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Dynamic Kinetic Reductive Conjugate Addition for Construction of Axial Chirality Enabled by Synergistic Photoredox/Cobalt Catalysis Wei Xiong,# Xuan Jiang,# Wen-Cheng Wang, Ying Cheng, Liang-Qiu Lu, Ke Gao,* and Wen-Jing Xiao*DOI: 10.1021/jacs.2c13538
Dearomatization-Rearomatization Reaction of Metal-Polarized Aza-ortho-Quinone Methides Bao-Cheng Wang,‡ Li Rao,‡ Kai-Xin Fang,‡ Bao-Le Qu, Fen-Ya Xiong, Ying Feng, Ying Tan,* Liang-Qiu Lu,* Wen-Jing Xiao DOI: 10.1002/anie.202301592
Advances in the construction of axially chiral biaryl-contained medium-sized rings via asymmetric catalysi Baole Qu, Lin He, Junwei Shi, Liangqiu Lu*, Wenjing Xiao,*DOI: 10.1360/SSC-2022-0244
Photoinduced Cobalt-Catalyzed Desymmetrization of Dialdehydes to Access Axial Chirality Hao Jiang,‡ Xiang-Kui He,‡ Xuan Jiang,‡ Wei Zhao, Liang-Qiu Lu, Ying Cheng,* and Wen-Jing Xiao*DOI: 10.1021/jacs.3c00462
Cobalt-Catalyzed Asymmetric Phospha-Michael Reaction of Diarylphosphine Oxides for the Synthesis of Chiral Organophosphorus Compounds Yu, X.-H.; Lu, L.-Q.; Zhang, Z.-H.; Shi, D.-Q.* and Xiao, W.-J. Org. Chem. Front., 2022, Article ASAP DOI: 10.1039/D2QO01483A
Taming Chiral Quaternary Stereocenters via Remote H-Bonding Stereoinduction in Palladium-Catalyzed (3+2) Cycloadditions Xiao, Y.-Q.; Li, M.-M.; Zhou, Z.-X.; Li, Y.-J.; Cao, M.-Y.; Liu, X.-P.; Lu, H.-H.; Li, R.; Lu, L.-Q.*; Beauchemin, A. M. and Xiao, W.-J. Angew. Chem. Int. Ed. 2022, In press. DOI: 10.1002/anie.202212444
Construction of enantioenriched eight-membered lactones via Pd-catalyzed asymmetric (6+2) dipolar annulation B.-C. Wang, Y. Wei, F.-Y. Xiong, B.-L. Qu, W.-J. Xiao, L.-Q. Lu*. Sci. China Chem. (2022) DOI: 10.1007/s11426-022-1374-4
De Novo Construction of Chiral Aminoindolines by Cu-Catalyzed Asymmetric Cyclization and Subsequent Discovery of an Unexpected Sulfonyl Migration Wang, B.-C.; Fang, T.-T.; Xiong, F.-Y.; Chen, P.; Fang, K.-X.; Tan, Y.*; Lu, L.-Q.* and Xiao, W.-J. J. Am. Chem. Soc. 2022, ASAP. DOI: 10.1021/jacs.2c08090
Construction of axial chirality via asymmetric radical trapping by cobalt under visible light Jiang, X.; Xiong, W.; Deng, S.; Lu, F.-D.; Jia, Y.; Yang, Q.; Xue, L.-Y.; Qi, X.-T.; Tunge, J. A.; Lu, L.-Q.* and Xiao, W.-J.* Nat., Catal. 2022, 5, 788-797. DOI: 10.1038/s41929-022-00831-1
Photoinduced C–O bond cleavage for copper-catalyzed allenyl radical cyanation Lu, F.-D.; Shu, Z.-C.; He, G.-F.; Bai, J.-C.; Lu, L.-Q.* and Xiao, W.-J.* Org. Chem. Front., 2022, 9, 5259-5263. DOI: 10.1039/D2QO00938B
High-order dipolar annulations with metal-containing reactive dipoles Zhang, M.-M.;† Qu, B.-L.;† Shi, B.;† Xiao, W.-J. and Lu, L.-Q.* Chem. Soc. Rev. 2022, 51, 4146-4174. DOI: 10.1039/D1CS00897H
Photoassisted Cobalt-Catalyzed Asymmetric Reductive Grignard-Type Addition of Aryl Iodides Jiang, X.; Jiang, H.; Yang, Q.; Cheng, Y.; Lu, L.-Q.*; J. A. Tunge and Xiao, W.-J.* J. Am. Chem. Soc. 2022, 144, 8347-8354. DOI: 10.1021/jacs.2c02481
Synthesis of Chiral Endocyclic Allenes by Palladium-Catalyzed Asymmetric Annulation Followed by Cope Rearrangement Shi, B.; Liu, J.-B.; Wang, Z.-T.; Wang, L.; Lan, Y.; Lu, L.-Q.* and Xiao, W.-J. Angew. Chem. Int. Ed. 2022, 61, e202117215. DOI: 10.1002/anie.202117215
Photoredox-Enabled Chromium-Catalyzed Alkene Diacylations Liu, J.;Lu, L.-Q.; Luo, Y.-X.; Zhao, W.; Sun, P.-C.; Jin, W.-W.; Qi, X.-T.*; Cheng, Y.* and Xiao, W.-J.* ACS Catal. 2022, 12, 1879–1885 DOI: 10.1021/acscatal.1c05672
A cooperative Pd/Co catalysis system for the asymmetric (4+2) cycloaddition of vinyl benzoxazinones with N-acylpyrazoles Wei Xiong, Xuan Jiang, Mao-Mao Zhang, Wen-Jing Xiao and Liang-Qiu Lu* Chem. Commun., 2021, 57, 13566-13569. DOI: 10.1039/D1CC05952A
Aerobic oxidation of C-H bonds to carboxylic acids enabled by decatungstate photocatalysis Jing Liu, Wei Zhao, Liang-qiu Lu, Yi-yin Liu, Ying Cheng,* and Wen-jing Xiao Green Synthesis and Catalysis, 2021, 2, 389-392. DOI: 10.1016/j.gresc.2021.10.003
A Dipolar Cyclization/Fragmentation Strategy for the Catalytic Asymmetric Synthesis of Chiral Eight-Membered Lactams Mao-Mao Zhang , Peng Chen , Wei Xiong , Xin-Shang Hui , Liang-Qiu Lu* and Wen-Jing Xiao CCS Chem., 2021, 3, 3383-3392. DOI: 10.31635/ccschem.021.202101476
Recent advances in transition-metal-catalysed asymmetric coupling reactions with light intervention F.-D. Lu,1 J. Chen,1 X. Jiang,1 J.-R. Chen, L.-Q. Lu,* and W.-J. Xiao* Chem. Soc. Rev., 2021, Advance Article DOI: 10.1039/D1CS00210D
Synthesis of hydroindoles via desymmetric [3+2] cycloadditions of para-quinamines with photogenerated ketenes D. Liu, B. Shi, H. Jiang, Y. Cheng, W.-J. Xiao, L.-Q. Lu* Chem. Commun., 2021, 57, 8496-8499. DOI: 10.1039/D1CC03352B
Photoredox Catalysis Unlocks a Nickel-Catalyzed Cyanation of Aryl Halides under Benign Conditions. Jia, Y.#; Liu, Y.-Y. #; Lu, L.-Q. #; Liu. S.-H.; Zhou, H.-B.; Lan, Y.* and Xiao, W.-J.* CCS Chem. 2021, 3, 2032–2041. DOI:10.31635/ccschem.021.202100934
Metallaphotoredox Catalysis for Multicomponent Coupling Reactions F.-D. Lu, G.-F. He, L.-Q. Lu,* and W.-J. Xiao* Green Chem., 2021, 23, 5379-5393. DOI: 10.1039/D1GC00993A
Enantioselective trapping of palladium-stabilized oxo-1,4-dipoles with photochemically generated ketenes Li, M.-M.; Qu, B.-L.; Xiao, Y.-Q.; Xiao, W.-J. and Lu, L.-Q.* Science Bulletin. 2021, 66, 1719-1722. DOI: 10.1016/j.scib.2021.04.03
A cooperative Pd/Co catalysis system for the asymmetric (4+2) cycloaddition of vinyl benzoxazinones with N-acylpyrazoles Wei Xiong, Xuan Jiang, Mao-Mao Zhang, Wen-Jing Xiao and Liang-Qiu Lu* Chem. Commun., 2021, 57, 13566-13569. DOI: 10.1039/D1CC05952A
Aerobic oxidation of C-H bonds to carboxylic acids enabled by decatungstate photocatalysis Jing Liu, Wei Zhao, Liang-qiu Lu, Yi-yin Liu, Ying Cheng,* and Wen-jing Xiao Green Synthesis and Catalysis, 2021, 2, 389-392. DOI: 10.1016/j.gresc.2021.10.003
A Dipolar Cyclization/Fragmentation Strategy for the Catalytic Asymmetric Synthesis of Chiral Eight-Membered Lactams Mao-Mao Zhang , Peng Chen , Wei Xiong , Xin-Shang Hui , Liang-Qiu Lu* and Wen-Jing Xiao CCS Chem., 2021, 3, 3383-3392. DOI: 10.31635/ccschem.021.202101476
Recent advances in transition-metal-catalysed asymmetric coupling reactions with light intervention F.-D. Lu,1 J. Chen,1 X. Jiang,1 J.-R. Chen, L.-Q. Lu,* and W.-J. Xiao* Chem. Soc. Rev., 2021, Advance Article DOI: 10.1039/D1CS00210D
Photoinduced Copper-Catalyzed Asymmetric Three-Component Coupling of 1,3-Dienes: An Alternative to Kharasch-Sosnovsky Reaction P.-Z. Wang, X. Wu, Y. Cheng, M. Jiang, W.-J. Xiao*, J.-R. Chen* Angew. Chem. Int. Ed. 2021, 60, 22956-22962. DOI: 10.1002/anie.202110084
Photoinduced Copper-Catalyzed Asymmetric C–O Cross-Coupling J. Chen# Y.-J. Liang# P.-Z. Wang, G.-Q. Li, B. Zhang, H. Qian, X.-D. Huan, W. Guan* W.-J. Xiao* J.-R. Chen* J. Am. Chem. Soc. 2021, 143,13382-11392. DOI: 10.1021/jacs.1c06535
Recent advances in radical-mediated transformations of 1,3-dienes P.-Z. Wang, W.-J. Xiao, J.-R. Chen* Chin. J. Catal. 2021, 42, ASAP. DOI: 10.1016/S1872-2067(21)63919-0
Visible-Light-Driven Photoredox-Catalyzed Three-Component Radical Cyanoalkylfluorination of Alkenes with Oxime Esters and a Fluoride Ion H. Qian, J. Chen, B. Zhang, Y. Cheng, W.-J. Xiao, J.-R. Chen* Org. Lett. 2021, 23, 6987–6992. DOI: 10.1021/acs.orglett.1c02686
Alkene Synthesis by Photo-Wolff-Kischner Reaction of Sulfur Ylides and N-Tosylhydrazones P.-P. Gao, D.-M. Yan, M.-H. Bi, M. Jiang, W.-J. Xiao, J.-R. Chen* Chem. Eur. J. 2021, 27, 14195-14201. DOI: 10.1002/chem.202102671
Visible-light-induced tandem radical addition/cyclization of 2-alkenylphenols and CBr4 for synthesis of 4-arylcoumarins L.-P. Tan# D. Liang# Y. Cheng, W.-J. Xiao, J.-R. Chen* Org. Chem. Front. 2021, 8, 5052-5057. DOI: 10.1039/d1qo00831e
Photoredox-Catalyzed Iminoalkenylation of Alkenes for Diastereoselective and Stereodivergent Synthesis of 2-Cinnamylpyrrolines X.-S. Zhou, J.-R. Chen* J. Org. Chem. 2021, 41, 2146-147. DOI: 10.6023/cjoc202100037
Synthesis of hydroindoles via desymmetric [3+2] cycloadditions of para-quinamines with photogenerated ketenes D. Liu, B. Shi, H. Jiang, Y. Cheng, W.-J. Xiao, L.-Q. Lu* Chem. Commun., 2021, 57, 8496-8499.DOI: 10.1039/D1CC03352B
Photoredox Catalysis Unlocks a Nickel-Catalyzed Cyanation of Aryl Halides under Benign Conditions. Jia, Y.#; Liu, Y.-Y. #; Lu, L.-Q. #; Liu. S.-H.; Zhou, H.-B.; Lan, Y.* and Xiao, W.-J.* CCS Chem. 2021, 3, 2032–2041. DOI:10.31635/ccschem.021.202100934
Metallaphotoredox Catalysis for Multicomponent Coupling Reactions F.-D. Lu, G.-F. He, L.-Q. Lu,* and W.-J. Xiao* Green Chem., 2021, 23, 5379-5393. DOI: 10.1039/D1GC00993A
Enantioselective trapping of palladium-stabilized oxo-1,4-dipoles with photochemically generated ketenes Li, M.-M.; Qu, B.-L.; Xiao, Y.-Q.; Xiao, W.-J. and Lu, L.-Q.* Science Bulletin. 2021, 66, 1719-1722. DOI: 10.1016/j.scib.2021.04.03
Asymmetric three-component olefin dicarbofunctionalization enabled by photoredox and copper dual catalysis P.-Z. Wang#, Y. Gao#, J. Chen, X.-D. Huan, W.-J. Xiao*, J.-R. Chen* Nat. Commun. 2021, 12, 1815. DOI: 10.1038/s41467-021-22127-x
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