刘龙,副教授/硕士生导师,2017年博士毕业于湖南大学,导师周永波教授,2018年以“E类高层次人才”引进海南大学。
主要研究方向:涉及过渡金属催化、有机磷化学、惰性化学键活化等有机合成方法学的开发。以第一作者或共同第一作者在国际期刊Organic Letters, Advanced Synthesis & Catalysis, The Journal of Organic Chemistry, Tetrahedron, Tetrahedron Letters上发表系列论文,授权专利2件。
主持的基金项目:
3. 海南省自然科学基金青年基金,220QN180,起止年月:2020-2023,5万,主持;
2. 海南省自然科学基金高层次人才项目,2019RC028,起止年月:2020-2022,10万,主持;
1. 海南大学E类人才科研基金启动项目,KYQD(ZR)1857,起止年月:2018-2023,36万,主持;
硕士招生方向:化学工程;应用化学
邮箱:hainanliulong@hainanu.edu.cn; hunanliulong@163.com
一作或通讯论文
(19)Jie Tang, Zhiyou Li, Qi Meng, Long Liu*, Tianzeng Huang, Chunya Li, Qiang Li and Tieqiao Chen.* CuH-Catalyzed Reductive Coupling of Nitroarenes with Phosphine Oxides for the Direct Synthesis of Phosphamides. J. Org. Chem. 2024, doi:10.1021/acs.joc.4c00522
(18)Lin, Ying#; Ye, Changxu#; Zhou, Meng; Tang, Zhi;* Liu, Long;* Wang, Yuansheng; Wang, Lingling; Chen, Tieqiao.*Pd-Catalyzed ortho-C–H Arylation of Free Anilines with Arylboric Acids Forming o-Amino Biaryls, Organic & Biomolecular Chemistry, 2024, DOI: 10.1039/D4OB00020J.
(17) Mengjie Cen, Xi Yang, Shanshan Zhang, Liguang Gan, Long Liu* and Tieqiao Chen*. Synthesis of acyl fluorides through deoxyfluorination of carboxylic acids. Org. Biomol. Chem., 2023,21, 9372-9378.
(16)Qi Dang, Jiani Chen, Tianbao Li, Long Liu,* Tianzeng Huang, Chunya Li, and Tieqiao Chen*. Palladium-Catalyzed Decarbonylative Annulation of 2‑Arylbenzoic Acids with Internal Alkynes toward Phenanthrenes. The Journal of Organic Chemistry, 2023, doi: 10.1021/acs.joc.3c01077.
(15)Kuan Liu, Dexiang Ding, Weitao Xing, Long Liu,* Shuo Zhang, Qi Meng and Tieqiao Chen,* Palladium catalysed deaminative/decarboxylative cross-coupling of organoammonium salts with carboxylic acids, Org. Biomol. Chem., 2023, doi: 10.1039/D2OB02251F
(14)Kuan Liu, Bin Song, Qi Dang, Long Liu,* Jie Tang, Tianzeng Huang, Chunya Li, Zhi Tang and Tieqiao Chen.* Walking Cations: Transition-Metal Free Benzyl Cation-Triggered sp2 C-H Phosphorylation and Etherification, Chinese Journal of Chemistry, 2022, doi: 10.1002/cjoc.202200426.
(13) Tao Zhang, Runji Wang, Jiani Chen, Long Liu,* Tianzeng Huang, Chunya Li, Zhi Tang and Tieqiao Chen*, Base-promoted direct E-selective olefination of organoammonium salts with sulfones toward stilbenes and conjugated 1, 3-dienes. Org. Biomol. Chem., 2022, DOI: 10.1039/D2OB00716A.
(12) Tao Zhang, Kunyu Wang, Yuting Ke, Yuanyuan Tang, Long Liu,* Tianzeng Huang, Chunya Li, Zhi Tang and Tieqiao Chen.* Transition-metal-free and base promoted C–C bond formation via C–N bond cleavage of organoammonium salts. Org. Biomol. Chem., 2021, DOI: 10.1039/D1OB01468D.
(11) Yuanyuan Tang, Kuan Liu, Jinjin Zhang, Long Liu,* Tianzeng Huang, Chunya Li, Zhi Tang and Tieqiao Chen.* Palladium-Catalyzed Stereo-Selective Difunctionalization of Bicyclic Alkenes with Organoammonium Salts and Organoboronic Compounds. The Journal of Organic Chemistry, 2021, 86, 11937-11947.
(10)Long Liu, Yuanyuan Tang, Kunyu Wang, Tianzeng Huang, Tieqiao Chen.* Transition-Metal-Free and Base-Promoted Carbon-Heteroatom Bond Formation via C-N Cleavage of Benzyl Ammonium Salts. The Journal of Organic Chemistry, 2021, DOI: 10.1021/acs.joc.0c02992.
(9) Kaiqiang Xu,† Long Liu,† Zhaohui Li, Tianzeng Huang, Kang Xiang, Tieqiao Chen.* Controllable Phosphorylation of Thioesters: Selective Synthesis of Aryl and Benzyl Phosphoryl Compounds. The Journal of Organic Chemistry, 2020, 85, 14653-14663.
(8) Zhaohui Li,† Long Liu,† Kaiqiang Xu, Tianzeng Huang, Xinyi Li, Bin Song , and Tieqiao Chen* Palladium-Catalyzed N-Acylation of Tertiary Amines by Car-boxylic Acids: A Method for the Synthesis of Amides. Organic Letters, 2020, 22, 5517-5521.
(7) Hong Chen,† Long Liu,† Tianzeng Huang, Jing Chen,* Tieqiao Chen.* Direct Dehydrogenation for the Synthesis of α,β-Unsaturated Carbonyl Compounds. Advanced Synthesis & Catalysis, 2020, 362, 3332-3346.
(6) Long Liu, Wen-Qing Yu, Tianzeng Huang, Tieqiao Chen.* Palladium-Catalyzed Alkynylation of Aromatic Amines via in situ Formed Trimethylammonium Salts, Tetrahedron Letters, 2020, 61, 151647.
(5) Long Liu, Kaiqiang Xu, Yuan Wang, Wenqi Wang, Hanshuang Xu, Tianzeng Huang, Tieqiao Chen.* Palladium-Catalyzed Phosphorylation of Benzyl Ammonium Triflates with P(O)H Compounds, Tetrahedron, 2020, 76, 131020.
(4) Long Liu, Dan Zhou, Min Liu, Yongbo Zhou, Tieqiao Chen.* Palladium-Catalyzed Decarbonylative Alkynylation of Amides, Organic Letters, 2018, 20, 2741-2744.
(3) Long Liu, Liang-Wei Qian, Shaofeng Wu, Jianyu Dong,* Qing Xu, Yongbo Zhou,* Shuang-Feng Yin. Selective Aerobic C–H Amination of Phenols with Primary Amines over Copper toward Benzoxazoles, Organic Letters, 2017, 19, 2849-2852.
(2) Long Liu, Kang Sun, Xuyu Ji, Jianyu Dong,* Yongbo Zhou,* Shuang-Feng Yin. BF3-catalyzed Oxidative Tandem Annulation- aromatization of Naphthols with Terminal Aryl Alkenes, Tetrahedron, 2017, 73, 2698-2704.
(1) Long Liu, Xuyu Ji, Jianyu Dong,* Yongbo Zhou,* Shuang-Feng Yin. Metal-Free Oxidative Annulation of 2-Naphthols with Terminal Alkynes Affording 2-Arylnaphtho[2,1-b]furans, Organic Letters, 2016, 18, 3138-3141.
授权专利
(3) 刘龙,张涛,陈铁桥,黄添增,唐智,李春娅,一种E式内部烯烃类化合物的合成方法,2023,7,14,中国,ZL202210002836.X(授权)
(2) 周永波,刘龙,董建玉,尹双凤,一种N-芳基萘并呋喃酮亚胺类化合物及其合成方法,2021.7.20,中国,ZL201810600313.9(授权)
(1) 周永波,刘龙,冀旭宇,董建玉,尹双凤,韩立彪, 一种萘并呋喃类化合物的合成方法, 2017.6.20, 中国, ZL201510422479.2 (授权)