个人简介
Education
1982-1987 Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, CHINA. Received Ph.D. degree in December, 1987 (with Prof. Yao-Zeng Huang).
1978-1982 Department of Chemistry, Lanzhou University, Lanzhou, CHINA. Received B.Sc. degree in June, 1982.
EAcademic Career
1999- Professor, Institute of Elemento-organic Chemistry, Nankai University, Tianjin, CHINA.
1997-1999 Professor, Institute of Fine Chemicals, East China University of Science and Technology, Shanghai, CHINA.
1996-1997 Associate professor, Institute of Fine Chemicals, East China University of Science and Technology, Shanghai, CHINA.
1994-1996 Postdoctoral associate, Department of Chemistry, Trinity University, Texas, USA. (with Prof. Michael P. Doyle).
1992-1994 Postdoctoral associate, Institute of Organic Chemistry, Basel University, Basel, SWITZERLAND (with Prof. Andreas Pfaltz).
1990-1991 Postdoctoral associate, Max-Planck Institute of Polymer Science, Mainz, GERMANY (with Prof. Klaus Müllen).
1988-1990 Postdoctoral associate, Institute of Fine Chemicals, East China University of Science and Technology, Shanghai, CHINA (with Prof. Zheng-Hua Zhu).
Honors & Awards
2021 National Outstanding Professional and Technical Talents
2019 Research Achievement Award of Nankai University
2019 First Prize of National Natural Science Award
2018 Future Science Prize---The Physical Science Prize
2018 Chemistry Contribution Award (Chinese Chemical Society and CNPC)
2017 Boehringer-Ingelheim Lecturer at California Institute of Technology
2016 Gest Professor, Shanghai Institute of Technology
2014 National Outstanding Scientist (China Association for Science and Technology)
2014 Novartis Lecturer (the Scripps Research Institute)
2013 Fellow of Royal Society of Chemistry
2012 Prize of Chiral Chemistry (Chinese Chemical Society)
2009 Academician of Chinese Academy of Sciences
2007 JSPS Fellowship Award (Japan Society for the Promotion of Science)
2006 Yao-Zeng Huang Prize of Organometallics (Chinese Chemical Society)
2005 Prize for Creation in Organic Synthesis (Chinese Chemical Society, Division of Organic Chemistry)
1999 Cheung Kong Scholar (Ministry of Education of China)
1997 Award for Outstanding Young Scientists (National Natural Science Foundation of China)
Professional Memberships
2019- Associate editor, Chemical Journal of Chinese University
2018- Associate editor, CCS Chemistry
2016- Member, Editorial Advisory Board of Helvetica Chimica Acta
2016- Editorial Board of National Science Review
2014- Member, Editorial Advisory Board of Tetrahedron & Tetrahedron Lett.
2014- Member, Advisory Editorial Board of J. Org. Chem.
2012- Member, Advisory Editorial Board of Asian J. Org. Chem.
2011- Member, Editorial Board of Advanced Synthesis & Catalysis
2010- Member, Advisory Editorial Board of Chemical Science
2009- Member, Editorial Board of Series of Topics in Organometallic Chemistry
2008- Member, Editorial Board of Journal of Molecular Catalysis A: Chemical
2007- Member, Editorial Board of Chinese Journal of Organic Chemistry
近期论文
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Biao Wang, Tian-Ze Zhang, Li-Jun Xiao* and Qi-Lin Zhou*. Nickle-Catalyzed Intermolecular Reductive Coupling of Styrene and Its Derivatives with Imines Using Methanol as a Reductant. ACS Catal. 2023, 13, 8692.
Ming-Ming Li, Tian-Ze Zhang, Lei Cheng, Wei-Guo Xiao, Jin-Tao Ma, Li-Jun Xiao* and Qi-Lin Zhou*. Ketone α-alkylation at the more-hindered site. Nat. Commun. 2023, 14, 3326.
Ling Dai, Ying-Ying Chen, Li-Jun Xiao and Qi-Lin Zhou*. Intermolecular Enantioselective Benzylic C(sp3)-H Amination by Cationic Copper Catalysis. Angew. Chem. Int. Ed. 2023, 62, e202304427.
Jia-Bin Pan, Xuan-Ge Zhang, Yi-Fan Shi, Ai-Cui Han, Yu-Jia Chen, Jing Ouyang, Mao-Lin Li* and Qi-Lin Zhou*. A Spiro Phosphamide Catalyzed Enantioselective Proton Transfer of Ylides in a Free Carbene Insertion into N-H Bonds. Angew. Chem. Int. Ed. 2023, 62, e202300691.
Fan Yang, Jian-Hua Xie* and Qi-Lin Zhou*. Highly Efficient Asymmetric Hydrogenation Catalyzed by Iridium Complexs with Tridentate Chiral Spiro Aminophosphine Ligands. Acc. Chem. Res. 2023, 56, 332-349.
Xiao-Ya Sun, Bo-Ying Yao, Bin Xuan, Li-Jun Xiao* and Qi-Lin Zhou*. Recent Advances in Nickle-Catalyzed Asymmetric Hydrofunctionalization of Alkenes. Chem. Catal. 2022, 2, 3140-3162.
Biao Wang, Xian-Ming Liu, Kai-Xiang Zhang, Wei-Ming Feng, Li-Jun Xiao* and Qi-Lin Zhou*. Diastereoselective and Enantioselective Nickle-Catalyzed Reductive Coupling of Imines and Unactivated Alkenes. CCS Chem. 2023, 5, 814-822.
Wei-Ming Feng, Xian-Ming Liu, Li-Jun Xiao* and Qi-Lin Zhou*. Synthesis of Tricyclic [1,2-α]Indoles via Nickle-Catalyzed Intramolecular Imine-Alkene Coupling. Adv. Synth. Catal. 2022. 364. 1.
Mao-Lin Li, Jia-Bin Pan, and Qi-Lin Zhou*. Enantioselective Synthesis of amino acids from ammonia. Nat. Catal. 2022, 5, 571-577.(Mao-Lin Li and Jia-Bin Pan contributed equally.)
Lei Zhang, Xu Cheng*, and Qi-Lin Zhou*. Electrochemical Synthesis of Sulfonyl Fluorides with Triethylamine Hydrofluoride. Chin. J. Chem. 2022, 40, 1687-1692.
Biao Wang, Min-Jie Zhou*, and Qi-Lin Zhou*. Visible-Light-Induced α-γ-C(sp3)-H Difunctionalization of Piperidines. Org. Lett. 2022, 24, 2894.
Lin-Ping Li, Jia-Qi Han, Yun-Ting Liu, Fan Yang, Xiong Wu, Jian-Hua Xie*, and Qi-Lin Zhou. A Three-Steps Process to Facilitate the Enantioselective Assembly of Cis-Fused Octahydrophenanthrenes with a Quaternary Stereocenter. Org. Lett. 2022, 24, 2590.
Xiao-Gen Li, Fu Li, Yue Xu, Li-Jun Xiao, Jian-Hua Xie, Qi-Lin Zhou*. Hydrogenation of Esters by Manganese Catalysts. Adv. Synth. Catal. 2022. 364. 744.
Xue-Song Gu, Ying Xiong, Fan Yang, Na Yu, Pu-Cha Yan*, Jian-Hua Xie*, and Qi-Lin Zhou. Enantioselective Hydrogenation toward Chiral 3-Aryloxy Tetrahydrofurans Enabled by Spiro Ir-PNN Catalysts Containing an Unusual 5-Substituted Chiral Oxazoline Unit. ACS Catal. 2022, 12, 4, 2206-2211.
Tian-Yuan Zhao, Li-Jun Xiao, Qi-Lin Zhou*. Nickel-Catalyzed Desymmetric Reductive Cyclization/Coupling of 1,6-Dienes: An Enantioselective Approach to Chiral Tertiary Alcohol. Angew. Chem. Int. Ed. 2021, 61, e202115702.
Lei Cheng, Ming-Ming Li, Mao-Lin Li, Li-Jun Xiao, Jian-Hua Xie and Qi-Lin Zhou*. Nickle-Catalyzed Regio- and Enantioselective Hydroarylation of 1,3-Dienes with Indoles. CCS Chem. 2021, 3, 3260-3267.
Ying Xiong, Han Lin, Chang-Liang Zhu, Yong-Hong Chen, Rong Ye, Guan-Wen Hu, Jian-Hua Xie*, and Qi-Lin Zhou. Asymmetric Hydrogenation of Racemic α-Aryl-β-ethoxycarbonyl Cyclopentanones via Dynamic Kinetic Resolution and Its Application to the Synthesis of (+)-Burmaniol A. Org Lett. 2021, 23, 22, 8883-8887.
Wei-Min Feng, Tian-Yu Li, Li-Jun Xiao*, and Qi-Lin Zhou*. Nickel-Catalyzed Intramolecular Hydroalkenylation of Imines. Org Lett. 2021, 23, 20, 7900-7904.
Liang-Liang Yang, Jin Cao, Tian-Yuan Zhao. Shou-Fei Zhu*, and Qi-Lin Zhou*. Chiral Dirhodium Tetraphosphate-Catalyzed Enantioselective Si-H Bond Insertion of α-Aryldiazoacetates. J. Org. Chem. 2021, 86, 14, 9692-9698.
Huai-Yu Bin, Li Cheng, Xiong Wu, Chang-Liang Zhu, Xiao-Hui Yang*, Jian-Hua Xie*, and Qi-Lin Zhou. Asymmetric hydrogenation of exocyclic γ,δ-unsaturated β-ketoesters to functionalized chiral allylic alcohols via dynamic kinetic resolution. Chem. Sci. 2021, 12, 7793-7799.
Qian-Kun Zhao, Xiong Wu, Fan Yang, Pu-Cha Yan*, Jian-Hua Xie*, and Qi-Lin Zhou. Catalytic Asymmetric Hrdrogenation of 3-Ethoxycarbonyl Quinolin-2-ones and Coumarins. Org. Lett. 2021, 23, 3593-3598.
Qian-Kun Zhao, Xiong Wu, Lin-Ping Li, Fan Yang, Jian-Hua Xie*, and Qi-Lin Zhou. Asymmetric Hydrogenation of β-Aryl Alkylidene Malonate Esters: Installing an Ester Group Significantly Increases the Efficiency. Org Lett. 2021, 23, 1675-1680.
Dan Yang, Ai-Jiao Yang, Yong Chen, Jian-Hua Xie*, and Qi-Lin Zhou. Asymmmetric Hydrogenation of Racemic 6-Aryl 1,4-Dioxaspiro[4.5]decan-7-ones to Functionalized Chiral β-Aryl Cyclohexanols via a Dynamic Kinetic Resolution. Org. Lett. 2021, 23, 1616-1620.
Tian-Yuan Zhao, Ke Li, Liang-Liang Yang, Shou-Fei Zhu, and Qi-Lin Zhou*. Nickel-Catalyzed Desymmertrizing Cyclization of 1,6-Dienes to Construct Quaternary Stereocenters. Org. Lett. 2021, 23, 10, 3814-3817.
Liang-Liang Yang, Jing Ouyang, Hui-Na Zou, Shou-Fei Zhu*, and Qi-Lin Zhou*. Enantioseletive Insertion of Alkynyl Carbenes into Si-H Bonds: An Efficient Access to Chiral Propargylsilanes and Allenylsilanes. J. Am. Chem. Soc. 2021, 143, 17, 6401-6406.
Xiao-Gen Li, Qi-Lin Zhou*. Manganese-Catalyzed Selective Hydrogenative Cross-Coupling of Nitriles and Amines to Form Secondary Imines. Adv. Synth. Catal. 2021, 363, 1-6.
Chao Fan, Qi-Lin Zhou*. Nickel-Catalyzed group transfer of radicals enables hydrocyanation of alkens and alkynes. Chem. Catalysis. 2021, 1, 1-12.
Chao Fan, Jing Hou, Yu-Jia Chen, Kui-Ling Ding*, and Qi-Lin Zhou*. Rhodium-Catalyzed Regioselective Hydroformylation of Alkynes to α,β-Unsaturated Aldehydes Using Formic Acid. Org. Lett, 2021, 23, 6, 2074-2077.
Liu-Yang Pu, Fan Yang, Ji-Qiang Chen, Ying Xiong, Jian-Hua Xie*, and Qi-Lin Zhou*. Enantioselective Total Synthesis of Pentacyclic Proaporphine Alkaloid (-)-Misramine. Adv. Synth. Catal. 2021, 363. 785.
Ming-Ming Li, Lei Cheng, Li-Jun Xiao, Jian-Hua Xie, Qi-Lin Zhou*.Palladium-Catalyzed Asymmetric Hydrosulfonylation of 1,3-Dienes with Sulfonyl Hydrazides. Angew, Chem, Int, Ed. 2021, 60, 2948-2951,
Ji-Min Yang, Feng-Kai Guo, Yu-Tao Zhao, Qiao Zhang, Ming-Yao Huang, Mao-Lin Li, Shou-Fei Zhu*, and Qi-Lin Zhou*. Insertion of Alkylidiene Carbenes into B-H Bonds. J. Am. Chem. Soc. 2020, 142, 50, 20924-20929.
Yuan-Yuan Ren, Hong-Xiang Mao, Dr.Meng-Yang Hu, Prof.Shou-Fei Zhu*, Prof.Qi-Lin Zhou*. Cu/PCy3-Catalyzed Formal Carbene Insertion into Electron-Deficient C-H Bonds. ChemCatChem, 2020, 12(17), 4267-4271.
Liu-Yang Pu, Fan Yang, Ji-Qiang Chen, Ying Xiong, Huai-Yu Bin, Jian-Hua Xie*, and Qi-Lin Zhou*. Enantioselective Total Syntheses of Pentacyclic Homeproaporphine Alkaloids. Org. Lett. 2020, 22, 19, 7526-7530.
Cheng Lei, Zhou Qilin. Advances on Nickel-Catalyzed C(sp3)-C(sp3) Bond Formation(镍催化构筑sp3碳碳键反应研究进展）. Acta Chimica Sinica,2020, 78, 1017-1029.
Mao-Lin Li, Yao Li, Jia-Bin Pan, Yi-Hao Li, Song Song, Shou-Fei Zhu*, and Qi-Lin Zhou*. Carboxyl Group-Directed Iridium-Catalyzed Enantioselective Hydrogenation of Aliphatic γ-Ketoacids .ACS Catal. 2020, 10, 17, 10032-10039.
Liang-Liang Yang, Declan Evans, Bin Xu, Wen-Tao Li, Mao-Lin Li, Shou-Fei Zhu*, K. N. Houk*, and Qi-Lin Zhou*. Enantioselective Diarylcarbene Insertion into Si-H Bonds Induced by Electronic Properties of the Carbenes.J. Am. Chem. Soc. 2020, 142, 28, 12394-12399.
Feng-Hua Zhang, Fa-Jian Zhang, Mao-Lin Li, Jian-Hua Xie and Qi-Lin Zhou*. Enantioselective hydrogenation of dialkyl ketones. Nat. Catal 2020, 3, 621-627.
Yun-Yu Hua, Huai-Yu Bin, Tao Wei, Hou-An Cheng, Zu-Peng Lin, Xing-Feng Fu, Yuan-Qiang Li, Jian-Hua Xie*, Pu-Cha Yan* and Qi-Lin Zhou. Iridium-Catalyzed Asymmetric Hydrogenation of γ- and δ-Ketoacids for Enantioselective Synthesis of γ- and δ-Lactones. Org. Lett. 2020, 22, 818-822. (Yun-Yu Hua and Huai-Yu Bin contributed equally)
You Li, Yu-Tao Zhao, Ting Zhou, Meng-Qing Chen, Yi-Pan Li, Ming-Yao Huang, Zhen-Chuang Xu, Shou-Fei Zhu,* and Qi-Lin Zhou. Highly Enantioselective O-H Bond Insertion Reaction of α-Alkyl- and α-Alkenyl-α-diazoacetates with Water. J. Am. Chem. Soc. 2020, 142, 23, 10557-10566.
Yi-Pan Li, Shou-Fei Zhu,* and Qi-Lin Zhou.* Chiral Spiro Phosphoramide-Catalyzed Sulfa-Michael Addition/enantioselective Protonation of Exocyclic Enones. Org. Lett. 2019, 21, 9391-9395.
Lei Cheng, Ming-Ming Li, Biao Wang, Li-Jun Xiao,* Jian-Hua Xie, and Qi-Lin Zhou.* Nickel-Catalyzed Hydroalkylation and Hydroalkenylation of 1,3-Dienes with Hydrazones. Chem. Sci. 2019, 10, 10417-10420.
Xue-Song Gu, Xiao-Gen Li, Jian-Hua Xie,* and Qi-Lin Zhou. Recent Progress in Homogeneous Catalytic Hydrogenation of Esters. Acta Chim. Sinica 2019, 77, 598-612. (Review)
Xin-Yang Lv, Chao Fan, Li-Jun Xiao,* Jian-Hua Xie, and Qi-Lin Zhou.* Ligand-Enabled Nickel-Catalyzed Enantioselective Hydroarylation of Styrenes and 1,3-Dienes with Arylboronic Acids. CCS Chem. 2019, 1(4) 328-334.
Yi-Pan Li, Zi-Qi Li, Biying Zhou, Mao-Lin Li, Xiao-Song Xue, Shou-Fei Zhu,* and Qi-Lin Zhou.* Chiral Spiro Phosphoric Acid-Catalyzed Friedel-Crafts Conjugate Addition/ Enantioselective Protonation Reactions. ACS Catal. 2019, 9. 6522-6529.
Xue-Song Gu, Na Yu, Xiao-Hui Yang, An-Te Zhu, Jian-Hua Xie,* and Qi-Lin Zhou. Enantioselective Hydrogenation of Racemic α-Arylamino Lactones to Chiral Amino Diols with Site-Specifically Modified Chiral Spiro Iridium Catalysts. Org. Lett. 2019, 21, 4111-4115.
Feng-Hua Zhang, Chen Wang, Jian-Hua Xie, and Qi-Lin Zhou.* Synthesis of Tridentate Chiral Spiro Aminophosphine-oxazoline Ligands and Application to Asymmetric Hydrogenation of α-Keto Amides. Adv. Synth. Catal. 2019, 361, 2832-2835.
Wen Che, Yu-Zhen Li, Jin-Chi Liu, Shou-Fei Zhu, Jian-Hua Xie, and Qi-Lin Zhou.* Stereodiverse Iterative Synthesis of 1,3-Polyol Arrays through Asymmetric Catalytic Hydrogenation. Formal Total Synthesis of (−)-Cyanolide A. Org. Lett. 2019, 21, 2369-2373.
Wen Che, Danyang C. Wen, Shou-Fei Zhu, and Qi-Lin Zhou.* Enantioselective Total Synthesis of (−)‐Doliculide Using Catalytic Asymmetric Hydrogenations. Helv. Chim. Acta 2019, 102, e1900023.
Chao Fan, Xin-Yang Lv, Li-Jun Xiao,* Jian-Hua Xie, and Qi-Lin Zhou.* Alkenyl Exchange of Allylamines via Nickel(0)-Catalyzed C−C Bond Cleavage. J. Am. Chem. Soc. 2019, 141, 2889-2893.
Min-Jie Zhou, Shou-Fei Zhu, and Qi-Lin Zhou.* Iodine-Catalyzed Oxidative Rearrangement of Amines to α-Amino Acetals and α-Amino Aldehydes. Adv. Synth. Catal. 2019, 361, 1289-1294.
Li-Jun Xiao, Meng-Chun Ye,* and Qi-Lin Zhou.* Nickel-Catalyzed Highly Atom-Economical C–C Coupling Reactions with π Components. Synlett. 2019, 30, 361-369. (Account)
Huai-Yu Bin, Ke Wang, Dan Yang, Xiao-Hui Yang, Jian-Hua Xie,* and Qi-Lin Zhou. Scalable Enantioselective Total Synthesis of (‐)‐Goniomitine. Angew. Chem., Int. Ed. 2019, 58, 1174-1177.
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