N021. S. Ju, C. Zhang, B. Tang, L. L. Liu, D. W. Stephan*, Y. Wu* The Lewis superacidic aluminium cation: [(NHC)Al(C6F5)2]+ Chem. Commun., 2024, 60, 698-701
https://pubs.rsc.org/en/content/articlelanding/2024/CC/D3CC05440C
N020. V. Bedi, D. Mandal, Z. Hussain, S.-M. Chen, Y. Wu*, Z.-W. Qu*, S. Grimme, D. W. Stephan* The impact of Lewis acid variation on reactions with di-tert-butyl diazo diesters Dalton Trans., 2024, 53, 439-443
https://pubs.rsc.org/en/content/articlelanding/2024/dt/d3dt03506a
N019. J. Xiong, M. Yan, L. Jin, W. Song, L. Xiao, D. Xu, Chunyang Zhai*, D. W. Stephan*, J. Guo* B(C6F5)3-catalyzed hydrogermylation of enones: a facile route to germacycles. Org. Biomol. Chem., 2023, 21, 8098-8101
https://pubs.rsc.org/en/content/articlelanding/2023/OB/D3OB01402A
N018. M. Yan, L. Xiao, J. Xiong, L. Jin, D. W. Stephan*, J. Guo* Borane catalyzed transesterification of tert-butyl esters using α-aryl α-diazoesters. Org. Biomol. Chem., 2023, 21, 8279-8283
https://pubs.rsc.org/en/content/articlelanding/2023/OB/D3OB01548C
N017. Y. Luo,+ Z. Zhao,+ T. Chen, Y. Li, Y. Zhao, D. W. Stephan*, Y. Wu* Stannyl phosphaketene as a synthon for phosphorus analogues of β-lactam. Chem. Commun., 2023, 59, 10956-10959
https://pubs.rsc.org/en/content/articlelanding/2023/cc/d3cc03117a
N016. T. Chen, S. Ju, M. Tong, Y. Zhao, Y. Wu*, D. W. Stephan* Synthesis and characterization of phosphate-catecholate chelated Nd(III), Zr(IV) and Al(III) complexes. Eur. J. Inorg. Chem., 2023, 26, e202300443. (Invited contribution in the special collection of "Chinese EurJIC Talents")
https://doi.org/10.1002/ejic.202300443
N015. Z. Hussain, Y. Luo, Y. Wu*, Z.-W. Qu*, S. Grimme, D. W. Stephan* Reactivity of frustrated Lewis pairs with BOC protected diazocarboxylates: FLP capture of diazene. Chem. Commun., 2023, 59, 6191-6194
https://pubs.rsc.org/en/content/articlelanding/2023/cc/d3cc01571h
N014. Z. Hussain, Y. Luo, Y. Wu*, Z.-W. Qu*, S. Grimme, D. W. Stephan* Diazene Chemistry: Metal-Free Models of N2 Reduction Intermediates. J. Am. Chem. Soc. 2023, 145, 7101–7106
https://pubs.acs.org/doi/10.1021/jacs.3c01887
N013. W. Song, J. Guo*, D. W. Stephan* B(C6F5)3-catalyzed Wolff rearrangement/[2 + 2] and [4 + 2] cascade cyclization of α-diazoketones with imines. Org. Chem. Front., 2023, 10, 1754-1758
https://pubs.rsc.org/en/content/articlelanding/2023/qo/d3qo00054k
N012. L. Xiao, L. Jin, Y. Zhao, J. Guo*, D. W. Stephan* B(C6F5)3-catalyzed cyclopropanation of 3-alkenyl-oxindoles with diazomethanes Chem. Commun., 2023, 59, 1833-1836.
https://pubs.rsc.org/en/content/articlelanding/2023/cc/d2cc06744g
N011. T. Chen, Y. Mei, L. L. Liu*, Y. Zhao, Y. Wu*, D. W. Stephan* Alkoxyphosphorane /Borane Cooperative alkylations: A Frustrated Lewis Pair Version of the Mitsunobu Reaction Chem. Eur. J. 2023, 29, e202300264
https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202300264
N010. D. Mandal, Z. Hussain, Y.-A. Luo, Y. Wu*, D. W. Stephan* Transient Hydroboration and hydroalumination of activated azo-species: Avenues to NBO and NAlO-heterobicycles Chem. Commun., 2023, 59, 780-783
https://pubs.rsc.org/en/content/articlepdf/2023/cc/d2cc06207k
N009. J. Tan, C. Hu, X. Yang, S. Ju, L. Cao, Y. Wu*, L. L. Liu*, D. W. Stephan* Structure and reactivity studies of the aluminum analogue of Piers' borane [HAl(C6F5)2]3 Chem. Commun., 2023, 59, 282-285.
https://pubs.rsc.org/en/content/articlelanding/2022/cc/d2cc06075b
N008. Z. Zhao, J. Tan, T. Chen, Z. Hussain, Y. Li, Y. Wu*, D. W. Stephan* Ambiphilic Behavior of Ge(II)-Pseudohalides in Inter- and Intramolecular Frustrated Lewis Pair Alkyne Addition Reactions Inorg. Chem. 2022, 61, 18670–18677
https://doi.org/10.1021/acs.inorgchem.2c03171
N007. L. Jin, X. Zhou, Y. Zhao, J. Guo,* D. W. Stephan* Catalyst-dependent chemoselective insertion of diazoalkanes into N-H\C-H\O-H\C-O bonds of 2-hydroxybenzothiazoles Org. Biomol. Chem., 2022, 20, 7781-7786
https://doi.org/10.1039/D2OB01048H
N006. D. Mandal, T. Chen, Z.-W. Qu*, S. Grimme, D. W. Stephan* Reactions of Frustrated Lewis Pairs with Chloro-Diazirines: Cleavage of N=N Double Bonds, Angew. Chem. Int. Ed. 2022, 134, e202209241.
https://onlinelibrary.wiley.com/doi/10.1002/anie.202209241
N005. D. Mandal, T. Chen, Z.-W. Qu*, S. Grimme, D. W. Stephan* Reactions of diethylazo-dicarboxylate with Frustrated Lewis pairs, Chem. Eur. J. 2022, 28, e202201701
https://doi.org/10.1002/chem.202201701
N004. Y. Zhao, L. Jin, J. Guo,* and D. W. Stephan* Catalytic hydroaminations of alkynes: a facile protocol to vinyl-carbazole derivatives via a frustrated Lewis pair mechanism，Chem. Commun., 2022, 58, 3039–3042.
https://doi.org/10.1039/D1CC07171H
N003. Y. Wu,*+ Z. Zhao,+ T. Chen, J. Tan, Z.-W. Qu,* S. Grimme, Y. Zhao, D. W. Stephan* The varied Frustrated Lewis Pair Reactivity of the Germylene Phosphaketene (CH{(CMe)(2,6-iPr2C6H3N)}2)GePCO, Chem. Eur. J., 2022, 28, e202200666
https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202200666
N002. Y. Zhao, D. Mandal, J. Guo,* Y. Wu, D. W. Stephan,* B(C6F5)3-Catalyzed site-selective N1-alkylation of benzotriazoles with diazoalkanes, Chem. Commun., 2021,57, 7758-7761
https://pubs.rsc.org/en/content/articlelanding/2021/cc/d1cc03048e
N001. X. Yang, R. Wei, Y. Shi, L. L. Liu, Y. Wu,* Y. Zhao, D. W. Stephan,* Oxyphosphoranes as precursors to bridging phosphate-catecholate ligands, Chem. Commun. 2021, 57, 1194-1197
https://pubs.rsc.org/en/content/articlelanding/2021/cc/d0cc07736d
Publications from Toronto Lab: https://sites.chem.utoronto.ca/chemistry/staff/DSTEPHAN/pubs.html