Dongxu Zuo,^ǁ Qun Wang,^ǁ Long Liu, Tianzeng Huang, Michal Szostak,* Tieqiao Chen,* Highly Chemoselective Transamidation of Unactivated Tertiary Amides by Electrophilic N–C(O) Activation via Amide-to-Acyl Iodide Re-Routing, Angew. Chem., Int. Ed., 2022, DOI: 10.1002/anie.202202794