个人简介

B. Eng, Kyoto University, Japan; Ph.D. Kyoto University, Japan; Postdoctoral Fellow, Colorado State University, USA. Education: 1970Bachelor, Kyoto University, Japan 1972Master, Kyoto University, Japan 1975Ph D., Kyoto University, Japan (Professor M. Kumada) 1976-1977 Postdoctoral Fellow, Colorado State University, USA (Professor L. S. Hegedus) Appointments: 1975-1989 Research Associate, Department of Synthetic Chemistry, Kyoto University, Japan 1989-1994 Professor, Catalysis Research Center, Hokkaido University, Japan 1994-2012 Professor, Department of Chemistry, Kyoto University, Japan 2012-present Professor, I, Singapore Memberships: American Chemical Society The Chemical Society of Japan The Society of Synthetic Organic Chemistry, Japan Pharmaceutical Society of Japan Catalysis Society of Japan The Society of Silicon Chemistry, Japan

研究领域

Synthetic Organic Chemistry/Organometallic Chemistry and Catalysis

Synthetic Organic Chemistry: Selective organic synthesis catalyzed by transition metal complexes, particularly new carbon–carbon bond forming reactions Organometallic Chemistry: Mechanistic understanding of catalytic reactions by characterization of key intermediates and kinetic studies Catalysis: Asymmetric catalysis, development of a new type of catalytic asymmetric reactions and design of new chiral ligands

近期论文

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Cobalt-Catalyzed Asymmetric 1,6-Addition of (Triisopropylsilyl)acetylene to α,β,γ,δ-Unsaturated Carbonyl Compounds. Sawano, T.; Ashouri, A.; Nishimura, T.; Hayashi, T. J. Am. Chem. Soc. 2012, 134, in press. Rhodium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzooxasilines via Enantioselective Transmetalation. Shintani, R.; Maciver, E.; Tamakuni, F.; Hayashi, T. J. Am. Chem. Soc. 2012, 134, 16955–16958. Ruthenium-Catalyzed Transformation of Aryl and Alkenyl Triflates to Halides. Imazaki, Y.; Shirakawa, E.; Hayashi, T. J. Am. Chem. Soc. 2012, 134, 14760–14763. Effect of Chiral Diene Ligands in Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to a,b-Unsaturated Sulfonyl Compounds. Nishimura, T.; Takiguchi, Y.; Hayashi, T. J. Am. Chem. Soc. 2012, 134, 9086–9089. Palladium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzosiloles via Enantioselective C–H Bond Functionalization. Shintani, R.; Otomo, H.; Ota, K.; Hayashi, T. J. Am. Chem. Soc. 2012, 134, 7305–7308. Asymmetric Synthesis of (Triaryl)methylamines by Rhodium-Catalyzed Addition of Arylboroxines to Cyclic N-Sulfonyl Ketimines. Nishimura, T.; Noishiki, A.; Tsui, G. C.; Hayashi, T. J. Am. Chem. Soc. 2012, 134, 5056–5059. Rhodium/Diene-Catalyzed Tandem 1,4-Shift/1,4-Addition of cis-2-Arylethenylboronic Acids to Enones: Density Functional Theory Modeling and Asymmetric Catalysis. Sasaki, K.; Nishimura, T.; Shintani, R.; Kantchev, E. A. B.; Hayashi, T. Chem. Sci. 2012, 3, 1278–1283. Iron-Copper Cooperative Catalysis in the Reactions of Alkyl Grignard Reagents: Exchange Reaction with Alkenes and Carbometalation of Alkynes. Shirakawa, E.; Ikeda, D.; Masui, S.; Yoshida, M.; Hayashi, T. J. Am. Chem. Soc. 2012, 134, 272–279. Cross-Coupling of Aryl Grignard Reagents with Aryl Halides through SRN1 Pathway. Shirakawa, E.; Hayashi, Y.; Ito, K.; Watabe, R.; Uchiyama, N.; Konagaya, W.; Masui, S.; Hayashi, T. Angew. Chem. Int. Ed. 2012, 51, 218–221. A Chiral Chelating Diene as a New Type of Chiral Ligand for Transition Metal Catalysts: Its Preparation and Use for the Rhodium-Catalyzed Asymmetric 1,4-Addition. Hayashi, T.; Ueyama, K.; Tokunaga, N.; Yoshida, K. J. Am. Chem. Soc. 2003, 125, 11508–11509. [cited 221] Catalytic Cycle of Rhodium-Catalyzed Asymmetric 1,4-Addition of Organoboronic Acids. Arylrhodium, Oxa-p-allylrhodium, and Hydroxorhodium Intermediates. Hayashi, T.; Takahashi, M.; Takaya, Y.; Ogasawara. M. J. Am. Chem. Soc. 2002, 124, 5052–5058. [cited 355] Rhodium-Catalyzed Asymmetric 1,4-Addition of Aryl- and Alkenylboronic Acids to Enones. Takaya, Y.; Ogasawara, M.; Hayashi, T.; Sakai, M.; Miyaura, N. J. Am. Chem. Soc. 1998, 120, 5579–5580. [cited 420] Asymmetric Synthesis Catalyzed by Chiral Ferrocenylphosphine-Transition-Metal Complexes. 8. Palladium-Catalyzed Asymmetric Allylic Amination. Hayashi, T.; Yamamoto, A.; Ito, Y.; Nishioka, E.; Miura, H.; Yanagi, K. J. Am. Chem. Soc. 1989, 111, 6301-6311. [cited 318] Catalytic Asymmetric Aldol Reaction: Reaction of Aldehydes with Isocyanoacetate Catalyzed by a Chiral Ferrocenylphosphine-Gold(I) Complex. Ito, Y.; Sawamura, M.; Hayashi, T. J. Am. Chem. Soc. 1986, 108, 6405–6406. [cited 478] Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II): An Effective Catalyst for Cross-Coupling of Secondary and Primary Alkyl Grignard and Alkylzinc Reagents with Organic Halides. Hayashi, T.; Konishi, M.; Kobori, Y.; Kumada, M.; Higuchi, T.; Hirotsu, K. J. Am. Chem. Soc. 1984, 106, 158–163. [cited 658] Asymmetric Synthesis Catalyzed by Chiral Ferrocenylphosphine-Transition Metal Complexes. I. Preparation of Chiral Ferrocenylphosphines. Hayashi, T.; Mise, T.; Fukushima, M.; Kagotani, M.; Nagashima, N.; Hamada, Y.; Matsumoto, A.; Kawakami, S.; Konishi, M.; Yamamoto, K.; Kumada, M. Bull. Chem. Soc. Jpn. 1980, 53, 1138–1151. [cited 433]