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成果及论文


2023年:

38. Yinggao Meng,‡ Manman Song,‡ Yue Wang, Yuxin Wang and Er-Qing Li* Palladium-catalyzed asymmetric (4 + 3) cycloaddition of N-2,2,2-trifluoroethylisatin ketimines: access to optically active spirooxindoles. Org. Chem. Front., 2023,10, 2648-2652

37. Li Jing, Zhong-Jun Li* and Er-Qing Li* Palladium-catalyzed (3 + 2) annulations of 1,3-bis-electrophilic motifs: straightforward synthesis of functionalized pyrrolidines. Org. Chem. Front., 2023,10, 2746-2751.


36. Qian Wang, Yinggao Meng,* Lulu Wu, Er-Qing Li* Recent advances in annulations enabled by nucleophilic Lewis base/metal dual catalysis. Chin. Chem. Lett. 2023, 34, 108544

2022年:

35. Yinggao Meng, Qian Wang, Xinyu Yao, Donghui Wei, Ying-Guo Liu,* Er-Qing Li,* and Zheng Duan* Rigid P‑Chiral Phosphorus Ligands for Highly Selective PalladiumCatalyzed (4+2) and (4+4) Annulations. Org. Lett. 2022, 24, 9205−9209.

34. Yue Wang, Er-Qing Li,* and Zheng Duan* Ligand-Dependent, Palladium-Catalyzed Stereodivergent Synthesis of Chiral Tetrahydroquinolines. Chem. Sci.2022,138131-8136

33.  Zhipeng Zhang, Li Jing, Er-Qing Li,* Zheng Duan*  Cooperative Palladium-Catalyzed and P(NEt2)3-Mediated (4+1) Annulation of Isatins with 2-Hydroxymethylallylcarbonates.  

Org. Chem. Front., 20229, 3215-3221


  



32. Ke Li, Zhipeng Zhang, Jiahui Zhu,  Yuxin Wang,  Jing Zhao,  Er-Qing Li* and Zheng Duan* Diastereodivergent Synthesis of Fully Disubstituted Spiro[indoline-3,2'-pyrrolidin]-2-ones via Tuneable Lewis base/Brønsted base-promoted (3+2) Cycloadditions. Org. Chem. Front. 2022 9, 19 - 24.  https://pubs.rsc.org/en/content/articlelanding/2021/qo/d1qo01124c († These authors contributed equally to this work)


2021年:

31. Siming Jia, Mengmeng Ma, Er-Qing Li,*Zheng Duan,* and Françis Mathey  Design of 1‑Phosphanorbornene Derivatives as Chiral Organocatalysts for Enantioselective (4 + 2) Annulation Reactions of γ‑Benzyl Allenoates. Org. Lett. 2021,  23, 3337-3342.  https://pubs.acs.org/doi/10.1021/acs.orglett.1c00833


30.  Yue Wang,   Manman Song,   Er-Qing Li  and  Zheng Duan  Auto-Tandem Palladium/Phosphine Cooperative Catalysis: Synthesis of Bicyclo[3.1.0]hexenes by Selective Activation of Morita–Baylis–Hillman Carbonates. Org. Chem. Front.,  20218, 3366-3371https://pubs.rsc.org/en/content/articlelanding/2021/qo/d1qo00330e#!divAbstract


29. Ke Li, Zhenjie Gan, Er-Qing Li,*and Zheng Duan*  Phosphine-Catalyzed (4 + 2) Cycloaddition of Conjugated Dienes with Enones and Its Asymmetric Variant. Org. Lett. 2021,  23(8), 3094-3099.1c00780.https://pubs.acs.org/doi/10.1021/acs.orglett.1c00780



28.  Zhenjie Gan,* Ke Li, Hui Zhang, Er-Qing Li*  Copper/GanPhos-Catalyzed 1,3-Dipolar Cycloaddition of Azo­methine Ylides: An Efficient Access to Chiral Pyrrolidine Spirocycles.   Synthesis  202153(07): 1331-1340  https://www.thieme-connect.com/products/ejournals/abstract/10.1055/s-0040-1706599





2020年:



27. Wei Hu, Er-Qing Li, Zheng Duan* and Francois Mathey, Concise synthesis of phospholene and its P-stereogenic derivatives. J. Org. Chem. 2020, 85, 14772–14778https://pubs.acs.org/doi/10.1021/acs.joc.0c00545


26. Hao Cui, Ke LI, Yue Wang, Manman Song, Congcong Wang, Donghui Wei,* Er-Qing Li,* Zheng Duan* and Francois Mathey, Copper(I)/Ganphos Catalysis: Enantioselective Synthesis of Diversified Spirooxindoles Using Alkyl Substituted Imino Ester and Methyleneindolinones. Org. Biomol. Chem., 2020, 18, 3740-3746https://pubs.rsc.org/en/content/articlelanding/2020/ob/d0ob00546k#!divAbstract


25.  Ruiping Han, Yue Ding, Xueke Jin and Er-Qing Li,* Silver/palladium relay catalyzed 1,3-dipole annulation/allylation reactions to access fully substitutedallyl imidazolidines.  Org. Biomol. 

Chem.  2020, 1818, 646-649 https://pubs.rsc.org/en/content/articlelanding/2020/ob/c9ob02633a#!divAbstract



2019年:

         



23.  Zhenjie Gan, Yanchuan Gong, Yunpeng Chu, Er-Qing Li,* You Huang* and Zheng Duan* Phosphine-catalyzed regiodivergent annulations of γ-substituted allenoates with conjugated dienes. Chem. Commun.201955, 10120 - 10123.   https://pubs.rsc.org/en/content/articlelanding/2019/CC/C9CC05207K#!divAbstract 



22.  马蓉,  宋格格, 奚秋贞, 杨柳, 李二庆*, 段征有机磷催化γ-甲基联烯酸酯[3 + 2]环化反应 有机化学2019 2019, 39 (8), pp 2196-2202http://sioc-journal.cn/Jwk_yjhx/CN/10.6023/cjoc201901040


21.  Mengna Zhi, Zhenjie Gan, Rong Ma, Hao Cui, Er-Qing Li*, Zheng Duan*, François Mathey, Ag/P Stereogenic Phosphine Catalyzed Enantioselective 1, 3-Dipolar Cycloadditions: A Method to Optically Active Pyrrolidines. Org. Lett.201921, 3210–3213. https://pubs.acs.org/doi/10.1021/acs.orglett.9b00926


20.  Zhenjie Gan,Mengna Zhi, Ruiping Han,Er-Qing Li,Zheng Duan,* François Mathey P-Stereogenic Phosphines Directed Copper (I)-Catalyzed Enantioselec-tive 1, 3-Dipolar Cycloadditions. Org. Lett.201921, 2782–2785. https://pubs.acs.org/doi/10.1021/acs.orglett.9b00734


19.  Yan-Chuan Gong,Yue Wang, Er-Qing Li,* Hao Cui, Zheng DuanEnantio- and Diastereoselective Synthesis of β Aryl-β pyrazolyl α-Amino Acid Esters via Copper-Catalyzed Reaction of Azomethine Ylides with Benzylidenepyrazolones. Adv. Synth. Catal. 2019, 361 , 1389-1393. https://onlinelibrary.wiley.com/doi/full/10.1002/adsc.201801137


2018年:

18.    Qiu-Zhen Xi, Zhen-Jie Gan, Er-Qing Li,* Zheng Duan*  Brønsted Acid Tuned, Lewis Base Promoted [4 + 2] Annulation Reactions of Allenoates with Electron-deficient Olefins.  Eur. J. Org. Chem. 2018, 4917-4925. https://onlinelibrary.wiley.com/doi/full/10.1002/ejoc.201800917


17. Phosphine‐Catalyzed [3 + 2] Annulation of  γ‐Substituted Allenoates: Novel Access to Functionalized Cyclopentenes and Bicyclic[3, 3, 0]octene Derivatives. Li Erqing, Jin Hongxing and Huang You * ChemistrySelect 20183, 12007-12010. 

Before ZZU

16. Bifunctional-Phosphine-Catalyzed Sequential Annulations of Allenoates and Ketimines: Construction of Functionalized Poly-heterocycle Rings. Li Erqing, Jin Hongxing, Jia Penghao, Dong Xuelin, and Huang You * Angew. Chem. Int. Ed. 2016, 55, 11591 –11594.  

15. Divergent Phosphine Catalyzed [2 + 4] or [3 + 2] Cycloaddition Reactions of γ- Substituted Allenoates with Oxo-dienes. Li Erqing, Chang Meijia, Liang Ling and Huang You * Eur. J. Org. Chem. 2015, 710-714.  

14. Phosphine-catalyzed Domino Reaction: A Novel Sequential [2+3] and [3+2] Annulation Reaction of γ-Substituent Allenoates to Construct Bicyclic[3, 3, 0]octene Derivatives.  Li, Erqing; Huang, You* Chem. Commun., 2014, 50, 948-950

13. Phosphine-Catalyzed Domino Reaction: A Novel Method Access to Functionalized Bicyclic Skeletons Li, Erqing; Huang, You* Chem. Eur. J., 2014, 20, 3520

12. Phosphine-Catalyzed Sequential [2 +3] and [3 + 2] Annulation Domino Reaction of γ- Benzyl Substituted Allenoates with α,β-Unsaturated Ketimines To Construct Aza-bicyclo[3, 3, 0]octane Derivatives. Li, Erqing; Jia, Penghao; Liang, Ling; Huang, You* ACS Catal. 2014, 4, 600-603.
11. Phosphine-Catalyzed [4+2] Annulation of gamma-Substituent Allenoates: Facile Access to Functionalized Spirocyclic Skeletons. Li, Erqing; Huang, You*; Liang, Ling; Xie Peizhong. Org. Lett. 2013, 15, 3138-3141

10. Tuning Catalysts to Tune the Products: Phosphine-Catalyzed Aza-Michael Addition Reaction of Hydrazones with Allenoates.  Li, Erqing; Xie, Peizhong; Yang, Lihua, Liang Ling, Huang You*. Chem. Asian J. 2013, 8, 603-610

合作发表论文:

9. Wei Hu, Er-Qing Li, Zheng Duan* and Francois Mathey, Concise synthesis of phospholene and its P-stereogenic derivatives. J. Org. Chem. 202085, 14772–14778.

8. Jin Hongxing, Li Erqing, Huang You*  Divergent synthesis of hydropyridine derivatives via nitrogen-containing Lewis base mediated regioselective [4+2] cyclizations Org. Chem. Front. 20174, 2216-2220. 

7. Jin Hongxing, Zhang Qinglong, Li Erqing, Jia, Penghao, Li Ning, Huang You* Phosphine-catalyzed intramolecular Rauhut-Currier reaction: enantioselective synthesis of hydro-2H-indole derivatives  Org. Biomol. Chem.201715, 7097-7101.

6.  Liang Ling, Li Erqing, Dong Xuelin, and Huang You*  DABCO-Mediated [4 + 4]-Domino Annulation: Access to Functionalized Eight-Membered Cyclic Ethers.Org. Lett. 2015, 17, 4914-4917.

5. Dong Xuelin, Liang Ling, Li Erqing, and Huang You * Highly Enantioselective Intermolecular Cross Rauhut–Currier Reaction Catalyzed by a Multifunctional Lewis Base Catalyst.  Angew. Chem. Int. Ed201554, 1621-1624.

4. Liang, Ling; Li, Erqing; Xie, Peizhong; Huang You*, Phosphine Initiated Domino Reaction: A Convenient Method for the Preparation of Spiro-cyclopentanones.   Chem. Asian J. 2014, 9, 1270-1273.

3. Xie, Peizhong; Li, Erqing; Zheng, Jie; Li, Xin; Huang, You*; Chen, Ruyu, Tunable Phosphine-Mediated Domino Reaction: Selective Synthesis of 2,3-Dihydrofurans and Biaryls.  Adv. Synth. Catal2013355, 161 – 169.

2.  Yang, Lihua; Xie, Peizhong; Li, Erqing; Li, Xin; Huang, You*; Chen, Ruyu Phosphine-catalyzed Domino Reaction: an Efficient Method for the Synthesis of Highly Functionalized Spirooxazolines. Org. Biomol. Chem201210, 7628-7634.

1. Xie, Peizhong; Wang, Liye; Yang, Lihua; Li, Erqing; Ma, Jianze; Huang, You*; Chen, Ruyu. Domino Reaction for the Chemo- and Stereoselective Synthesis of Trans-2,3-Dihydrobenzofurans from N-Thiophosphinyl Iimines and Sulfur Ylides.  J. Org. Chem. 2011, 76, 7699-7705