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Chemistry/Organic and Inorganic Synthesis

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Danielle Tokarz, Richard Cisek, Omar El-Ansari, George S. Espie, Ulrich Fekl, Virginijus Barzda. 'Organization of Astaxanthin within Oil Bodies of Haematococcus pluvialis Studied with Polarization-Dependent Harmonic Generation Microscopy'. PLOS ONE 2014, 9, e107804. Danielle Tokarz, Richard Cisek, Serguei Krouglov, Lukas Kontenis, Ulrich Fekl and Virginijus Barzda. 'Molecular Organization of Crystalline β-carotene in Carrots Determined with Polarization Dependent Second and Third Harmonic Generation Microscopy'. J. Phys. Chem. B 2014, 118, 3814-3822. Danielle Tokarz, Richard Cisek, Ulrich Fekl and Virginijus Barzda. 'The Molecular Second Hyperpolarizability of the Light-Harvesting Chlorophyll a/b Pigment-Protein Complex of Photosystem II'. J. Phys. Chem. B 2013, 177, 11069–11075. Margaret L. Scheuermann, Avery T. Luedtke, Susan K. Hanson, Ulrich Fekl, Werner Kaminsky, and Karen I. Goldberg. 'Reactions of Five-Coordinate Platinum(IV) Complexes with Molecular Oxygen'. Organometallics 2013, 32, 4752–4758. Li Dang, Mohamed F. Shibl, Xinzheng Yang, Daniel J. Harrison, Aiman Alak, Alan J. Lough, Ulrich Fekl, Edward N. Brothers, Michael B. Hall. 'Apparent Anti-Woodward-Hoffmann Addition to a Nickel Bis(dithiolene) Complex: The Reaction Mechanism Involves Reduced, Dimetallic Intermediates'. . Inorg. Chem. 2013, 52, 3711–3723. Danielle Tokarz, Richard Cisek, Nicole Prent, Ulrich Fekl and Virginijus Barzda. 'Measuring Molecular Second Hyperpolarizability in Absorptive Solution by the Third Harmonic Generation Ratio Technique', Analyt. Chim. Acta 2012, 755, 86–92. Danielle Tokarz, Richard Cisek, Martyna Garbaczewska, Daaf Sandkuijl, Xinping Qiu, Bryan Stewart, Joel D. Levine, Ulrich Fekl and Virginijus Barzda. 'Carotenoid based bio-compatible labels for third harmonic generation microscopy'. PCCP 2012, 14, 10653–10661. Neilson Nguyen, Alan J. Lough and Ulrich Fekl. 'Rapid, Covalent Addition of Phosphine to Dithiolene in a Molybdenum Tris(dithiolene). A New Structural Model for Dimethyl Sulfoxide Reductase'. Inorg. Chem. 2012, 51, 6446–6448. Li Dang, Mohamed F. Shibl, Xinzheng Yang, Aiman Alak, Daniel J. Harrison, Ulrich Fekl, Edward N. Brothers, Michael B. Hall. 'The Mechanism of Alkene Addition to a Nickel Bis(dithiolene) Complex: The Role of the Reduced Metal Complex'. J. Am. Chem. Soc. 2012, 134, 4481–4484. Ulrich Fekl, Biprajit Sarkar, Wolfgang Kaim, Marco Zimmer-De Iuliis, Neilson Nguyen. 'Tuning of the Spin Distribution between Ligand- and Metal-Based Spin: Electron Paramagnetic Resonance of Mixed-Ligand Molybdenum Tris(dithiolene) Complex Anions'. Inorg. Chem. 2011, 50, 8685–8687. Margaret L. Scheuermann, Ulrich Fekl, Werner Kaminsky and Karen I. Goldberg. 'Metal-Ligand Cooperativity in O2 Activation: Observation of a “Pt-O-O-C” Peroxo Intermediate'. Organometallics 2010, 29, 4749-4751. Neilson Nguyen, Daniel J. Harrison, Alan J. Lough, Antonio G. De Crisci, and Ulrich Fekl. ‘Molybdenum Dithiolene Complexes as Structural Models for the Active Sites of Molybdenum(IV) Sulfide Hydrodesulfurization Catalysts’. Eur. J. Inorg. Chem. 2010, 3577-3585. Antonio G. De Crisci, Gordon K. Hamer, and Ulrich Fekl. ‘The First Aryldiazenido Complex of Platinum(IV): An NMR-Study on the Addition of Aryldiazonium to Platinum(II)’. J. Coord. Chem. 2010, 63, 2928-2938. Antonio G. De Crisci, Vincent T. Annibale, Gordon K. Hamer, Alan J. Lough and Ulrich Fekl. ‘Characterization of a Rhodium-Sparteine Complex, [((―)-sparteine)Rh(η4-COD)]+: Crystal Structure and DNMR/DFT Studies on Ligand-Rotation Dynamics’. Dalton Trans. 2010, 39, 2888-2902. Daniel J. Harrison and Ulrich Fekl. ‘Catalytic Production of Sulfur Heterocycles (Dihydrobenzodithiins): A New Application of Ligand-Based Alkene Reactivity’. Chem. Commun. 2009, 7572-7574.

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