Mayr, Herbert - Ludwig-Maximilians-Universität München

个人简介

Studied chemistry at LMU München 1974 PhD, LMU München 1975-1976 Postdoctoral research, Case Western Reserve Univ. Cleveland, Ohio/USA 1976-1984 Research associate, Univ. Erlangen-Nürnberg 1980 Habilitation, Univ. Erlangen-Nürnberg 1984-1991 Pro

研究领域

Kinetics of polar organic and metal-organic reactions Reactivity scales for nucleophiles and electrophiles Carbocationic polymerizations

近期论文

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[370] Feineinstellung der nucleophilen Reaktivität von Bor-at-Komplexen aus Aryl- und Heteroarylboronsäureestern Fine-Tuning of the Nucleophilic Reactivities of Boron-Ate Complexes Derived From Aryl and Heteroaryl Boronic Esters G. Berionni, A. I. Leonov, P. Mayer, A. R. Ofial, H. Mayr, Angew. Chem. 2015, 127, 2820-2824; Angew. Chem. Int. Ed. 2015, 54, 2780-2783. [deutsch-download][english-download] Scales of Lewis Basicities toward C-centered Lewis Acids (Carbocations) H. Mayr, J. Ammer, M. Baidya, B. Maji, T. A. Nigst, A. R. Ofial, T. Singer, J. Am. Chem. Soc. 2015, 137, 2580-2599. Stereoselektive Synthese und Reaktionen von in Position 3 funktionalisierten sekundären Alkyllithiumverbindungen Stereoselective Synthesis and Reactions of Secondary Alkyllithium Reagents Functionalized at the 3-Position K. Moriya, D. Didier, M. Simon, J. M. Hammann, G. Berionni, K. Karaghiosoff, H. Zipse, H. Mayr, P. Knochel, Angew. Chem. 2015, 127, 2793-2796; Angew. Chem. Int. Ed. 2015, 54, 2754-2757. [deutsch-download] [english-download] Quantification of Ion-Pairing Effects on the Nucleophilic Reactivities of Benzoyl- and Phenyl-Substituted Carbanions in Dimethylsulfoxide F. Corral Bautista, R. Appel, J. S. Frickel, H. Mayr, Chem. Eur. J. 2015, 21, 875-884. Structures and Reactivities of 2-Trityl- and 2-(Triphenylsilyl)pyrrolidine-Derived Enamines: Evidence for Negative Hyperconjugation with the Trityl Group H. Erdmann, F. An, P. Mayer, A. R. Ofial, S. Lakhdar, H. Mayr, J. Am. Chem. Soc. 2014, 136, 14263-14269. Mechanisms of Hydride Abstractions by Quinones X. Guo, H. Zipse, H. Mayr, J. Am. Chem. Soc. 2014, 136, 13863-13873. Quantification of the Ambident Electrophilicities of Halogen-Substituted Quinones X. Guo, H. Mayr, J. Am. Chem. Soc. 2014, 136, 11499-11512. Di- and Triarylmethylium Ions as Probes for the Ambident Reactivities of Carbanions Derived from 5-Benzylated Meldrum’s Acid X. Chen, Y. Tan, G. Berionni, A. R. Ofial, H. Mayr, Chem. Eur. J. 2014, 20, 11069-11077. In-situ-Abfangmethode zur Metallierung funktionalisierter Arene und Heteroarene mit TMPLi in Gegenwart von ZnCl2 und anderen Metallsalzen New In Situ Trapping Metalations of Functionalized Arenes and Heteroarenes with TMPLi in the Presence of ZnCl2 and Other Metal Salts A. Frischmuth, M. Fernández, N. M. Barl, F. Achrainer, H. Zipse, G. Berionni, H. Mayr, K. Karaghiosoff, P. Knochel, Angew. Chem. 2014, 126, 8062-8066; Angew. Chem. Int. Ed. 2014, 53, 7928-7932. [deutsch-download][english-download] Structures and Reactivities of Iminium Ions Derived From Substituted Cinnamaldehydes and Various Chiral Imidazolidin-4-ones F. An, S. Paul, J. Ammer, A. R. Ofial, P. Mayer, S. Lakhdar, H. Mayr, Asian J. Org. Chem. 2014, 3, 550-555. Hydrocarbierung von CC-Dreifachbindungen: Quantifizierung der nucleophilen Reaktivität von Inamiden Hydrocarbation of CC-Triple Bonds: Quantification of the Nucleophilic Reactivity of Ynamides H. A. Laub, G. Evano, H. Mayr, Angew. Chem. 2014, 126, 5068-5072; Angew. Chem. Int. Ed. 2014, 53, 4968-4971. [deutsch-download][english-download] Electrophilicities of 1,2-Disubstituted Ethylenes D. S. Allgäuer, H. Mayr, Eur. J. Org. Chem. 2014, 2956-2963. Electrophilic Alkylations of Vinylsilanes - A Comparison of α- and β-Silyl Effects H. A. Laub, H. Mayr, Chem. Eur. J. 2014, 20, 1103-1110. Nucleophilicity Parameters of Pyridinium Ylides and Their Use in Mechanistic Analyses D. S. Allgäuer, H. Mayr, J. Am. Chem. Soc. 2013, 135, 15216-15224. Ambidente Reaktivität von Formaldehyd-N,N-dialkylhydrazonen Ambident Reactivities of Formaldehyde N,N-Dialkylhydrazones B. Maji, K. Troshin, H. Mayr, Angew. Chem. 2013, 125, 12116-12120; Angew. Chem. Int. Ed. 2013, 52, 11900-11904. [deutsch-download][english-download] Manifestation of Polar Reaction Pathways of 2,3-Dichloro-5,6-dicyano-p-benzoquinone X. Guo, H. Mayr, J. Am. Chem. Soc. 2013, 135, 12377-12387. One-Pot Two-step Synthesis of 1-Ethoxycarbonyl-indolizines via Pyridinium Ylides D. S. Allgäuer, H. Mayr, Eur. J. Org. Chem. 2013, 6379-6388. Struktur und ambidente Reaktivität von Azolium-Enolaten Structures and Ambident Reactivities of Azolium Enolates B. Maji, H. Mayr, Angew. Chem. 2013, 125, 11370-11374; Angew. Chem. Int. Ed. 2013, 52, 11163-11167. [deutsch-download][english-download] Nichtbindende Wechselwirkungen in der Organokatalyse: Modulierung konformativer Diversit?t und Reaktivit?t im MacMillan-Katalysator Non-Covalent Interactions in Organocatalysis: Modulating Conformational Diversity and Reactivity in the MacMillan Catalyst M. C. Holland, S. Paul, W. B. Schweizer, K. Bergander, C. Mück-Lichtenfeld, S. Lakhdar, H. Mayr, R. Gilmour, Angew. Chem. 2013, 125, 8125-8129; Angew. Chem. Int. Ed. 2013, 52, 7967-7971. [deutsch-download][english-download] Photogeneration of Carbocations: Applications in Physical Organic Chemistry and the Design of Suitable Precursors J. Ammer, H. Mayr, J. Phys. Org. Chem. 2013, 26, 956-969.