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成果及论文

2025:

6.    Lingjie Zhang, Minghao Huang, and Jiliang Zhou,* A dicationic distibine stabilized by intramolecular π-π interaction and second-sphere coordination, Chem. Commun. 2025, 61, 8592.

5.        Zichen Zhang, Kunlong Li, Minghao Huang, Ting Chen, and Jiliang Zhou,* The Outstanding Ambiphilicity of Trialkylstibines among Trialkylpnictines: Power for Stepwise Deoxygenation and N−N Coupling of Nitroarenes, J. Am. Chem. Soc. 2025147, 10066.

4.        Yuankai Li, Huan Mu, Zhuchunguang Liu, Zexin Qi, Jiliang Zhou, and Zhaowen Dong,* Dicationic 1‑Germa and 1‑Stannavinylidenes: Synthesis, Structure, and ReactivityJACS Au 20255, 1289.

2024:

3.        Minghao Huang, Kunlong Li, Zichen Zhang, and Jiliang Zhou,* Antimony Redox Catalysis: Hydroboration of Disulfides through Unique Sb(I)/Sb(III) Redox Cycling, J. Am. Chem. Soc. 2024146, 20432.

2.        Zhuchunguang Liu, Zhijun Wang, Huan Mu, Yihan Zhou, Jiliang Zhou, and Zhaowen Dong,* Synthesis and redox catalysis of Carbodiphosphorane ligated stannyleneNat. Commun. 202415, 9849.

1.        Kunlong Li, Minghao Huang, and Jiliang Zhou,* A Monoanionic Pincer Ligand with Pendant Phosphazene Arms: Stabilization of Main-Group and Transition Metal Complexes, Eur. J. Inorg. Chem. 2024, 27, e202300567.

独立工作前代表性成果:

1.        Jiliang Zhou, Liu Leo Liu, Levy L. Cao and Douglas W. Stephan,* Base-Stabilized [PO]+/[PO2]+ Cations, Angew. Chem. Int. Ed. 2019, 58, 18276.

2.        Jiliang Zhou, Liu Leo Liu, Levy L. Cao and Douglas W. Stephan,* The Arene-Stabilized η5-Pentamethylcyclopentadienyl Arsenic Dication [(η5-Cp*)As(toluene)]2+, Angew. Chem. Int. Ed. 2019, 58, 5407.

3.        Jiliang Zhou, Liu Leo Liu, Levy L. Cao, and Douglas W. Stephan,* A Phosphorus Lewis Super Acid: η5-Pentamethylcyclopentadienyl Phosphorus Dication, Chem 2018, 4, 2699.

4.        Jiliang Zhou, Liu Leo Liu, Levy L. Cao, and Douglas W. Stephan,* Nitrogen-Based Lewis Acids: Synthesis and Reactivity of a Cyclic (Alkyl)(Amino)Nitrenium Cation, Angew. Chem. Int. Ed. 2018, 57, 3322.