个人简介
Research Experience:
B.S. (1997) & Ph.D. (2002) from Kyoto U. (Mentor: Prof. Koichiro Oshima)
Postdoctoral fellow (2002-2003) at U. Tokyo (Mentor: Prof. Eiichi Nakamura)
Assistant Professor (2003-2008) at Kyoto U. (Dept. Material Chem., Oshima Group)
Associate Professor (2008-2009) at Kyoto U. (Dept. Material Chem., Oshima Group)
Associate Professor (2009-2015) at Kyoto U. (Dept. Chem., Osuka Group)
Project Leader of ACT-C, JST (2012-present, concurrent position)
Visiting Associate Professor at Institute for Molecular Science (2014-2015, concurrent position)
Professor (2015-present) at Kyoto U. (Dept. Chem.)
Visiting Associate Professor/Professor at Institute for Molecular Science (2014-2016, concurrent position)
Awards and Fellowships:
Mukaiyama Award, 2016
JACI New Chemical Technology Research Encouragement Award, 2015
The Young Scientists’ Prize, The Commendation for Science and Technology by the Minister of Education, Culture, Sports, Science and Technology, 2011
Mitsui Chemicals Catalysis Science Award of Encouragement, 2011
The Chemical Society of Japan Award For Young Chemists, 2009
Eisai Award in Synthetic Organic Chemistry, Japan, 2007
Banyu Young Chemist Award, 2007
Thieme Journal Award, 2006
Japan Society for the Promotion of Science (JSPS) Research Fellowship SPD, 2003
JSPS Research Fellowship PD, 2002
Bulletin of the Chemical Society of Japan Award, 2001
JSPS Research Fellowship DC1, 1999–2002
研究领域
Organic Chemistry (Synthesis/Reactions/Structure/Functions)
Development of new reactions utilizing organometallic species, transition metal catalysts, and heteroatoms
Creation of new functional molecules based on new organic transformations
近期论文
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Palladium‐Catalyzed Mizoroki‐Heck‐Type Alkenylation of Monoaryldialkylsulfoniums
Daisuke Uno, Hiroko Minami, Shinya Otsuka, Keisuke Nogi, and Hideki Yorimitsu*
Chem. Asian J. 2018, in press.
DOI: 10.1002/asia.201800489
Palladium-Catalyzed Insertion of Isocyanides into the C–S Bonds of Heteroaryl Sulfides
Shinya Otsuka, Keisuke Nogi, and Hideki Yorimitsu*
Angew. Chem. Int. Ed. 2018, 57, 6653–6657.
DOI: 10.1002/anie.201802369
Palladium-catalyzed Homo-coupling of Heteroarylsulfoniums via Borylation/Suzuki-Miyaura Coupling Sequence
Hiroko Minami, Keisuke Nogi, and Hideki Yorimitsu*
Heterocycles 2018, in press.
DOI: 10.3987/COM-18-S(T)78
Sigmatropic Rearrangements of Hypervalent-Iodine-Tethered Intermediates for the Synthesis of Biaryls
Mitsuki Hori, Jing-Dong Guo, Tomoyuki Yanagi, Keisuke Nogi, Takahiro Sasamori, and Hideki Yorimitsu*
Angew. Chem. Int. Ed. 2018, 57 4663–4667.
DOI: 10.1002/anie.201801132
Palladium-Catalyzed Amination of Aryl Sulfoxides
Yuto Yoshida, Shinya Otsuka, Keisuke Nogi, and Hideki Yorimitsu*
Org. Lett. 2018, 20, 1134–1137.
DOI: 10.1021/acs.orglett.8b00060
Iridium-Catalyzed Hydroarylation of Conjugated Dienes via π-Allyliridium Intermediates
Midori Nagamoto, Hideki Yorimitsu, and Takahiro Nishimura*
Org. Lett. 2018, 20 828–831.
DOI: 10.1021/acs.orglett.7b03969
Palladium-Catalyzed Borylation of Aryl Sulfoniums with Diborons
Hiroko Minami, Shinya Otsuka, Keisuke Nogi, and Hideki Yorimitsu*
ACS Catal. 2018, 8 579–583.
DOI: 10.1021/acscatal.7b03841
C–S Bond Alkynylation of Diaryl Sulfoxides with Terminal Alkynes by Means of a Palladium–NHC Catalyst
Yuto Yoshida, Keisuke Nogi, and Hideki Yorimitsu*
Synlett 2017, 28 2561–2564.
DOI: 10.1055/s-0036-1591676
Hydroxoiridium-Catalyzed Hydroarylation of Alkynes and Bicycloalkenes with N-Sulfonylbenzamides
Midori Nagamoto, Jun-ichi Fukuda, Miyuki Hatano, Hideki Yorimitsu, and Takahiro Nishimura*
Org. Lett. 2017, 19 5952–5955.
DOI: 10.1021/acs.orglett.7b02950
Manganese-Catalyzed Ring Opening of Benzofurans and Its Application to Insertion of Heteroatoms into the C2–O Bond
Shun Tsuchiya, Saito Hayate, Keisuke Nogi, and Hideki Yorimitsu*
Org. Lett. 2017, 19 5557–5560.
DOI: 10.1021/acs.orglett.7b02660
Nickel-Catalyzed Cross-Coupling Reaction of Aryl Sulfoxides with Arylzinc Reagents: A Case that Leaving Group is an Oxidant
Keita Yamamoto, Shinya Otsuka, Keisuke Nogi, and Hideki Yorimitsu*
ACS Catal. 2017, 7, 7623–7628.
DOI: 10.1021/acscatal.7b02347
Palladium-Catalyzed Arylation of Benzylic C–H Bonds of Azaarylmethanes with Aryl Sulfides
Ke Gao, Keita Yamamoto, Keisuke Nogi, and Hideki Yorimitsu*
Synlett 2017, 28 2956–2960.
DOI: 10.1055/s-0036-1589098
Regioselective C–H Sulfanylation of Aryl Sulfoxides by Means of Pummerer-Type Activation
Hitomi Kawashima, Tomoyuki Yanagi, Chien-Chi Wu, Keisuke Nogi, and Hideki Yorimitsu*
Org. Lett. 2017, 19 4552–4555.
DOI: 10.1021/acs.orglett.7b02147
Robust Palladium-Catalyzed Arylation of Catalyst-Poisoning ortho-Sulfanyl Aryl Halides with Tetraarylborates and Its Application to Synthesis of π-Extended Dibenzothiophenes
Dhananjayan Vasu,Jan Niklas Hausmann, Hayate Saito, Tomoyuki Yanagi, Hideki Yorimitsu*, and Atsuhiro Osuka
Asian J. Org. Chem. 2017, 6, 1390-1393. (front cover picture)
DOI: 10.1002/ajoc.201700323
Iridium-catalyzed sp3 C–H Alkylation of 3-Carbonyl-2-(alkylamino)pyridines with Alkenes
Masaki Nagai, Midori Nagamoto, Takahiro Nishimura*, Hideki Yorimitsu
Chem. Lett. 2017, 46, 1176–1178.
DOI: 10.1246/cl.170373
Rh/Cu-co-catalyzed Ring-opening Diborylation of Dibenzothiophenes for Aromatic Metamorphosis via Diborylbiaryls
Hayate Saito, Keisuke Nogi and Hideki Yorimitsu*
Chem. Lett. 2017, 46, 1122–1125.
DOI: 10.1246/cl.170415
Palladium-Catalyzed Double Borylation of Diaryl Sulfoxides with Diboron
Hayate Saito, Keisuke Nogi and Hideki Yorimitsu*
Synthesis 2017, 49 4769–4774.
DOI: 10.1055/s-0036-1588848
Hydroxoiridium-Catalyzed Hydroalkylation of Terminal Alkenes with Ureas by C(sp3)−H Bond Activation
Daisuke Yamauchi, Takahiro Nishimura* and Hideki Yorimitsu
Angew. Chem. Int. Ed. 2017, 56, 7200.
DOI: 10.1002/anie.201702169
Iridium-Catalyzed Regio- and Enantioselective Hydroarylation of Alkenyl Ethers by Olefin Isomerization
Yusuke Ebe, Mitsuki Onoda, Takahiro Nishimura* and Hideki Yorimitsu
Angew. Chem. Int. Ed. 2017, 56, 5607.
DOI: 10.1002/anie.201702286
Palladium-Catalyzed Cross-Coupling of Aryl Chlorides with Arylsilatranes
Yutaro Yamamoto, Alexandre Baralle, Anaïs Godefroy, Kei Murakami, Hideki Yorimitsu,* and Atsuhiro Osuka
Heterocycles 2017, 95, 568.
DOI: 10.3987/COM-16-S(S)21
Aromatic Metamorphosis of Dibenzofurans into Triphenylenes Starting with Nickel-Catalyzed Ring-Opening C–O Arylation
Yuto Kurata, Shinya Otsuka , Norihito Fukui, Keisuke Nogi, Hideki Yorimitsu*, and Atsuhiro Osuka
Org. Lett. 2017, 19, 1274.
DOI: 10.1021/acs.orglett.6b03861
Asymmetric hydroarylation of vinyl ethers catalyzed by a hydroxoiridium complex: azoles as effective directing groups
Daisuke Yamauchi, Takahiro Nishimura* and Hideki Yorimitsu
Chem. Commun., 2017, 53, 2760.
DOI: 10.1039/C7CC00238F
Base-Free Palladium-Catalyzed Hydrodechlorination of Aryl Chlorides with Pinacol Borane
Yutaro Yamamoto, Keisuke Nogi, Hideki Yorimitsu*, and Atsuhiro Osuka
ChemistrySelect 2017, 2, 1723.
DOI: 10.1002/slct.201700189
Synthesis of Dibenzophosphole Oxides from Dibenzothiophene Dioxides and Phenylphosphine by Two Successive SNAr Reactions
Mitsuki Onoda, Yoshinari Koyanagi, Hayate Saito, M. Bhanuchandra, Yoshihiro Matano*, and Hideki Yorimitsu*
Asian J. Org. Chem. 2017, 6, 257.
DOI: 10.1002/ajoc.201600612