李春娅,副教授,2020年9月博士毕业于日本筑波大学,导师韩立彪教授,2020年11月入职海南大学化学工程与技术学院。
主要研究方向:主要从事有机磷化合物的新的合成方法及其机理的研究。以第一作者在期刊Green Chemistry发表论文1篇,The Journal of Organic Chemistry发表论文1篇,Organometallics发表论文1篇,Dalton Transactions发表论文1篇。
发表论文
[1]Chunya Li and Li-Biao Han*. Palladium-Catalyzed Solvent-Free Preparation of Arylphosphonates ArP(O)(OAr)2 from (ArO)3P via the Michaelis–Arbuzov Rearrangement. Organometallics, 2020, 39, 3613-3617.
[2]Chunya Li, Yuta Saga, Shun-ya Onozawa, Shu Kobayashi, Kazuhiko Sato, Norihisa Fukaya, and Li-Biao Han*. Wet and Dry Processes for the Selective Transformation of Phosphonates to Phosphonic Acids Catalyzed by Brønsted Acids. J. Org. Chem., 2020, doi.org/10.1021/acs.joc.0c00550.
[3]Chunya Li, Qi Wang, Jian-Qiu Zhang, Jingjing, Ye, Ju Xie, Qing Xu* and Li-Biao Han*. Water Determines the Products: an Unexpected Brønsted Acid-Catalyzed PO-R Cleavage of P(III) Esters Selectively Producing P(O)-H and P(O)-R Compounds. Green Chem., 2019, 21, 2916-2922.
[4]Chunya Li, Tieqiao Chen* and Li-Biao Han*. Iron-catalyzed clean dehydrogenative coupling of alcohols with P(O)-H compounds: a new protocol for ROH phosphorylation. Dalton Trans., 2016, 45, 14893-14897.
学术会议
1.Chunya Li, Li-Biao Han. Water Determines the Selectivity: Facile Room Temperature C-O Cleavage of P(III) Esters by Brønsted Acids Leading to a Mild and Efficient Halide-Free Michaelis–Arbuzov Rearrangement. 日本化学会第99春季年会, 2019.03.16-2019.03.19 (Oral Presentation).
2.Chunya Li, Li-Biao Han. Brønsted Acid-Catalyzed Hydrolysis of Phosphonates to Phosphonic Acids. 日本第46回有機典型元素化学討論会, 2019.12.05-2019.12.07 (Poster Presentation).
主持项目
1. 海南省自然科学基金高层次人才项目,立项,2022.01.01-2024.12.30, 10万元,主持。
2. 海南省自然科学基金青年基金项目,221QN173,2021.09-2024.06, 5万元,主持。
2. 海南大学科研启动基金项目,KYQD(ZR)-21051,2020.11-2025.11, 10万元,主持。