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稀土金属有机配合物的合成,结构及其催化性能等。

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The salt-free diamido complexes of lanthanide supported by b-diketiminate:Synthesis, characterization, and their catalytic activity for the polymerization of acrylonitrile and e-caprolactone, M. Q. Xue, Y. M. Yao, Q. Shen*, Y. Zhang, J. Organomet. Chem., 2005, 690, 4685. Monoaryloxo Ytterbium(III) Chlorides Supported by b-Diketiminato Ligands as Novel Initiators for the Living Ring-Opening Polymerization of e-Caprolactone, M. Q. Xue, H. M. Sun, H. Zhou, Y. M. Yao, Q. Shen*, Y. Zhang, J. Polym. Sci. Part A: Polym. Chem., 2006, 44, 1147. Syntheses and Structures of Tris-b-Diketiminate Lanthanide Complexes and Their High Activity for Ring-Opening Polymerization of e-Caprolactone and L-Lactide, M. Q. Xue, R. Jiao, Y. Zhang, Y. M. Yao, Q. Shen*, Eur. J. Inorg. Chem. 2009, 4110. A Comparative Study on Reactivity of Tris-β-Diketiminate Ytterbium Complexes: Steric Effect of β-Diketiminato Ligand, R. Jiao, M. Q. Xue,, X. D. Shen, Y. Zhang, Y. M. Yao, Q. Shen*, Eur. J. Inorg. Chem. 2010, 2523. New reaction of b-diketiminatoeuropium complex: sterically induced oxidation-coupling of b-diketiminato ligands, R. Jiao,X. D. Shen,M. Q. Xue,,Y. Zhang, Y. M. Yao, Q. Shen*, Chem. Commun. 2010,46,4118. Deprotonation of β-Diketiminate in Sterically Demanding β-(Diketiminato)lanthanide Complexes: Influence of Lanthanide Metals, R. Jiao, M. Q. Xue,, X. D. Shen, Y. Zhang, Y. M. Yao, Q. Shen*, Eur. J. Inorg. Chem. 2011, 1448.

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