研究成果
方向一、具有圆偏振发光性质的发光纳米超螺旋纤维的构筑
通过氨基酸、胆固醇等手性取代基诱导AIE分子骨架产生螺旋构象进而形成超分子螺旋纤维。所制备的纳米/微米螺旋纤维具有圆二色性、圆偏振发光特性，是重要的发光微纳器件材料。
代表性工作 基于AIE小分子的发光纳米螺旋纤维的构筑
https://pubs.acs.org/doi/10.1021/acsnano.0c09802
https://pubs.acs.org/doi/10.1021/acsnano.9b00218（高被引论文）
https://pubs.acs.org/doi/10.1021/acs.macromol.0c01140
https://onlinelibrary.wiley.com/doi/10.1002/asia.201801469
https://onlinelibrary.wiley.com/doi/10.1002/smll.201601542
方向二、超分子组装的表/界面组装和手性放大规律的研究
超分子结构的形成不仅决定于分子的化学结构， 而且受环境因素， 如溶剂、表面界面的影响。揭示分子化学结构与外部因素对分子组装的协同作用, 对于设计具有特定结构的功能材料具有重要意义。
https://onlinelibrary.wiley.com/doi/10.1002/smll.201601542
https://pubs.acs.org/doi/10.1021/acs.langmuir.8b03358
https://pubs.acs.org/doi/10.1021/acs.jpcc.9b02205
方向三：多重刺激响应AIE材料的设计合成
设计基于AIE骨架的气体、pH响应、力致变色材料， 代表性研究工作发表在化学、材料学著名杂志Angew Angewandte Chemie International Edition（高被引论文）,Adv. Funct. Mater等。
https://onlinelibrary.wiley.com/doi/10.1002/anie.201910530
https://onlinelibrary.wiley.com/doi/10.1002/adfm.201900516
https://pubs.rsc.org/en/content/articlelanding/2021/mh/d1mh009
方向四：金属团簇的制备及在化学生物传感方面的应用
设计基于金、铜的金属发光团簇，用于生物分子、手性分子检测的传感器制备
基于纤维纳米晶为手性模板的复合圆偏振发光材料的制备
https://pubs.acs.org/doi/10.1021/acsami.0c10069
论文与专著章节
50. Zhang H., Chang X., C. Ma, G. Huang*, B. S. Li*, B. Z. Tang*Two Cholesterol-Containing Pyrene Derivatives: Subtle Spacer Difference, Diverse Stimuli-Responsive Luminescence, Chirality and Self-Assembly Behavior, 2022, ACS Appl. Mater. Inter. Accepted
49. Jiang, Y.; Shi, Y.; Hu, D.; Peng, Q.; * Huang, G.;* , Li, B. S.* Insight into Isomeric Effect on the Photoluminescence and Mechanoluminescence of Cyanostilbene Derivatives 2022, J Phys. Chem. L Accepted
48. Xia, Q.; Xie, W.; He, T.; Zhan, H.; Zhao, Z.; Huang, G.*; Li, B. S.*, Tang B. Z. A Versatile Tetraphenylethene Derivative Bearing Ex-De Emission, Multi-state Mechanochromism, Reversible Photochromism, CPL and its Applications in Multimodal Anti-counterfeiting,2022, CCS Chemistry ,Accepted
47. Zhang, H.;Ma, H.; Huang, W.; Gong, W.; He, Z.; Huang, G.; * Li, B. S.;* Tang，B. Z. * Controllable room temperature phosphorescence, mechanoluminescence and polymorphism of a carbazole derivative，Mater. Hor.，2022, 8，2816-2822
46. Xie, W.; Chang, X. ; Chen, L.; Liu, L.; Huang, G.* ; Li, B. S.* Construction of a multicolored emission tetraphenylethene derivative in response to multiple stimuli, Dyes& Pigments, 2021, 195, 109729
45. Zhang, H.; Ma, B.; Lin, F.; Yang, Z.; Huang, G.* ; Li, B. S.*; Tang, B. Z.* New shoots from old roots: multiple stimuli-responsive properties of a common tetraphenylethene derivative，Mater. Chem. Front. 2022, 6 (2) , 176-181
44. Xia, Q.; Meng, L. M.; He, T. C.; Huang, G.*; Li, B. S.*; Tang, B. Z.* Direct Visualization of Chiral Amplification of Chiral AIE Molecules in Nematic Liquid Crystals, from Molecular Scale to the Bulk. ACS nano. 2021, 15, 4956-4966.
43. Zhang, H.; Li, W. L.; Huang, Q. Y.; Huang, G.*; Chi, Z. G.; Li, B. S.* A multi-stimuli responsive tetraphenylethene derivative: Self-reversible mechanochromism, mechanoluminescence, switchable photochromism. Dyes& Pigments. 2021, 187, 109128
42. Halawa, M. I.; Mostafa, M.; Wu, G. X.; Li, B. S.* Amplified anodic electrogenerated chemiluminescence of tris(2,2′-bipyridyl)ruthenium(II) for ultrasensitive detection of bambuterol: Application to content uniformity testing. J. Electroanal. Chem. 2021, 880, 114881.
41. Jiang, Y.; Chang, X.; Xie, W.; Huang, G.; * Li, B. S.* Cyano-Containing Tetraphenylethene Isomers: Similar Bright Mechanoluminescence, but Diverse Recoverable Processes. Mater. Chem. Front 2021, 5, 885-892.
40. Halawa, M. I.; Wu, G. X.; Li, B. S.* Development of luminol-based chemiluminescence approach for ultrasensitive sensing of Hg(II) using povidone-I2 protected gold nanoparticles as an efficient coreactant. Anal Bioanal Chem 413, 649–659 (2021).
39. Zhang, H.; Zhang, H.; Huang, G.;* Li, B. S.* Two Tetraphenylethene-Pyrene Isomers: Distinct Fluorescence and Mechanochromic Properties. Dyes & Pigments 2021, 185, 108947.
38. Liu, Q.; Xia, Q.; Xiong, Y.; Li, B. S.*; Tang, B. Z. * Circularly Polarized Luminescence and Tunable Helical Assemblies of Aggregation-Induced Emission Amphiphilic Polytriazole Carrying Chiral L-Phenylalanine Pendants. Macromolecules 2020, 53, 6288-6298.
37. Halawa, M. I.*; Li, B. S.*; Xu, G.* Novel Synthesis of Thiolated Gold Nanoclusters Induced by Lanthanides for Ultrasensitive and Luminescent Detection of the Potential Anthrax Spores’ Biomarker. ACS Appl. Mater. Inter. 2020, 12, 32888-32897.
36. Huang, G.; Chang, X.; Jiang Y.; Lin B.; Li. B. S.*; Tang, B. Z.* Multi-stimuli responsive cyanostilbene derivatives: pH, amine vapor sensing and mechanoluminescence Mater. Chem. Front., 2020,4, 1720-1728.
35. Halawa, M. I.; Mostafa, I. M.; Tolba, M. M.; El-Shabrawy, Y.; Li, B. S.* Development of Ru(Bpy)32+-Amisulpride Electrogenerated Chemiluminescence System for Ultrasensitive and Selective Detection of Amisulpride in Pharmaceuticals and Real Plasma. J. Electroanal. Chem. 2020, 864, 114059.
34. 夏庆，袁勤、Jason Ng, 唐本忠，李冰石*. 基于氨基酸取代的噻咯分子的超分子组装结构的构筑 功能高分子学报 2019, 32, 705
33. Huang, G. X.; Xia, Q.; Huang, W. B.; Tian, J. W.; He, Z. K.; Li, B. S.*, Tang, B. Z.* Multiple Anti-Counterfeiting Guarantees from a Simple Tetraphenylethylene Derivative - High-Contrasted and Multi-State Mechanochromism and Photochromism, Angew. Chem. Int. Ed. 2019, 58, 17978-17983. (高被引论文)
32. Huang, G. X.; Jiang, Y. Q.; Wang, J. G.; Li, Z.; Li, B. S.*, Tang, B. Z.* The influence of intermolecular interactions and molecular packings on mechanochromism and mechanoluminescence – a tetraphenylethylene derivative case, J. Mater. Chem. C, 2019,7, 12709-12716.
31. Jiang, Y.; Wang, J; Huang, G.；* Li Z.；Li B. S.*, Tang, B. Z.* Insight from the old: mechanochromism and mechanoluminescence of two amine-containing tetraphenylethylene isomers, J. Mater. Chem. C. 2019, 7, 11790.
30. Chen, Y. T.; Xue, S.; Xia, Q.; Li, H. K.; Liu, Q. M.; Li, B. S.*,Tang, B. Z.* Surface Effect on The Self-Assembly of Nanofibers Revealed by in Situ AFM Imaging and Molecular Simulation J. Phys. Chem. C 2019, 123, 9292-9297.
29. Zhang, J.; Liu, Q.; Wu, W.; Peng, J.; Zhang, H.; Song, F.; He, B.; Wang, X.; Sung, H. H. Y.; Chen, M.; Li, B. S.*; Liu, S. H.; Lam, J. W. Y.; Tang, B. Z.* Real-Time Monitoring of Hierarchical Self-Assembly and Induction of Circularly Polarized Luminescence from Achiral Luminogens. ACS Nano 2019, 13, 3618-3628. (高被引论文)
28. Huang, G.; Jiang, Y.; Yang, S.; Li, B. S.*; Tang, B. Z. * Multistimuli Response and Polymorphism of a Novel Tetraphenylethylene Derivative. Adv. Funct. Mater. 2019, 29, 1900516.
27. Li, B. S.*; Huang, X. J.; Li, H. K.*; Xia, W. J.; Xue, S.; Xia, Q.; Tang, B. Z.*; Solvent and Surface/Interface Effect on the Hierarchical Assemblies of Chiral Aggregation-Induced Emitting Molecules, Langmuir 2019, 35, 3805−3813.
26. Li, H.; Li, B. S.*; Tang, B. Z.* Molecular Design, Circularly Polarized Luminescence, and Helical Self-Assembly of Chiral Aggregation-Induced Emission Molecules. Chemistry – An Asian Journal 2019, 14, 674-688.
25. Huang, G.; Wen, R.; Wang, Z.; Li, B. S.*; Tang B. Z.* Novel chiral aggregation induced emission molecules: self-assembly, circularly polarized luminescence and copper(II) ion detection Mater. Chem. Front. 2018, 2, 1884.
24. Liu, Q.; Xia, Q.; Wang, S.; Li, B. S.*; Tang B. Z.* In situ visualizable self‐assembly, aggregation induced emission and circularly polarized luminescence of tetraphenylethene and alanine based chiral polytriazole J. Mater. Chem. C. 2018, 6, 4807
23. Xue, S.; Meng, L.; Wen, R.; Shi, L.; Lam, J. W.; Tang, Z.; Li, B. S.*; Tang, B.Z. *Unexpected aggregation induecd circular dichoism, circular polarized luminescence and helical assembly from achiral hexaphenylsilole(HPS), RSC Advances, 2017, 7, 24841
22. Li, H.；Li, B. S.*; Tang, B. Z. * Helicity, assembly, and circularly polarized luminescence of chiralAIEgens Proc. of SPIE，invited keynote paper, 2016，Vol. 9940 99400A-1-99400A-8.
21. Li, H., Xue, S.；H. Su B. Shen, Z. Cheng. J. W. Y. Lam, Kam Sing Wong, H. Wu, Li, B. S.*, Tang B. Z.*, Nanofibers: Click Synthesis, Aggregation-Induced Emission and Chirality, Circularly Polarized Luminescence, and Helical Self-Assembly of a Leucine-Containing Silole (封面论文) Small, 2016,12,6593-6601
20. Li, B. S.*; Wen R.; Xue S.; Shi L.; Tang, Z. Y.; Wang, Z, M.b; Tang, B. Z.* Fabrication of circular polarized luminescent helical fibers from chiral phennanthro[9,10]imidazole derivatives, Mater. Chem. Front, 2017, 1, 646
19. Li,H.; Cheng,J.; Deng,H.; Zhao,E.; Shen,B.; J. W. Y. Lam,; Wong, C.; Wu,K. S.; Li, B. S.*; Tang, B. Z.*, Synthesis, optical properties, and helical self-assembly of a bivalinecontaining tetraphenylethene Sci. Rep. 2016, 6, 19277.
18. Li,H.; Cheng, J.; Deng,H.; Zhao, E.; Shen, B.; J. W. Y. Lam,; Wong, C.; Wu, K. S.; Li, B. S.*; Tang, B. Z.*, Aggregation-induced chirality, circularly polarized luminescence, and helical self-assembly of aleucine-containing AIE luminogen J. Mater. Chem. C. 2015, 3, 2399 – 2404.
17. Li, H.; Cheng, J.; Zhao, Y.; Lam, J. W. Y.; Wong, K. S.; Wu, H.; Li, B. S.*; Tang, B. Z.* L-Valine methyl ester-containing tetraphenylethene: aggregation-induced light emission and circular dichroism, circularly polarised luminescence, and helical self-assembly Mater. Hori. 2014, 1, 518-521.
16. Ng, J. C. Y.; Li, H.; Yuan, Q.; Liu, J.; Liu, C.; Fan, X.; Li, B. S.* and Tang, B. Z.* Valine containing silole, synthesis, aggregation induced chirality, luminescence enhancement, chiral polarized luminescence and self-assembled structures J. Mater. Chem. C, 2014, 2, 4615 – 4621.
15. Li, B. S.*; Lam, J. W. Y.; Yu, Z. and Tang, B. Z.Tunable Helical Assemblies of L-Alanine Methyl Ester-Containing Polyphenylacetylene Langmuir, 2012, 28, 5770–5774.
14. Li, B. S.*; Wei, B.; M. C. Goh Direct visalization of the formation of RecA/dsDNA complexes at the single-molecule level Micron, 2012, 43, 1073-1075
13. Li, B. S.; Goh, C.*, Direct Evidence of the Role of AT
PγS in the Binding of Single-Stranded Binding Protein (Escherichia coli) and RecA to Single-Stranded DNA Langmuir, 2010, 26, 14755-14758
12. Li, B. S.; Goh, C.* Direct visualization of the formation and structure of RecA/dsDNA complexes Micron, 2010, 41, 227-231.
11. Cheuk, K. K. L.; Li, B. S.; Lam, J. W. Y.; etc. Synthesis, Chain Helicity, Assembling Structure, and Biological Compatibility of Poly(phenylacetylene)s Containing L-Alanine Moieties Macromolecules, 2008, 41, 5997–6005
10. Cheuk, K. K; Lam, J. W. Y; Li, B. S.; Xie, Y. and Tang, B. Z. Decorating Conjugated Polymer Chains with Naturally Occurring Molecules: Synthesis, Solvatochromism, Chain Helicity, and Biological Activity of Sugar-Containing Poly(phenylacetylene)s Macromolecules, 2007, 40(8), 2633-2642.
9. Goh, C.*; Li, B. S. Reply to Comment on “Direct and Real-Time Visualization of the Disassembly of a Single RecA-DNA-ATPçS Complex Using AFM Imaging in Fluid”, Nano Lett., 2007, 7, 1110-1111.
8. Li, B. S.; Sattin, B.; Goh, C. Direct and real-time visualization of the disassembly of a single RecA-DNA-ATP gamma S complex using AFM imaging in fluid, Nano Lett., 2006, 6, 1474-1478.
7. Li, C. J.; Guo, Y. G.; Li, B. S.; Wang, C. R.; Wan, L. J.; Bai, C. L. "Template Synthesis of Sc@C82 Nanowires and Nanotubes at Room Temperature" Adv. Mater. 2005, 17(1), 71-73
6. Li, B. S.; Kang, S. Z. etc. Self-assembling of polyacetylene bearing amino acid attachment on mica, in solution and on water surface Langmuir, 2004, 20, 7598-7603.
5. Li, B. S.; Chen, J.; Zhu, C. etc. Formation of vesicular fibers and porous film from chiral oligomers, Langmuir 2004, 24, 2515-2518.
4. Li, B. S.; Cheuk, K. K. L.; Yang, D.; Lam, J. W. Y.; Wan, L. J.; Bai, C.; Tang, B. Z. Self-Assembling of an Amphiphilic Polyacetylene Carrying L-Leucine Pendants: A Homopolymer Case. Macromolecules 2003, 36, 5447-5450.
3. Li, B. S.; Cheuk, K. K. L.; Ling, L.; Chen, J.; Xiao, X.; Bai, C.; Tang, B. Z. Synthesis and Hierarchical Structures of Amphiphilic Polyphenylacetylenes Carrying L-Valine Pendants. Macromolecules 2003, 36, 77-85.
2. Li, B. S.; Li, G. P.; Wang, C.; Wang, M.; Wang, D. C.; Bai, C. Structure-Governed Growth Phenomenon of a Trichosanthin Crystal. Langmuir 2002, 18, 6723-6726.
1. Li, B. S.; Cheuk, K. K. L.; Salhi, F.; Lam, J. W. Y.; Cha, J. A. K.; Xiao, X.; Bai, C.; Tang, B. Z. Tuning the Chain Helicity and Organizational Morphology of an L-Valine-Containing Polyacetylene by Ph Change. Nano Lett. 2001, 1, 323-328.
论著章节：
4. Li, B. S.; Cheuk, K.K.L.; Chen, J.; Xiao, X.; Bai, C.; Tang, B. Z. “Vesicular and Tubular Nanoassemblies of an Helical Amphiphilic Polyacetylene” In Nano Science and Technology–Novel Structures and Phenomena; Tang, Z. K., Sheng, P., Eds.; Taylor & Francis: London, 2003; Chapter 9, pp 98–104.
3. Cheuk, K. K. L.; Li, B. S.; Tang, B. Z.“Polyacetylene Nanostructures” In Encyclopedia of Nanoscience and Nanotechnology; Nalwa, H. S., Ed.; American Scientific Publishers: CA, 2004; Vol. 8, pp 703–713 (invited review).
2. Cheuk,K. K. L.; Li, B. S.; Lam, J. W. Y.; Chen, J.; Bai, C.; Tang, B. Z. “Amphiphilic Conjugated Polymers with Tunable Chain Helicity and Organizational Morphology” In Advanced Nanomaterials and Nanodevices; Gao, H., Fuchs, H., Chen, D., Eds.; Institute of Physics Publishing Ltd: Philadelphia, PA, 2003; pp 87–107 (invited paper).
1. Tang, B. Z.; Cheuk, K. K. L.; Salhi, F.; Li, B. S.; Lam, J. W. Y.; Cha,J. A. K.; Xiao, X. D. In Synthetic Macromolecules with Higher Structure order, Khan, I.M., Ed.; American Chemistry Society: ACS Symposium Series 812, Washington, DC, 2001 chapter 10, pp 133-148.