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1997.09 - 2001.07 厦门大学化学系学习,获理学学士学位 2001.07 - 2009.08 中科院福建物构所工作(最后职称:助理研究员)、学习(导师:杨国昱研究员) 2002.09-2005.07 中科院福建物构所学习,获理学硕士学位 2006.09-2009.01 中科院福建物构所学习,获理学博士学位 2009.09-2013.05 美国加州州立大学长滩分校生化系博士后(导师:Prof.Xianhui Bu) 2013.06-至今 福州大学化学学院 教授 博士生导师

研究领域

主要从事簇基功能材料的结构化学基础研究

近期论文

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D.H. Li, X.Y. Zhang, J.Q. Lv, P.W. Cai, Y.Q. Sun, C. Sun*, S.T. Zheng*, Photo-Activating Biomimetic Polyoxomolybdate for Boosting Oxygen Evolution in Neutral Electrolytes, Angew. Chem. Int. Ed, 2023, 62, e202312706. D.H. Li, N. Shi, Y.J. Wang, P.W. Cai, Y.Q. Sun,* S.T. Zheng,* An organic–inorganic hybrid polyoxoniobate decorated by a Co(iii)-amine complex for electrocatalytic urea splitting, Inorg. Chem. Front., 2023, 10, 4789-4796. Y.J. Wang, L. Yu, Y.Q. Sun,* S.T. Zheng,* Two unprecedented germanoniobate frameworks based on high-nuclear peanut-shaped {Ge12Nb38} and {Ge14Nb38} clusters, Chem. Commun, 2023, in press. Z.W. Guo, Y. Chen, X.X. Li,* S.T. Zheng*, Precisely manipulation of core composition of core-shell-type cobalt polyoxoniobates and proton conduction study, Chin. Chem. Lett, 2023, in press. K.X. Lian, H.B. Chen, Y.D. Lin, X.X. Li,* S.T. Zheng,* Polyoxometalate-based all-inorganic open frameworks, Coord. Chem. Rev. 2023, 497(15), 215440. H. Yang, G. Yue, T. Li, L. Du, H. Li,* Z. Chen, S.T. Zheng,* The Old Polyoxometalates in New Application as Molecular Resistive Switching Memristors, Eur. J. Inorg. Chem, 2023, in press. Z.Y. Liu, J.P. Ye, Y.L. Li, Y.Q. Sun, X.X. Li, C. Sun,* S.T. Zheng,* Cadmium-containing windmill-like heteropolyoxoniobate macrocycle with high yield for catalyzing Knoevenagel condensation, Dalton Trans., 2023, 52, 1193. Y. Guan, H.B. Chen, R. Ge, Q.X. Zeng, P.W. Cai, C. Sun, Y.Q. Sun, X.X. Li*, S.T. Zheng,* Development of a New Heteropolyoxotantalate Cluster for Multidimensional Polyoxotantalate Mterials, Inorg. Chem, 2023, in press. Y.J. Wang, N. Shi, C. Sun, Y.Q. Sun* S.T. Zheng*, Reversible Thermochromism and Stable Resistance Switching Behaviors Based on a Co(III)-Complex-Linked Polyoxoniobate, Inorg. Chem, 2023, in press. G. Yuan, H.B. Chen, R. Ge, Q.X. Zeng, P.W. Cai, Y.Q. Sun, X.X. Li,* S.T. Zheng,* Development of a new heteropolyoxotantalate cluster for multi-dimensional polyoxotantalate materials, Chem. Commun, 2023, in press. Z.W. Guo, L.H. Lin, J.P. Ye, Y. Chen, X.X. Li, S. Lin,* J.D. Huang,* S.T. Zheng,* Core-Shell-Type All-Inorganic Heterometallic Nanoclusters: Record High-Nuclearity Cobalt Polyoxoniobates for Visible-Light-Driven Photocatalytic CO2 Reduction, Angew. Chem. Int. Ed, 2023, 62, e202305260. H. Yu, Y.D. Lin, S.L. Huang, X.X. Li, C. Sun,* S.T. Zheng,* Photochromic Polyoxoniobates with Photoinduced "D-f-A" Electron Transfer Mechanism, Angew. Chem. Int. Ed, 2023, 62, e202302111. Y. Yu, R.D. Lai, C. Sun, Y.Q. Sun, Q.X. Zeng, X.X. Li,* S.T. Zheng,* Oxalate-assisted assembly of two polyoxotantalate supramolecular frameworks with proton conduction property, Chem. Commun, 2023, 59, 3735. X.H. Zheng, B. Li, L.J. Shen, Y.N. Cao,* Y.Y. Zhan,* S.T. Zheng,* S.P. Wang, L.L. Jiang, Oxygen vacancies engineering of Fe doped LaCoO3 perovskite catalysts for efficient H2S selective oxidation, Applied Catalysis B: Environmental, 2023, 329, 122526. Y.L. Wang, Y.L. Wu, Q.X. Zeng,* X.X. Li,* S.T. Zheng, Two new inorganic-organic hybrid polyoxotantalates with proton conduction property, J. Solid. State. Chem, 2023, 322, 123943. Q.S Lai, X.X. Li*, S.T. Zheng,* All-inorganic POM cages and their assembly: a review, Coord. Chem. Rev. 2023, 482, 215077. B.W. X.X. Li,* S.T. Zheng,* J.P. Xie,* The first polyoxoniobate-templated silver cluster with temperature-dependent luminescent emission, Chem. Commun, 2023, 59, 2927-2930. Z.Y. J.P. Ye, C. Sun,* S.T. Zheng,* Liu Cadmium-containing Windmill-like Heteropolyoxoniobate Macrocycle with High Yield for Catalyzing Knoevenagel Condensation, Dalton, 2023, 52, 1193-1197. Y. Guan, H.P. Xiao, X.X. Li,* S.T. Zheng,* Recent advances on syntheses, structures and properties of polyoxotantalates, Polyoxometalate, 2023, accepted. P.X. Wu, Z.W. Guo, R.D. Lai, X.X. Li, C. Sun,* S.T. Zheng,* Giant Polyoxoniobate-Based Inorganic Molecular Tweezers: Metal Recognitions, Ion-Exchange Interactions and Mechanism Studies, Angew. Chem. Int. Ed, 2023, 62, e202217926. Z.K. Zhu, Y.Y. Lin, R.D. Lai, X.X. Li, Y.Q. Sun,* S.T. Zheng,* A series of high-nuclear planar equilateral triangle-shaped {Ln6(µ3-OH)6} cluster encapsulated polyoxoniobates with frequency dependent magnetic property, Chin. Chem. Lett, 2023, accepted. R.D. Lai, Z.K. Zhu, Y.L. Wu, Y.Q. Sun, S. Cai, X.X. Li,* S.T. Zheng,* Proton conductive polyoxometalate architectures constructed from lanthanide-incorporated polyoxoniobate cages, Inorg. Chem, 2023, in press. R.D. Lai, H.L. Feng, Y.Q. Sun,* X.X. Li, S.T. Zheng,* A lanthanide–tellurium heterometal encapsulated sandwich-type heteropolyoxoniobate with a 3D pcu-type hydrogen-bonded network, Dalton Trans, 2022, 51, 10571-10577. J.X. Jing, N. Shi, Y.Q. Sun,∗ X.X. Li, S.T. Zheng,* An inorganic-organic hybrid polyoxotungstogermanate based on [Ln( α-GeW11O39)2] dimer and dimethylammonium: Synthesis, crystal structure and photoluminescence property, J. Mol. Struct, 2022, 1250, 131686. R.D. Lai, J. Zhang, X.X. Li,* S.T. Zheng,* G.Y. Yang,* Assemblies of Increasingly Large Ln-Containing Polyoxoniobates and Intermolecular Aggregation-Disaggregation Interconversions, J. Am. Chem. Soc, 2022, 144, 19603-19610. H.P. Xiao, Y.S. Hao, X.X. Li,* P. Xu,* M.D. Huang, S.T. Zheng,* A Water-Soluble Antimony-Rich Polyoxometalate with Broad-Spectrum Antitumor Activities, Angew. Chem. Int. Ed, 2022, 61, e202210019. 陈慧娜,李新雄*,郑寿添*, 铌多酸三维框架材料的研究进展与展望, 高等学校化学学报, 2022, 43, 20210625. B.Q. Hong, Y.j. Qi, R.D. Lai, R. Ge, S.T. Zheng, X.X. Li*, Two luminescent metal-organic frameworks with temperature-dependent emission, J. Solid State Chem, 2022, 309, 122967. H. Yu, Y.D. Lin, Z.Y. Liu, Y.Q. Sun,* S.T. Zheng,* A 3D Indium-containing Polyoxoniobate Framework Based on {In5Nb71}n Helical Pillars, Inorg. Chem, 2022, 61, 8112-8116. S. Peng, Y. Li, R. Ge, W.X. Chen, T.Y. Wang, X.X Li,* S.T. Zheng,* Designed assembly of heterometallic zeolite-like framework materials from two different superteteahedral metal clusters, Chem. Commun, 2022, 6789-6792. Y. Li, Y.D. Yang, R. Ge, Z.H Lv, C.B Tian, B.W. Wei, X.X. Li,* N.F. Zhuang,* S.T. Zheng,* A stable 3d-4f heterometallic cluster with magneto-optical activity, Inorg. Chem, 2022, 8746-8751. M.Y. Yao, Y.F. Liu, X.X. Li,* G.P. Yang,* S.T. Zheng,* The largest Se-4f cluster incorporated polyoxometalate with high Lewis acid-base catalytic activity, Chem. Commun, 2022, 5737-5740. Y. L. Wu, Y. J. Wang, Y. Q. Sun,* X. X. Li, S. T. Zheng*, Two high-nuclearity isopolyoxoniobates containing {Nb54O151}-based helical nanotubes for the decomposition of chemical warfare agent simulants, Chem. Commun, 2022, 58, 3322-3325. Z.K. Zhu, J. Zhang, Y.C. Cong, R. Ge, Z. Li, X.X. Li*, S.T. Zheng*, Two Giant Calixarene-Like Polyoxoniobate Nanocups {Cu12Nb120} and {Cd16Nb128} Built From Mixed Macrocyclic Cluster Motifs, Angew. Chem. Int. Ed, 2022, 61, e202113381. Z. Li, Z.H. Lv, H. Yu, Y.Q. Sun, X.X. Li,* S.T. Zheng*, Giant Ln30-Cluster Embedded Polyoxotungstate Nanoclusters with Exceptional Proton-Conducting and Luminescent Properties, CCS Chem, 2022, 4, 2938-2945. Z.Y. Liu, Y.D. Lin, H. Yu, H.N. Chen, Z.W. Guo, X.X. Li,* S.T. Zheng,* Recent advances in polyoxoniobate-catalyzed reactions, Tungsten, 2022, 4, 81-98. Y. Chen, Z.W Guo, X.X Li, S.T. Zheng,* G.Y. Yang,* Multicomponent Cooperative Assembly of Nanoscale Boron-Rich Polyoxotungstates with 22 and 30 Boron Atoms, CCS Chem, 2022, 4, 1305-1314. S. Peng, Y.J. Qi, X.H. Li, C. Sun, L.Y. Li, X.X. Li,* S.T. Zheng, Q. Zhang *, Two isomeric zeolite-like metal–organic frameworks with mechanically responsive luminescence emission and gas adsorption properties, CrystEngComm, 2021, 23, 5753–5757. N. Shi, Y.J. Wang, X.X. Li, Y.Q. Sun,* S.T. Zheng,* An inorganic Co-containing heteropolyoxoniobate: reversible chemochromism and H2O-dependent proton conductivity properties, Inorg. Chem. Front, 2021, 8, 5225–5233. Z.H. Zhong, J.X. Jing, X.X. Li, Y.Q. Sun,* S.T. Zheng, Two new 3D tubular polyoxoniobates frameworks based on {SiNb18O54} clusters with proton conduction properties, Inorg. Chem. Commun, 2021, 2021,132,108813. Y. D. Lin, R. Ge, C.B. Tian, C. Sun, Y.Q. Sun, Q.X. Zeng,* X.X. Li*, S.T. Zheng, 3d–4f Heterometallic cluster incorporated polyoxoniobates with magnetic properties, Chem. Commun., 2021, 57, 8624. R. Ge, J. H. Liu, X.H. Li, L. Li, Y.G. Sun, Z. Li, X.X. Li*, S.T. Zheng*, Luminescent cluster-organic frameworks constructed from predesigned supertetrahedral {Ln4Zn6} secondary building units, Chem. Commun, 2021, 6927. Y.R. Huang, X.L. Lin, B. Chen, H.D. Zheng, Z.R. Chen, H.H. Li*, S.T. Zheng*, Thermal-Responsive Polyoxometalate-Metalloviologen Hybrid: Reversible Intermolecular Three-Component Reaction andTemperature-Regulated Resistive Switching Behaviors, Angew. Chem. Int. Ed, 2021, 60, 16911. Y.L. Wu, Z.H. Zhong, P.X. Wu, X.X. Li, Y.Q. Sun*, S.T. Zheng*, A Peanut-like Sb-embedded Polyoxoniobate Cage with Hydrolytic Decomposition for Chemical Warfare Agent, Eur. J. Inorg. Chem, 2021, 1051. P.X. Wu, R.D. Lai, R. Ge, C. Sun, G.Q. Wang, X.X. Li*, S.T. Zheng*, A Tellurium-Substituted Heteropolyniobate with Unique π-π Stacking and Ionic Conduction Property, Inorg. Chem, 2021, 2021, 60, 6162–6166. Y.D. Lin, Z.K Zhu, R. Ge, H. Yu, Z. Li, C. Sun, Y.Q. Sun, X.X. Li*, S.T. Zheng*, Pronton conductive polyoxoniobate frameworks constructed from nanoscale {Nb68O200} cages, Chem. Commun, 2021, 2021, 57, 4702-4705. R.T. Zhang, H.P. Xiao, Z. Li, M. Wang, Y.F. Xie, Y.D. Ye, X.X Li,* S.T. Zheng*, Two highly stable inorganic-organic hybrid 3-D frameworks based on Cu–Ln incorporated polyoxometalates for selective dye removal and proton conduction, CrystEngComm, 2021, 23, 2973. G. Rui, X.X. Li*, S.T. Zheng*, Advances in polyoxometalate-templated high-nuclear silver clusters, Coord. Chem. Rev. 2021, 435, 213787. Y. Chen, Z.W. Guo, X.X. Li*, S.T. Zheng*, Two novel nickel cluster substituted polyoxometalates: syntheses, structures and their photocatalytic activities, magnetic behaviors, and ion-conduction properties, Inorg. Chem. Front, 2021, 8, 1303. X.X. Li, S.T. Zheng,* Three-dimensional metal-halide open frameworks, Coord. Chem. Rev. 2021, 430, 213663. Z.K. Zhu, Y.Y. Lin, X.X. Li, D. Zhao*, S.T. Zheng*, Integration of Metallacycles and Polyoxometalate Macrocycles, Inorg. Chem. Front, 2021, 8, 1297. Y.L. Wu, Y.Q. Sun*, X.X. Li, S.T. Zheng*, A new dimeric isopolyoxoniobate {β-H4Nb52O150} decorated with copper (II)-ethylenediamine for hydrolytic decomposition of chemical warfare agent simulant DMMP, Inorg. Chem. Commun, 2020, 113, 107815. Y.L. Wu, R.T. Zhang, Y.Q. Sun,* X.X. Li, S.T. Zheng,* A series of cube-shaped polyoxoniobates encapsulating octahedral Cu12XmOn clusters with hydrolytic decomposition for chemical warfare agents, Frontiers in Chemistry, 2020, 586009. S.Y. Wu, Y.J. Wang, J.X. Jing, X.X. Li, Y.Q. Sun*, S.T. Zheng* Two organic–inorganic hybrid polyoxotungstoger manates containing organic ligand chelated Fe–Dy heterometallic clusters and frequency dependent magnetic properties, Inorg. Chem. Front., 2020, 7, 498-504. Y. Dong, Q. Han, K. Ma, F. Song, S.T. Zheng, Y. Ding,* Study two kind different catalytic behaviors for K4H1.2[Co0.6(H2O)0.6SiW11.4O39.4]-cocatalyzed visible light driven water oxidation in pH 1–7 media, Journal of Catalysis, 2020, 392, 29-38. J.H. Liu, J. Zhang, D. Zhao, L.D. Lin, Y.Q. Sun, X.X. Li.* S.T. Zheng,* Incorporation of Heterovalent Copper-Oxo and Copper-Halide Clusters for Fabrication of Three Porous Cluster Organic Frameworks: Syntheses, Structures and Iodine Adsorption/Release Study, Crystengcomm. 2020, 22, 821-828. J. Zhang, R.D. Lai, Y.L. Wu, Z.K. Zhu, Y.Q. Sun, Z.Q. Xing*, X.X. Li,* S.T. Zheng, High-dimensional Polyoxoniobates Constructed From Lanthanide-incorporated High-nuclear {[Ln(H2O)4]3[Nb24O69(H2O)3]2} Secondary Building Units, Chem. Asian J. 2020, 15, 1574. J.H. Liu, L.D. Lin, G.Q. Wang, L.Y. Li, Y.Q. Sun, X.X. Li,* S.T. Zheng,* All-inorganic open frameworks based on gigantic four-shell Ln@W8@Ln8@(SiW12)6 clusters, Chem. Commun., 2020, 56, 10305-10308. Y.Y. Lin, J. Zhang, Z.K. Zhu, Y.L. Wu, Y.Q. Sun, X.X. Li*, S.T. Zheng, An ultrastable {SiNb18O54}-based hybrid polyoxoniobate framework for selective removal of crystal violet from aqueous solution and proton-conduction, Inorg. Chem. Commun, 2020, 113, 107766. Z.K. Zhu, L.D. Lin, J. Zhang, X.X. Li, Y.Q. Sun,* S.T. Zheng,* A rare 4-connected a neb-typed 3D chiral polyoxometalate framework based on {KNb24O72} cluster, Inorg. Chem. Front, 2020, 7, 3919. Z.K. Zhu, Y.Y. Lin, L.D. Lin, X.X. Li, Y.Q. Sun,* S.T. Zheng,* A Rare 3D Porous Inorganic-Organic Hybrid Polyoxometalate Framework Based on Cubic Polyoxoniobate-Cupric-Complex Cage with High Water Vapor Adsorption Capacity, Inorg. Chem. 2020, 59(17), 11925-11929.

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