Sergeev, Alexey - University of Liverpool

个人简介

Alexey Sergeev obtained his undergraduate degree from Saint-Petersburg State University and his PhD degree from Moscow State University (2005, Prof. Irina P. Beletskaya), Russia. After a short stay in industry, he conducted postdoctoral studies with Prof. Matthias Beller at Leibniz Institute for Catalysis, Rostock, Germany (2006-2009). In 2009, Alexey moved to the United States to join the group of Prof. John F. Hartwig at the University of Illinois at Urbana-Champaign and then at the University of California, Berkeley. In 2012, Alexey returned to Europe to start his independent career at the University of Liverpool and the Stephenson Institute for Renewable Energy as a Lecturer in Chemistry.

研究领域

Research interests in our group focus on organometallic chemistry and homogeneous catalysis related to energy and clean generation of chemicals. We seek to develop novel catalytic transformations to establish milder, safer and shorter routes to fuels and value-added chemicals. In particular, we exploit the unique reactivity of well-defined metal complexes in the selective scission of C-H and C-C bonds in hydrocarbons, and in activation of small molecules.

近期论文

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Linear-Selective Hydroarylation of Unactivated Terminal and Internal Olefins with Trifluoromethyl-Substituted Arenes A Heterogeneous Nickel Catalyst for the Hydrogenolysis of Aryl Ethers without Arene Hydrogenation Selective, Nickel-Catalyzed Hydrogenolysis of Aryl Ethers A General and Efficient Catalyst for Palladium-Catalyzed C−O Coupling Reactions of Aryl Halides with Primary Alcohols Synthesis and Catalytic Applications of Stable Palladium Dioxygen Complexes Palladium-Catalyzed Hydroxylation of Aryl Halides under Ambient Conditions Palladium Catalysts for the Formylation of Vinyl Triflates To Form α,β-Unsaturated Aldehydes Palladium-Catalyzed Formylation of Aryl Bromides: Elucidation of the Catalytic Cycle of an Industrially Applied Coupling Reaction Synthesis and Crystal Structure of Palladium(0) and Arylpalladium(II) Bromide Complexes of Cata CX ium A Arylamidate palladium complexes containing deprotonated phthalimide and p-methylbenzamide: possibility of their participation in reductive elimination One-Pot Synthesis of Symmetrical Di- and Triarylamines Using Urea as the Source of the Amino Group Urea as ammonia equivalent in aryl halides amination catalyzed by palladium complexes Palladium-Catalyzed Amination and Amidation of Benzo-Fused Bromine-Containing Heterocycles Variation of Xanthphos-Based Bidentate Ligands in the Palladium-Catalyzed Reaction Aryl Halides with Ureas (Engl. Transl.) Variation of xanthene-based bidentate ligands in the palladium-catalyzed arylation of ureas Palladium-Catalyzed Arylation of Ureas (Engl. Transl.) Palladium-catalyzed reaction of aryl halides with ureas