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个人简介

2002-2006 武汉大学 化学与分子科学学院 理学学士 2006-2011 武汉大学 化学与分子科学学院 理学博士 2012-2016 美国麻省理工学院 化学系 博士后 2016 美国麻省理工学院 化学系 研究科学家 2016-2021 复旦大学 高分子科学系 青年研究员 2021-至今 复旦大学 高分子科学系 教授

研究领域

高分子合成方法学研究 流动化学合成技术开发 功能性高分子材料合成

近期论文

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S. Han, P. Wen, H. Wang, Y. Zhou, Y. Gu, L. Zhang, Y. Shao-Horn,* X. Lin,* M. Chen* "Sequencing Polymers to Enable Solid-State Lithium Batteries" Nat. Mater., 2023, 22, 1515-1522. C. Zhou, Z. Zhang, W. Li, M. Chen* "Organocatalyzed Photo-Controlled Synthesis of Ultrahigh-Molecular-Weight Fluorinated Alternating Copolymers" Angew. Chem. Int. Ed., 2023, https://doi.org/10.1002/anie.202314483. P. Wen, Y. Zeng, L. Zhang, T. Wang, J. M. Cogen, C. L. P. Shan, Y. Liu, M. Chen* "Strengthening ethylene-methacrylic acid ionomer with single-boron-based molecules as cross-linkers in dynamic networking" RSC Appl. Polym., 2024, https://doi.org/10.1039/D3LP00178D. Z. Zhang, K. Chen, B. Ameduri,* M. Chen* "Fluoropolymer Nanoparticles Synthesized via Reversible-Deactivation Radical Polymerizations and Their Applications" Chem. Rev., 2023, 123, 12431-12470. K. Chen, X. Guo, M. Chen* "Controlled Radical Copolymerization toward Well-Defined Fluoropolymers" Angew. Chem. Int. Ed., 2023, 62, e202310636. B. Wu, J. Li, S. Han, J. Mao, P. Wen, M. Chen,* Y. Zhao, J. Lin, X. Lin* "In-situ synthesis of fluoropolymer-grafted Nanohybrid electrolyte as ion reservoir for Li-metal batteries" Giant, 2023, 16, 100201. S. Han, B. Wu, H. Wang, P. Wen, L. Zhang, X. Lin,* M. Chen* "Designing F/P Hybrid Polymer as Ultrastable Cationic Shielding Interphase for High-Performance Lithium Metal Batteries" Angew. Chem. Int. Ed., 2023, 62, e202308724. L. Zhang, H. Zhou, Y. Gu., M. Chen* "Light-Driven Organocatalyzed Controlled Radical Polymerization from Sulfonyl Chloride Initiators Promoted by Bis(thiocarbonyl) Disulfides" Macromolecules, 2023, 56, 6010-6018. H. Zhou,# L. Zhang,# P. Wen, Y. Zhou, Y. Zhao, Q. Zhao, Y. Gu., R. Bai, M. Chen* "Initiator-Activation Strategy Enabled Organocatalyzed Reversible-Deactivation Radical Polymerization Driven by Light" Angew. Chem. Int. Ed., 2023, 62, e202304461. Y. Zhao, Y. Chen, H. Zhou, Y. Zhou, K. Chen, Y. Gu., M. Chen* "Controlled Radical Copolymerization of Fluoroalkenes by Using Light-Driven Redox-Relay Catalysis" Nature Synthesis, 2023, 2, 653-662. W. Li, W. Xie, F. Shao, J. Qian, S. Han, P. Wen, J. Lin, M. Chen,* X. Lin* "Molecular Engineering of Interplanar Spacing via π-Conjugated Phenothiazine Linkages for High-Power 2D Covalent Organic Framework Batteries" Chem 2023, 9, 117-129. J. Yi, M. Chen* "Photo-Induced Copolymerization of Chlorotrifluoroethylene and Methyl Isopropenyl Ether" Acta Chim. Sinica 2023, 81, doi: 10.6023/A23080387. W. Li, P. Wen, Y. Ren, W. Xie, J. Lin, M. Chen, Y. Yang,* X. Lin* "A Polysiloxane-Enabled Ternary Eutectic Electrolyte with Fast Ion Transport under Extreme Conditions" ACS Energy Lett. 2023, 8, 5128-5135. L. Zhang, Z. Zhang, M. Chen* "Dispersity Regulation in Photo-Controlled Radical Polymerization by Merging Aryl Sulfonyl Chloride Initiators and Mixed Disulfide Agents" Chem. Res. Chin. Univ. 2023, 39, 816-821. P. Wen, H. Wang,* M. Xu, L. Zhang, H. Zheng, J. Xie, M. Chen* "Strengthening cellulose acetate via solution-reprocessible dynamic interaction with poly(4-pinacolatoborylstyrene) cross-linkers" J. Appl. Polym. Sci. 2023, 140, e54625. P. Wen, Y. Liu, J. Mao, X. Liu, W. Li, Y. Ren, Y. Zhou, F. Shao, M. Chen, J. Lin, X. Lin* "Tuning desolvation kinetics of in-situ weakly solvating polyacetal electrolytes for dendrite-free lithium metal batteries" J. Energy Chem. 2023, 79, 340-347. C. Zhou, H. Zhou, S. Tang, F. Zhang, S. Lei, Z. Li,* M. Chen, J. Liu* "Facile synthesis of aryl-triazine linked two-dimensional covalent organic frameworks via "two-in-one" strategy for phenolic compounds adsorption" Mater. Lett. 2023, 332, 133493. Y. Zeng,# Q. Quan,# P. Wen, Z. Zhang, M. Chen* "Organocatalyzed Controlled Radical Copolymerization toward Hybrid Functional Fluoropolymers Driven by Light" Angew. Chem. Int. Ed. 2022, 61, e202215628. Q. Quan, Y. Zhao, K. Chen, H. Zhou, C. Zhou, M. Chen* "Organocatalyzed Controlled Copolymerization of Perfluorinated Vinyl Ethers and Unconjugated Monomers Driven by Light" ACS Catal. 2022, 12, 7269-7277. K. Chen, Y. Zhou, S. Han, Y. Liu, M. Chen* "Main-Chain Fluoropolymers with Alternating Sequence Control via Light-Driven Reversible-Deactivation Copolymerization in Batch and Flow" Angew. Chem. Int. Ed. 2022, 61, e202116135 (hot paper). Y. Zhou, Y. Fu, M. Chen* "Facile control of molecular weight distribution via droplet-flow light-driven reversible-deactivation radical polymerization" Chin. J. Chem. 2022, 40, 2305-2312. Y. Zeng, Y. Zhou, Q. Quan, M. Chen* "Facile Access to gem-Trifluoromethyl/Boron-Functionalized Polymers via Free Radical Copolymerization and Cotelomerization" Macromolecules 2022, 55, 1524-1532. Z. Wang, Y. Zhou, M. Chen* "Computer-Aided Living Polymerization Conducted under Continuous-Flow Conditions" Chin. J. Chem. 2022, 40, 285-296. Y. Zhou, Q. Quan, M. Chen* "Recent Developments of Reversible Deactivation Radical Polymerization in Flow" Journal of Functional Polymers (功能高分子学报) 2022, 35(3), 203-220. C. Zhou, H. Zhou, S. Tang, F. Zhang, S. Lei, Z. Li,* M. Chen,* J. Liu* "Aryl-aryl linked two-dimensional covalent organic frameworks/cellulose composite monolith with hierarchical structure for aqueous dyes adsorption" J. Appl. Polym. Sci. 2022, 139, e52967. H. Zhou, C. Zhou, S. Tang, F. Zhang, S. Lei, Z. Li,* J. Liu,* M. Chen "High efficiency solution synthesis of aryl-aryl linked two-dimensional covalent organic frameworks with remarkable adsorption performance for polycyclic aromatic hydrocarbons (PAHs)" Mater. Lett. 2022, 307, 131002. M. Ma, F. Shao, P. Wen, K. Chen, J. Li, Y. Zhou, Y. Liu, M. Jia, M. Chen,* X. Lin* "Designing Weakly Solvating Solid Main-Chain Fluoropolymer Electrolytes: Synergistically Enhancing Stability toward Li Anodes and High-Voltage Cathodes" ACS Energy Lett. 2021, 6, 4255–4264. Q. Quan, M. Ma, Z. Wang, Y. Gu, M. Chen* "Visible-Light Enabled Organocatalyzed Controlled Alternating Terpolymerization of Perfluorinated Vinyl Ethers" Angew. Chem. Int. Ed. 2021, 60, 20443-20451 (VIP). Y. Gu, Y. Liu, M. Chen* "High-Level Hierarchical Morphology Reinforcing Covalent Adaptable Networks" Chem. 2021, 7, 1990-1992. Y. Chen, L. Zhang, Y. Jin, X. Lin,* M. Chen* "Recent Advances in Living Cationic Polymerization with Emerging Initiation/Controlling Systems" Macromol. Rapid. Commun. 2021, 42, 2100148. M. Jia, P. Wen, Z. Wang, Y. Zhao, Y. Liu, J. Lin, M. Chen,* X. Lin* "Fluorinated bifunctional solid polymer electrolyte synthesized under visible light for stable lithium deposition and dendrite-free all-solid-state batteries" Adv. Funct. Mater. 2021, 31, 2101736. Y. Gu, P. Lin, C. Zhou, M. Chen* "Machine Learning-assisted systematical polymerization planning: case studies on reversible-deactivation radical polymerization" Sci. China Chem. 2021, 64, 1039-1046. Y. Zhou, S. Han, Y. Gu, M. Chen* "Facile Synthesis of Gradient Copolymers Enabled by Droplet-Flow Photo-Controlled Reversible Deactivation Radical Polymerization" P. Wen, Y. Zhao, Z. Wang, J. Lin, M. Chen,* X. Lin* "Solvent-Free Synthesis of the Polymer Electrolyte via Photo-Controlled Radical Polymerization: Toward Ultrafast In-Built Fabrication of Solid-State Batteries under Visible Light" ACS Appl. Mater. Interfaces 2021, 13, 8426–8434. Z. Wang, Y. Gu, M. Ma, Y. Liu, M. Chen* "Strengthening Polyethylene Thermoplastic through A Dynamic Covalent Networking Additive Based on Alkylboron Chemistry" Macromolecules 2021, 54, 1760-1766. F. Zhong, M. Ma, Z. Zhong, X. Lin*, M. Chen* "Interfacial growth of free-standing PANI films: toward high-performance all-polymer supercapacitors" Chem. Sci. 2021, 12, 1783-1790. Z. Zhong, Y. Chen, Y. Zhou, M. Chen* "Challenges and Recent Developments of Photoflow-Reversible Deactivation Radical Polymerization (RDRP)" Chinese J. Polym. Sci. 2021, 39, 1069-1083. E. Wang, K. Chen, Y. Chen, J. Zhang, X. Lin,* M. Chen* “Porous Polymeric Ligand Promoted Copper-Catalyzed C-N Coupling of (Hetero)Aryl Chlorides under Visible-Light Irradiation" Sci. China Chem. 2021, 64, 17-21. Y. Gu, Z. Wang, H. Gong, M. Chen* "Investigations into CTA-Differentiation-Involving Polymerization of Fluorous Monomers: Exploitation of Experimental Variances in Fine-Tuning of Molecular Weights" Polym. Chem. 2020, 11, 7402-7409. X. Qing, J. Li, Z. Wang, M. Chen, J. Lin, X. Lin* "A functionalized metal organic framework-laden nanoporous polymer electrolyte for exceptionally stable lithium electrodeposition" Chem. Commun. 2020, 56, 15533-15536. S. Han, Y. Gu, M. Ma, M. Chen* "Light-Intensity Switch Enabled Nonsynchronous Growth of Fluorinated Raspberry-Like Nanoparticles" Chem. Sci. 2020, 11, 10431-10436. Y. Zhao, M. Ma, X. Lin, M. Chen* “Photoorganocatalyzed Divergent Reversible-Deactivation Radical Polymerization toward Linear and Branched Fluoropolymers" Angew. Chem. Int. Ed. 2020, 59, 21470-21474. K. Jiang, S. Han, M. Ma, L. Zhang, Y. Zhao, M. Chen* "Photoorganocatalyzed Reversible-Deactivation Alternating Copolymerization of Chlorotrifluoroethylene and Vinyl Ethers under Ambient Conditions: Facile Access to Main-Chain Fluorinated Copolymers" J. Am. Chem. Soc. 2020, 142, 7108-7115. Q. Quan, H. Wen, S. Han, Z. Wang, Z. Shao, M. Chen* "Fluorous-Core Nanoparticle-Embedded Hydrogel Synthesized via Tandem Photo-Controlled Radical Polymerization: Facilitating the Separation of Perfluorinated Alkyl Substances from Water" ACS Appl. Mater. Interfaces 2020, 12, 24319-24327. J. Zhang, E. Wang, Y. Zhou, L. Zhang, M. Chen,* X. Lin* "A Metal-Free Synthesis of 1,1-Diphenylvinylsulfides with Thiols via Thioetherification under Continuous-Flow Conditions" Org. Chem. Front. 2020, 7, 1490-1494. L. Zhang, K. Jiang, X. Shen, Y. Gu, X. Lin,* M. Chen* "Thienyl Chloride Initiated Living Cationic Polymerization: A General and Efficient Access toward Terminally Functionalized Poly(vinyl ether)s" Macromolecules 2020, 53, 1536-1542. Z. Wang, Y. Gu, M. Ma, M. Chen* "Strong, Reconfigurable, and Recyclable Thermosets Cross-Linked by Polymer-Polymer Dynamic Interaction based on Commodity Thermoplastics" Macromolecules 2020, 53, 956-964. E. Wang, J. Zhang, Z. Zhong, K. Chen, M. Chen* "Shuttling Catalyst: Facilitating C-C bond formation via cross-couplings with a thermoresponsive polymeric ligand" Isr. J. Chem. 2020, 60, 419-423. H. Gong, Y. Gu, Y. Zhao, Q. Quan, S. Han, M. Chen* "Precise Synthesis of Ultra-High-Molecular-Weight Fluoropolymers Enabled by Chain-Transfer-Agent Differentiation under Visible-Light Irradiation" Angew. Chem. Int. Ed. 2020, 59, 919-927. F. Zhong, Y. Zhou, M. Chen* "The Influence of Mixing on Chain Extension by Photo-Controlled/Living Radical Polymerization under Continuous-Flow Conditions" Polym. Chem. 2019, 10, 4879-4886. E. Wang, M. Chen* "Catalyst Shuttling Enabled by a Thermoresponsive Polymeric Ligand: Facilitating Efficient Cross-Couplings with Continuously Recyclable ppm Levels of Palladium" Chem. Sci. 2019, 10, 8331-8337. Y. Zhou, Y. Gu, K. Jiang, M. Chen* "Droplet-Flow Photopolymerization Aided by Computer: Overcoming the Challenges of Viscosity and Facilitating the Generation of Copolymer Libraries" Macromolecules 2019, 52, 5611-5617. H. Gong, M. Ma, Y. Zhou, Y. Zhao, Y. Gu, M. Chen* "Photoredox Controlled Living Polymerization" Journal of Functional Polymers (功能高分子学报) 2019, 32, 271-291. K. Jiang,# L. Zhang,# Y. Zhao, J. Lin, M. Chen* "Palladium-Catalyzed Cross-Coupling Polymerization: A New Access to Cross-Conjugated Polymers with Modifiable Structure and Tunable Optical/Conductive Properties" Macromolecules 2018, 51, 9662-9668. Q. Quan, H. Gong, M. Chen* "Preparation of Semifluorinated Poly(meth)acrylates by Improved Photo-Controlled Radical Polymerization without the Use of Fluorinated RAFT Agent: Facilitating Surface Fabrication with Fluorinated Materials" Polym. Chem. 2018, 9, 4161-4171. H. Gong, Y. Gu, M. Chen* "Controlled/Living Radical Polymerization of Semifluorinated (Meth)acrylates" Synlett 2018, 29, 1543-1551 (invited review). Y. Zhao, H. Gong, K. Jiang, S. Yan, J. Lin and M. Chen* "Organocatalyzed Photoredox Polymerization from Aromatic Sulfonyl Halides: Facilitating Graft from Aromatic C-H Bonds" Macromolecules 2018, 51,938-946. X. Shen, H. Gong, Y. Zhou, Y. Zhao, J. Lin,* M. Chen* “Unsymmetrical Difunctionalization of Cyclooctadiene under Continuous Flow Conditions: Expanding the Scope of Ring Opening Metathesis Polymerization” Chem. Sci. 2018, 9, 1846-1853. H. Gong, Y. Zhao, X. Shen, J. Lin, M. Chen* “Organocatalyzed Photocontrolled Radical Polymerization of Semi-fluorinated (Meth)acrylates Driven by Visible Light” Angew. Chem. Int. Ed. 2018, 57, 333-337. W. Zhang, M. Huang, S. Abdullatif, M. Chen, Y. Shao-Horn, J. A. Johnson,* "Reduction of (Meth)acrylate-Based Block Copolymers Provides Access to Self-Assembled Materials with Ultrasmall Domains", Macromolecules 2018, 51, 6757–6763. M. Huang,# S. Feng,# W. Zhang, L. Giordano, M. Chen, C. V. Amanchukwu, R. Anandakathir, Y. Shao-Horn,* J. A. Johnson,* "Fluorinated Aryl Sulfonimide Tagged (FAST) salts: modular synthesis and structure–property relationships for battery applications", Energy Environ. Sci. 2018, 11, 1326-1334. S. Feng,# M. Chen,# L. Giordano, M. Huang, W. Zhang, C. V. Amanchukwu, R. Anandakathir, Y. Shao-Horn* and J. A. Johnson,* "Mapping a stable solvent structure landscape for aprotic Li–air battery organic electrolytes", J. Mater. Chem. A 2017, 5, 23987-23998. Y. Gu, K. Kawamoto, M. Zhong, M. Chen, M. J. A. Hore, A. M. Jordan, L. T. J. Korley, B. D. Olsen, J. A. Johnson,* "Semibatch Monomer Addition as a General Method to Tune and Enhance the Mechanics of Polymer Networks via Loop-defect Control", Proc. Natl. Acad. Sci. U.S.A. 2017, 114, 4875-4880. M. Chen, S. Deng, Y. Gu, J. Lin, M. J. MacLeod, J. A. Johnson,* “Logic-Controlled Radical Polymerization with Heat and Light: Multiple-Stimuli Switching of Polymer Chain Growth via a Recyclable, Thermally Responsive, Gel Photo-Redox Catalyst”, J. Am. Chem. Soc. 2017, 139, 2257-2266. M. Chen,# Y. Gu,# A. Singh, M. Zhong, A. M. Jordan, S. Biswas, L. T. J. Korley, A. C. Balazs, J. A. Johnson,* ''Living Additive Manufacturing: Transformation of Parent Gels into Diversely Functionalized Daughter Gels Made Possible by Visible Light Photoredox Catalysis'', ACS Cent. Sci. 2017, 3, 124-134. M. Chen,# M. Zhong,# J. A. Johnson,* “Light-Controlled Radical Polymerization: Mechanisms, Methods, and Applications”, Chem. Rev. 2016, 116, 10167?10211. M. Chen, J. A. Johnson*, “Improving Photo-controlled Living Radical Polymerization from Trithiocarbonates through the Use of Continuous-flow Techniques", Chem. Commun. 2015, 51, 6742-6745. M. Chen, M. J. MacLeod, Jeremiah A. Johnson,* “Visible-Light-Controlled Living Radical Polymerization from a Trithiocarbonate Iniferter Mediated by an Organic Photoredox Catalyst", ACS Macro Lett. 2015, 4, 566?569. M. Chen, S. Ichikawa, S. L. Buchwald*, “Rapid and Efficient Copper-Catalyzed Finkelstein Reaction of (Hetero)Aromatics under Continuous-Flow Conditions", Angew. Chem. Int. Ed. 2015, 54, 263-266. M. Chen, S. L. Buchwald*, “Rapid and Efficient Trifluoromethylation of Aromatic and Heteroaromatic Compounds Using Potassium Trifluoroacetate Enabled by a Flow System", Angew. Chem. Int. Ed. 2013, 52, 11628-11631. M. Chen, S. L. Buchwald*, "Continuous-Flow Synthesis of 1-Substituted Benzotriazoles from Chloronitrobenzenes and Amines in a C-N Bond Formation/Hydrogenation/ Diazotization/ Cyclization Sequence", Angew. Chem. Int. Ed. 2013, 52, 4247-4250. M. Chen, X. Zheng, W. Li, J. He, A. Lei*, “Palladium-Catalyzed Aerobic Oxidative Cross-Coupling Reactions of Terminal Alkynes with Alkylzinc Reagents", J. Am. Chem. Soc. 2010, 132, 4101-4103. M. Chen, J. Wang, Z. Chai, C. You, A. Lei*, “C-X (X=Br, I) Bond-Tolerant Aerobic Oxidative Cross-Coupling: A Strategy to Selectively Construct β-Aryl Ketones and Aldehydes", Adv. Synth. Catal. 2012, 354, 341-346. M. Chen, Y. Weng, A. Lei*, "Asymmetric Cycloisomerization of 1, n-Enynes Catalyzed by Transition Metals", Progress in Chemistry, 2010, 22, 1341-1352. A. Lei*, W. Liu, C. Liu, M. Chen, "Arylation of Unactivated Arenes", Dalton Trans. 2010, 39, 10352-10361. W. Yin, C. He, M. Chen, H. Zhang, A. Lei*, "Nickel-Catalyzed Oxidative Coupling Reaction of Two Different Terminal Alkynes Using O2 as the Oxidant at Room Temperature: Facile Syntheses of Unsymmetric 1,3-Diynes", Org. Lett. 2009, 11, 709-712. M. Chen, Y. Weng, M. Guo, H. Zhang, A. Lei*, "Nickel-Catalyzed Reductive Cyclization of Unactivated 1, 6-Enynes in the Presence of Organozinc Reagents", Angew. Chem. Int. Ed. 2008, 47, 2279-2282. C. Liu, C. He, W. Shi, M. Chen, A. Lei*, "Ni-Catalyzed Mild Arylation of α-Halocarbonyl Compounds with Arylboronic Acids", Org. Lett. 2007, 9, 5601-5604. A. Lei*, M. Chen, M. He, X. Zhang, "Asymmetric Hydrogenation of Pyridines: Enantioselective Synthesis of Nipecotic Acid Derivatives", Eur. J. Org. Chem. 2006, 4343-4347. L.-J. Deng, J. Liu, J.-Q. Huang, Y. Hu, M. Chen, Y. Lan, J.- H. Chen, A. Lei, Z. Yang*, "Effect of lithium chloride on tuning the reactivity of Pauson- Khand reactions catalyzed by palladium-tetramethylthiourea", Synthesis 2007, 16, 2565-2570. L.-S. Cai, S.-L. Gong, M. Chen, C.-Y. Wu*, "Vinyl Crown Ether as a Novel Radical Crosslinked Sol-Gel SPME Fiber for Determination of Organophosphorus Pesticides in Food Samples", Anal. Chim. Acta 2006, 559, 89-96.

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