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姚昌广 南昌大学化学化工学院副教授    

研究方向:过渡金属配合物设计及催化性能,烯烃、极性单体可控聚合,生物基高分子合成,小分子活化


联系方式:chguyao@163.com


教育与工作背景:

2020/05 至今:南昌大学化学化工学院副教授

2015/12–2019/12:博士后,King Abdullah University of Science and Technology,

                                金属有机化学(合作导师:Kuo-Wei Huang 教授)

2009/09–2015/07:硕博连读,中国科学院长春应用化学研究所,高分子物理与化学国家重点实验室,高分子化学(导师:崔冬梅 研究员)

2005/09–2009/07:本科,陕西师范大学,材料化学


代表性论文:

[10] Changguang Yao, Xiufang Wang and Kuo-Wei Huang*. “Nitrogen Atom Transfer Mediated by a New PN3P-Pincer Nickel Core via a Putative Nitrido Nickel Intermediate” Chem. Commun. 2018,54, 3940–3943.

[9] Changguang Yao, Fei Lin, Meiyan Wang, Dongtao Liu, Bo Liu, Na Liu, Zichuan Wang, Shiyu Long, Chunji Wu* and Dongmei Cui*. “Highly Syndioselective 3,4-Trans Polymerization of (E)-1-(4-Methylphenyl)-1,3-butadiene by Fluorenyl N-Heterocyclic Carbene Ligated Lutetium Bis(alkyl) Precursor” Macromolecules 2015, 48, 1999–2005. 

[8] Changguang Yao, Na Liu, Shiyu Long, Chunji Wu and Dongmei Cui*. “Highly cis-1,4-Selective Coordination Polymerization of Polar 2-(4-Methoxyphenyl)-1,3-Butadiene and Copolymerization with Isoprene Using a β-Diketiminato Yttrium Bis(alkyl) Complex” Polym. Chem. 2016, 7, 12641270.

[7] Changguang Yao, Priyanka Chakraborty, Emanuele Aresu, Huaifeng Li, Chao Guan, Chunhui Zhou, Lan-Chang Liang* and Kuo-Wei Huang*. “Monomeric Nickel Hydroxide Stabilized by a Sterically Demanding Phosphorus-Nitrogen PN3P-pincer Ligand: Synthesis, Reactivity and Catalysis”. Dalton Trans., 2018, 47, 16057–16065.
[6] Changguang Yao, Tonghuan Zhang, Chunhui Zhou and Kuo-Wei Huang*. “Interrogating the Steric Outcome During H2 Heterolysis: In-Plane Steric Effects in the Regioselective Protonation of the PN3P-Pincer Ligand” Dalton Trans., 2019, 48, 12817–12821.

[5] Changguang Yao, Dongtao Liu, Ping Li, Chunji Wu, Shihui Li, Bo Liu and Dongmei Cui*. “Highly 3,4-Selective Living Polymerization of Isoprene and Copolymerization with ε-Caprolactone by an Amidino N-heterocyclic Carbene Ligated Lutetium Bis(alkyl) Complex” Organometallics 2014, 33, 684–691.

[4] Changguang Yao, Chunji Wu, Baoli Wang and Dongmei Cui*. “Copolymerization of Ethylene with 1-Hexene and 1-Octene Catalyzed by Fluorenyl N-Heterocyclic Carbene Ligated Rare-Earth Metal Precursors” Organometallics 2013, 32, 2204–2209. 

[3] Changguang Yao, Hongyan Xie and Dongmei Cui*. “Highly 3,4-Selective Living Polymerization of 2-Phenyl-1,3-Butadiene with Amidino N-Heterocyclic Carbene Ligated Rare-Earth Metal Bis(alkyl) Complexes” RSC Adv. 2015, 5, 93507–93512.

[2] Dongtao Liu, Changguang Yao, Rong Wang, Meiyan Wang, Zichuan Wang, Chunji Wu, Fei Lin, Shihui Li, Xinhua Wan and Dongmei Cui*. “Highly Isoselective Coordination Polymerization of ortho-Methoxystyrene with β-Diketiminato Rare-Earth-Metal Precursors” Angew. Chem. Int. Ed. 2015, 54, 5205–5209.

[1] Zhaohe Liu, Changguang Yao, Chunji Wu, Zhongfu Zhao* and Dongmei Cui*. “Additive-Triggered Chain Transfer to a Solvent in Coordination Polymerization” Macromolecules 2020, 53, 1205–1211.

申请专利:

1. 崔冬梅*,姚昌广,吴春姬,刘波,亚历山大·特里弗诺夫:稀土催化剂组合及其用于异戊二烯类化合物的3, 4-聚合(ZL 2013 1 0689037.5)
2. 崔冬梅*,姚昌广,吴春姬,刘波: 2-芳基-1, 3丁二烯3, 4-聚合物及其制备方法(ZL 2015 1 0224201.4)
3. 崔冬梅*,姚昌广,刘东涛,吴春姬: 2-芳基-1, 3丁二烯顺-1, 4-聚合物及其制备方法(ZL 2015 1 0224184.4)
4. 崔冬梅*,吴春姬,姚昌广: 茂金属配合物及其制备方法、催化剂组合物(ZL 2013 1 0478190.3, US 9896519 B2, EP 3056505 B1, JP 6302565 B2)