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研究领域

功能配合物,有机金属化学,催化 基于多齿含氮,氧或磷配体的过渡金属配合物的合成,表征以及应用于均相催化:1) 活性Lewis酸催化的新型反应。2)导向的C-H健的活化及其氧化。3)CO2的均相催化氢化和转化。

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Jing Zhang, Tulaza Vaidya, William, W. Brennessel, Alison, J. Frontier, and Richard Eisenberg,"Dicationic Palladium(II) Complexes as Active Lewis Acid Catalysts for Polarized Nazarov Cyclization"Organometallics, 2010, 29, 3341. Abdurrahman C. Atesin, Jing Zhang, Tulaza Vaidya, William, W. Brennessel, Alison, J. Frontier, and Richard, Eisenberg, "Synthesis, Characterization, and Catalytic Propertie of New Electrophilic Iridium(III) complexes Containing the R-(+)-2,2’-Bis(diphenylphosphino)-1,1’-binaphthyl Ligand " Inorg. Chem. 2010, 49,4331. Jing Zhang, Roberto Pattacini, Pierre Braunstein "Tridentate Assembling Ligands Based on Oxazoline and Phosphorus Donors in Dinuclear Pd(I)-Pd(I) complexes " Inorg. Chem. 2009, 48,11954. Boopathy Gnanaprakasam, Jing Zhang, and David Milstein "Direct Synthesis of imines from alcohols and amines with liberation of H2" Angew. Chem. Int. Ed. 2010, 49, 1468. Jing Zhang, Eugene Khaskin, Nicholas P. Anderson, Peter Y. Zavalij and Andrei N. Vedernikov "Catalytic Aerobic Oxidation of Substituted 8-Methylquinolines in PdII – 2,6-Pyridinedicarboxylic Acids Systems" J. Chem Soc. Chem. Commun. 2008, 3625. Jing Zhang, Linda J. W. Shimon, and David Milstein"Stable Carbene and Diazoalkane Complexes of the Same Complex System. Synthesis, Structure and Reactivity of PNP-Ru(II) Fluorenylidene and Diazofluorene Complexes" Organometallics, 2008, 27, 3526. Jing Zhang, Mark Gandelman, Linda J. W. Shimon, and David Milstein "Electron-rich, Bulkyl PNN-type Ruthenium Complexes: Synthesis, Characterization and Catalysis of alcohol dehydrogenation " J. Chem. Soc., Dalton Trans. 2007, 107. Jing Zhang, Gregory Leitus, Yehoshoa Ben-David, David Milstein "Mild, Homogeneous Catalytic Hydrogenation of Esters to Alcohols" Angew. Chem. Int. Ed. 2006, 45, 1113. Jing Zhang, Gregory Leitus, Yehoshoa Ben-David, David Milstein "Facile Conversion of Alcohols into esters and Dihydrogen Catalyzed by New Ruthenium Complexes" J. Am. Chem. Soc. 2005, 127, 10840; this paper was Highlighted in Science, 2005, 309, 803.

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