistry, 2022, 40, 2933-2938.

[46] Zhang L, Liu L, Huang T, Dong Q,* Chen T Q.* Palladium-Catalyzed Cyclobutanation of Aryl Sulfonates through both C–O and C–H Cleavage. Organometallics, 2020, 39, 11, 2189-2196.

[47] Yang J, Chen T Q,* Zhou Y B, Yin S F, Han L-B.* Mechanistic Studies on the Palladium Catalyzed Cross Dehydrogenative Coupling of P(O)-H Compounds with Terminal Alkynes: Stereochemistry and Reactive Intermediates. Organometallics, 2015, 34, 5095-5098.

[48] Li C Y, Chen T Q,* Han L-B.* Iron-Catalyzed Clean Dehydrogenative Coupling of Alcohols with P(O)-H Compounds: a New Protocol for ROH Phosphorylation. Dalton Transactions, 2016, 45, 14893-14897.

[49] Chen T Q, Zhang J-S, Han L-B.* Dehydrogenative Coupling Involving P(O)-H Bonds: a Powerful Way for the Preparation of Phosphoryl Compounds. Dalton Transactions, 2016, 45, 1843-1849.

[50] Li X, Chen T Q,* Saga Y, Han L-B.* Iron-Catalyzed Cross Coupling of P-H/C-O Bonds: Efficient Synthesis of α-Alkoxyphosphorus Compounds. Dalton Transactions, 2016, 45, 1877-1880.

[51] Zhang J-S, Liu L, Chen T Q,* Han L-B, Transition Metal-Catalyzed Three-Component Difunctionalization of Alkenes, Chemistry – an Asian Journal, 2018, 13, 2277-2291.

[52] Liu C,* Xing Y-Y, Zhou T, Chen, T Q,* Hong X,* Szostak M.* Carboxylic-Phosphoric Anhydrides as Direct Electrophiles for Decarbonylative Hirao Cross-Coupling of Carboxylic Acids: DFT Investigation of Mechanistic Pathway. Chemistry- An Asian Journal, 2023, DOI: 10.1002/asia.202201262.

[53] Jin H, Gu C, Xiao Z, Tan Q, Liu L, Han L-B,* Chen W-H, Chen T Q,* Highly Chemoselective Reduction of Phosphine Oxides through Electrophilic Activation of the P=O Bond with Anhydride. European Journal of Organic Chemistry, 2023, accept.

[54] Zhang J-S, Chen T Q,* Han L-B.* Palladium-Catalyzed Direct Decarbonylative Phosphorylation of Benzoic Acids with P(O)-H Compounds. European Journal of Organic Chemistry, 2020, 2020, 1148-1153.

[55] Zhang S, Yang L, Fu J, Tan Q, Liu K, Huang T*, Li C, Liu L, Chen T Q*. Palladium-catalyzed and Norbornene-mediated C-H Amination and C-O Alkenylation of Aryl Triflates. Organic & Biomolecular Chemistry, 2023, DOI: 10.1039/D3OB00260H.

[56] Liu K, Ding D, Xing W, Liu L,* Zhang S, Meng Q, Chen T Q,* Palladium catalysed deaminative/decarboxylative cross-coupling  of organoammonium salts with carboxylic acids, Organic & Biomolecular Chemistry, 2023, doi: 10.1039/D2OB02251F

[57] Zhang T, Wang K, Ke Y, Tang Y, Liu L,* Huang T, Li C, Tang Z, Chen T Q.* Transition-metal-free and base promoted C-C bond formation via C-N bond cleavage of organoammonium salts. Organic & Biomolecular Chemistry, 2021, 19, 8237-8240. 

[58] Ye R Z, Cao Y J, Xi X X, Liu L, Chen T Q.* Metal- and radical-free aerobic oxidation of heteroaromatic methanes: an efficient synthesis of heteroaromatic aldehydes. Organic & Biomolecular Chemistry, 2019, 17, 4220-4224.

[59] Zhang M-Z,* Wang X, Gong M-Y, Chen L, Shi W-B,* He S-H, Jiang Y, Chen T Q.* An efficient iodine pentoxide-triggered iodocarbocyclizations for the synthesis of iodooxindoles in water. Organic & Biomolecular Chemistry, 2018, 16, 5197-5202.

[60] Chen L, Zhu Y Y, Chen T Q,* Liu L, Zhang J-S, Han L-B.* Direct C-OH/P(O)-H Dehydration Coupling Forming Phosphine Oxides. Organic & Biomolecular Chemistry, 2018, 16, 5090-5093.

[61] Zhang J-S, Zhang J-Q, Chen T Q,* Han L-B.* t-BuOK-Mediated Reductive Addition of P(O)-H Compounds to Terminal Alkynes Forming β-Arylphosphine oxides. Organic & Biomolecular Chemistry, 2017, 15, 5462-5467.

[62] Liu M, Chen X, Chen T Q,* Yin S F.* Facile and General Acid-Catalyzed Deuteration at Methyl Groups of N-Heteroarylmethanes. Organic & Biomolecular Chemistry, 2017, 15, 2507-2511.

[63] Liu M, Chen X, Chen T Q,* Xu Q, Yin S F.* Metal-Free Oxidative para-Acylation of Unprotected Anilines with N-Heteroarylmethanes. Organic & Biomolecular Chemistry, 2017, 15, 9845-9854.

[64] Huang Y, Chen T Q,* Li Q, Zhou Y B, Yin S F.* Copper Catalysed Direct Amidation of Methyl Groups with N-H Bonds. Organic & Biomolecular Chemistry, 2015, 13, 7289-7293.

[65] Lin Y, Li D, Zhang J, Tang Z,* Liu L, Huang T, Li C, Chen T Q.* I-2/NaH2PO2-mediated deoxyamination of cyclic ethers for the synthesis of N-aryl-substituted azacycles. New Journal of Chemistry, 2021, 45, 21011-21014.

[66] Cao Y, Liu L, Huang T, Chen T Q.* Iodine-catalyzed a,b-dehydrogenation of ketones and aldehydes generating conjugated enones and enals. New Journal of Chemistry, 2020, 44, 8697-8701.

[67] Wang Q, Liu L, Dong J,* Chen T Q.* Metal-free thioesterification of amides generating acyl thioesters. New Journal of Chemistry, 2019, 43, 9384-9388.

[68] Xiao J, Yang J, Chen T Q,* Han L-B.* Nickel-Catalyzed α-Benzylation of Sulfones with Esters via C-O Activation. RSC Advances, 2016, 6, 42656-42659.

[69] Li S, Chen T Q,* Saga Y, Han L-B.* Chloroform-Based Atherton-Todd-Type Reactions of Alcohols and Thiols with Secondary Phosphine Oxides Generating Phosphinothioates and Phosphinates. RSC Advances, 2015, 5, 71544-71546.

[70] Chen T Q,* Tan Q, Liu L, Huang T, Han L-B.* Phosphorylation of Carboxylic Acids and Their Derivatives with P(O)–H Compounds Forming P(O)–C Bonds. Synthesis, 2020, 52, A-L.

[71] Chen T Q, Han L-B.* Optically Active H-Phosphinates and Their Stereospecific Transformations to Optically Active P-Stereogenic Organophosphoryl Compounds. Synlett, 2015, 26, 1153-1163.

[72] Huang T-Z, Chen T Q,* Saga Y, Han L-B.* Me3P-catalyzed addition of hydrogen phosphoryl compounds P(O)H to electron-deficient alkenes: 1 to 1 vs 1 to 2 adducts. Tetrahedron, 2017, 73, 7085-7093.

[73] Xu T, Zhou X, Han Y, Zhang L, Liu L, Huang T, Li C, Tang Z, Wan S,* Chen T Q.* Palladium-catalyzed stereo-selective three-component cis-1,2-arylalkynylation of bicyclic alkenes with aryltriflates and terminal alkynes. Tetrahedron Letters, 2022, 97, 153799.

[74] Liu L, Yu W-Q, Huang T, Chen T Q.* Palladium-catalyzed alkynylation of aromatic amines via in situ formed trimethylammonium salts. Tetrahedron Letters, 2020, 61, 151647.

[75] Liu L, Xu K, Wang Y, Wang W., Xu H, Huang T, Chen T Q.* Palladium-catalyzed phosphorylation of benzyl ammonium triflates with P(O)H compounds. Tetrahedron, 2020, 76, 131020.

[76] Yang J, Xiao J, Chen T Q,* Han L -B.* Nickel-Catalyzed Phosphorylation of Aryl Triflates with P(O)-H Compounds. Journal of Organometallic Chemistry, 2016, 820, 120-124.

[77] Chen T Q, Xiao J, Zhou Y B, Yin S F, Han L -B.* Nickel-Catalyzed (E)-Selective Semihydrogenation of Internal Alkynes with Hypophosphorous Acid. Journal of Organometallic Chemistry, 2014, 749: 51-54.

[78] Xiao J, Li Q, Chen T Q,* Han L -B.* Copper-Mediated Selective Aerobic Oxidative C3-Cyanation of Indoles with DMF. Tetrahedron Letters, 2015, 56, 5937-5940.

[79] Lei J,† Su L B,† Zeng K,† Chen T Q,† Qiu R H, Zhou Y B, Au C-T, Yin S F,* Recent advances of catalytic processes on the transformation of alkynes into functional compound. Chemical Engineering Science, 2017, 171, 404-425 (†:First co-author).

[80] Chen T Q, Zhou Y B, Guo C C,* Han L -B.* Selective Addition of P(O)-H Bonds to Alkynes Catalyzed by Transition Metals Immobilized on Polystyrene-Bound Triphenylphosphine. Chemistry Letters, 2013, 42, 1065-1067.

[81] Chen T Q, Zhou Y B, Yin S-F, Zhao Y L, Goto M, Han L -B.* Identification of Alkenyl and Arylpalladium Hydrides by the Aid of Hydrosilanes. Chemistry Letters, 2013, 42, 1227-1229.

[82] Yang J, Xiao J, Zhou Y B,* Chen T Q,* Yin S F, Han L-B.* Recent Advances in the Synthesis of Organophosphorus Compounds via Cross Coupling between Readily Available Materials and P-H Compounds. Chinese Journal of Organic Chemistry, 2017, 37, 1055-1068.

[83] Chen T Q, Liu L, Huang T, Han L-B. Synthesis and Reactivity of Group 10 Transition Metal Complexes with Alkenylphosphoryl Compounds. Chinese Journal of Organic Chemistry, 2019, 39, 2183-2187.

[84] Chen T Q, Han L-B.* Oxidative Addition of (RO)2P(O)H to Pt(0) Complexes Generating Pt-H Complexes: P(O)-H Bond Cleavage vs P(O-H) Bond Cleavage. Heteroatom Chemistry, 2018, e21460.

[85] Zhao Y L, Chen T Q,* Wang X B, Han L-B.* A Convenient Stereoselective Reduction of gem-Dibromides with a Combination of Dimethyl Phosphite and Potassium Carbonate. Phosphorus, Sulfur, and Silicon and the Related Elements, 2015, 190, 1820-1827.

 

其它论文列表(参与):

[1] Li Q, Chen T Q, Xu Q, Han L-B. Rhodium- and Iridium-Catalyzed Asymmetric Addition of Optically Pure P-Chiral H-Phosphinates to Aldehydes Leading to Optically Active α-Hydroxyphosphinates. Chemistry – A European Journal, 2016, 22, 6213–6217 (Highlighted in synfacts: synfacts, 2016, 12(07), 0710).

[2] Yoshimura A, Saga Y, Sato Y, Ogawa A, Chen T Q, Han L-B. An efficient base-catalyzed double addition of H-phosphine oxides to alkynes. Tetrahedron Letters, 2016, 57, 3382-3384.

[3] Sheng W-B, Chen T Q, Zhang M-Z, Tian M, Jiang G F, Guo C-C. Copper porphyrin-catalyzed aerobic oxidative coupling of terminal alkynes with high TON. Tetrahedron Letters, 2016, 57, 1641-1643.

[4] Zhou Y B, Li Z W, Yang X, Chen X L, Li M, Chen T Q, Yin S-F. Phosphorous Acid Promoted Hydration-Condensation of Aromatic Alkynes with Aldehydes Affording Chalcones in an Oil/Water Two-Phase System. Synthesis-Stuttgart, 2016, 48, 231-237.

[5] Xiong B Q, Feng X F, Zhu L Z, Chen T Q, Zhou Y B, Au C-T, Yin S-F. Direct Aerobic Oxidative Esterification and Arylation of P(O)-OH Compounds with Alcohols and Diaryliodonium Triflates. ACS Catalysis, 2015, 5, 537−543.

[6] Chen X L, Ji F Y, Zhao Y L, Liu Y X, Zhou Y B, Chen T Q, Yin S-F. Copper-Catalyzed Aerobic Oxidative C(aryl)-OH Bond Functionalization of Catechols with Amines Affording Benzoxazoles. Advanced Synthesis & Catalysis, 2015, 357: 2924-2930.

[7] Zhao Y L, Chen X L, Chen T Q, Zhou Y B, Yin S-F, Han L-B. Catalyst-Free and Selective C–N Bond Functionalization: Stereospecific Three-Component Coupling of Amines, Dichloromethane, and >P(O)H Species Affording α-Aminophosphorus Compounds. The Journal of Organic Chemistry, 2015, 80, 62–69.

[8] Li Q, Huang Y, Chen T Q, Zhou Y B, Xu Q, Yin S-F, Han L-B. Copper-Catalyzed Aerobic Oxidative Amination of sp3C–H Bonds: Efficient Synthesis of 2-Hetarylquinazolin-4(3H)-ones. Organic Letters, 2014, 16: 3672-3675.

[9] Cao H Y, Chen T Q, Zhou Y B, Han D-Q, Yin S-F, Han L-B. Copper-Catalyzed Selective Semihydrogenation of Terminal Alkynes with Hypophosphorous Acid. Advanced Synthesis & Catalysis, 2014, 536: 765-769(Inside cover).

[10] Chen X L, Chen T Q, Zhou Y B, Au C-T, Han L-B, Yin S-F. Efficient Synthesis of Propargylamines from Terminal Alkynes, Dichloromethane and Tertiary Amines over Silver Catalysts. Organic & Biomolecular Chemistry, 2014, 12: 247-250.

[11] Chen X L, Chen T Q, Zhou Y B, Han D Q, Han L-B, Yin S-F. Metal-free Aerobic Oxidative C–N Bond Cleavage of Tertiary Amines for the Synthesis of N-Heterocycles with High Atom Efficiency. Organic & Biomolecular Chemistry, 2014, 12: 3802-3807.

[12] Xiong B Q, Zhu L Z, Feng X F, Lei J, Chen T Q, Zhou Y B, Han L B, Au C T, Yin S-F. Direct Amidation of Carboxylic Acids with Tertiary Amines: Amide Formation over Copper Catalysts through C-N Bond Cleavage. European Journal of Organic Chemistry, 2014, 20: 4244-4247.

[13] Xiong B Q, Ye Q Q, Feng X F, Zhu L Z, Chen T Q, Zhou Y B, Au C T, Yin S-F. Base-promoted O-deprotonation/alkylation reaction of P(O)-OH compounds with alkyl halides. Tetrahedron, 2014, 70, 9057-9063.

[14] Chen X L, Chen T Q, Xiang Y Q, Zhou Y B, Han D Q, Han L-B, Yin S-F. Metal-Free Regioselective Hydrobromination of Alkynes through C-H/C-Br Activation. Tetrahedron Letters, 2014, 55: 4572-4575.

[15] Zhao Y L, Zhou Y B, Chen T Q, Yin S-F, Han L-B. Synthesis and molecular structure of tetranuclear Cu4P4 complexes with R2P–O–PR2 ligands. Inorganica Chimica Acta, 2014, 422: 36-39.

[16] Zhou Y B, Yang J, Chen T Q, Yin S-F, Han D Q, Han L-B. Stereospecific Aerobic Oxidative Dehydrocoupling of P(O)–H Bonds with Amines Catalyzed by Copper. Bulletin of the Chemical Society of Japan, 2014, 87: 400-402.

 

书籍:

1. Tieqiao Chen, Li-Biao Han, Oxidative Couplings with C-H Bonds Forming C-P and C-S Bonds, in Green Oxidation in Organic Synthesis, Ed.s Ning Jiao and Shannon S. Stahl, Wiley, Chichester, UK, 2019.

2. Tieqiao Chen, Chenglong Li, Li-Biao Han, Heteroatom—Heteroatom Bond Formation through Cross-Dehydrogenative Coupling. In Science of Synthesis: Cross-Dehydrogenative Coupling, Maiti, D., Ed.; Thieme: Stuttgart, (2023); Vol. 1, 521-549.

 

会议报告

[1] Chen T Q,酸/碘协同催化惰性酰胺的转氨化反应,精细化工国际学术研讨会,湖南,岳阳,2022.11.6-2022.11.10 (邀请报告).

[2] Chen T Q,立体选择性合成烯基磷化合物,第十届岭南有机化学论坛,广东,广州,2021.11.19-2021.11.22 (邀请报告).

[3] Chen T Q,脱氢策略合成有机磷化合物,中国化学会第32届学术年会,广东,珠海,2021.4.18-2021.4.22 (oral talk).

[4] Chen T Q, 脱氢策略合成有机磷化合物,海南大学人事处,海南,海口,2021.3.30 (Invited talk).

[5] Chen T Q,脱氢策略合成有机磷化合物,第二届热带海洋资源利用与绿色化工研讨会,海南大学,海南,海口,2020.02.20 (oral talk).

[6] Chen T Q,脱氢策略合成有机磷化合物,第三届中南有机化学论坛,海南师范大学,海南,海口,2019.11.09 (大会报告).

[7] Chen T Q过渡金属催化磷酸化:绿色合成有机磷化合物,第二届中南有机化学论坛,广西师范学院,广西化学化工学会,广西民族大学,南宁,中国,2018.11.09-2018.11.11 (invited talk).

[8] Chen T Q绿色合成有机磷化合物,第八届岭南有机化学论坛,广西师范大学,桂林,中国,2018.10.11-2018.10.13 (invited talk).

[9] Chen T Q, 基于Z-H键转化的绿色合成及其机理研究, 2017年海南省化学化工学科论坛与发展研讨会。海南师范大学,海口,中国, 2017.11.18-2017.11.19 (invited talk).

[10] Chen T Q, 过渡金属催化C-Z/P-HZ = O,S,CN)交叉偶联构建C-P键,第十一届全国磷化学化工学术讨论会. 武汉, 2017.10.21-2017.10.23 (invited talk). 

[11] Chen T Q, 过渡金属催化C-O键活化构建C-Z键,第十五届全国均相催化学术讨论会. 杭州, 2017.9.26-2017.9.29 (Oral Talk).

[12] Chen T Q. 过渡金属催化脱氢偶联反应合成有机磷化合物,一带一路绿色化学高端论坛,兰州,2017714-16 (Poster).

[13] Chen T Q, Yoshimura A, Han L-B. Ni-catalyzed C-O/Z-H cross coupling forming C-Z bonds. International Symposium on C-O activation (ISCO-2016). Himeji, Hyogo, Japan, 2016.10.25-2016.10.27 (Oral Talk).

[14] Chen T Q, Han L-B. Synthesis of organophosphorus compounds via metal-catalyzed dehydrogenative couplings. The 43rd Symposium on Main Group Element Chemistry. Sendai, Japan, 2016.12.08-2016.12.10 (Poster).

[15] Chen T Q. 基于Z-H键转化的绿色合成及其机理研究. 海南师范大学,海口,中国, 2016.10.15 (Oral Talk).

 

会议论文与专利列表

[1] 陈铁桥,付磊,袁拥军,胡伯羽,郭灿城. 活性有机胺促进的苯分子氧氧化羟基化的研究. 11届全国络合(均相)催化会议,湖南长沙:2009.10

[2] 陈铁桥,韩立彪. 羰基酸,零价过渡金属(镍,钯,铂)配合物与炔烃化学选择性的合成烯基金属配合物:甲酸选择性还原炔烃的机理研究. 中国化学会第28届学术年会,四川成都:2012.4

[3] 陈铁桥,韩立彪. 钯催化的高化学选择性的高价H-膦螺烷与炔烃的加成及其机理研究. 中国化学会第28届学术年会,四川成都:2012.4

[4] 黄庆,陈铁桥,刘向丹,曾旭,盛文兵,郭灿城. CoTPP的合成经验动力学研究. 11届全国络合(均相)催化会议. 湖南长沙:2009.10

[5] 刘向丹,黄庆,陈铁桥,盛文兵,郭灿城. MnClTPP的合成经验动力学研究. 11届全国络合(均相)催化会议. 湖南长沙:2009.10

[6] 尹双凤,陈铁桥,韩立彪,黄尧,周永波. 一种二级、三级芳香酰胺化合物的合成方法.发明专利,申请号:201410634539.2

[7] 尹双凤,韩立彪,陈铁桥,黄尧,周永波. 一种一级芳香酰胺化合物的合成方法. 发明专利,申请号:201410635839.2

[8] 郭灿城,罗伟平,陈铁桥,刘强. 四芳基卟啉的合成方法与设备. PCT. ZL 200910043414.1; WO 2010130065.

 

学术奖励

[1] 张继树,陈铁桥*,韩立彪*. 碱金属促进的sp3-氰键和sp3-磷键的连续断裂:肉桂腈与P(O)-H化合物的还原偶联. 15届全国均相催化学术讨论会. 杭州:2017,优秀墙报奖

[2] 刘敏,陈铁桥*,周永波,尹双凤*. 铜催化氮杂芳基甲烷与醇的氧气氧化直接酯化反应. 14届全国络合(均相)催化会议. 大连:2015,优秀墙报奖

[3] 黄庆,陈铁桥,刘向丹,曾旭,盛文兵,郭灿城*. CoTPP的合成经验动力学研究. 11届全国络合(均相)催化会议. 长沙:2009,优秀墙报奖

[4] 陈铁桥,尹双凤,韩立彪. 羧酸和第10族过渡金属配合物与炔烃的高立体和区域选择性氢金属化反应极其甲酸和炔烃的高选择性氢化反应. 2012年度湖南省化学化工学会优秀论文一等奖,2012-9. 颁奖单位:湖南省化学化工学会

[5] 沈如伟,陈铁桥,尹双凤. 羧酸和第10族过渡金属配合物与炔烃的高立体和区域选择性氢金属化反应及其甲酸和炔烃的高选择性氢化反应. 湖南省第14届自然科学优秀学术论文一等优秀论文,2012-9. 颁奖单位:湖南省科学技术厅

 

基金支持

[1] /碘协同催化惰性酰胺C-N键的活化与转化研究,22261015,国家自然科学基金,33万,2023-2026,主持。

[2] 过渡金属催化酰胺C-N键活化与官能团化反应的研究,21871070,国家自然科学基金,66万,2019-2022,主持。

[3] 过渡金属催化惰性C-O键官能团化反应及其机理研究,21403062,国家自然科学基金,26万,2015-2017,主持。

[4] 有机磷功能化学品的绿色制造,XTCX2022STA01,海南大学协同创新中心A类项目(海南省重大),海南省科技厅,400万,2023-2025,主持。

[5] 羧酸类药物的羧基改性与生物活性研究,ZDYF2020168,海南省重点研发计划,80万,2020-2022,主持。

[6] 过渡金属催化C-H/P-H键脱氢偶联构建C-P键的研究,2015JJ3039,湖南省自然科学基金青年基金,4万,2015-2017,主持。

[7] 利用过渡金属催化脱氢偶联策略构建P-Z键的研究,219MS005,海南省自然科学基金面上项目,10万,2019-2020,主持。

[8] 海南大学C类高层次人才引进经费,300+250万,主持。

[9] 过渡金属催化脱氢偶联反应构建P-Z键的研究,国家自然科学基金,67万,2016-2019,第一参与。

[10] 末端炔烃交叉偶联反应的精密控制及机理研究,国家自然科学基金,66万,2016-2019,第一参与。

[11] 基于“金属有机骨架体”的生物-化学催化体系的建立和催化串联反应性能研究,国家自然科学基金,66万,2016-2019,第一参与。