Hock, Adam S. - Illinois Institute of Technology

个人简介

B.S. University of Delaware Ph.D. Massachusetts Institute of Technology

研究领域

Our research interests include solar energy conversion, catalysis, electronic materials, and chemical structure and bonding. Within this context we focus on developing rational synthetic methods to prepare earth-abundant and inexpensive materials for photon capture, innovative homogeneous and heterogeneous catalysts, and unique reactivity models. We conduct highly collaborative research through our affiliation with Argonne National Laboratory. Students in the Hock group will learn to synthesize and characterize novel substances throughout the course of their research. We routinely use techniques such as multi-nuclear NMR, UV-Vis spectroscopy, FTIR spectroscopy, and x-ray crystallography to characterize molecular substances. The composition and properties of new materials are routinely determined by Rutherford Backscattering Spectroscopy (RBS), Scanning and Tunneling Electron Microscopy (SEM & TEM), and diffraction methods as well as optical, electrical, and other measurements where appropriate.

近期论文

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Hu, B.; “Bean” Getsoian, A.; Schweitzer, N. M.; Das, U.; Kim, H.; Niklas, J.; Poluektov, O.; Curtiss, L. A.; Stair, P. C.; Miller, J. T.; Hock, A. S. Selective propane dehydrogenation with single-site CoII on SiO2 by a non-redox mechanism. Journal of Catalysis, 2015, 322, 24. Kraft, S. J.; Zhang, G.; Childers, D.; Dogan, F.; Miller, J. T.; Nguyen, S. T.; Hock, A. S. Rhodium Catechol Containing Porous Organic Polymers: Defined Catalysis for Single-Site and Supported Nanoparticulate Materials. Organometallics 2014, 33, 2517. Krogman, J. P.; Gallagher, J. R.; Zhang, G.; Hock, A. S.; Miller, J. T.; Thomas, C. M. Assignment of the oxidation states of Zr and Co in a highly reactive heterobimetallic Zr/Co complex using X-ray absorption spectroscopy (XANES) Dalton Transactions 2014, 43, 13852. Tanabe, K. K.; Ferrandon, M. S.; Siladke, N. A.; Kraft, S. J.; Zhang, G.; Niklas, J.; Poluektov, O. G.; Lopykinski, S. J.; Bunel, E. E.; Krause, T. R.; Miller, J. T.; Hock, A. S.; Nguyen, S.T. Discovery of Highly Selective Alkyne Semihydrogenation Catalysts Based on First-Row Transition-Metallated Porous Organic Polymers. Angewandte Chemie International Edition 2014, 53, 12055. McCarthy, R. F.; Weimer, M. S.; Emery, J. D.; Hock, A. S.; Martinson, A. B. F. Oxygen-Free Atomic Layer Deposition of Indium Sulfide. ACS Applied Materials and Interfaces 2014, 6, 12137. Kim, S. B.; Sinsermsuksakul, P.; Hock, A. S.; Pike, R. D.; Gordon, R. G. Synthesis of N-Heterocyclic Stannylene (Sn(II)) and Germylene (Ge(II)) and a Sn(II) Amidinate and Their Application as Precursors for Atomic Layer Deposition. Chemistry of Materials 2014, 26, 3065. Schweitzer, N. M.; Hu, B.; Das, U.; Kim, H.; Greeley, J.; Curtiss, L. A.; Stair, P. C.; Miller, J. T.*; Hock, A. S.*, Propylene Hydrogenation and Propane Dehydrogenation by a Single-Site Zn2+ on Silica Catalyst. ACS Catalysis 2014, 4 (4), 1091-1092. Riha, S. C.; Racowski, J. M.; Lanci, M. P.; Klug, J. A.; Hock, A. S.*; Martinson, A. B. F.* Phase discrimination through oxidant selection in low-temperature atomic layer deposition of crystalline iron oxides. Langmuir. 2013, 29, 3439. Kraft, S. J.; Sánchez, R. H.; Hock, A. S.* A Remarkably Active Iron Catecholate Catalyst Immobilized in a Porous Organic Polymer. ACS Catalysis. 2013, 3, 826. Kraft, S. J.; Hu, B.; Zhang, G.; Miller, J. T.; Hock, A. S.* In Situ X-ray Absorption Spectroscopy and Nonclassical Catalytic Hydrogenation with an Iron(II) Catecholate Immobilized on a Porous Organic Polymer. European Journal of Inorganic Chemistry. Special Issue on Small Molecule Activation 2013, 2013, 3972. Sinsermsuksakul, P.; Heo, J.; Noh, W.; Hock, A. S.; Gordon, R. G. Atomic Layer Deposition of Tin Monosulfide Thin Films. Advanced Energy Materials. 2011, 1, 1116. Heo, J.; Hock, A. S.; Gordon, R. G. Low Temperature Atomic Layer Deposition of Tin Oxide. Chemistry of Materials. 2010, 22, 4964. Marinescu, S. C.; Singh, R.; Hock, A. S.; Wampler, K. M.; Schrock, R. R.; Mu¨ller, P. Syntheses and Structures of Molybdenum Imido Alkylidene Pyrrolide and Indolide Complexes. Organometallics. 2008, 27, 6570. Wampler, K. M.; Schrock, R. R.; Hock, A. S. Synthesis of Molybdenum Imido Alkylidene Complexes That Contain Siloxides. Organometallics. 2007, 26, 6674. Hock, A. S.; Schrock, R. R. Oxidative Reactions of the MoIV Dialkyl Complex [{(3-CF3C6H4NCH2CH2)2NMe}Mo(CH2SiMe3)2]. Chemistry – An Asian Journal. 2007, 2, 867. Blanc, F.; Thivolle-Cazat, J.; Basset, J.-M.; Copéret, C.; Hock, A. S.; Tonzetich, Z. J.; Schrock, R. R. Highly Active, Stable, and Selective Well-Defined Silica Supported Mo Imido Olefin Metathesis Catalysts. J Am Chem Soc. 2007, 129, 1044. Weare, W. W.; Schrock, R. R.; Hock, A. S.; Müller, P. Synthesis of Molybdenum Complexes that Contain “Hybrid” Triamidoamine Ligands, [(Hexaisopropylterphenyl-NCH2CH2)2NCH2CH2N-aryl]3-, and Studies Relevant to Catalytic Reduction of Dinitrogen. Inorganic Chemistry. 2006, 45, 9185. Sinha, A.; Lopez, L. P. H.; Schrock, R. R.; Hock, A. S.; Müller, P. Reactions of M(N-2,6-i-Pr2C6H3)(CHR)(CH2R‘)2 (M = Mo, W) Complexes with Alcohols To Give Olefin Metathesis Catalysts of the Type M(N-2,6-i-Pr2C6H3)(CHR)(CH2R‘)(OR‘?‘). Organometallics. 2006, 25, 1412. Tonzetich, Z. J.; Schrock, R. R.; Hock, A. S.; Müller, P. Synthesis, Characterization, and Activation of Zirconium and Hafnium Dialkyl Complexes that Contain a C2-Symmetric Diaminobinaphthyl Dipyridine Ligand. Organometallics. 2005, 24, 3335. Schrock, R. R.; Gabert, A. J.; Singh, R.; Hock, A. S. Synthesis of High Oxidation State Bimetallic Alkylidene Complexes for Controlled ROMP Synthesis of Triblock Copolymers. Organometallics. 2005, 24, 5058.