Ren, Tong - Purdue University - Department of Chemistry

个人简介

Ph.D., Texas A&M University, 1990 Postdoctorate, Massachusetts Institute of Technology, 1991-93

研究领域

We are pursuing several research fronts rooted in synthetic and physical inorganic chemistry, with emphasis on compounds of importance in electronic and opto-electronic materials, biomimetic chemistry, and energy science. Our effort in the area of carbon-rich organometallic materials focuses on the synthesis and characterization of conjugated Ru2-alkynyl compounds. For their materials application, we are also interested in surface immobilization, SAM formation, current-voltage (I-V) characteristics at nanoscale, and second and third order optical nonlinearity of these compounds. Specific aims include: 1.Molecular wires and devices based on monodisperse oligomeric Ru2-alkynyls 2.Peripheral covalent modifications for supramolecular assembly of metal alkynyl compounds 3.Conjugated and non-conjugated dendrimers of a Ru2 core for photovoltaic application 4.Hierarchical assemblies of nanoparticles with Ru2-oligoyne linkers 5.Bioconjugates of Ru2-alkynyl as sensors (DNA chips) for genomic applications We are interested in biomimetic chemistry of organophosphorous compounds, including functional models of organophosphorous hydrolases and recognition of phosphate containing metabolites. Also of interest is green oxygenation chemistry of organic sulfides. Specific aims include: 1. Detoxification and decontamination protocols for both G- and V-type chemical warfare agents 2.Selective binding of phosphate mono- and di-esters with bimetallic complexes 3.Expedient oxygenation of organic sulfides with inexpensive catalysts 4.Effective removal of dibenzothiophene from fossil fuels via oxygenation-extraction strategy

近期论文

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Dylan J. Thompson, Julia E. Barker Paredes, Leslie Villalobos, Marco Ciclosi, Rachel J. Elsby, Bin Liu, Phillip E. Fanwick and Tong Ren Diruthenium(II,III) Tetracarboxylates Catalyzed H2O2 Oxygenation of Organic Sulfides Inorganica Chimica Acta 2015 424 150-155 Jie-Wen Ying Zhi Cao Charles Campana You Song Jing-Lin Zuo Sarah F. Tyler Tong Ren Linear Trimers of Diruthenium Linked by Polyyndiyl or Phenylenediethynyl Bridges: A Family of Unique Electronic Wires Polyhedron 2015 86 76-80 Timothy D. Cook, Sean N. Natoli, Phillip E. Fanwick and Tong Ren Dimeric Complexes of CoIII(cyclam) with Polyyndiyl Bridge Organometallics 2015 34 686-689 Zhi Cao, Bin Xi, Diane S. Jodoin, Lei Zhang, Steven P. Cummings, Yang Gao, Sarah F. Tyler, Phillip E. Fanwick, Robert J. Crutchley, and Tong Ren Diruthenium-Polyyn-diyl-Diruthenium Wires: Electronic Couplings in the Long Distance Regime J. Am. Chem. Soc. 2014 136 12174–12183 Dylan Thompson, Yang Zhang and Tong Ren Polyoxometalate [ -SiW10O34(H2O)2]4- on MCM-41 as Catalysts for Sulfide Oxygenation with Hydrogen Peroxide J. Mol. Cat. A: Chem. 2014 392 188-193 John A. Gladysz Robin B. Bedford Makoto Fujita Fran?ois P. Gabbai¨ Karen I. Goldberg Patrick L. Holland Jaqueline L. Kiplinger Michael J. Krische Janis Louie Connie C. Lu Jack R. Norton Marina A. Petrukhina Tong Ren Shannon S. Stahl T. Don Tilley Charles Edwin Webster M. Christina White Gregory T. Whiteker Organometallics Roundtable 2013–2014 Organometallics 2014 33 1505-1527 Timothy D. Cook Phillip E. Fanwick Tong Ren Unsymmetric Mononuclear and Bridged Dinuclear Co(III)-cyclam Acetylides Organometallics 2014 33 4621-4624 Sujitra Pookpanratana, Iulia Savchenko, Sean N. Natoli, Steven P. Cummings, Lee J. Richter, Joseph W. F. Robertson, Curt A. Richter, Tong Ren and Christina A. Hacker Attachment of a DirutheniumCompound to Au and SiO2/Si Surfaces by "Click" Chemistry Langmuir 2014 30 10280-10289 Julia Savchenko, Zhi Cao, Sean N. Natoli, Steven P. Cummings, Boone M. Prentice, Phillip E. Fanwick and Tong Ren New Diruthenium Bis-alkynyl Compounds as Potential Ditopic Linkers Organometallics 2013 32 6461-6467 Leslie Villalobos and Tong Ren Oxygenation of organic sulfides catalyzed by simple Fe(III) salts Inorg. Chem. Commun. 2013 28 - 52-54 Leslie Villalobos, Julia E. Barker Paredes, Zhi Cao and Tong Ren TBHP Oxygenation of Organic Sulfides Catalyzed by Diruthenium(II,III) Tetracarboxylates Inorg. Chem. 2013 52 12545-12552 Yang Zhang, Eileen C. Judkins, David R. McMillin, Dhairya Mehta and Tong Ren Mesoporous Silica Supported Ruthenium Oxide Nanoparticulates as Efficient Catalysts for Photo-induced Water Oxidation ACS Catal. 2013 3 2474-2478 Steven P. Cummings, Julia Savchenko, Phillip E. Fanwick, Anastasia Kharlamova, and Tong Ren Diruthenium Alkynyl Compounds with Phosphonate Capping Groups Organometallics 2013 32 1129-1132 Steven P. Cummings, Phillip E. Fanwick, Julia Savchenko and Tong Ren Diruthenium Arylacetylide Compounds with Masked Diazonium Capping Groups J. Organomet. Chem. 2013 745-746 93-97 Zhi Cao, Phillip E. Fanwick, William P. Forrest, Yang Gao and Tong Ren New Fe(III)(cyclam) Complexes Bearing Axially Bound geminal-Diethynylethenes Organometallics 2013 32 4684-4689 Julia Savchenko; Phillip E. Fanwick; H?kon Hope; Yang Gao; Charu K. Yerneni and Tong Ren New Diruthenium (II,III) Compounds Bearing Terminal Olefin Groups Inorg. Chim. Acta 2013 396 144-148 Leslie Villalobos, Zhi Cao, Phillip E. Fanwick and Tong Ren Diruthenium(II,III) tetramidates as a new class of oxygenation catalysts Dalton Trans. 2012 41 - 644-650 William P. Forrest, Zhi Cao, Kerry M. Hassell, Boone M. Prentice, Phillip E. Fanwick, and Tong Ren Diruthenium(III,III) Bis-alkynyl Compounds with Donor/Acceptor Substituted geminal-Diethynylethene (gem-DEE) Ligands Inorg. Chem. 2012 51 - 3261–3269 Xu-Min Cai, Xiang-Yi Zhang, Julia Savchenko, Zhi Cao, Tong Ren, and Jing-Lin Zuo New Linear pi-Conjugated Diruthenium Compounds Containing Axial Tetrathiafulvalene-acetylide Ligands Organometallics 2012 31 - 8591–8597 Zhi Cao; William P. Forrest; Yang Gao; Phillip E. Fanwick; Tong Ren trans-[Fe(cyclam)(C2R)2]+: A New Family of Fe(III) Bis-Alkynyl Compounds Organometallics 2012 31 - 6199-6206