Tiara[5]arenes, five‐fold symmetric macrocycles consisting of phenolic units linked by para‐substituted methylene bridges, were synthesized by H. Zuilhof, A. C.‐H. Sue, and co‐workers. In their Research Article (DOI: 10.1002/anie.201913055), the construction and derivatization are demonstrated, along with solid‐state structures, host–guest properties in solution, and application as nonporous adaptive crystals for the separation of benzene and cyclohexane.

中文翻译：

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Tiara [5]芳烃：合成，固态构象研究，宿主-客体特性以及作为无孔自适应晶体的应用

Tiara [5]芳烃是由对位取代的亚甲基桥连接的酚单元组成的五重对称大环，由AC-H的H. Zuilhof合成。苏和同事。在他们的研究文章（DOI：10.1002 / anie.201913055）中，其结构和衍生化以及固态结构，溶液中的主体-客体特性以及作为无孔自适应晶体用于苯和环己烷分离的应用得到了证明。