1. 研究生课程
课程1:催化材料基础与应用
参考书:
教案ppt:
第二章,表面与吸附(链接)
第四章,催化机理与研究方法(链接)
注:如有对该课程感兴趣的老师或者学生,欲进一步地交流,请发送邮件至yuanqingwang@shu.edu.cn
课程2:催化过程的原位光谱学
参考书:
2. 本科生课程:电催化实验综合设计(AI+课程)
A. 催化剂的合成
B. 催化剂的谱学表征(原位,Operando)
拉曼光谱-仪器篇讲义(链接)
C. 标准电化学测试文献分享:
1. Akbashev, A. R., Electrocatalysis Goes Nuts. ACS Catalysis 2022, 4296-4301. http://doi.org/10.1021/acscatal.2c00123 *正确地看待所谓“高影响”论文
2. Xia, Y.-F.; Guo, P.; Li, J.-Z.; Zhao, L.; Sui, X.-L.; Wang, Y.; Wang, Z.-B., How to appropriately assess the oxygen reduction reaction activity of platinum group metal catalysts with rotating disk electrode. iScience 2021, 24 (9), 103024. https://doi.org/10.1016/j.isci.2021.103024
3. Anantharaj, S.; Noda, S.; Driess, M.; Menezes, P. W., The Pitfalls of Using Potentiodynamic Polarization Curves for Tafel Analysis in Electrocatalytic Water Splitting. ACS Energy Letters 2021, 6 (4), 1607-1611. http://doi.org/10.1021/acsenergylett.1c00608 *如何正确地进行Tafel分析
4. Yu, L.; Ren, Z., Systematic study of the influence of iR compensation on water electrolysis. Materials Today Physics 2020, 14, 100253. https://doi.org/10.1016/j.mtphys.2020.100253 *iR补偿
5. Niu, S.; Li, S.; Du, Y.; Han, X.; Xu, P., How to Reliably Report the Overpotential of an Electrocatalyst. ACS Energy Letters 2020, 5 (4), 1083-1087. http://doi.org/10.1021/acsenergylett.0c00321 *参比电极的选择与维护
6. Li, D.; Batchelor-McAuley, C.; Compton, R. G., Some thoughts about reporting the electrocatalytic performance of nanomaterials. Applied Materials Today 2020, 18, 100404. https://doi.org/10.1016/j.apmt.2019.05.011
7. Ji, S. G.; Kim, H.; Park, C.; Kim, W.; Choi, C. H., Underestimation of Platinum Electrocatalysis Induced by Carbon Monoxide Evolved from Graphite Counter Electrodes. ACS Catalysis 2020, 10 (18), 10773-10783. https://doi.org/10.1021/acscatal.0c01783 *讨论对电极的影响
8. Wei, C.; Rao, R. R.; Peng, J.; Huang, B.; Stephens, I. E. L.; Risch, M.; Xu, Z. J.; Shao-Horn, Y., Recommended Practices and Benchmark Activity for Hydrogen and Oxygen Electrocatalysis in Water Splitting and Fuel Cells. Adv Mater 2019, 31 (31), e1806296. http://doi.org/10.1002/adma.201806296 **推荐,详细讨论了各种实验细节
9. Wei, C.; Sun, S.; Mandler, D.; Wang, X.; Qiao, S. Z.; Xu, Z. J., Approaches for measuring the surface areas of metal oxide electrocatalysts for determining their intrinsic electrocatalytic activity. Chemical Society Reviews 2019, 48 (9), 2518-2534. http://doi.org/10.1039/C8CS00848E *讨论如何测试金属氧化物的电化学活性面积
10. Anantharaj, S.; Kundu, S., Do the Evaluation Parameters Reflect Intrinsic Activity of Electrocatalysts in Electrochemical Water Splitting? ACS Energy Letters 2019, 4 (6), 1260-1264. http://doi.org/10.1021/acsenergylett.9b00686 *催化剂载量的影响
11. Voiry, D.; Chhowalla, M.; Gogotsi, Y.; Kotov, N. A.; Li, Y.; Penner, R. M.; Schaak, R. E.; Weiss, P. S., Best Practices for Reporting Electrocatalytic Performance of Nanomaterials. ACS Nano 2018, 12 (10), 9635-9638. http://doi.org/10.1021/acsnano.8b07700
12. Li, G.; Anderson, L.; Chen, Y.; Pan, M.; Abel Chuang, P.-Y., New insights into evaluating catalyst activity and stability for oxygen evolution reactions in alkaline media. Sustainable Energy & Fuels 2018, 2 (1), 237-251. http://doi.org/10.1039/C7SE00337D
13. Garcia, A. C.; Koper, M. T. M., Effect of Saturating the Electrolyte with Oxygen on the Activity for the Oxygen Evolution Reaction. ACS Catal 2018, 8 (10), 9359-9363. http://doi.org/10.1021/acscatal.8b01447 *讨论吹扫气体的影响
14. Stevens, M. B.; Enman, L. J.; Batchellor, A. S.; Cosby, M. R.; Vise, A. E.; Trang, C. D. M.; Boettcher, S. W., Measurement Techniques for the Study of Thin Film Heterogeneous Water Oxidation Electrocatalysts. Chemistry of Materials 2017, 29 (1), 120-140. http://doi.org/10.1021/acs.chemmater.6b02796 **推荐,实验细节的讨论非常精彩
15. Elgrishi, N.; Rountree, K. J.; McCarthy, B. D.; Rountree, E. S.; Eisenhart, T. T.; Dempsey, J. L., A Practical Beginner’s Guide to Cyclic Voltammetry. Journal of Chemical Education 2017, 95 (2), 197-206. http://doi.org/10.1021/acs.jchemed.7b00361 *入门:循环伏安法的介绍
16. Chen, R.; Yang, C.; Cai, W.; Wang, H.-Y.; Miao, J.; Zhang, L.; Chen, S.; Liu, B., Use of Platinum as the Counter Electrode to Study the Activity of Nonprecious Metal Catalysts for the Hydrogen Evolution Reaction. ACS Energy Letters 2017, 2 (5), 1070-1075. http://doi.org/10.1021/acsenergylett.7b00219 *讨论Pt对电极
17. Trotochaud, L.; Young, S. L.; Ranney, J. K.; Boettcher, S. W., Nickel–Iron Oxyhydroxide Oxygen-Evolution Electrocatalysts: The Role of Intentional and Incidental Iron Incorporation. Journal of the American Chemical Society 2014, 136 (18), 6744-6753. http://doi.org/10.1021/ja502379c *讨论电解液中常见Fe污染
18. Frydendal, R.; Paoli, E. A.; Knudsen, B. P.; Wickman, B.; Malacrida, P.; Stephens, I. E. L.; Chorkendorff, I., Benchmarking the Stability of Oxygen Evolution Reaction Catalysts: The Importance of Monitoring Mass Losses. ChemElectroChem 2014, 1 (12), 2075-2081. https://doi.org/10.1002/celc.201402262 *电催化剂稳定性的重要性
19. McCrory, C. C. L.; Jung, S.; Peters, J. C.; Jaramillo, T. F., Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction. Journal of the American Chemical Society 2013, 135 (45), 16977-16987. http://doi.org/10.1021/ja407115p *提出标准测试的protocol
3. 有用的链接:
A. 推荐的科学类杂志
3. Nature Catalysis 4. Nature Chemistry
5. Nature Communications 6. JACS 7. Angewandte Chemie
8. ACS Catalysis 9. Journal of Catalysis 10. Applied Catalysis B: Environmental 11. ChemCatChem
12. JPCC 13. Journal of The Electrochemical Society 14. Electrochimica Acta 15. ChemElectroChem
B. 推荐的科学新闻网站
C. 推荐的科学信息网站
1. 化学品信息检索sigma-aldrich (https://www.sigmaaldrich.cn/CN/zh)
2. 化学品订购阿拉丁 (https://www.aladdin-e.com/)
3. 思想家公社(http://sobereva.com/)
4. VASP Wiki(https://www.vasp.at/wiki/index.php/Main_page)
5. COD开放晶体数据库(http://www.crystallography.net/cod/)
6. Bilbao晶体数据库(https://www.cryst.ehu.es)
7. NIST标准XPS数据(https://srdata.nist.gov/xps/selEnergyType.aspx)
8. NIST Chemistry WeBook (https://webbook.nist.gov/chemistry/) *美国国家标准与技术研究院数据库
9. Spectral Database for Organic Compounds(https://sdbs.db.aist.go.jp/sdbs/cgi-bin/direct_frame_top.cgi)
10. Horiba Technology - Spectroscopy(*Horiba公司光谱仪技术手册)
11. Spectroscopyonline(*分子光谱学技术文章) 12. 拉曼技术文章
13. THORLABS(*丰富的光学元件与技术资料)14. Edmund Optics(*所有与激光用光学件相关的资源) 15. 海洋光学(*OEM光谱仪)
16. 世伟洛克Swagelok (*管材配件资源) 17. Bronkhorst 18. Pico Technology 19. Linkam 20. Harrick Solutions
21. EPICS(https://epics.anl.gov/)*仪器自动控制
22. Materials Project (https://materialsproject.org/)*计算材料数据库,美国
23. NOMAD(https://nomad-coe.eu/)*计算材料数据库,欧洲
24. Catalyst Hub(http://www.catalysthub.net/) *催化剂计算数据库
25. 中研环科 26. 复享光谱 27. 高仕睿联 28. 天津艾达 29. 上海辰华 30. 合肥科晶 31. 上海沅方
33. Agilent技术资料(https://www.agilent.com.cn/en-us/library/usermanuals?N=135)
D. 推荐的课件、视频资源
1. MIT Open Course (最好的在线课程教育资源)
尤其推荐Prof. Sadoway的课程MIT3.091Introduction to Solid State Chemistry (视频链接)
Prof. Robert Guy Griffin等的课程MIT5.61物理化学(讲义链接)
2. FHI lectures:Modern Methods in Heterogeneous Catalysis Research (弗里·茨哈伯研究所从2002年至2018年举办的催化课程,涵盖催化研究的各个方面(偏向多相催化),每个Topic的主讲者都是本领域的顶尖专家)
(http://www.fhi-berlin.mpg.de/acnew/department/pages/teaching/pages/)
3. 台湾大学鄭原忠教授课程资源:Quantum Dynamic and Spectroscopy (内含物理化学二教授视频)
(https://quantum.ch.ntu.edu.tw/online_courses/index.html)
4. 台湾交通大学許根玉教授课程:物理光学
(https://www.bilibili.com/video/BV1eD4y1S7mv/)
5. 挪威科技大学(NTNU)Prof. Jacob Linder: Classical Lagrangian Mechanics
(https://cosmolearning.org/courses/classical-lagrangian-mechanics/)
6. 牛津大学Prof. Steve Simon: Solid State Basics
(https://podcasts.ox.ac.uk/series/oxford-solid-state-basics)
7. Youtube理论化学学习资源TMP Chem
(https://www.youtube.com/c/TMPChem/featured)
8. Sherrill Group's Lecture Series in Theoretical Chemistry
(https://cosmolearning.org/courses/sherrill-groups-lecture-series-theoretical-chemistry/)
9. 北京大学田光善主讲量子力学
(https://www.bilibili.com/video/BV1yb411G7bo?p=1)
10. 中科院黄明宝主讲量子化学
(https://v.youku.com/v_show/id_XNTIxODcyNTY0.html)
11. 南京大学胡安主讲固体物理
(https://www.bilibili.com/video/BV1Uf4y1k7CE?p=1)