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手性化合物的合成、拆分、结构及其立体化学和应用; 手性化合物的溶液和固体CD光谱; 镜面对称性破缺(Mirror Symmetry Breaking)—发现、表征及其应用

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Shi-Gang Wan, Li-Rong Lin, Li-Li Zeng, Yi-Ji Lin, Hui Zhang. Efficient optical resolution of water-soluble self-assembled tetrahedral M4L6 cages with 1,1′-bi-2-naphthol. Chem. Commun., 2014, 50(97): 15301-15304. 章慧, 颜建新, 吴舒婷, 李丹, 万仕刚, 丁雷, 林丽榕. 对固体圆二色光谱测试方法的再认识—兼谈“浓度效应”. 物理化学学报, 2013, 29(12): 2481-2497. ZHANG Hui, YAN Jian-Xin, WU Shu-Ting, LI Dan, WAN Shi-Gang, DING Lei, LIN Li-Rong. Further Understanding on the Measurement Methods for Solid-State Circular Dichroism Spectroscopy—Discussion on Concentration Effects. Acta Phys. -Chim. Sin., 2013, 29(12): 2481-2497. 赵檑, 万仕刚, 陈成栋, 林以玑, 方雪明, 章慧. 基于非手性邻苯酚胺衍生物的半醌Fe(III)络合物的镜面对称性破缺及其绝对构型关联. 物理化学学报, 2013, 29(6): 1183-1191. Zhao L, Wan S G, Chen C D, Lin Y J, Fang X M, Zhang H. Mirror Symmetry Breaking and Absolute Configuration Correlations of Fe(III) Complexes with Achiral Substituted o-Iminobenzosemiquinonato Ligands. Acta Phys. -Chim. Sin., 2013, 29(6): 1183-1191. Xiao Ma, Chen-Sheng Lin, Hui Zhang, Yi-Ji Lin, Sheng-Min Hu, Tian-Lu Sheng and Xin-Tao Wu. Synthesis, spectral and redox switchable cubic NLO properties of chiral dinuclear iron cyanide/isocyanidebridged complexes. Dalton Trans., 2013, 42(34): 12452-12459. Chun Lin, Wenna Liu, Jun Fan, Yuekui Wang, Shengrun Zheng, Ran Lin, Hui Zhang, Weiguang Zhang, Synthesis of a novel cyclodextrin-derived chiral stationary phase with multiple urea linkages and enantioseparation toward chiral osmabenzene complex. Journal of Chromatography A, 2013, 1283, 68-74. Lirong Lin, Weizhen Fan, Shui Chen, Jie Ma, Wangxia Hu, Yiji Lin, Hui Zhang, Rongbin Huang. Photochromism of (E)-4-phenyl-1-(pyridine-2-ylmethylene)semicarbazide. New J. Chem., 2012, 36(12): 2562-2567 Meiying Wei, Biao Wu, Lei Zhao, Hui Zhang, Shaoguang Li, Yanxia Zhao, Xiao-Juan Yang. A bis- bisurea receptor with the R,R-cyclohexane-1,2-diamino spacer for phosphate and sulfate ions. Org. Biomol. Chem., 2012, 10(44): 8758-8761. Yiji Lin, Fang Zou, Shigang Wan, Jie Ouyang, Lirong Lin, Hui Zhang. Dynamic chiral-at-metal stability of tetrakis(d/l-hfc)Ln(III) complexes capped with an alkali metal cation in solution. Dalton Trans., 2012, 41(22): 6696-6706 章慧, 林丽榕. 配位化学中的镜面对称性破缺. 大学化学, 2012, 27(1): 1-12; 2011, 26(6): 8-15. 刘成勇, 颜建新, 林以玑, 李丹, 方雪明, 章慧. cis-[Ni(NCS)2tren]的镜面对称性破缺:螯环的特殊手性构象. 物理化学学报, 2012, 28(2): 257-264. Yiji Lin, Shigang Wan, Fang Zou, Yuekui Wang, Hui Zhang. Structure-chiroptical property relationship of kinetically labile camphor-derivative β-diketone Yb(III) complexes: The adducts coexist as diastereomer or not ? New J. Chem., 2011, 35(11): 2584-2590. Jian Wang, Lixi Zeng, Dongdong Ding, Xiangjun Li, Hui Zhang, Hong Zhao, Jun Fan, Weiguang Zhang and Yujian He. Studies on the interaction of achiral cationic pseudoisocyanine with chiral metal complexes. Phys. Chem. Chem. Phys., 2011, 13(37): 16741-16747. Lei Ding, Lirong Lin, Chengyong Liu, Hongkun Li, Anjun Qin, Yan Liu, Ling Song, Hui Zhang, Ben Zhong Tang, and Yufen Zhao. Concentration Effect in Solid-State CD Spectra of Chiral Atropisomeric Compounds. New J. Chem., 2011, 35(9): 1781-1786. Jian Wang, Chengyong Liu, Dongdong Ding, Lixi Zeng, Qian Cao, Hui Zhang, Hong Zhao, Yimin Yang, Kaixiang Xiang, Yujian He, Guangwei Wang. Aggregation of anionic porphrin with chiral metal complexes and the competitive binding influences of surfactant and polyelectrolyte. New J. Chem., 2011, 35(7): 1424-1432 Ran Lin, Hong Zhang, Shunhua Li, Leiqi Chen, Weiguang Zhang, Ting Bin Wen, Hui Zhang, Haiping Xia. pH-Switchable Inversion of the Metal-Centered Chirality of Metallabenzenes: Opposite Stereodynamics in Reactions of Ruthenabenzene with L- and D-Cysteine. Chem. Eur. J., 2011, 17(8): 2420-2427. Xiao-Lan Tong, Tong-Liang Hu, Jiong-Peng Zhao, Yue-Kui Wang, Hui Zhang and Xian-He Bu. Chiral magnetic metal-organic frameworks of MnII with achiral tetrazolate-based ligands by spontaneous resolution. Chem. Commun., 2010, (45): 8543-9545. Guochun Yang, Yunjie Xu, Jianbo Hou, Hui Zhang, and Yufen Zhao. Diastereomers of the Pentacoordinate Chiral Phosphorus Compounds in Solution: Absolute Configurations and Predominant Conformations. Dalton Trans., 2010, 39(30): 6953-6959. Wu L, Wang J, Zhu C F, lin Y J, Chen L Q, Fan J, Zhang H. Synthesis, characterization, structures and magnetic property of chiral oxalate-bridged dicopper(II) complexes. Science in China Series B: Chemistry, 2010, 53(7): 1255-1260. Zhao J, Zheng M X, Lin Y J, Chen Y C, Ruan Y P, Zhang H. Inclusion Resolution of 1,1'-Bi-2-naphthol: Crystal Structure and CD Spectroscopy of the Inclusion Complexes. Acta Phys. -Chim. Sin. 2010, 26(7): 1832-1836. Jian Wang, Dongdong Ding, Lixi Zeng, Qian Cao, Yujian He, Hui Zhang. Transformation, Memorization and Amplification of Chirality in Cationic Co(III) Complexes-Porphyrin Aggregates. New J. Chem., 2010, 34(7): 1394-1400.

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