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成果及论文

独立工作期间:

2024:

[10] H. Wang , X. Xu , L. Cao , Xin Tao*, Synthesis of 9,9′-Bifluorenylidene-Based Porous Aromatic Frameworks (BF-PAFs) for Photocatalytic Production of Hydrogen Peroxide. Synthesis 2024 (Accepted).


[9] C. Dong, J. Yu, X. Tao*, H. Wang*, G. Zhu*, Open-Shell Resonance of Germanium-Alkyne Porous Organic Radical Polymer for Boosting Sodium-Ion Storage. Adv. Funct. Mater. 2024, 2410372.


[8] H. Wang, X. Xu, L. Cao, Z. Zhang, J. Li, X. Liu, X. Tao*, G. Zhu, Enhanced photocatalytic performance of tetraphenylethylene-based porous aromatic frameworks by bandgap adjustment for the synthesis of benzimidazoles. EES. Catal. 2024, 2, 1100-1110.


[7] T. Gao, F. Xu, H. Wang, X. Tao*, G. Zhu, Synthesis of Isocyanurate-Imidazolium-Derived Flexible Ionic Porous Organic Polymers for CO2 Fixation. ACS Appl. Polym. Mater. 2024, 6, 5878–5889.


[6] X. Xu, H. Wang, Z. Zhang, J. Li, X. Liu, X. Tao*, G. Zhu, Donor–acceptor type triphenylamine-based porous aromatic frameworks (TPA-PAFs) for photosynthesis of benzimidazoles. Nanoscale 2024, 16, 11138-11145.


[5] L. Cao+, C. Wang+, H. Wang, X. Xu, X. Tao*, H. Tan*, G. Zhu*, Rationally Designed Cyclooctatetrathiophene-Based Porous Aromatic Frameworks (COTh-PAFs) for Efficient Photocatalytic Hydrogen Peroxide Production. Angew. Chem. Int. Ed. 2024, 63, e202402095. (+contributed equally)


[4] H. Wang+, F. Meng+,  X. Tao*, B(C6F5)3-catalysed isomerization of terminal olefins. New J. Chem. 2024, 48, 4304-4309. (+contributed equally)


2023:

[3] C. Dong, L. Cao, X. Xu, X. Tao*, G. Zhu, Atom-Economical Synthesis of Lewis Acidic Boron Containing Porous Organic Polymers via Hydroboration Polymerization for Basic Chemical Capture. Small Methods 2023, 2301302.


[2] H. Wang+, Y. Cui+, J. Shi, X. Tao*, G. Zhu, Porous carbon supported Lewis acid-base sites as metal-free catalysts for the carbonylation of glycerol with urea. Appl. Catal. B: Environ. 2023, 330, 122457. (+contributed equally)


[1] C. Dong, J. Chu, L. Cao, F. Cui, S. Liang, X. Zhang, X. Tao*, H. Wang*, G. Zhu*, A Three-Dimensional Silicon-Diacetylene Porous Organic Radical Polymer, CCS Chem. 2023, 5, 607–615.


博士及博后期间:

[15] X. Tao, K. Škoch, C. G. Daniliuc, G. Kehr, G. Erker,* Borane-induced ring closure reaction of oligomethylene-linked bis-allenes,  Chem. Sci. 2020, 11, 1542.

[14] X. Tao, C. G. Daniliuc, K. Soloviova, C. A. Strassert, G. Kehr, G. Erker,* Arylallenes and the Halogeno-B(C6F5)2 Reagents: Facile Formation of 2-Borylindenes,  Chem. Commun. 2019, 55, 10166.

[13] X. Tao, C. Wölke, C. G. Daniliuc, G. Kehr, G. Erker,* Halogenoborane Mediated Allene Cyclooligomerization, Chem. Sci. 2019, 10, 2478.

[12] X. Tao, C. G. Daniliuc, G. Kehr, G. Erker,* Borane Induced Dimerization of Arylallene, Angew. Chem. Int. Ed. 2018, 57, 13922.

[11] F. Ge,+ X. Tao,+ C. G. Daniliuc, G. Kehr, G. Erker,* The Borole Route to Reactive Pentafluorophenyl-substituted Diboranes(4),  Angew. Chem. Int. Ed. 2018, 57, 14570. (+contributed equally).

[10] X. Tao, C. G. Daniliuc, R. Knitsch, M. R. Hansen, H. Eckert, M. Lübbesmeyer, A. Studer, G. Kehr, G. Erker,* The Special Role of B(C6F5)3 in the Single Electron Reduction of Quinones by Radicals,  Chem. Sci. 2018, 9, 8011.

[9] X. Tao, C. G. Daniliuc, O. Janka, R. Pöttgen, R. Knitsch, M. R. Hansen, H. Eckert, M. Lübbesmeyer, A. Studer, G. Kehr, G. Erker,* Reduction of Dioxygen by Radical/B(p-C6F4X)3 Pairs to Give Isolable Bis(borane)superoxide Compounds,  Angew. Chem. Int. Ed. 2017, 56, 16641. 

[8] X. Tao, G. Kehr, C. G. Daniliuc, G. Erker,* Selective Metal-free HB(C6F5)2 Catalyzed Allene Cyclotrimerization: Formation of 1,3,5-Trimethylenecyclohexane and Its Trishydroboration Product, Angew. Chem. Int. Ed. 2017, 56, 1376. 

[7] X. Tao, F. Türkyilmaz, C. G. Daniliuc, G. Kehr, G. Erker,* Reactions of strongly electrophilic alkenyl(pentafluorophenyl)boranes with the TEMPO Radical, J. Organomet. Chem.  2017, 847, 167. 

[6] X. Tao, G. Kehr, X. Wang, C. G. Daniliuc, S. Grimme, G. Erker,* Rapid Dihydrogen Cleavage by Persistent Nitroxide Radicals under Frustrated Lewis Pair Conditions, Chem. Eur. J. 2016, 22, 9504. 

[5] X. Tao, Q. Wu, H. Huo, W. Gao, Y. Mu,* New Titanium(IV) Complexes with 2-Cyclopentadienylbenzylamido Ligands: Synthesis, Characterization, and Catalytic Properties for Ethylene Polymerization and Copolymerization with 1-Hexene, Organometallics 2013, 32, 4815.

[4] X. Tao, W. Gao, HHuo, Y. Mu*, Achiral Cs-Symmetric Half-Sandwich Scandium(III) Complexes with Imine-Cyclopentadienyl Ligands Catalyze Isotactic Polymerization of 1-Hexene , Organometallics 2013, 32, 1287.

[3] Q. Zhang, X. Tao,* T. Song, Y. Mu,* Pentamethylcyclopentadienyltitanium aryl(pyridyl)amide complexes: Synthesis, characterization and catalytic performance for olefin polymerization, J. Organomet. Chem. 2016, 804, 18.

[2] A. Ueno, J. Yu, X. Tao, C. G. Daniliuc, G. Kehr, G. Erker*“Unusual 1,1-Hydroboration Route to a Reactive Unsaturated Vicinal Frustrated Phosphane/Borane Lewis Pair”,  Organometallics 2018, 37, 2665.

[1] L. Zhang, W. Gao, X. Tao, Q. Wu, Y. Mu*, L. Ye, New Chromium(III) Complexes with Imine-Cyclopentadienyl Ligands: Synthesis, Characterization, and Catalytic Properties for Ethylene Polymerization, Organometallics 2011, 30, 433.