1. Wan-Er Gan, Yong-Shun Wu, Bin Wu , Chun-Yuan Fang, Jian Cao,* Zheng Xu,* and Li-Wen Xu*, Copper-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Benzoxasiloles, Angew. Chem. Int. Ed. 2024, e202317973(1 of 7).

    https://onlinelibrary.wiley.com/doi/epdf/10.1002/anie.202317973

2. Fang-Ying Ling, Fei Ye, Xiao-Jun Fang, Xiao-Hua Zhou, Wei-Sheng Huang, Zheng Xu and Li-Wen Xu*, An unusual autocatalysis with an air-stable Pd complex to promote enantioselective synthesis of Si-stereogenic enynes, Chem. Sci. 2023, 14, 1123-1131. 

https://pubs.rsc.org/en/content/articlepdf/2023/sc/d2sc06181c

3. Li Li, Wei-Sheng Huang, Zheng Xu, Li-Wen Xu*, Catalytic asymmetric silicon-carbon bond-forming transformations based on Si–H functionalization, Sci China Chem. 2023, 66, 1654-1687. 

    https://link.springer.com/article/10.1007/s11426-022-1480-y

4. Han-Qi Zhou, Fang-Ying Ling, Xiao-Jun Fang, Hua-Jie Zhu, Li Li,*Fei Ye, Zheng Xu and Li-Wen Xu*, An unusual trans-hydrosilylation of prochiral 1,1-disubstituted cyclopropenes revealing the different nature of asymmetric palladium and rhodium catalysis, Org. Chem. Front. 2023, 10, 430–439.

    https://pubs.rsc.org/en/content/articlepdf/2023/qo/d2qo01688e

5. Xin-Long Yu, Jia-Wei Hu, Jian Cao * and Li-Wen Xu*, Metal-free photocatalyzed allylic silylation of allyl acetates and chlorides, Org. Chem. Front. 2023, 10, 4836-4842.

    https://pubs.rsc.org/en/content/articlepdf/2023/qo/d3qo01088k

6. Xiao-Hua Zhou, Jun-Hui Zhu, Guang-Ao Song, Xin-Li Jiang,  Xiao-Jun Fang,  Zheng Xu and Li-Wen Xu*, Palladium-catalyzed C(sp3 )–Si cross-coupling silylation of benzyl halides with hydrosilanes, Org. Chem. Front. 2023, 10, 5443-5450.

https://pubs.rsc.org/en/content/articlepdf/2023/qo/d3qo01277h

7. Wei-Ke Zhu, Hua-Jie Zhu, Xiao-Jun Fang, Fei Ye, Jian Cao, Zheng Xu, and Li-Wen Xu*, Rhodium-Catalyzed Hydrolytic Cleavage of the Silicon−Carbon Bond of Silacyclobutanes to Access Silanols, Org. Lett. 2023, 25, 7186−7191. 

https://pubs.acs.org/doi/epdf/10.1021/acs.orglett.3c02611

8.  Jun-Han Ma, Philippe Jubault, Samuel Couve-Bonnaire, Li-Wen Xu,* and Jean-Philippe Bouillon*, Solvent-Dependent Rhodium-Catalyzed Divergent Hydrofunctionalization of Triffuoromethylalkenes, Org. Lett. 2023, 25, 4928−4933. 

https://pubs.acs.org/doi/epdf/10.1021/acs.orglett.3c01754

9. Jian Cao*, Li-Wen Xu, Palladium- and nickel-catalyzed cascade enantioselective ring-opening/coupling reactions of cyclobutanones, Chem. Commun. 2023, 59, 3373–3382.

    https://pubs.rsc.org/en/content/articlepdf/2023/cc/d3cc00205e

10. Wei-Sheng Huang, Hao Xu, Hua Yang, Li-Wen Xu*, Catalytic Synthesis of Silanols by Hydroxylation of Hydrosilanes: From Chemoselectivity to Enantioselectivity, Chem. Eur. J. 2024, 30, e202302458(1-20).

    https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/chem.202302458

11. Wei-Sheng Huang, Fang-Ying Ling, Xiao-Jun Fang, Yu-Ming Cui, Fei Ye, Zheng Xu, Jian Cao, Hua Yang, Li-Wen Xu*, Synthesis of 2,3-Dihydrosiloles via Palladium-Catalyzed Heck-type Arylation of Silacyclopentenes with Aryl Iodides, Synthesis 2023, 55, 1577-1585.

12. Zhu, Weike, Li-Wen Xu*, Enantioselective Rhodium-Catalyzed Dual Ring Expansion of Spirosilabicyclobutane with Alkynes, Chin. J. Org. Chem. 2023, 43, 362-364.

13. Xing-Feng Bai, Yu-Ming Cui, Jian Cao, Li-Wen Xu*, Atropisomers with Axial and Point Chirality: Synthesis and Applications, Acc. Chem. Res. 2022, 55, 2545−2561.

     https://pubs.acs.org/doi/epdf/10.1021/acs.accounts.2c00417

14. Yan Zeng, Xiao-Jun Fang, Ren-He Tang, Jing-Yu Xie, Feng-Jiao Zhang , Zheng Xu*, Yi-Xue Nie, Li-Wen Xu*, Rhodium-Catalyzed Dynamic Kinetic Asymmetric Hydrosilylation to Access Silicon-Stereogenic Center, Angew. Chem.Int. Ed. 2022, 61, e202214147(1 - 6). 

      https://onlinelibrary.wiley.com/doi/epdf/10.1002/anie.202214147

15. Lu-Lu Han, Yu-Ming Cui,* Qin Yang, Li-Lei Fang, Li-Wen Xu*, Palladium-Catalyzed Transient Chirality Transfer and Atroposelective C-H Functionalization to Access Quaternary Stereocenters, Angew. Chem. Int. Ed. 2022, 61, e202211922 (1 of 5).

   https://onlinelibrary.wiley.com/doi/epdf/10.1002/anie.202211922

16. Hualan Wang, Xiaogang Zhang,*Yan Li,* and Li-Wen Xu*, Siloxane-based Organosilicon Materials in Electrochemical Energy Storage Devices, Angew. Chem.Int. Ed. 2022, 61, e202210851, 1-17.

     https://onlinelibrary.wiley.com/doi/epdf/10.1002/anie.202210851

17. Qing Wang, Kang-Bao Zhong, Hao Xu, Shi-Nan Li, Wei-Ke Zhu, Fei Ye, Zheng Xu, Yu Lan,*and Li-Wen Xu*, Enantioselective Nickel-Catalyzed Si−C(sp2) Bond Activation and igratory Insertion to Aldehydes: Reaction Scope and Mechanism, ACS Catal. 2022, 12, 4571−4580.

     https://pubs.acs.org/doi/epdf/10.1021/acscatal.2c00533

18. Lin-Xuan Fang, Yun-Gang Feng, Li Li, Guan-Wu Yin, Hualan Wang, Zheng Xu, Li-Wen Xu*, Cyclotriphophazene-Centered Six-Arm Eugenol-Linked Low-Dielectric Materials with High Thermostability and Transparency, ACS Sustainable Chem. Eng. 2022, 10, 13133–13144.

       https://pubs.acs.org/doi/epdf/10.1021/acssuschemeng.2c03951

19. Hao Xu, Xiao-Jun Fang, Wei-Sheng Huang, Zheng Xu, Li Li, Fei Ye, Jian Cao and Li-Wen Xu*, Catalytic regio- and stereoselective silicon–carbon bond formations on unsymmetric gemdifluorocyclopropenes by capture of silyl metal species, Org. Chem. Front, 2022, 9, 5272-5280.

    https://pubs.rsc.org/en/content/articlepdf/2022/qo/d2qo00943a

20.  Wan-Er Gan, Jian Cao * and Li-Wen Xu*，Palladium-catalyzed enantioselective domino ring-opening/Hiyama coupling of cyclobutanones: development and application to the synthesis of (+)-herbertene-1,14-diol, Org. Chem. Front. 2022, 9, 5798-5801. 

     https://pubs.rsc.org/en/content/articlepdf/2022/qo/d2qo01239a

21. Xiao-Hua Zhou, Xiao-Jun Fang, Fang-Ying Ling, Zheng Xu,* Li-Quan Hong*, Fei Ye and Li-Wen Xu*,  Catalytic C(sp)-Si cross-coupling silylation of alkynyl bromides with hydrosilanes by palladium catalysis, Org. Chem. Front. 2022, 9, 5891-5898. 

      https://pubs.rsc.org/en/content/articlepdf/2022/qo/d2qo01253g?page=search

22. Kun-Long Song, Bin Wu, Wan-Er Gan, Yan Zeng, Yu-Jie Zhang, Jian Cao *, Li-Wen Xu*, Stereo-divergent synthesis of silyl-enyne via palladium-catalyzed coupling of alkynes and iodosilanes, Org. Chem. Front. 2022, 9, 3718–3722. 

      https://pubs.rsc.org/en/content/articlepdf/2022/qo/d2qo00622g

23. Wei-Sheng Huang, Qing Wang, Hua Yang, Li-Wen Xu*, State-of-the-Art Advances in Enantioselective Transition-Metal-Mediated Reactions of Silacyclobutanes, Synthesis 2022, 54, 5400–5408.