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研究领域

太阳能催化水氧化,杂环化学和有机合成研究 1.有机合成方法学及其在功能分子构建中的应用; 2.与光系统II相关的释氧中心的化学模拟, Porphyrins 与Corroles金属络合物的研究; 3.含硫过渡金属络合物的研究, 氢酶活性中心的化学模拟; 4.精细化工产品的合成 (药物及其中间体, 农药, 染料和发光材料等).

近期论文

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Gerald Dyker, Dirk Hildebrandt, Jianhui Liu, Klaus MerzDomino Process with Isobenzopyrylium cation Intermediate Angew. Chem., Int. Ed. 2003, 42, 4399-4402 Xien Liu, Jianhui Liu, Kun Jin, Xichuan Yang, Qinji Peng, Licheng Sun Synthesis, Characterization and Some Properties of amide-linked Porphyrin-ruthenium(II) Tris(bipyridine) Cmplexes Tetrahedron 2005, 61, 5655-5662 Shi Jiang, Jianhui Liu, Licheng SunA furan-containing diiron azadithiolate hexacarbonyl complex with unusual lower catalytic proton reduction potential Inorg. Chem. Commun. 2006, 9(3), 290-2 Weiming Gao, Jianhui Liu, Changneng Chen, Linhong Weng, Kun Jin, Bjorn Akermark, Licheng Sun Synthesis, structures and electrochemistry properties of amino-derivatives of diiron azadithiolates as active site models of Fe-only hydrogenase Inorg. Chim. Acta 2006, 359, 1071-1080 Xien Liu, Jianhui Liu, Jingxi Pan, Ruikui Chen, Yong Na, Weiming Gao, Licheng SunA Novel Ruthenium(II) Tris(bipyridine)-Zinc Porphyrin-Rhenium Carbonyl Triad: Synthesis and Optical Properties Tetrahedron 2006, 62, 3674-3680 Wei Zhang, Jianhui Liu, Kun Jin, Licheng SunSynthesis of Some New 4-Substituted-3, 5-Bis(2-Pyridyl)-1H-PyrazoleJ. Heterocyclic Chem. 2006, 43, 1669-1672 Minna Li, Jianhui Liu, Changzhi Zhao, Licheng SunAryl-Diamide Centered Binuclear Ruthenium (II) tris(bipyridine) Complexes: Synthesis, Photophysical, Electrochemical and Electrochemiluminescence Properties J. Organomet. Chem. 2006, 691, 4189-4195 Weiming Gao, Jianhui Liu, Bjorn Akermark, Licheng SunBidentate phosphine ligand based Fe2S2-containing macromolecules: synthesis, characterization, and catalytic electrochemical hydrogen production Inorg. Chem., 2006, 45, 9169-9171 Yan Gao, Jianhui Liu, Mei Wang, Yong Na, Bjorn Akermark, Licheng SunManganese corrole complexes as catalysts for water oxidationJ. Porphyrins Phthalocyanines, 2006, 10, 403 Jianhui Liu, Enrico Muth, Ulrich Flke, Gerald Henkel, Klaus Merz, Janelle Sauvageau, Erik Schwake, Gerald DykerAlkylation of Arenes with Benzylic and Propargylic Alcohols -- Classical versus Fancy CatalystsAdv. Synth. Catal. 2006, 348, 456-462 Shi Jiang, Jianhui Liu, Yu Shi, Zhen Wang, Bjorn Akermark, Licheng SunPreparation, Characteristics and Crystal Structures of Novel N-Heterocyclic Carbene Substituted Furan- and Pyridine-Containing Azadithiolate Fe-S Complexes Polyhedron 2007, 26(7), 1499-1504 Yan Gao, Jianhui Liu, Mei Wang, Yong Na, Bjorn Akermark, Licheng SunSynthesis and characterization of manganese and copper corrole xanthene complexes as catalysts for water oxidation Tetrahedron 2007, 63, 1987 Zhen Wang, Jianhui Liu, Chengjiang He, Shi Jiang, Bjorn Akermark, Licheng SunDiiron Azadithiolates with Hydrophilic Phosphatriaza-adamantane Ligand as Iron-Only Hydrogenase Active Site Models: Synthesis, Structure, and Electrochemical Study Inorg. Chim. Acta 2006, 360, 2411-2419 Weiming Gao, Jianhui Liu, Bjorn Akermark, Licheng SunFacile and Highly Efficient Light-induced PR3/CO Ligand Exchange: A Novel Approach to the Synthesis of [(μ-SCH2NnPrCH2S)Fe2(CO)4(PR3)2]J. Organomet. Chem. 2007, 692, 1579-1583 Weiming Gao, Jesper Ekstrom, Jianhui Liu, Changneng Chen, Lars Eriksson, Linhong Weng, Bjorn Akermark, Licheng SunBinuclear Iron-Sulfur Complexes with Bidentate Phosphine Ligands as Active Site Models of Fe-Hydrogenase and Their Catalytic Proton ReductionInorg. Chem., 2007, 46, 1981-1991 Shi Jiang,Jianhui Liu, Yu Shi,Zhen Wang, Bjorn Akermark, Licheng SunFe-S complexes containing five-membered heterocycles: novel models for the active site of hydrogenases with unusual low reduction potentialDalton Trans., 2007, 896-902 Ming Xia, Jianhui Liu, Yan Gao, Bjorn Akermark, Licheng SunSynthesis, and Photophysical and Electrochemical Study of Tyrosine Covalently Linked to High Valent Copper (III) and Manganese (IV) ComplexesHelv. Chim. Acta, 2007, 90, 553-561

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