成果及论文 - 香港中文大学谢作伟院士团队

2019

290. Catalytic Cascade Dehydrogenative Cross-Coupling of BH/CH and BH/NH: One-Pot Process to Carborano-Isoquinolinone
Au, Y. K.; Lyu, H.; Quan, Y.; Xie, Z.
J. Am. Chem. Soc. 2019, 141, 12855-12862.

289. How long a C–C bond can be? An example of extraordinary long C–C single bond in 1,2-diarylamino-o-carborane

Wu, Y.; Zhang, J.; Xie, Z.
Chin. Chem. Lett. 2019, ASAP.

288. Rhodium catalyzed cascade cyclization featuring B–H and C–H activation: one-step construction of carborane-fused N-polyheterocycles
Lyu, H.; Zhang, J.; Yang, J.; Quan, Y.; Xie, Z.
J. Am. Chem. Soc. 2019, 141, 4219-4224.

287. Controlled functionalization of o-carborane viatransition metal catalyzed B–H activation
Quan, Y.; Xie, Z.
Chem. Soc. Rev. 2019, ASAP.

286. Nucleophilic substitution: a facile strategy for selective B–H functionalization of carboranes
Quan, Y.; Tang, C.; Zhang, J.; Xie, Z.
Dalton Trans. 2019, ASAP.

285. Copper catalyzed/mediated direct B–H alkenylation/alkynylation in carboranes
Chen, Y.; Au, Y. K.; Quan, Y.; Xie, Z.
Sci China Chem, 2019, 62, 74-79.

2018

284. Regioselective Nucleophilic Alkylation/Arylation of B–H Bonds in o-Carboranes: An Alternative Method for Selective Cage Boron Functionalization
Tang, C.; Zhang, J.; Zhang, J.; Xie, Z.
J. Am. Chem. Soc., 2018, 140, 16423-16427.

283. Broad Scope Extra‐Annular [4 + 2] Cycloaddition of o‐Carboryne with Styrenes: Efficient Route to Carborane‐Fused Polycyclics
Zhang, J.; Xie, Z.
Chin. J. Chem. 2018, 36, 1041-1046.

282. Rhodium catalyzed cascade cyclization featuring B–H and C–H activation: one-step construction of carborane-fused N-polyheterocycles
Lyu, H.; Quan, Y.; Xie, Z.
Chem. Sci., 2018, 9, 6390-6394

281. Reaction of o‐Carboryne with Furans: Facile Synthesis of Carborane-Fused Oxanorbornenes and Their Derivatives
Zhang, R.; Yuan, Y.; Qiu, Z.; Xie, Z.
Chin. J. Chem. 2018, 36, 273-279.

280. 16th International Meeting on Boron Chemistry (IMEBORON XVI)
Xie, Z.
Pure Appl. Chem. 2018, 90, 605.

279. Enantioselective Synthesis of Chiral-at-Cage o-Carboranes via Pd-Catalyzed Asymmetric B–H Substitution
Cheng, R.; Li, B.; Wu, J.; Zhang, J.; Qiu, Z.; Tang, W.; You, S. L.; Tang, Y.; Xie, Z.
J. Am. Chem. Soc. 2018, 140, 4508-4511.

278. Transition‐Metal‐Like Behavior of Monovalent Boron Compounds: Reduction, Migration, and Complete Cleavage of CO at a Boron Center
Wang, H.; Wu, L.; Lin, Z.; Xie, Z.
Angew. Chem. Int. Ed. 2018, 57, 8708-8713.

277. Borylene Insertion into Cage B–H Bond: A Route to Electron-Precise B–B Single Bond
Wang, H.; Zhang, J.; Lee, H. K.; Xie, Z.
J. Am. Chem. Soc. 2018, 140, 3888-3891.

276. Synthesis, structure and reactivity of a carborane-fused silylene 1-{[PhC(NtBu)2]Si}-1,2-C2B10H11
Wang, H.; Zhang, J.; Xie, Z.
J. Organomet. Chem. 2018, 865, 173-177.

275. Transition‐Metal‐Catalyzed Selective Cage B−H Functionalization of o‐Carboranes
Quan, Y.; Qiu, Z.; Xie, Z.
Chem. Eur. J. 2018, 24, 2795-2805.

274. Cage carbon-substitute does matter for aggregation-induced emission features of o-carborane-functionalized anthracene triads
Wu, X.; Guo, J.; Quan, Y.; Jia, W.; Jia, D.; Chen, Y.; Xie, Z.
J. Mater. Chem. C 2018, 15, 4140-4149.

273. Synthesis of carborane-fused carbo- and heterocycles via zirconacyclopentane intermediates
Cui, C. X.; Ren, S.; Qiu, Z.; Xie, Z.
Dalton Trans. 2018, 47, 2453-2459.

272. Synthesis, structure and aromaticity of carborane-fused carbo- and heterocycles
Chan, T. L.; Xie, Z.
Chem. Sci. 2018, 9, 2284-2289.

271. Cyclic amino(carboranyl) silylene: synthesis, structure and reactivity
Wang, H.; Chan, T. L.; Xie, Z.
Chem. Commun. 2018, 54, 385-388.

2017

270. Broad Scope [4 + 2] Cycloaddition of o-Carboryne with Pentafulvenes Using 1-Li-2-OTf-o-C2B10H10 as Precursor
Zhang, J.; Qiu Z.; Xie, Z.
Organometallics 2017, 36, 3806-3811.

269. Synthesis, Structure and Reactivity of a Borylene Cation [(NHSi)2B(CO)]+ Stabilized by Three Neutral Ligands
Wang, H.; Wu, L.; Lin, Z.; Xie, Z.
J. Am. Chem. Soc. 2017, 139, 13680-13683.

268. Transition Metal Catalyzed Regioselective B (4)‐Halogenation and B (4, 5)‐Diiodination of Cage B‐H Bonds in o‐Carboranes
Lyu, H.; Quan, Y.; Xie, Z.
Chem. Eur. J. 2017, 23, 14866-14871.

267. Reversible Photothermal Isomerization of Carborane-Fused Azaborole to Borirane: Synthesis and Reactivity of Carbene-Stabilized Carborane-Fused Borirane
Wang, H.; Zhang, J.; Xie, Z.
Angew. Chem. Int. Ed. 2017, 56, 9198-9201.

266. Direct Nucleophilic Substitution Reaction of Cage B−H Bonds by Grignard Reagents: A Route to Regioselective B4-Alkylation of o-Carboranes
Tang, C.; Zhang, J.; Xie, Z.
Angew. Chem. Int. Ed. 2017, 56 , 8642-8646.

265. Iridium-catalysed regioselective borylation of carboranes via direct B-H activation
Cheng, R.; Qiu, Z.; Xie, Z.
Nat Commun. 2017, 8, 14827.

264. Reactivity of mixed-sandwich zirconacarborane alkyls with polar unsaturated molecules
Liu, D.; Qiu, Z.; Xie, Z.
J. Organomet. Chem. 2017, 847, 97-104.

263. Dehydrogenative cross-coupling of o-carborane with thiophenes via Ir-catalyzed regioselective cage B–H and C (sp2)–H activation
Quan, Y.; Lyu, H.; Xie, Z.
Chem. Commun. 2017, 53, 4818-4821.

262. Cycloheptatrienyl dicarbollyl zirconium complexes: Building blocks for the preparation of multidecker sandwich complexes
Bannenberg, T.; Glöckner, A.; Lemke, M.; Yang, J.; Xie, Z.; Tamm, M.; Jones, P. G.
J. Organomet. Chem. 2017, 828, 83-88.

261. Photoarylation of Iodocarboranes with Unactivated (Hetero)Arenes: Facile Synthesis of 1,2-[(Hetero)Aryl]n-o-Carboranes (n = 1,2) and o-Carborane-Fused Cyclics
Ni, H.; Qiu, Z.; Xie, Z.
Angew. Chem. Int. Ed. 2017, 56, 712-716.

2016

260. Enantioselective Construction of Cyclobutanes: A New and Concise Approach to the Total Synthesis of (+)-Piperarborenine B
Hu, J.-L.; Feng, L-W.; Wang, L.; Xie, Z.; Tang, Y.; Li, X.
J. Am. Chem. Soc. 2016, 138, 13151-13154.

259. Transition Metal Catalyzed Direct Amination of Cage B(4)−H Bond in o-Carboranes: Synthesis of Tertiary, Secondary and Primary o-Carboranyl Amines
Lyu, H.; Quan, Y.; Xie, Z.
J. Am. Chem. Soc. 2016, 138, 12727-12730.

258. Rh-Catalyzed Regioselective Cage B-H Hydroxylation of o-Carboranes with O2 or Air
Lyu, H.; Quan, Y.; Xie, Z.
Angew. Chem. Int. Ed. 2016, 55, 11840-11844.

257. **Unique properties of C,C′-linked nido-biscarborane tetraanions. Synthesis, structure and bonding of ruthenium monocarbollide via unprecedented cage carbon extrusion**
Zhao, D.; Zhang, J.; Lin, Z.; Xie, Z.
Chem. Commun. 2016, 52, 9992-9995.

256. Phosphine-catalyzed cage carbon functionalization of o-carborane: facile synthesis of alkenylcarboranes
Zheng, F.; Leung, T. F.; Chan, K. W.; Sung H. H. Y.; William, I. D. ; Xie, Z.; Jia, G.
Chem. Commun. 2016, 52, 10767-10770.

255. Synthesis and Structural Characterization of Carbene-Stabilized Carborane-Fused Azaborolyl Radical Cation and Dicarbollyl-Fused Azaborole
Wang, H.; Zhang, J.; Lin, Z.; Xie, Z.
Organometallics, 2016, 35, 2579-2582.

254. Synthesis, structure and reactivity of mixed-sandwich zirconacarborane methyl complex (η5-C5Me5)[η1: η5-(R2NCH2CH2)C2B9H10]ZrMe
Liu, D.; Qiu, Z.; Xie, Z.
J. Organomet. Chem. 2016, 822, 144-153.

253. Palladium catalyzed regioselective B–C (sp) coupling via direct cage B–H activation: synthesis of B(4)-alkynylated o-carboranes
Quan, Y.; Tang, C.; Xie, Z.
Chem. Sci., 2016, 7, 5838-5845.

252 . [3-N 2 -o-C 2 B 10 H 11 ][BF 4 ]: A Useful Synthon for Multiple Cage Boron Functionalization of o-Carborane
Zhao , D. ; Xie, Z.
Chem. Sci., 2016, 7, 5635-5639.

251. The synthesis, structure and reactivity of an imine-stabilized carboranylphosphorus(I) compound
Chan, T. L.; Xie, Z.
Chem. Commun. 2016, 52, 7280-7283.

250. Reaction of [η1: η5-(R2NCH2CH2) C2B9H10] TaMe3 with Isonitriles: Effects of Nitrogen Substituents on Product Formation
Xiang, L. ; Xie, Z.
Organometallics, 2016, 35, 1430-1439.

249. Visible-Light-Promoted Photocatalytic B−C Coupling via a Boron-Centered Carboranyl Radical: Facile Synthesis of B(3)-Arylated o-Carboranes
Zhao, D.; Xie, Z.
Angew. Chem. Int. Ed., 2016, 55, 3166-3170.

248. Tantallacarborane Mediated Consecutive C–C and C–N Coupling Reactions of Alkyl Isonitriles: A Facile Route to N-Heterocycles
Xiang, L.; Xie, Z.
Organometallics 2016, 35, 233-241.

247. Facile Synthesis of N-Carboranyl Amines through an ortho-Carboryne Intermediate
Cheng, R.; Zhang, J.; Zhang, J.; Qiu, Z.; Xie, Z.
Angew. Chem. Int. Ed., 2016, 55, 1751-1754.

245. Palladium-catalyzed regioselective diarylation of o-carboranes by direct cage B-H activation
Quan, Y.; Xie, Z.
Angew. Chem. Int. Ed., 2016, 55, 1295-1298.

245. Recent Advances in the Chemistry of Carborynes
Zhao, D.; Xie, Z.
Coord. Chem. Rev. 2016, 314, 14-33.

2015

244. DFT Studies on Structures, Stabilities, and Electron Affinities of closo-Supercarboranes C2Bn–2Hn (n = 13–20)
Zhang, J; Lin, Z.; Xie, Z.
Organometallics 2015, 34, 5576-5588.

243. The synthesis and structure of a carbene-stabilized iminocarboranyl-boron(I) compound
Wang, H.; Zhang, J.; Lin, Z.; Xie, Z.
Chem. Commun. 2015, 51, 16817-16820.

242. An unprecedented Formal [5 + 2] Cycloaddition of Nitrones with o-Carboryne via Tandem [3 + 2] Cycloaddition/Oxygen Migration/Aromatization Sequence
Zhao, D.; Zhang, J.; Xie, Z.
J. Am. Chem. Soc. 2015, 137, 13938-13942.

241. Palladium-Catalyzed Direct Dialkenylation of Cage BH Bonds in o-Carboranes through Cross-Coupling Reactions
Lyu, H.; Quan, Y.; Xie, Z.
Angew. Chem. Int. Ed., 2015, 54, 10623-10626.

240. Asymmetric Hydroamination Catalyzed by A New Chiral Zirconium System: Reaction Scope and Mechanism
Zhou, X.; Wei, B.; Sun, X.-L.; Tang, Y.; Xie, Z.
Chem. Commun. 2015, 51, 5751-5753.

239. Dearomative [2 + 2] Cycloaddition and Formal C-H Insertion Reaction of o-Carboryne with Indoles: Synthesis of Carborane-Functionalized Heterocycles
Zhao, D.; Zhang, J.; Xie, Z.
J. Am. Chem. Soc. 2015, 137, 9423-9428.

238. Facile Synthesis of o-Carborane-Substituted Alkenes and Allenes by a Regioselective Ene Reaction of 1,3-Dehydro-o-carborane
Zhao, D.; Zhang, J.; Xie, Z.
Chemistry—A European Journal. 2015, 21, 10334-10337.

237. Highly Diastereoselective and Enantioselective Formal [4 + 3] Cycloaddition of Donor-acceptor Cyclobutanes with Nitrones
Hu, J.-L.; Wang, L.; Xu, H.; Tang, Y.; Xie, Z.
Org. Lett., 2015, 17, 2680–2683.

236. Nickel-Catalyzed Cross-Coupling Reactions of o-Carboranyl with Aryl Iodides: Facile Synthesis of 1-Aryl-o-Carboranes and 1,2-Diaryl-o-Carboranes
Tang, C.; Xie, Z.
Angew. Chem. Int. Ed., 2015, 54, 7662-7665.

235. o-Carborane Functionalized Pentacenes: Synthesis, Molecular Packing and Ambipolar Organic Thin film Transistors
Guo, J.; Liu, D.; Zhang, J,; Zhang, J,; Miao, Q.; Xie, Z.
Chem. Commun. 2015, 51, 12004-12007.

234. Palladium-Catalyzed Regioselective Intramolecular Coupling of o-Carborane with Aromatics via Direct Cage B-H Activation
Quan, Y.; Qiu, Z.; Xie, Z.
J. Am. Chem. Soc. 2015, 137, 3502–3503.

233. Reaction of N-heterocyclic Carbenes with 13-Vertex Closo-carboranes: Synthesis and Structural Characterization of Zwitterionic Salts of 13-Vertex Nido-carboranes
Zheng, F.; Xie, Z.
Org. Chem. Front., 2015, 2, 55-59 .

232. Reactivity of Traditional Metal-Carbon (Alkyl) versus Nontraditional Metal-Carbon (Cage) Bonds in Organo-Rare-Earth Metal Complexes [η5:σ-(C9H6)(C2B10H10)]Ln(CH2C6H4-o-NMe2)(THF)2
Yang, J; Xie, Z.
Organometallics 2015, 34, 2494-2499.

231. Supercarborane Radical Anions with 2n + 3 Electron Counts: A Combined Experimental and Theoretical Study
Zhang, J; Fu, X.; Lin, Z.; Xie, Z.
Inorg. Chem. 2015, 54, 1965-1973.

230. Synthesis, Structure and Reactivity of Highly Constrained-geometry Yttracarborane Alkyl [σ:η5-(C9H6)C2B9H10]Y[η2-(CH3OCH2CH2OCH3)]2
Yang, J; Shen, H.; Xie, Z.
J. Organomet. Chem. 2015, 798, 204-208.

229. Synthesis, structure and reactivity of rare-earth metallacarborane alkyls [η1:η5-O(CH2)2C2B9H9]Ln(σ:η1-CH2C6H4-o-NMe2)(THF)2
Yang, J; Xie, Z.
Dalton Trans. 2015, 44, 6630-6637.

228. Synthesis, Structure, and Alkyne Insertion of a Mixed-sandwich Zirconacarborane Alkyl
Liu, D; Qiu, Z.; Xie, Z.
Inorg. Chem. Front., 2015, 2, 467-472.

2014

227. Transition-Metal- Promoted Functionalization of Carboranes Advances in Organometallic Chemistry and Catalysis
Qiu, Z.; Xie, Z. Edited by Pombeiro, A. J. L.
Wiley 2014, p. 81-96.

226. One Stone Kills Three Birds: Novel Boron-Containing Vesicles for Potential BNCT, Controlled Drug Release, and Diagnostic Imaging
Chen, G.; Yang, J.; Lu, G.; Liu, P-C.; Chen, Q.; Xie, Z.; Wu, C.
Mol. Pharmaceutics 2014, 11, 3291-3299.

225. Synthesis of Carborane-Fused Cyclobutenes and Cyclobutanes
Yuan, Y.; Ren, S.; Qiu, Z.; Wang, S.; Xie, Z.
Sci. China Chem. 2014, 57, 1157-1163.

224. Transition Metal Mediated Functionalization of o-Carboranes
Xie, Z.
Sci. China Chem. 2014, 57, 1061-1063.

223. On Desilylation of 13-Vertex Carborane 1,2-Me2Si(CH2)2-1,2-C2B11H11
Zhang, J.; Xie, Z.
Chin. J. Chem. 2014, 32, 777-782.

222. Regioselective Insertion of o-Carborynes into the α-CH Bond of Tertiary Amines: Synthesis of α-Carboranylated Amines
Zhao, D.; Zhang, J.; Xie, Z.
Angew. Chem. Int. Ed., 2014, 53, 12902-12906.

221. Conversion of (η5-C2B9H10R)TaX3 (X = Me, NMe2) to (η6-C2B9H10R)TaX′ (X′ = NMe2, azaallyl) in the Absence of a Reducing Agent: Synthesis and Structure of Tantallacarboranes Incorporating an Arachno-η6-C2B9 Ligand
Xiang, L.; Xie, Z.
Chem. Commun. 2014, 50, 8249-8252.

220. Iridium Catalyzed Regioselective Cage Boron Alkenylation of o-Carboranes via Direct Cage B-H Activation
Quan, Y.; Xie, Z.
J. Am. Chem. Soc. 2014, 136, 15513–15516.

219. 1,3-Dehydro-o-carborane: Generation and Reaction with Arenes
Zhao, D.; Zhang, J.; Xie, Z.
Angew. Chem. Int. Ed., 2014, 53, 8488-8491.

218. Diels-Alder Reaction of o-Carboryne with Fulvenes: Synthesis of Carboranonorbornadienes and Their Transformations
Zhang, J.; Qiu, Z.; Xu, P.-F.; Xie, Z.
ChemPlusChem. 2014, 79, 1044-1052.

217. Insight into Reaction Mechanism of [2 + 2 + 1] Cross-Cyclotrimerization of Carboryne with Alkene and Trimethylsilylarylalkyne Mediated by Nickel Complex
Zhang, J.; Quan, Y.; Lin, Z.; Xie, Z.
Organometallics 2014, 33, 3556-3563.

216. Synthesis, Structure, and Reactivity of 13- and 14-Vertex Carboranes
Zhang, J.; Xie, Z.
Acc. Chem. Res. 2014, 47, 1623–1633.

215. Transition-Metal-Mediated Three-Component Cascade Cyclization: Selective Cage B-C(sp2) Coupling of
Carborane with Aromatics and Synthesis of Carborane-Fused Tricyclics.
Quan, Y.; Qiu, Z.; Xie, Z.
J. Am. Chem. Soc. 2014, 136, 7599–7602.

214. Generation and reactivity of o-carborynes.
Qiu, Z.; Xie, Z.
Dalton Trans. 2014, 43, 4925-4934.

213. Synthesis and structural characterization of 14-vertex germa-, stanna-, and plumba-carboranes.
Zheng, F.; Xie, Z.
Dalton Trans. 2014, 43, 4986-4992.

2014

212. Three-Component [2+2+1] Cross-cyclotrimerization of Carboryne, Unactivated Alkene, and Trimethylsilylalkyne Co-mediated by Zr and Ni.
Quan, Y.; Zhang, J.; Xie, Z.
J. Am. Chem. Soc. 2013, 135, 18742-18745.

211. Synthesis and Characterization of 14-Vertex Carboranes.
Zhang, J.; Zheng, F.; Xie, Z.
Organometallics 2013, 32, 7399-7406.

210. Reaction of Li2C2B10Me8H2 with NiCl2. Ligand Effects on Stability of Ni-Octamethylcarboryne Complexes.
Qiu, Z.; Deng, L.; Xie, Z.
J. Organomet. Chem. 2013, 747, 225-228.

209. Reaction of [ η 1 : η5 -(Me2NCH2CH2)C2B9H10]TaMe3 with Aryl Isonitriles: Tantallacarborane-mediated Facile
Cleavage of C-N Multiple Bonds.
Xiang, L.; Mashima, K.; Xie, Z.
Chem. Commun. 2013, 49, 9039-9041.

208. Reaction of 13-Vertex Carborane μ-1,2-(CH2)4-1,2-C2B11H11 with Nucleophiles: Linkage Effect on Product Formation.
Zhang, J.; Xie, Z.
Inorg. Chem. 2013, 52, 10677-10684.

207. Palladium-catalyzed Selective Fluorination of o-Carboranes
Qiu, Z.; Q. Y.; Xie, Z.
J. Am. Chem. Soc. 2013, 135, 12192-12195.

206. Synthesis of Neutral Group 4 Metal-carboryne Complexes and Their Reactivity toward Unsaturated
Molecules.
Ren, S.; Qiu, Z.; Xie, Z.
Organometallics. 2013, 32, 4292-4300.

205. Copper-Catalyzed Highly Enantioselective Cyclopentannulation of Indoles with Donor-Acceptor
Cyclopropanes.
Xiong, H.; Xu, H.; Liao, S.; Xie, Z.; Tang, Y.
J. Am. Chem. Soc. 2013, 135, 7851-7854.

204. Reactions of 13-Vertex Carboranes with Strong Bases: Synthesis and Structural Characterization of Carborane Monoanions with exo-π Bonding.
Zheng, F.; Zhang, J.; Fu, X.; Xie, Z.
Chem. Asian J. 2013, 8, 1886-1891.

203. Supercarboranes: Achievements and Perspectives.
Zhang, J.; Xie, Z.
Pure Appl. Chem. 2013, 85, 661-670.

2012

202. Constrained-geometry Titanacarborane Monoamides: from Synthesis and Reactivity to Catalytic Applications.
Shen, H.; Xie, Z. Edited by Hosmane, N. S.
Boron Science 2012, 517-528.

201. Synthesis, Structure and Ethylene Polymerization Behavior of Group 4 Metal Complexes Bearing
Salicylaldaminato Ligands with Appended Donor Functionality.
Wang, X.; Sit, M.-M.; Sun, J.; Tang, Y.; Xie, Z.
Acta Chim. Sinica 2012, 70, 1909-1916.

200. Synthesis, Structure and Properties of Mixed-sandwich Cobalta- and Ferra-carboranes with Carbon-atoms-
adjacent' C2B9 and C2B10 Systems.
Qiu, Z.; Wong, K.-H.; Xie, Z.
J. Orgnomet. Chem. 2012, 721-722, 97-103.

199. Reaction of 13-Vertex Carborane μ-1,2-(CH2)3-1,2-C2B11H11 with Nucleophiles: Scope and Mechanism.
Zhang, J.; Xie, Z.
Inorg. Chem. 2012, 51, 12976-12987.

198. Reaction of o-Carboranes with Sterically Demanding N-heterocyclic Carbene: Synthesis and Structural
Characterization of 1:1 Adducts.
Zheng, F.; Xie, Z.
Dalton Trans. 2012, 41, 12907-12914.

197. Reaction of Zirconocene-Carboryne with Alkenes: Synthesis and Structure of Zirconacyclopentanes with a
Carborane Auxiliary
Ren, S; Qiu, Z; Xie, Z
Organometallics 2012, 31, 4435-4441.

196. Formal Insertion of o-Carborynes into Ferrocenyl C-H Bonds: A Simple Access to o-Carboranylferrocenes
Wang, S. R.; Xie, Z.
Organometallics 2012, 31, 4544-4550.

195. Reaction of Carboryne with Alkylbenzenes
Wang, S. R.; Xie, Z.
Organometallics 2012, 31, 3316-3323.

194. Reaction of Carboryne with Styrene and Its Derivatives.
Wang, S. R.; Xie, Z.
Tetrahedron 2012. 68, 5269-5278.

193. Transition-Metal-Promoted or -Catalyzed Exocyclic Alkyne Insertion via Zirconacyclopentene with Carborane Auxiliary: Formation of Symmetric or Unsymmetric Bezeocarboranes.
Ren,S.; Qiu, Z.; Xie, Z.
J. Am. Chem. Soc. 2012, 134, 3242-3254.

192. Synthesis, Sructural Characterization, and Reactivity of Late Transition-metal Complexes Bearing Linked Cyclopentadienyl–carboranyl Ligands.
Liu, D.; Qiu, Z.; Chan, H.-S.; Xie, Z.
Canadian Journal of Chemistry , 2012, 90, 108-117.

191. Three-Component [2+2+2] Cycloaddition of Carboryne, Unactivated Alkene, and Alkyne via Zirconacyclopentane Mediated by Nickel: One-Pot Synthesis of Dihydrobenzocarborane.
Ren, S.; Qiu, Z.; Xie, Z.
Angew. Chem. Int. Ed. 2012, 1010-1013.　

190. A newly-designed PE-supported arsine for efficient and practical catalytic Wittig olefination.
Wang, P.; Liu, C.; Sun, X.; Chen, S.; Li, J.; Xie, Z.; Tang, Y.
Chem. Commun. 2012, 290-292.

2011

189. Synthesis and Reaction of Neutral and Cationic Alkyltantalum Complexes with a Linked
Cyclopentadienyl-Carboranyl Ligand.
Tsurugi, H.; Qiu, Z..; Yamamoto, K.; Müller,R.; Mashima, K.; Xie, Z.
Organometallics 2011, 30, 5960-5964.

188. Ti-amide Catalyzed Synthesis of Cyclic Guanidines from Di-/Triamines and Carbodiimides.
Shen, H.; Wang, Y.; Xie, Z.
Organic Letters, 2011, 13, 4562-4565.

187. Intramolecular Hydroamination of Aminoalkenes Catalyzed by a Cationic Zirconium Complex.
Wang, X.; Chen Z.; Sun, X.; Tang, Y.; Xie, Z.
Organic Letters, 2011, 13, 4758-4761.

186. Reaction of a Zirconocene-Carboryne Complex with Pyridines: Ligand C-H Activation.
Ren,S.; Xie, Z.
Organometallics 2011, 30, 5953-5959.

185. Selective Cage Boron/Carbon Extrusion Reaction of 13-Vertex Carborane μ-1,2-(CH2)3–1,2-C2B11H11:
Formation of nido-CB10, closo-CB10, and closo-C2B10 Species.
Zhang, J.; Chan, H.-S.; Xie, Z.
Chem. Commun. 2011, 8082-8084.

184. Atom-economical Synthesis of 2-Aminoimidazoles via [3 + 2] Annulation Catalyzed by Titanacarborane
Monoamide.
Wang, Y.; Shen, H.; Xie, Z.
Synlett 2011, 969-973.

183. Facile Synthesis of ansa-Zirconocenes Incorporating a Linked Dicarbollyl Ligand via Direct Deboration of
Zirconocene Carboranyl Complexes
Sit, M.-M.; Chan, H.-S.; Xie, Z.
Organometallics 2011, 30, 3449-3452.

182. Transition Metal-Carboryne Complexes: Synthesis, Bonding, and Reactivity.
Qiu, Z.; Ren, S.; Xie, Z.
Acc. Chem. Res. 2011, 44, 299-309.

181. Regioselective Insertion of Carborynes into Ethereal C-H Bond: Facile Synthesis of a-Carboranylated Ethers.
Wang, S. R.; Qiu, Z.; Xie, Z.
J. Am. Chem. Soc. 2011, 133, 5760-5763.

180. Synthesis and Structure of Rare-Earth-Metal Dicarbollide Complexes with an Imidazolin-2-iminato Ligand
Featuring Very Short Metal−Nitrogen Bonds.
Trambitas, A. G.; Yang, J.; Melcher, D.; Daniliuc, C. G.; Jones, P. G.; Xie. Z; Tamm, M.
Organometallics 2011, 30, 1122-1129.

179. Synthesis, Structural Characterization, and Reactivity of Group 4 Metallacarboranes Bearing the Ligand
[H2C(C5Me4)(C2B9H10)]3−.
Liu, D.; Shen, H.; Wang, Y.; Cai, Y.; Xie, Z.
Chemistry—An Asian Journal. 2011, 6, 628-637.

178. Highly Diastereroselective Synthesis of Dihydrofurans and Dihydropyrroles via Pyridine Catalyzed Formal [4+1]
Annulation.
Liu, C.; Zhu, B.; Zheng, J.; Sun, X.; Xie, Z.; Tang, Y.
Chem. Commun. 2011, 1342-1344.

2010

177. Reaction of [η5:ϭ-Me2C(C5H4)(C2B10H10)]Ru(NCCH3)2 with Internal Alkynes: Synthesis and Structural
Characterization of Ruthenium-cyclobutadiene and Ruthenacyclopentatriene complexes.
Qiu, Z.; Sun, Y.; Xie, Z.
Sci. China Chem. 2010, 53, 2123-2128.

176. Palladium/Nickel-Cocatalyzed Cycloaddition of 1,3-Dehydro-o-Carborane with Alkynes. Facile Synthesis of
C,B-Substituted Carboranes.
Qiu, Z.; Xie, Z.
J. Am. Chem. Soc. 2010, 132, 16085-16093.

175. Synthesis and Structural Characterization of Group 10 Metal-Carboryne Complexes.
Qiu, Z.; Deng L.; Chan, H.-S.; Xie, Z.
Organometallics 2010, 29, 4541-4547.

174. Recent Progress in the Chemistry of Supercarboranes.
Zhang, J.; Xie, Z.
Chemistry--An Asian Journal. 2010, 5, 1742-1757.

173. Atom-Economical Synthesis of N-Heterocycles via Cascade Inter-/Intramolecular C-N Bond-Forming Reactions
Catalyzed by Ti Amides.
Shen, H.; Xie, Z.
J. Am. Chem. Soc. 2010, 132, 11473-11480.

172 . Insertion of Carboryne into Aromatic Rings: Formation of Cyclooctatetraenocarboranes.
Wang, S. R.; Qiu, Z.; Xie, Z.
J. Am. Chem. Soc. 2010, 132, 9988-9989.

171. Nickel-Catalyzed Regioselective [2+2+2] Cycloaddition of Carboryne with Alkynes.
Qiu, Z.; Wang, S. R.; Xie, Z.
Angew. Chem. Int. Ed. 2010, 49, 4649-4652.　
　
170. Asymmetric Nazarov Reaction Catalyzed by Chiral Tris(oxazoline)/Copper(II).
Cao, P.; Deng C.; Zhou Y.-Y.; Sun X.-L.; Zheng J.-C.; Xie Z.; Tang Y.
Angew. Chem. Int. Ed. 2010, 49, 4463-4466.

2009

169. Unique Chemical Properties of Metal-carbon Bonds in Metal-carboranyl and Metal-carboryne Complexes.
Qiu, Z.; Xie, Z.
Sci. China Ser. B-Chem. 2009, 52, 1544-1558.　

168. [O-NSR]TiCl 3-Catalyzed Copolymerization of Ethylene with Functionalized Olefins.
Yang, X.-H.; Liu, C.-R.; Wang, C.; Sun, X.-L.; Guo, Y.-H.; Wang, X.-K.; Wang, Z.; Xie, Z.; Tang, Y.
Angew. Chem. Int. Ed. 2009, 48 , 8099-8102.

167. Metallacarboranes Incorporating an arachno-η6-C2B9 Ligand. Sit, M.-M.; Chan, H.-S.; Xie, Z. Organometallics 2009, 28, 5998-6002.　

166. Synthesis and Structural Characterization of Zirconium-Carboryne Complexes.
Ren, S.; Deng, L.; Chan, H.-S.; Xie, Z.
Organometallics 2009, 28, 5749-5756.

165. Reaction of a 14-Vertex Carborane with Nucleophiles: Formation of nido-C 2B12, nido-C2B11, and closo-CB11 Carborane Anions.
Zhang, J.; Zheng, F.; Chan, H.-S.; Xie, Z.
Inorg. Chem. 2009, 48 , 9786-9791.　

164. Re-examination of Dynamics of Polyelectrolytes in Salt-Free Dilute Solutions by Designing and Using a Novel Neutral-Charged-Neutral Reversible Polymer.
Zhou, K.; Li, J.; Lu, Y.; Zhang, G.; Xie, Z.; Wu, C.
Macromolecules 2009, 42, 7146-7154.

163. Nickel-Catalyzed Three-Component [2+2+2] Cycloaddition Reaction of Arynes, Alkenes, and Alkynes.
Qiu, Z.; Xie, Z.
Angew. Chem. Int. Ed. 2009, 48, 5729-5732.　

162. Reaction of Zirconocene-Carboryne Precursor with Alkynes: An Efficient Route to Zirconacyclopentenes Incorporating a Carboranyl Unit.
Ren, S.; Chan, H.-S.; Xie, Z.
Organometallics 2009, 28, 4106-4114.

161. Multistep One-Pot Wittig/Nazarov Reaction for Construction of Cyclopentenone with Diazo Compounds and Acid Chlorides.
Cao, P.; Sun, X.-L.; Zhu, B.-H.; Shen, Q.; Xie, Z.; Tang, Y.
Org. Lett. 2009, 11, 3048-3051.

160. Constrained-geometry ruthenium carboranyl complexes and their unique chemical properties.
Shen, H.; Xie, Z.
Chem. Commun. 2009, 2431-2445.

159. Titanacarborane mediated C-N bond forming/breaking reactions.
Shen, H.; Xie, Z.
J. Organomet. Chem. 2009, 694, 1652-1657.

158. Synthesis, Structure, and Reactivity of Zirconacyclopentene Incorporating a Carboranyl Unit.
Ren, S.; Chan, H.-S.; Xie, Z.
J. Am. Chem. Soc. 2009, 131, 3862-3863.

157. Nickel-Mediated Three-Component Cycloaddition Reaction of Carboryne, Alkenes, and Alkynes.
Qiu, Z.; Xie, Z.
J. Am. Chem. Soc. 2009, 131, 2084-2085.

2008

156. Reaction of 13-Vertex Carboranes with Nucleophiles: Unprecedented Cage Carbon Extrusion and Formation of Monocarba-closo-Dodecaborate Anions.
Zhang, J.; Chan, H.-S.; Xie, Z.
Angew. Chem. Int. Ed. 2008, 47, 9447-9449.

155. The Coil-to-Globule-to-Coil Transition of Linear Polymer Chains in Dilute Aqueous Solutions: Effect of Intrachain Hydrogen Bonding.
Zhou, K.; Lu, Y.; Li, J.; Shen, L.; Zhang, G.; Xie, Z.; Wu, C.
Macromolecules 2008, 41, 8927-8931.

154. Hydrogen-Mediated Metal-Carbon to Metal-Boron Bond Conversion in Metal-Carboranyl Complexes.
Liu, D.; Dang. L.; Sun, Y.; Chan, H.-S.; Lin, Z.; Xie, Z.
J. Am. Chem. Soc. 2008, 130, 16103-16110.

153. Ehtylene Homopolymerization and Copolymerization with -Olefins Catalyzed by Titanium Complexes Bearing [O-NSR] Tridentate Ligands.
Gao, M.-L.; Gu, Y.-F.; Wang, C.; Yao, X.-L.; Sun, X.-L.; Li, C.-F., Qian, C.-T.; Liu, B.; Ma, Z.; Tang, Y.; Xie, Z.; Bu, S.-Z.; Gao, Y.
J. Molecular Catalysis A: Chemical,2008, 292, 62-66.

152. Synthesis, Structure, and Reactivity of Group 4 Metallacarboranes Bearing the Ligand [Me2C(C9H6)(C2B9H10)]3-.
Liu, D.; Wang, Y.; Chan, H.-S.; Xie, Z.
Organometallics 2008, 27, 5295-5302.

151. Synthesis and Structural Characterization of Constrained–Geometry Organolanthanide Chlorides and Alkyls Incorporating the Ligand [η5:σ–(C9H6)C2B10H10]2–.
Shen, H.; Chan, H.-S.; Xie, Z.
Organometallics 2008, 27, 5309-5316.

150. A Facile and Practical Synthetic Route to 1,1’-Bis(o-carborane).
Ren, S.; Xie, Z.
Organometallics 2008, 27, 5167-5168.

149. Nickel-mediated coupling reactions of carboryne with alkenes: a synthetic route to alkenylcarboranes.
Qiu, Z.; Xie, Z.
Angew. Chem. Inter. Ed. 2008, 47, 6572-6575.

148. One-Pot Screening of Titanium Catalysts for Ethylene Polymerization.
Yang, X.-H.; Sun, X.-L.; Han, F.-B.; Liu, B.; Tang, Y.; Wang, Z.; Gao, M.-L.; Xie, Z.; Bu, S.-Z.
Organometallics 2008, 27, 4618-4624.

147. Synthesis and Structural Characterization of Group 4 Metal Complexes Bearing Pentavalent Phosphorus-Bridged Ligands [(C13H8)(iPr2N)P(-O)(C2B10H10)]2- and [(C13H9)(iPr2N)P(O)(C2B9H10)]2-.
Wang, H.; Shen, H.; Chan, H.-S.; Xie, Z.
Organometallics 2008, 27, 3964-3970.

146. Synthesis, Structural Characterization, and Reactivity of Group 4 Metallacarboranes Containing the Ligand [Me2C(C5H4)(C2B9H10)]3-.
Wang, Y.; Liu, D.; Chan, H.-S.; Xie, Z.
Organometallics 2008, 27, 2825-2832.

145. Titanacarborane amide catalyzed transamination of guanidines.
Shen, H.; Xie, Z.
Organometallics 2008, 27, 2685-2687.

144. Copolymerization of ethylene with cycloolefins by titanium complexes containing tridentate [O-NSR] ligands.
Gao, M.-L.; Sun, X.-L.; Gu, Y.-F.; Yao, X.-L.; Li, C.-F.; Bai, J.-Y.; Wang, C.; Ma, Z.; Tang, Y.; Xie, Z.; Bu, S.-Z.; Qian, C.
J. Polym. Sci. Part A: Polym. Chem. 2008, 46, 2807-2819.

143. Synthesis, structure, and reactivity of Group 4 metallacycles incorporating a Me2C-linked cyclopentadienyl-carboranyl ligand.
Sit, M.-M.; Chan, H.-S.; Xie, Z.
Dalton Trans. 2008, 1454-1464.

142. Synthesis, Structural Characterization, and Reactivity of Group 4 Metal Complexes Derived from 1-Indenyl-1,2-carborane.
Shen, H.; Chan, H.-S.; Xie, Z.
Organometallics 2008, 27, 1157-1168.

141. Synthesis, Folding, and Association of Long Multiblock (PEO23-b-PNIPAM124)750 Chains in Aqueous Solutions.
Zhang, Q.; Ye, J.; Lu, Y.; Nie, T.; Xie, D.; Song, Q.; Chen, H.; Zhang, G.; Tang, Y.; Wu, C.; Xie, Z.
Macromolecules 2008, 41, 2228-2234.

140. Folding of Long Multiblock Copolymer (PI-b-PS-b-PI)n Chains Prepared by the Self-Assembly Assisted Polypolymerization (SAAP) in Cyclohexane.
Hong, L.; Zhu, F.; Li, J.; Ngai, T.; Xie, Z.; Wu, C.
Macromolecules 2008, 41, 2219-2227.

2007

139. Reaction of [s:h5-(C9H6)C2B9H10]Zr(NMe2)(DME) with Guanidines: Metallacarborane-Mediated C-N Bond Cleavage and 1,5-Sigmatropic Rearrangement.
Shen, H.; Chan, H.-S.; Xie, Z.
J. Am. Chem. Soc. 2007, 129, 12934-12935.　

138. Advances in the Chemistry of Carboranes and Metallacarboranes with More than 12 Vertices.
Deng, L.; Xie, Z.
Coord. Chem. Rev. 2007, 251, 2452-2476.

137. Ph3As-Catalyzed Wittig-Type Olefination of Aldehydes with Diazoacetate in the Presence of Na2S2O4.
Cao, P.; Li, C.-Y.; Kang, Y.-B.; Xie, Z.; Sun, X.-L.; Tang, Y.
J. Org. Chem. 2007, 72, 6628-6630.

136. Ethylene-Norbornene Copolymerization by New Titanium Complexes bearing tridentate ligands. Sidearm effects on catalytic activity.
Gao, M.; Wang, C.; Sun, X.; Qian, C.; Ma, Z.; Bu, S.; Tang, Y.; Xie, Z.
Macromol. Rapid Commun. 2007, 28, 1511-1516.

135. Synthesis and Crystal Structure of a 13-Vertex Carborane Radical Anion with 2n + 3 Framework Electrons.
Fu, X.; Chan, H.-S.; Xie, Z.
J. Am. Chem. Soc. 2007, 129, 8964-8965.

134. Synthesis, Structure, and Reactivity of [s:h1:h5-(OCH2)(Me2NCH2)C2B9H9]Ti(NR2) (R = Me, Et).
Shen, H.; Chan, H.-S.; Xie, Z.
Organometallics 2007, 26, 2694-2704. 　

133. A Journey from 12-Vertex to 14-Vertex Carboranes and to 15-Vertex Metallacarboranes.
Deng, L.; Xie, Z.
Organometallics 2007, 26, 1832-1845.

132. Synthesis, Structure, Reactivity, and Thermal Isomerization of Boron-Substituted 13-Vertex Cobaltacarboranes (h 5-Cp)Co(h6-R2C2B10Me8H2) (R = H, Et).
Deng, L.; Chan, H.-S.; Xie, Z.
Inorg. Chem. 2007, 46, 2716-2724.

131. Role of C,C’-Linkage in the Formation and Stabilization of Supercarboranes. Synthesis and Structure of Carbon-Atoms-Apart 13-Vertex Carborane and 14-Vertex Metallacarborane.
Zhang, J.; Deng, L.; Chan, H.-S.; Xie, Z.
J. Am. Chem. Soc. 2007, 129, 18-19.

2006

130. Guanylation of Amines Catalyzed by a Half-Sandwich Titanacarborane Amide Complex.
Shen, H.; Chan, H.-S.; Xie, Z.
Organometallics 2006, 25 , 5515-5517.

129. Ruthenium-Mediated Coupling/Cycloaddition of the Cyclopentadienyl in [h5:s-Me2C(C5H4)(C2B10H10)]Ru(NCCH3)2 with Alkynes: Facile Formation of Tricycles.
Sun, Y. Chan, H.-S.; Zhao, H.; Lin, Z.; Xie, Z.
Angew. Chem. Int. Ed. 2006, 45, 5533.

128. Reaction Scope and Mechanism of Sterically Induced Ruthenium-Mediated Intramolecular Coupling of o-Carboranyl with Cyclopentadienyl. Synthesis and Structure of Ruthenium Complexes Incorporating Doubly-Linked Cyclopentadienyl-Carboranyl Ligands.
Sun, Y.; Chan, H.-S.; Xie, Z.
Organometallics 2006, 25, 4188.

127. Synthesis, Structural Characterization, Reactivity, and Thermal Stability of [h5:s-Me2C(C5H4)(C2B10H10)]Ti(R)(NMe2).
Wang, H.; Wang, Y.; Chan, H.-S.; Xie, Z.
Inorg. Chem. 2006, 45, 5675.

126. Reaction of [h5:s-Me2C(C5H4)(C2B10H10)]Ru(NH2Prn)2 with Alkynes. Control Synthesis and Structural Characterization of Ruthenium Aminocarbene and Enamine Complexes.
Sun, Y.; Chan, H.-S.; Xie, Z.
Organometallics 2006, 25 , 3447-3453.

125. Synthesis and Structure of 14- and 15-Vertex Ruthenacarboranes.
Deng, L.; Zhang, J.; Chan, H.-S.; Xie, Z.
Angew. Chem. Int. Ed. 2006, 45 , 4309-4313.

124. Nickel-Mediated Regioselective [2 + 2 + 2] Cycloaddition of Carboryne with Alkynes.
Deng, L.; Chan, H.-S.; Xie, Z.
J. Am. Chem. Soc. 2006, 128, 7728-7729.

123. Reactions of [η5:σ-Me2C(C5H4)(C2B10H10)]Ru(COD) with Lewis bases: Synthesis, structure, and electrochemistry of ruthenium amine, nitrile, carbene, phosphite and phosphine complexes.
Sun, Y.; Chan, H.-S.; Dixneuf, P. H.; Xie, Z.
J. Organomet. Chem. 2006, 691, 3071-3082.

122. Reaction of [η5:s-Me2C(C5H4)(C2B10H10)]Ru(NCCH3)2 with Me3SiCCR. Synthesis and Structural Characterization of Mononuclear Ruthenium Bis(vinylidene) and Vinylvinylidene Complexes.
Sun, Y.; Chan, H.-S.; Dixneuf, P. H.; Xie, Z.
Organometallics 2006, 25, 2719-2721.

121. Synthesis and Structural Characterization of New Carboranyl-Indenyl Ligands and Their Lanthanide Complexes.
Shen, H.; Chan, H.-S.; Xie, Z.
Organometallics 2006, 25, 2617-2625.

120. Synthesis, Structure, and Olefin Polymerization Behavior of Constrained-Geometry Group 4 Metallacarboranes Incorporating Imido-Dicarbollyl Ligands.
Gao, M.; Tang, Y.; Xie, M.; Qian, C.; Xie, Z.
Organometallics 2006, 25, 2578-2584.

119. Pentavalent vs Trivalent Phosphorus-Bridged Ligands. Synthesis and Structural Characterization of Unexpected Group 4 Metal Complexes Incorporating an Indenylide Unit, [σ:σ-iPr2NP(O)(C9H6)(C2B10H10)]M(NR2)2.
Wang, H.; Chan, H.-S.; Xie, Z.
Organometallics 2006, 25, 2569-2573.

118. Synthesis, Structure, and Reactivity of 13-Vertex Carboranes and 14-Vertex Metallacarboranes.
Deng, L.; Chan, H.-S.; Xie, Z.
J. Am. Chem. Soc. 2006, 128, 5219-5230.

117. Group 4 Metallocenes Incorporating Constrained-Geometry Carboranyl Ligands.
Xie, Z.
Coord. Chem. Rev. 2006, 250, 259-272.

2005

116. Reduction of 1,2-(CH2)n-1,2-C2B10H10 by Group 1 Metals. Effects of Bridge Length/Rigidity on the Formation of Carborane Anions.
Deng,L.; Cheung, M.-S.; Chan, H.-S.; Xie, Z.
Organometallics 2005, 24, 6244-6249.

115. Highly Electrophilic Half-Sandwich Group 4 Metallacarborane Alkyls. C-H/C-O Activation and Alkyne Insertion Reactions at Neutral Metal Complexes.
Cheung, M.-S.; Chan, H.-S.; Xie, Z.
Organometallics 2005, 24, 5217-5220.

114. Synthesis, Structure, and Reactivity of a Zirconocene-Carboryne Precursor.
Deng, L.; Chan, H.-S.; Xie, Z.
J. Am. Chem. Soc. 2005, 127, 13774-13775.

113. Synthesis, Structural Characterization, and Reactivity of 13-Vertex Lanthanacarboranes Bearing h7-arachno-Carboranyl Ligands.
Cheung, M.-S.; Chan, H.-S.; Xie, Z.
Organometallics 2005, 24, 4468-4474.

112. Functional Sidearm Promoted Electron-Transfer Reactions: A New Route to Metallacarboranes Incorporating the h7-arachno-Carboranyl Ligands.
Cheung, M.-S.; Chan, H.-S.; Bi, S.; Lin, Z.; Xie, Z.
Organometallics 2005,24, 4333-4336.

111. Synthesis, Structural Characterization, and Reactivity of Rare Earth Complexes Incorporating Lewis Base Appended nido-Carborane Anions of the C2B9 and C2B10 Systems.
Cheung, M.-S.; Chan, H.-S.; Xie, Z.
Organometallics 2005, 24, 4207-4215.

110. Role of Carborane in Polymerization and Insertion Reactions.
Xie, Z.
Chin. J. Chem. 2005, 23, 1100-1102.

109. Synthesis and Structural Characterization of Mono- and Bisfunctional o-Carboranes.
Cheung, M.-S.; Chan, H.-S.; Xie, Z.
Dalton Trans. 2005, 14, 2375-2381.

108. Synthesis, Characterization, and Reactivity of Terminal Titanium Imido Complexes Incorporating Constrained-Geometry Carboranyl Ligands.
Wang, H.; Chan, H.-S.; Xie, Z.
Organometallics 2005, 24, 3772-3779.

107. Synthesis, Structural Characterization, and Catalytic Properties of Group 4 Metal Complexes Incorporating a Phosphorus-Bridged Indenyl-Carboranyl Constrained-Geometry Ligand.
Wang, H.; Chan, H.-S.; Okuda, J.; Xie, Z.
Organometallics 2005, 24, 3118-3124.

106. A New Synthetic Route to High-Valent Half-Sandwich Group 4 Metallacarborane Alkyls. Synthesis and Structural Characterization of [h1:h6-(Me2NCH2CH2)C2B10H11]Hf(CH2SiMe3)2.
Cheung, M.-S.; Chan, H.-S.; Xie, Z.
Organometallics 2005, 24, 3037-3039.

105. Synthesis, Reactivity, and Structural Characterization of a 14-Vertex Carborane.
Deng, L.; Chan, H.-S.; Xie, Z.

Angew. Chem. Int. Ed. 2005, 44, 2128 –2131.

1999

54. Synthesis and Structural Characterization of Novel Organolanthanide Clusters Containing Amido and Imido Groups.
Wang, S.; Yang. Q.; Mak, T.-C.-W.; Xie, Z.
Organometallics 1999, 18, 5511-5517.

53. Cyclopentadienyl vs Indenyl Substituents. Organolanthanide Complexes and Biscarborane Compounds Derived from a Versatile Ligand, Me2Si(C9H7)(C2B10H11).
Wang, S.; Yang, Q.; Mak, T.C.W.; Xie, Z.
Organometallics 1999, 18 , 4478-4487.

52. Is There a Continuum from Organosamarium Hydroxo to Oxo compounds? Crystal structures of [{(Me3Si)2C5H3}2Sm]2(u-O)(u-OH2) and Three Distinct Crystalline Forms of [{(Me3Si)2C5H3}2Sm(u-OH)]2.
Xie, Z.; Liu, Z.; Chui, K.; Xue, F.; Mak, T.C.W.
J. Organomet. Chem.1999, 588, 78-82.

51. A New Class of Metallacarboranes: Synthesis and Molecular Structure of the First Example of an Organolanthanide Compound Bearing an η7-Carboranyl Ligand.
Xie, Z.; Chui, K.; Yang, Q.; Mak, T.C.W.
Organometallics 1999, 18, 3947-3949.

50. Pi-Arene/Cation Structure and Bonding. Solvation versus Ligand Binding in Iron(III) Tetraphenylporphyrin Complexes of Benzene, Toluene, p-Xylene, and [C60]Fullerene.
Evans, D.R.; Fackler, N.L.P.; Xie, Z.; Richard, C.E.F.; Boyd, P.D.W.; Reed, C.A.
J. Am. Chem. Soc. 1999, 121, 8466-8474.

49. Exo-nido- versus closo-Lanthanacarboranes. Synthesis and Structure of exo-nido-[(C6H5CH2)2C2B10H10]Ln(DME)3, [exo-nido-{(C6H5CH2)2C2B9H9}Ln(THF)3]2 (Ln = Sm, Yb), and closo-exo-[(C6H5CH2)2C2B10H10]4Sm2Na3.
Xie, Z.; Liu, Z.; Yang, Q.; Mak, T.C.W.
Organometallics 1999, 18, 3603-3609.

48. Application of a New Versatile Ligand to Lanthanide(II) Chemistry: Synthesis, Reactivity, and Structure of a New Class of Organolanthanide Complexes.
Xie, Z.; Wang, S.; Yang, Q.; Mak, T.C.W.
Organometallics 1999, 18, 2420-2427.

47. [{[(η7-C2B10H12)(η6-C2B10H12)U][K2(THF)5]}2]: A Metallacarborane Containing the Novel h7-C2B10H12 4- Ligand.
Xie, Z.; Yan. C.; Yang, Q.; Mak, T.C.W.
Angew. Chem. Int. Ed. 1999, 38, 1761-1763.

46. Synthesis, Reactivity, and Structural Characterization of Organolanthanide Compounds Incorporating both Cyclopentadienyl and Carboranyl Groups.
Xie, Z.; Wang, S.; Zhou, Z.Y.; Mak, T.C.W.
Organometallics 1999, 18, 1641-1652.

45. Synthesis and Structure of the First Tetranuclear Organolanthanide Cluster Containing a u4-Imido Group.
Xie, Z.; Wang, S.; Yang. Q.; Mak, T.C.W.
Organometallics 1999, 18, 1578-1579.

44. Synthesis and structural characterization of new weakly coordinating anions. Crystal structure of Ag(1-CH 3-CB11H5X6) (X = H, Cl, Br, I).
Xie, Z.; Tsang, C.W.; Xue, F.; Mak, T.C.W.
J. Organomet. Chem. 1999,577, 197-204.

1998

43. Highly Chlorinated, Brominated, and Iodinated Icosahedral Carborane Anions: 1-H-CB11X11- ,1-CH3-CB11X11- (X = Cl, Br, I); 1-Br-CB11Br11-.
Xie, Z.; Tsang, C.W.; Sze, E.T.P.; Yang. Q.; Chan, D.T.W.; Mak, T.C.W.
Inorg. Chem.1998, 37, 6444-6451.

42. Synthesis and Reactivity of Cationic Lanthanide Metallocene Complexes. Hexabromocarborane and Tetraphenylborate as Counterions.
Xie, Z.; Liu, Z.; Zhou, Z.Y.; Mak, T.C.W.
J. Chem. Soc., Dalton Trans. 1998, 3367.

41. Synthesis, Molecular Structure, and Reactivity of Organolanthanide Fluoride Complexes, [{(Me 3Si)2C5H3}2Ln(u-F)]2 (Ln = La, Nd, Sm, Gd) and [(C5H5)2Ln(u-F)(THF)]2 (Ln = Y, Yb).
Xie, Z.; Chui, K.; Yang. Q.; Mak, T.C.W.; Sun,
J. Organometallics 1998, 17 , 3937-3944. 　

40. Synthesis and Structural Characterization of the First Mixed Lanthanacarborane Incorporating h5-Cyclopentadienyl and h6-Carboranyl Ligands.
Xie, Z.; Wang, S.; Zhou, Z.Y.; Mak, T.C.W.
Organometallics 1998, 17 , 1907-1909. 　

39. A New Versatile Ligand: Its Synthesis and Applications in Organolanthanide Chemistry.
Xie, Z.; Wang, S.; Zhou, Z.Y.; Xue, F.; Mak, T.C.W.
Organometallics 1998, 17, 489-491.

1997

38. Systematic studies on the reactions of lanthanide trichlorides with Na[1,3-bis(trimethylsilyl)cyclopentadienyl]. Crystal structures of [1,3-(Me3Si)2C5H3]3Ln (Ln = La, Nd, Gd, Dy).
Xie, Z.; Chui. K.; Liu, Z.; Xue, F.; Zhang, Z.; Mak, T.C.W.; Sun, J.
J. Organomet. Chem. 1997, 549, 239-244.

37. Synthesis and X-ray Crystal Structure of Bis[η 5-1,3-bis(trimethylsilyl)cyclopentadienyl] Lanthanide and Yttrium Iodide Complexes.
Xie, Z.; Liu, Z.; Xue, F.; Zhang, Z.; Mak, T.C.W.
J. Organomet. Chem. 1997, 542, 285-289.

36. Protonation of a Linear Oxo Bridged Diiron Unit without Rehybridization of the Bridging Oxygen: Structure of the (u-Hydroxo)bis(tetraphenylporphinatoiron(III)) Cation.
Evans, D.R.; Mathur, R.S.; Heerwegh, K.; Reed, C.A.; Xie, Z.
Angew. Chem. Int. Ed. 1997, 36, 1335-1337.

35. Synthesis and Crystal Structure of an Organolanthanide Fluoride, [{Me3Si)2C5H3}2Sm(u-F)]2.
Xie, Z.; Liu, Z.; Xue, F.; Mak, T.C.W.
J. Organomet. Chem. 1997, 539, 127-130.

34. Synthesis and Structural Characterization of closo- and exo-nido-Lanthanacarboranes.
Xie, Z.; Liu, Z.; Chiu K.Y.; Xue, F.; Mak, T.C.W.
Organometallics 1997, 16, 2460.

33. Chlorination of Icosahedral Carborane Anions. X-ray Crystal Structure of [Me3NH][CH3-1-CB11Cl11].
Xie, Z.; Tsang, C.W.; Xue, F.; Mak, T.C.W.
Inorg. Chem. 1997, 36, 2246.

32. Structural Diversity in Silver Salts of Hexahalogenocarborane Anions, Ag(CB11H6X6) (X = Cl, Br, I).
Xie, Z.; Wu, B.; Mak, T.C.W.; Manning, J.; Reed, C.A.
J. Chem. Soc. Dalton. Trans. 1997, 1213-1217.

31 . Five-coordinate Hydrogen: Neutron Diffraction Analysis of the Hydrido Cluster Complex [H2Rh13(CO)24]3-.
Bau, R.; Drabnis, M.H.; Garlascheli, L.; Klooster, W.T.; Xie, Z.; Koetzle, T. F.; Martinengo, S.
Science. 1997, 275, 1099-1102.

30. Recent Advances in Approaching Silylium Ions.
Xie, Z.
Youji Huaxue (Chin. J. Org. Chem.) 1997, 17, 126-133.

1996

29. Autoionization of SmI 3 in Tetrahydrofuran. X-ray Crystal Structure of the Ionic Complex [SmI2(THF)5][SmI4(THF)2].
Xie, Z.; Chiu, K. Y.; Wu, B.; Mak, T.C.W.
Inorg. Chem. 1996, 35, 5957-5958.

28. Approaching the Silylium Ion: Trends with Hexahalo (Cl, Br, I) Carboranes as Counterions.
Xie, Z.; Manning, J.; Reed, R.W.; Mathur, R.; Boyd, P.D.W.; Benesi, A.; Reed, C.A.
J. Am. Chem. Soc. 1996, 118, 2922-8.

1995

27. Isolation of a-Phosphenium Ion with a P-C σ Bond.
Reed, R.W.; Xie, Z.; Reed, C.A.
Organometallics 1995, 14, 5002-5004.

26. A Crystalline [H9O4]+ Hydronium Ion Salt with a Weakly Coordinating Anion.
Xie, Z.; Bau, R.; Reed, C.A.
Inorg. Chem. 1995, 34, 5403-5404.

25. The Silylium Ion (R3Si+) Problem: Effect of Alkyl Substituents R.
Xie, Z.; Bau, R.; Benesi, A.; Reed, C.A.
Organometallics 1995, 14, 3933-3941.

1994

24. The Search for the Least-Coordinating Anion: Derivatizing the Icosahedral Closo-Carborane Anion CB11H12-.
Reed, R.W.; Xie, Z.; Manning, J.; Mathur, R.; Bau, R.; Reed, C.A.
Phosphorus Sulfur Silicon Relat. Elem. 1994, 93-94, 485.

23. The "free" [Fe(tpp)]+ Ion and a New Route to the Least Coordinating Anion.
Xie, Z.; Bau, R.; Reed, C.A.
Angew. Chem. Int. Ed. Engl. 1994, 33, 2433-2434.

22. Isolation of a Protonated Silanol: But3Si(OH2)+.
Xie, Z.; Bau, R.; Reed, C.A.
J. Chem. Soc., Chem. Commun. 1994, 2519.

21. Ordered Structure of a Distorted C60 2- Fulleride Ion.
Paul, P.; Xie, Z.; Bau, R.; Boyd, P.D.W.; Reed, C.A.
J. Am. Chem. Soc. 1994, 116, 4145-4146.

20. New Weakly Coordinating Anions. III. Useful Silver and Trityl Salt Reagents of Carborane Anions.
Xie, Z.; Jelinek, T.; Bau, R.; Reed, C.A.
J. Am. Chem. Soc. 1994, 116, 1907-1913.

19. Triethylsilyl cations. Reply to comments.
Reed, C.A.; Xie, Z.
Science. 1994,263, 985-986.　

1993

18. Synthesis and Molecular Structure of an Ion Pair Compound [YCl2(THF)5]+[YCl4(THF)2]-.
Xie, Z.; Qian, C.; Sun, J; Jin, X.
Jiegou Huaxue (Chin. J. Struct. Chem.) 1993, 12, 107-110.

17. A New Weakly Coordinating Anion: Approaching the Silicenium Ion.
Xie, Z.; Liston, D.J.; Jeslinek, T.; Mitro, V.; Bau, R.; Reed, C.A.
J. Chem. Soc. Chem. Commun. 1993, 384-386.

16. Closely Approaching the Silylium Ion (R 3Si+).
Reed, C.A.; Xie, Z.; Bau, R.
Science. 1993, 262, 402-404.

1992

15. Organometallic Compounds of the Lanthanides. LXVI. Synthesis and X-Ray Crystal Structure of [O(CH2CH2C5H4)2Y( µ-OH)]2 and (MeC5H4)3Ho(H2O), Two Unusual Products of the Hydrolysis of Organolanthanide Compounds.
Schumann, H.; Goerlitz, F.H.; Hahn, F.E.; Pickardt, J.; Qian, C.; Xie, Z.
Z. Anorg. Allg. Chem. 1992, 609, 131-138.

1991

14. Synthesis of Organolanthanide Hydride Containing an Intramolecular Coordination Bond and X-ray Crystal Structure of Yttrium Hydride Complex.
Qian, C; Deng, D; Xie, Z; Zheng, P; Wu, G.
J. Rare Earths (Special Issue) 1991, 1, 451-453.

13. Synthesis and Characterization of Binuclear Lanthanocene Complexes with 1,1'-(3-Oxa-pentamethylene)dicyclopentadienyl Ligand.
Xie, Z.; Qian, C.
Chin. Sci. Bull.1991, 36, 1834-1835.

12. Studies on Organolanthanide Complexes. XXXIX. Synthesis and Molecular Structure of (MeCp)3La (MeCp = CH3C5H4): a Tetrameric Complex of the Type [(MeCp)3La]4.
Xie, Z.; Hahn, F.E.; Qian, C.
J. Organomet. Chem. 1991, 414, C12-C14.

11. Studies on Organolanthanide Complexes. XXXVIII. New Organolanthanide Hydrides: Synthesis and Reactivity Towards Alkenes, Alkynes and Organic Halides.
Xie, Z.; Qian, C.; Huang, Y.
J. Organomet. Chem. 1991, 412, 61-69.

10. Organometallic Compounds of the Lanthanides. [1,1'-(3-Oxapentamethylene)dicyclopentadienyl]yttrium and -lutetium 3,5-dimethylpyrazolates. X-Ray Crystal Structure of [O(CH2CH2C5H4)2Ln(µ-N2C3HMe2)(µ-OH)Ln(C5H4CH2CH2)2O] (Ln = Yttrium, Lutetium).
Schumann, H.; Loebel, J.; Pickardt, J.; Qian, C.; Xie, Z.
Organometallics 1991, 10, 215-219.

1990	9. Studies on Organolanthanide Complexes. XXVI. Synthesis, Identification and Bonding Properties of {1,1'-(3-Oxapentamethylene)dicyclopentadienyl}(cyclopentadienyl)lanthanide Derivatives. Qian, C.; Xie, Z.; Huang. Y. J. Organomet. Chem. 1990, 398, 251-258.

1989

8. Mass Spectra of Organolanthanide Complexes.
Fu, G.; Xu, Y.; Xie, Z.; Qian, C.
Acta Chim. Sinica 1989, 5, 431-436.

7. Studies on Organolanthanide Complexes. XXI. Reduction of Alkenes with Yttrocene Chlorides/Sodium Hydride systems.
Qian, C.; Xie, Z.; Huang, Y.
Chin. Sci. Bull. 1989, 34, 1106-1109.
　

1988	6. Studies on Organolanthanide Complexes. XIX. Proton and Carbon-13 NMR Spectra of Dicyclopentadienyl Yttrium and Lutetium Chlorides. Chen, C.; Zhong, X.; Qian, C.; Xie, Z.; Huang, Y. Youji Huaxue (Chin. J. Org. Chem.) 1988, 8 , 235-237.

1987

5. "Recent Advances in Organolanthanide Chemistry" in "Advances in Organometallic Chemistry" edited by Huang, Y. and Qian, Y.
Qian, C.; Xie, Z.
Chemical Industry Press Beijing, China, 1987, p.401-430.

4. Studies on Organolanthanide Complexes. XVI. Reduction of Alkenes with Organolanthanide Complex/Sodium Hydride Systems.
Qian, C.; Deng, D.; Ye, C.; Xie, Z.; Ge, Y.; Li, Y.; Gu, Y.
Inorg. Chim. Acta 1987, 140, 21-24.

3. Studies on Organolanthanide Complexes. XVII. Syntheses and Identification of (1,1'-Pentamethylenedicyclopentadienyl)lanthanide Chlorides, -Yttrium Chloride and Yttrium Cyclopentadienyl Derivative.
Qian, C.; Xie, Z.; Huang, Y.
Inorg. Chim. Acta 1987, 139, 195-199.

2. Studies on Organolanthanide Complexes. XII. Synthesis, Identification and Reactivity of Organolanthanide and -Yttrium Chlorides with the Chelating 1,1'-(3-Oxapentamethylene)dicyclopentadienyl Ligand.
Qian, C.; Xie, Zuowei; Huang, Y.
J. Organomet. Chem. 1987, 323, 285-294.

1986	1. Crystal and Molecular Structure of Tetraphenyldiarsine. Ni, C.; Zhang, Z.; Xie, Z.; Qian, C.; Huang, Y. Jiegou Huaxue (Chin. J. Struct. Chem.) 1986, 5, 181-184.

285. Copper catalyzed/mediated direct B–H alkenylation/alkynylation in carboranesChen, Y.; Au, Y. K.; Quan, Y.; Xie, Z.Sci China Chem, 2019, 62, 74-79.

284. Regioselective Nucleophilic Alkylation/Arylation of B–H Bonds in o-Carboranes: An Alternative Method for Selective Cage Boron FunctionalizationTang, C.; Zhang, J.; Zhang, J.; Xie, Z.J. Am. Chem. Soc., 2018, 140, 16423-16427.

283. Broad Scope Extra‐Annular [4 + 2] Cycloaddition of o‐Carboryne with Styrenes: Efficient Route to Carborane‐Fused PolycyclicsZhang, J.; Xie, Z.Chin. J. Chem. 2018, 36, 1041-1046.

282. Rhodium catalyzed cascade cyclization featuring B–H and C–H activation: one-step construction of carborane-fused N-polyheterocyclesLyu, H.; Quan, Y.; Xie, Z.Chem. Sci., 2018, 9, 6390-6394

281. Reaction of o‐Carboryne with Furans: Facile Synthesis of Carborane-Fused Oxanorbornenes and Their DerivativesZhang, R.; Yuan, Y.; Qiu, Z.; Xie, Z.Chin. J. Chem. 2018, 36, 273-279.

278. Transition‐Metal‐Like Behavior of Monovalent Boron Compounds: Reduction, Migration, and Complete Cleavage of CO at a Boron CenterWang, H.; Wu, L.; Lin, Z.; Xie, Z.Angew. Chem. Int. Ed. 2018, 57, 8708-8713.

270. Broad Scope [4 + 2] Cycloaddition of o-Carboryne with Pentafulvenes Using 1-Li-2-OTf-o-C2B10H10 as PrecursorZhang, J.; Qiu Z.; Xie, Z.Organometallics 2017, 36, 3806-3811.

260. Enantioselective Construction of Cyclobutanes: A New and Concise Approach to the Total Synthesis of (+)-Piperarborenine BHu, J.-L.; Feng, L-W.; Wang, L.; Xie, Z.; Tang, Y.; Li, X.J. Am. Chem. Soc. 2016, 138, 13151-13154.

257. Unique properties of C,C′-linked nido-biscarborane tetraanions. Synthesis, structure and bonding of ruthenium monocarbollide via unprecedented cage carbon extrusionZhao, D.; Zhang, J.; Lin, Z.; Xie, Z.Chem. Commun. 2016, 52, 9992-9995.

256. Phosphine-catalyzed cage carbon functionalization of o-carborane: facile synthesis of alkenylcarboranesZheng, F.; Leung, T. F.; Chan, K. W.; Sung H. H. Y.; William, I. D. ; Xie, Z.; Jia, G.Chem. Commun. 2016, 52, 10767-10770.

255. Synthesis and Structural Characterization of Carbene-Stabilized Carborane-Fused Azaborolyl Radical Cation and Dicarbollyl-Fused AzaboroleWang, H.; Zhang, J.; Lin, Z.; Xie, Z.Organometallics, 2016, 35, 2579-2582.

254. Synthesis, structure and reactivity of mixed-sandwich zirconacarborane methyl complex (η5-C5Me5)[η1: η5-(R2NCH2CH2)C2B9H10]ZrMeLiu, D.; Qiu, Z.; Xie, Z.J. Organomet. Chem. 2016, 822, 144-153.

253. Palladium catalyzed regioselective B–C (sp) coupling via direct cage B–H activation: synthesis of B(4)-alkynylated o-carboranesQuan, Y.; Tang, C.; Xie, Z.Chem. Sci., 2016, 7, 5838-5845.

25. The Silylium Ion (R3Si+) Problem: Effect of Alkyl Substituents R.Xie, Z.; Bau, R.; Benesi, A.; Reed, C.A.Organometallics 1995, 14, 3933-3941.

8. Mass Spectra of Organolanthanide Complexes.Fu, G.; Xu, Y.; Xie, Z.; Qian, C.Acta Chim. Sinica 1989, 5, 431-436. 7. Studies on Organolanthanide Complexes. XXI. Reduction of Alkenes with Yttrocene Chlorides/Sodium Hydride systems.Qian, C.; Xie, Z.; Huang, Y. Chin. Sci. Bull. 1989, 34, 1106-1109.