个人简介

Education Ph.D The University of Western Ontario, Canada 2011 B.S. Mount Allison University, Canada 2007 Postdoctoral Fellow University of California, Riverside 2011-2012 Postdoctoral Fellow University of California, San Diego 2012-2013 Experience Assistant Professor Baylor University 2013-present

研究领域

Synthetic Main Group Chemistry

Research in the Martin group is focused on understanding new fundamental structure and bonding for boron. Carbon, boron�s neighbor is the most widely studied element while boron, in comparison is neglected. Despite this, boron is useful in a variety of areas and materials. Our research is focused on developing new bonding arrangements around the boron center and subsequently exploring the chemistry of these novel compounds. The desired compounds will have interesting properties and be examined for their utility in optoelectronics, Lewis acid mediated catalysis and small molecule activation reactions. Although our research is primarily focused on the p-block, organic and organometallic chemistry is a major component of our research. Students in the group will become experts in air/moisture sensitive manipulations specifically in glove box and Schlenk techniques. The characterization methods students will be exposed to include Multinuclear NMR Spectroscopy (1H, 11B, 13C, 31P), X-Ray Crystallography, Mass Spectrometry, as well as FT-IR and UV-Vis Spectroscopy.

近期论文

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“Ring Expansion Reactions of Pentaphenylborole with Dipolar Molecules as a Route to Seven-Membered Boron Heterocycles” Kexuan Huang and Caleb D. Martin*, Inorg. Chem., 2015, 54, 1869-1875. Link “Investigating the Ring Expansion Reaction of Pentaphenylborole and an Azide” Shannon A. Couchman, Trevor K. Thompson, David J. D. Wilson, Jason L. Dutton and Caleb D. Martin*, Chem. Commun., 2014, 11724-11726. Link “Cross-Coupling Reactions Between Stable Carbenes” Cory M. Weinstein, Caleb D. Martin, Liu Liu and Guy Bertrand, Angew. Chem. Int. Ed., 2014, 53, 6550-6553. “Carbene-stabilized main group radicals and radical ions” Caleb D. Martin, Michele Soleilhavoup and Guy Bertrand, Chem. Sci., 2013, 4, 3020-3030. “Exploring the reactivity of white phosphorus with electrophilic carbenes: synthesis of a P4 cage and P8 clusters” Caleb D. Martin, Cory M. Weinstein, Curtis E. Moore, Arnold L. Rheingold and Guy Bertrand, Chem. Commun., 2013, 49, 4486-4488. “31P NMR Chemical Shifts of Carbene-Phosphinidene Adducts as an Indicator of the π-Accepting Properties of Carbenes” Olivier Back, Martin Henry-Ellinger, Caleb D. Martin, David Martin and Guy Bertrand, Angew. Chem. Int. Ed., 2013, 52, 2939-2943. “Reactions of Diiminopyridine Ligands with Chalcogen Halides” Caleb D. Martinand Paul J. Ragogna, Inorg. Chem., 2012, 51, 2947-2953. “Substitution Matters: Isolating Phosphorus Diiminopyridine Complexes” Caleb D. Martin and Paul J. Ragogna, Dalton Trans., 2011, 40, 11976-11980. “Synthesis and Reactivity of Sulfur(II) Dications Stabilized Using Monodentate Ligands” Caleb D. Martin and Paul J. Ragogna, Inorg. Chem., 2010, 49, 8164-8172. “Reactions of -Diimine Ligands with the In Situ Generated “S(OTf)2” Synthon” Caleb D. Martin and Paul J. Ragogna, Inorg. Chem., 2010, 49, 4324-4330. “Remarkably stable chalcogen(II) dications” Caleb D. Martin, Christine M. Le and Paul J. Ragogna, J. Am. Chem. Soc., 2009, 131, 15126-15127. “Dicationic Sulfur Analogues of the N-Heterocyclic Silylene or Phosphenium cation” Caleb D. Martin, Michael J. Ferguson, Michael C. Jennings and Paul J. Ragogna, Angew. Chem. Int. Ed., 2009, 48, 2210-2213.