Koningsbruggen, Petra Van - Aston University - School of Engineering & Applied Science

个人简介

Degrees 28/10/1988: Master's degree in Chemistry Leiden University (Leiden, the Netherlands) 15/06/1994: Ph.D. degree Leiden University (Leiden, the Netherlands), Supervisor: Prof. dr. J. Reedijk (Leiden University, the Netherlands) Title of Ph.D. thesis: “The structures and magnetic properties of polynuclear copper(II) coordination compounds. 1,2,4-triazoles and acylamidrazones as ligands.” Teaching qualifications 15 February 2012:Postgraduate Certificate in Professional Practice in Higher Education (PGCPP) 16 April 2012: Fellow of the Higher Education Academy Languages Dutch, English, French, German, Italian 01/1995 – 07/1995 : Post-doctoral researcher Johannes-Gutenberg Universit?t Mainz, Germany Research group of Prof. dr. P. Gütlich 10/1995 – 08/1997: Post-doctoral researcher Université de Bordeaux, France Research group of Prof. dr. O. Kahn 09/1997 – 08/1998: Post-doctoral researcher University of Utah, Salt Lake City, USA Research group of Prof. dr. J. S. Miller 10/1998 – 02/2000: Research collaborator Johannes-Gutenberg Universit?t Mainz, Germany Research group of Prof. dr. P. Gütlich 03/2000 - 12/2003: Lecturer Johannes-Gutenberg Universit?t Mainz, Germany 01/2004 - 2010: Assistant Professor (Rosalind Franklin Fellow) University of Groningen, Groningen, The Netherlands Since June 2010 Lecturer in Inorganic Chemistry, Aston Unive

研究领域

Dr. P.J. van Koningsbruggen is an experimental inorganic chemist with a specialisation in the field of coordination chemistry. Since 1985 I have been focusing on various aspects of compounds of first-row transition metal ions (Mn, Fe, Ni, Co, Cu, Zn). In particular, the relation between synthetic procedures, structural features of the compounds and their physical (e.g. magnetic and electronic) properties has attracted my attention. In my research I have used a strategic and systematic approach to the design and obtaining of various types of functional materials and I have found this to be extremely worthwhile in unravelling structure-property relationships. I am convinced that the thus obtained knowledge is an essential pre-requisite for the on-going design and obtaining of materials with pre-determined and tuneable functional magnetic, electronic and/or optical properties. The synthetic approach that I use takes advantage of building blocks (metal fragments, anions, ligands etc.) which are assembled using tools from coordination chemistry (stereochemical preferences of the metal ion, coordination geometry etc.), as well as crystal packing efficiency considerations (stacking-, hydrogen bonding and van der Waals interactions etc.). Insight in these parameters is the key to understanding and tuning the physical behaviour and/or reactivity of these transition metal compounds. In addition, the versatility of organic synthesis and the possibility of associating organic and inorganic components on the molecular scale make it possible to propose the additional challenge of engineering multi-property materials which may display synergy between a combination of physical properties.

近期论文

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Powell, RE, Schwalbe, CH, Tizzard, GJ & van Koningsbruggen, PJ 2015, 'Caesium bis-(5-bromo-salicyl-aldehyde thio-semicarbazonato-?3O,N,S)ferrate(III): supramolecular arrangement of low-spin FeIIIcomplex anions mediated by Cs+cations' Acta Crystallographica Section C: Structural Chemistry, vol. 71, no. 3, pp. 169-174,10.1107/S2053229615001928 Powell, R, Schwalbe, C, Tizzard, GJ & Van Koningsbruggen, P 2014, 'Fe III in a low-spin state in caesium bis[3-ethoxysalicylaldehyde 4-methylthiosemicarbazonato(2–)-?3O2,N1,S]ferrate(III) methanol monosolvate' Acta Crystallographica Section C: Structural Chemistry, vol. 70, no. 6, pp. 595-598,10.1107/S2053229614008158 Matovic, ZD, Miletic, VD, Cendic, M, Meetsma, A, Van Koningsbruggen, PJ & Deeth, RJ 2013, 'Synthetic, crystallographic, and computational study of copper(II) complexes of ethylenediaminetetracarboxylate ligands' Inorganic Chemistry, vol. 52, no. 3, pp. 1238-1247,10.1021/ic301609t Antal, á, Jánossy, A, Forró, L, Vertelman, EJM, Van Koningsbruggen, P & Van Loosdrecht, PHM 2010, 'Origin of the ESR spectrum in the Prussian Blue analogue RbMn[Fe(CN)6]*H2O' Physical Review B, vol. 82, no. 1, pp. 014422,10.1103/PhysRevB.82.014422 Yemeli Tido, EW, Faulmann, C, Roswanda, R, Meetsma, A & van Koningsbruggen, PJ 2010, 'Tuning of the charge in octahedral ferric complexes based on pyridoxal-N substituted thiosemicarbazone ligands' Dalton Transactions, vol. 39, no. 6, pp. 1643-1651,10.1039/B911114J Miletic, VD, Meetsma, A, Van Koningsbruggen, P & Matovic, ZD 2009, 'Nickel(II) complexes of whole set of the simple ethylenediaminetetracarboxylate ligands: DFT study of complexes invoking molecular orbital and configurational analysis' Inorganic Chemistry Communications, vol. 12, no. 8, pp. 720-723,10.1016/j.inoche.2009.05.029 Molnár, G, Cobo, S, Mahfoud, T, Vertelman, EJM, van Koningsbruggen, PJ, Demont, P & Bousseksou, A 2009, 'Interplay between the charge transport phenomena and the charge-transfer phase transition in RbxMn[Fe(CN)6]y.zH2O' Journal of Physical Chemistry: Part C, vol. 113, no. 6, pp. 2586-2593,10.1021/jp8090478 Salmon, L, Vertelman, EJM, Murgui, CB, Cobo, S, Molnár, G, Van Koningsbruggen, P & Bousseksou, A 2009, 'Valence-tautomeric RbMnFe Prussian blue analogues: composition and time stability investigation' European Journal of Inorganic Chemistry, vol. 2009, no. 6, pp. 760-768,10.1002/ejic.200800978 Van Koningsbruggen, P, Noble, A & Meetsma, A 2009, 'Metal-organic-frameworks (MOF' s) based on dicyanoargentate units' Abstracts of Papers of the American Chemical Society. Van Koningsbruggen, P, Vertelman, EJM, Tchouka, H & Noble, A 2009, 'Synthesis, structures and physical properties of double metal cyanides' Abstracts of Papers of the American Chemical Society. van Koningsbruggen, PJ & Miller, JS 2008, 'Observation of a 331 K (58 °C) spin transition for bis[hydrotris(1,2,4-triazol-1-yl)borate]iron(II) by variable temperature infrared spectroscopy and magnetic susceptibility measurements' Solid state sciences, vol. 10, no. 12, pp. 1804-1806,10.1016/j.solidstatesciences.2008.04.030 Bhattacharjee, A, Van Koningsbruggen, PJ, Miller, JS & Gütlich, P 2008, 'M?ssbauer spectroscopic study of the thermal spin crossover in [Fe(II)(isoxazole)6](ClO4)2' Journal of Physics and Chemistry of Solids, vol. 69, no. 11, pp. 2713-2718,10.1016/j.jpcs.2008.06.141 Lummen, TTA, Gengler, RYN, Rudolf, P, Lusitani, F, Vertelman, EJM, J. van Koningsbruggen, PJ, Knupfer, M, Molodtsova, O, Pireaux, J-J & van Loosdrecht, PH 2008, 'Bulk and surface switching in Mn-Fe-based Prussian blue analogues' Journal of Physical Chemistry: Part C, vol. 112, no. 36, pp. 14158-14167,10.1021/jp711985f Luzon, J, Castro, M, Vertelman, EJM, Gengler, RYN, van Koningsbruggen, PJ, Molodtsova, O, Knupfer, M, Rudolf, P, van Loosdrecht, PHM & Broer, R 2008, 'Prediction of the equilibrium structures and photomagnetic properties of the Prussian blue analogue RbMn[Fe(CN)6] by density functional theory' Journal of Physical Chemistry: Part A, vol. 112, no. 25, pp. 5742-5748,10.1021/jp800210j Vertelman, EJM, Lummen, TTA, Meetsma, A, Bouwkamp, MW, Molnar, G, van Loosdrecht, PHM & van Koningsbruggen, PJ 2008, 'Light- and temperature-induced electron transfer in single crystals of RbMn[Fe(CN)6]H2O' Chemistry of Materials, vol. 20, no. 4, pp. 1236-1238,10.1021/cm7032965 Yemeli Tido, EW, Alberda van Ekenstein, GOR, Meetsma, A & van Koningsbruggen, PJ 2008, 'Study of neutral Fe(III) complexes of pyridoxal-N-substituted thiosemicarbazone with desolvation induced spin-state transformation above room temperature' Inorganic Chemistry, vol. 47, no. 1, pp. 143-153,10.1021/ic701695b Van Koningsbruggen, P, Vertelman, EJM & Tchouka, H 2008, 'Control of photomagnetic behavior in heterobimetallic Prussian Blue analogs' Abstracts of Papers of the American Chemical Society. Quesada, M, Kooijman, H, Gamez, P, Sánchez Costa, J, van Koningsbruggen, PJ, Weinberger, P, Reissner, M, Spek, AL, Haasnoot, JG & Reedijk, J 2007, '[Fe(μ-btzmp)2(btzmp)2](ClO4)2: a doubly-bridged 1D spin-transition bistetrazole-based polymer showing thermal hysteresis behaviour' Dalton Transactions, no. 46, pp. 5434-5440,10.1039/b709460d Quesada, M, Prins, F, Roubeau, O, Gamez, P, Teat, SJ, van Koningsbruggen, PJ, Haasnoot, JG & Reedijk, J 2007, 'A 2D [FeII-bistetrazole] coordination polymer exhibiting spin-crossover properties' Inorganica Chimica Acta, vol. 360, no. 13, pp. 3787-3796,10.1016/j.ica.2006.12.010 Yemeli Tido, EW, Vertelman, EJM, Meetsma, A & van Koningsbruggen, PJ 2007, 'Crystal structure and magnetic behaviour of a five-coordinate iron(III) complex of pyridoxal-4-methylthiosemicarbazone' Inorganica Chimica Acta, vol. 360, no. 13, pp. 3896-3902,10.1016/j.ica.2007.03.045