当前位置：
X-MOL 学术
›
Adv. Synth. Catal.
›
论文详情
Our official English website, www.x-mol.net, welcomes your
feedback! (Note: you will need to create a separate account there.)
Fullerotetrahydroquinolines: TfOH/TsOH ⋅ H2O-Mediated One-Pot Two-Step Synthesis and N-Alkylation/Acylation/Carboamidation Reaction
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2021-07-20 , DOI: 10.1002/adsc.202100659 Xiong Liu 1 , Xing-Yu Wang 1 , Rui Sun 1 , Min-Rong Huang 1 , Xiu-Shan Liu 1 , Hui-Juan Wang 1 , Fa-Bao Li 2 , Xu-Feng Liu 1 , Li Liu 2 , Chao-Yang Liu 1
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2021-07-20 , DOI: 10.1002/adsc.202100659 Xiong Liu 1 , Xing-Yu Wang 1 , Rui Sun 1 , Min-Rong Huang 1 , Xiu-Shan Liu 1 , Hui-Juan Wang 1 , Fa-Bao Li 2 , Xu-Feng Liu 1 , Li Liu 2 , Chao-Yang Liu 1
Affiliation
|
A series of N-unsubstituted/substituted fullerotetrahydroquinolines without a directly attached nitrogen atom were synthesized in moderate to good yields via a one-pot two-step reaction of [60]fullerene with arylamines and paraformaldehyde in the presence of trifluoromethanesulfonic acid and p-toluenesulfonic acid monohydrate. Aromatic primary amines produce N-unsubstituted fullereotetrahydroquinolines, while aromatic secondary amines give N-substituted fullereotetrahydroquinoline derivatives. As precursors, N-unsubstituted fullerotetrahydroquinolines could be further derivatized by the N-alkylation/acylation/carboamidation reactions to produce a large variety of N-substituted fullerotetrahydroquinolines containing Cl, NO2, C(O), and C(O)NH functional groups, which may have applications in the field of perovskite-based solar cells. Plausible reaction pathways for the formation of N-unsubstituted/substituted fullerotetrahydroquinolines were suggested to elucidate the above-mentioned reaction process.
中文翻译：
富勒四氢喹啉：TfOH/TsOH ⋅ H2O 介导的一锅两步合成和 N-烷基化/酰化/碳酰胺化反应
在三氟甲磺酸和对甲苯磺酸的存在下，通过 [60] 富勒烯与芳胺和多聚甲醛的一锅两步反应，合成了一系列没有直接连接氮原子的N-未取代/取代的富勒四氢喹啉。酸一水合物。芳族伯胺产生Ñ -未被取代fullereotetrahydroquinolines，而芳族仲胺，得到Ñ取代fullereotetrahydroquinoline衍生物。作为前体，N-未取代的富勒四氢喹啉可以通过N-烷基化/酰化/碳酰胺化反应进一步衍生，以产生多种N含有Cl、NO 2、C(O) 和C(O)NH 官能团的-取代的富勒四氢喹啉，可能在基于钙钛矿的太阳能电池领域有应用。提出了形成N-未取代/取代的富勒四氢喹啉的合理反应途径来阐明上述反应过程。
更新日期：2021-09-21
中文翻译：
富勒四氢喹啉：TfOH/TsOH ⋅ H2O 介导的一锅两步合成和 N-烷基化/酰化/碳酰胺化反应
在三氟甲磺酸和对甲苯磺酸的存在下，通过 [60] 富勒烯与芳胺和多聚甲醛的一锅两步反应，合成了一系列没有直接连接氮原子的N-未取代/取代的富勒四氢喹啉。酸一水合物。芳族伯胺产生Ñ -未被取代fullereotetrahydroquinolines，而芳族仲胺，得到Ñ取代fullereotetrahydroquinoline衍生物。作为前体，N-未取代的富勒四氢喹啉可以通过N-烷基化/酰化/碳酰胺化反应进一步衍生，以产生多种N含有Cl、NO 2、C(O) 和C(O)NH 官能团的-取代的富勒四氢喹啉，可能在基于钙钛矿的太阳能电池领域有应用。提出了形成N-未取代/取代的富勒四氢喹啉的合理反应途径来阐明上述反应过程。
京公网安备 11010802027423号