成果及论文 - 郑州大学环境催化研究小组

代表性论文

(1) Nature Communications 2025, In press.

(2) Nature Communications 2025, 16, 5909.

(3) Nature Communications 2025, 16, 2094.

(4) Angewandte Chemie International Edition 2025, 64, e202418496.

(5) Angewandte Chemie International Edition 2023, 62, e202213124.

(6) Journal of the American Chemical Society 2021, 143, 6551-6559.

(7) Angewandte Chemie International Edition 2018, 57, 491-495.

(8) Advanced Science 2024, 11, 2405668.

(9) Environmental Science & Technology 2019, 53, 11023-11030.

获奖

(1) 湖北省科学技术奖——自然科学奖一等奖 2025年（4/5）

(2) 河南省教育厅优秀科技论文奖一等奖 2023年（1/2）

2025

57. Wenna Guo,# Yangyang Zhang,# Jiaqi Tian, Zhongyi Liu, Bin Liu, Jun Li*, Atomic-Scale Interface Engineering in Bi/Bi₂O₃ Heterojunctions for Selective CO₂ Photoreduction to Methanol. Nature Communications 2025, In press.

56. Guolin Qian, Jianxing Li, Haolong Tan, Liye Tang, Xinglin Yu, Wentao Li, Sihan Ma, Quan Xie*, Jun Li*, Deng Long*, In-situ fabrication of oxygen vacancy rich S-scheme Bi2MoO6/MoSxSey heterojunction for efficient CO2 photoreduction with low-concentration. Applied Catalysis B: Environment and Energy 2026, 383, 126017.

55. Fan Mo, Haibo Li*, Peng Zhang*, Jun Li*, Orchestrating Catalytic Hotspots and Macromolecular Architectures: Molecular Engineering toward Zero-Waste Polymer Circularity. Advanced Powder Materials 2026, 5, 100357.

54. Yangyang Zhang#, Zhengkun Xie#, Shixuan Ge, Peiyang Li, Xiaotian Wang*, Zaiwang Zhao, Zhongyi Liu, Bin Liu*, Jun Li*, In-situ reconstruction of Ni-modulated BiO2-x for boosting electrocatalytic nitrite reduction to ammonia. Nano Research 2025, https://doi.org/10.26599/NR.2025.94908176.

53. Hao Liu#, Bin Yang#,*, Guangfu Liao, Baoyu Huang, Jun Li*, Raul D. Rodriguezd, Xin Jia*, Facilitating carrier kinetic behaviors in ultrathin porous carbon nitride nanosheets through a shear-repair strategy for peroxymonosulfate-assisted solar water purification. Nature Communications 2025, 16, 5909.

52. Kai Wang,* Yanjun Hu, Xiufan Liu, Jun Li,* Bin Liu,* Visible-Light-Driven CO2 Photoreduction over Atomically Strained Indium Sites in Ambient Air. Nature Communications 2025, 16, 2094.

51. Jiaqi Tian,# Yangyang Zhang,# Zuhao Shi,# Zhongyi Liu, Zaiwang Zhao, Jun Li,* Neng Li,* and Hongwei Huang,* Enabling Interfacial Lattice Matching by Selective Epitaxial Growth of CuS Crystals on Bi2WO6 Nanosheets for Efficient CO2 Photoreduction into Solar Fuels. Angewandte Chemie International Edition 2025, 64, e202418496. (Selected as a Hot paper)

50. Kai Wang,* Chuang Liu, Jingping Li, Qiang Cheng, Bin Liu, Jun Li,* Near-infrared-responsive sea-urchin-like Ag6Si2O7/Bi19Br3S27 S-scheme heterojunction for efficient CO2 photoreduction. Applied Catalysis B: Environment and Energy 2025, 361, 124560.

49. Ming Meng,*^,# Xi Wu,# Qingqing Chai,# Hucheng Zhou, Nan Qin, Honglei Yuan, Jin Liu,* Jun Li,* Enhanced interface coupling accelerates charge transfer of a MoO2-x/Bi2MoO6 Schottky junction for CO2 photoreduction to CH4. Rare Metals 2025, https://doi.org/10.1007/s12598-025-03629-9.

48. Chun Xiao, Zhuangzhuang Wang, Mingyu Zhang, Min Dai, Jiangfei Cao, Chunsheng Xie*, Jun Li*, 0-dimentionnal/1-dimentional S-scheme Ag2S/BiSI hetero-structured photocatalyst for superb Cr(VI) reduction under full spectrum irradiation. Journal of Colloid and Interface Science 2025, 682, 619-628.

47. Yi-ling Yang#, Cheng-yang Wang#,*, Nian-bo Wang, Hui-hui Gan*, Shu-fang Zhao, Jun Li,* Yan Zhang,* Ohmic-junction of Ag cluster decorated BiO_2-x with strong built-in electric field enables efficient photocatalytic sterilization: DFT and mechanism insights. Rare Metals 2025, https://doi.org/10.1007/s12598-025-03405-9.

2024年

46. Jun Li, Xinglong Liu, Xi Wu, Zhongyi Liu,* Zaiwang Zhao, Yifeng Liu, Shixue Dou, and Yao Xiao*, Selective CO2 Photoreduction into CH4 Triggered by the Synergy between Oxygen Vacancy and Ru Substitution under Near-Infrared Light Irradiation. Advanced Science 2024, 11, 2405668.

45. Jun Li,# Qingqing Chai,# Ranran Niu,# Wenfeng Pan, Zhiquan Chen, Liang Wang, Kai Wang,* Zhongyi Liu, Yifeng Liu, Yao Xiao,* Shixue Dou, and Bin Liu,* Identification of Intrinsic Vacancies and Polarization Effect on Ternary Halo-Sulfur-Bismuth Compounds for Efficient CO2 Photoreduction under Near-Infrared Light Irradiation. Carbon Energy 2024, 6, e598.

44. Baojing Huang,# Xinxin Fu,# Kai Wang,* Liang Wang, Hualei Zhang,* Zhongyi Liu, Bin Liu, Jun Li,* Chemically bonded BiVO₄/Bi₁₉Cl₃S₂₇ heterojunction with fast hole extraction dynamics for continuous CO₂ photoreduction. Advanced Powder Materials 2024, 3, 100140.

43. Jiaqi Tian,# Jianpeng Li,# Yadan Guo,* Zhongyi Liu, Bin Liu,* and Jun Li,* Oxygen vacancy mediated bismuth-based photocatalysts. Advanced Powder Materials 2024, 3, 100201.

42. Xiaoke Zhang,# Yangyang Zhang,# Jiaqi Tian, Yadan Guo, Zhongkui Zhou, Zhongyi Liu,* Zaiwang Zhao, Bin Liu, Jun Li,* Generating ¹O₂ and cobalt (IV)=O through efficient peroxymonosulfate activation by ZnCo₂O₄ nanosheets for pollutant control. Nano Research 2024, 17, 9, 8025-8035.

41. Feng Yue, Mengke Shi, Cong Li, Yang Meng, Shuo Zhang, Lan Wang, Yali Song, Jun Li*, Hongzhong Zhang*, S-scheme heterojunction Cu-porphyrin/TiO2 nanosheets with highly efficient photocatalytic reduction of CO2 in ambient air. Journal of Colloid and Interface Science 2024, 665, 1079-1090.

40. Feng Yue, Zhaoya Fan, Cong Li, Yang Meng, Shuo Zhang, Mengke Shi, Minghua Wang, Mario Berrettoni, Jun Li*, Hongzhong Zhang*, Electro-assisted photocatalytic reduction of CO2 in ambient air using Ag/TNTAs at the gas-solid interface. Materials Reports: Energy 2024, 4, 100269.

2023年

39. Xiangguang Kong, Jiajie Fan, Bingwei Feng, Jun Li*, Guidong Yang, Chao Xue*, Carbon dots-triggered the fabrication of miniature g-C₃N₄/CDs/WO₃ S-scheme heterojunction for efficient CO₂ photoreduction. Chemical Engineering Journal 2023, 476, 146774.

38. Xi Wu^#, Wenlei Zhang^#, Jun Li*, Quanjun Xiang*, Zhongyi Liu and Bin Liu*, Identification of the Active Sites on Metallic MoO2−x Nano‐Sea‐Urchin for Atmospheric CO2 Photoreduction Under UV, Visible, and Near‐Infrared Light Illumination. Angewandte Chemie International Edition 2023, 62, e202213124.

37. Kai Wang, Haotian Qin, Jun Li*, Qiang Cheng, Yanfang Zhu, Haiyan Hu, Jian Peng, Shuangqiang Chen*, Guohong Wang, Shulei Chou, Shixue Dou, Yao Xiao*. Metallic AgInS₂ nanocrystals with sulfur vacancies boost atmospheric CO₂ photoreduction under near-infrared light illumination. Applied Catalysis B: Environmental 2023, 332, 122763. (ESI高被引论文)

36. Xiaoke Zhang, Jin Liu*, Hongzhong Zhang, Zhen Wan, Jun Li*, Uncovering the pathway of peroxymonosulfate activation over Co_0.5Zn_0.5O nanosheets for singlet oxygen generation: Performance and membrane application. Applied Catalysis B: Environmental 2023, 327, 122429. (ESI高被引论文)

35. Ming Meng*, Liwei Wang, Chunyang Li, Kun Xu, Yuanyuan Chen, Jitao Li, Zhixing Gan, Honglei Yuan, Lizhe Liu*, Jun Li*, Boosting Charge Separation on Epitaxial In₂O₃ Octahedron-nanowire Crystal Facet-based Homojunctions for Robust Photoelectrochemical Water Splitting. Applied Catalysis B: Environmental 2023, 321, 122071.

34. Xiaoke Zhang^#, Jianhui Liu^#, Xiucheng Zheng*, Rong Chen, Meng Zhang*, Zhongyi Liu, Zhiyuan Wang, Jun Li*, Activation of oxalic acid via dual-pathway over single-atom Fe catalysts: mechanism and membrane application. Applied Catalysis B: Environmental 2023, 321, 122068.

33. Jianfeng Bao, Jun Li*, and Yiling Yang*, Surface Chemistry Mediated Near-Infrared Light Direct Driven Photocatalysis toward Solar Energy Conversion: Classification and Application in Energy, Environmental and Biological Fields. Solar RRL 2023, 2300588.

32. Xinquan Zhou, Luyun Zhang, Hui Wang, Weiwei Lu, Ruichang Zhang, Hanxiang Li, Jun Li*, Xuefeng Wei*, The regulation of generation rate facilitates the win-win of ROS yield and utilization efficiency in heterogeneous persulfate catalytic oxidation system. Separation and Purification Technology 2023, 323, 124389.

31. Hongzhong Zhang*, Zhaoya Fan, Qingqing Chai, Jun Li*, Facile Synthesis of a Bi₂WO₆/BiO_2-x Heterojunction for Efficient Photocatalytic Degradation of Ciprofloxacin under Visible Light Irradiation. Catalysts 2023, 13(3), 469.

2022年

30. Ranran Niu^#, Qiaoyun Liu^#, Baojing Huang, Zhongyi Liu, Wenfen Zhang, Zhikun Peng*, Zhiyuan Wang, Yongpeng Yang*, Zhenkun Gu, Jun Li*, Black phosphorus/Bi₁₉Br₃S₂₇ van der Waals heterojunctions ensure the supply of activated hydrogen for effective CO₂ photoreduction. Applied Catalysis B: Environmental 2022, 317,15, 121727.

29. Haiyang Wang^#, Ranran Niu^#, Jianhui Liu, Sheng Guo*, Yongpeng Yang, Zhongyi Liu, and Jun Li*, Electrostatic self-assembly of 2D/2D CoWO₄/g-C₃N₄ p-n heterojunction for improved photocatalytic hydrogen evolution: Built-in electric field modulated charge separation and mechanism unveiling. Nano Research 2022, 15, 6987-6998. (封面论文)(ESI高被引论文)

28. Jin Liu*, Juan Wu, Nannan Wang, Fengshou Tian, Jun Li*, Surface reconstruction of BiSI nanorods for superb photocatalytic Cr(VI) reduction under near-infrared light irradiation. Chemical Engineering Journal 2022, 435, 135152.

27. Yadan Guo, Shuaihang Li, Fan Yang, Chenxi Li, Yaoping Guo, Keng Xuan, Guanghui Wang, Yunhai Liu*, Jun Li*, Efficient charge separation in sulfur doped AgFeO₂ photocatalyst for enhanced photocatalytic U(VI) reduction: The role of doping and mechanism insights. Journal of Hazardous Materials 2022, 440, 129734.

26. Jianhui Liu^#, Qiaoyun Liu^#, Jun Li*, Xiucheng Zheng*, Zhongyi Liu, Xinxin Guan*, Photochemical conversion of oxalic acid on heterojunction engineered FeWO₄/g-C₃N₄ photocatalyst for high-efficient synchronous removal of organic and heavy metal pollutants. Journal of Cleaner Production 2022, 363, 132527.

25. Yanan Tian^#, Jun Li^#, Han Zhen, Xinxin Guan*, Xiaoli Zhang, Xiucheng Zheng*, Synthesis and enhanced photocatalytic performance of Ni²⁺-doped Bi₄O₇ nanorods with broad-spectrum photoresponse. Separation and Purification Technology 2022, 300, 121898.

24. Jin Liu*, Hongyu Chen, Chaosheng Zhu, Songfang Han, Jun Li*, Sijia She, Xiaoyong Wu*, Efficient simultaneous removal of tetracycline hydrochloride and Cr(VI) through photothermal-assisted photocatalytic-Fenton-like processes with CuO_x/γ-Al₂O₃. Journal of Colloid and Interface Science 2022, 622, 526-538.

23. Yanan Tian, Junyang Zhang, Wanyi Wang, Jianhui Liu, Xiucheng Zheng*, Jun Li*, Xinxin Guan*, Facile assembly and excellent elimination behavior of porous BiOBr-g-C₃N₄ heterojunctions for organic pollutants. Environmental Research 2022, 5, 112889. (ESI高被引论文)

22. Caiyan Gao, Keke Zhang, Lian Yi, Kai Wang, Xiaoyong Wu*, Jun Li*, Gaoke Zhang, Self-assembled ultrathin closely bonded 2D/2D heterojunction for enhanced visible-light-induced photocatalytic oxidation and reaction mechanism insights. Journal of Colloid and Interface Science 2022, 608, 2472-2481.

2021年

21. Jun Li^#, Wenfeng Pan^#, Qiaoyun Liu,* Zhiquan Chen, Zhijie Chen, Xuezhen Feng, and Hong Chen*. Interfacial Engineering of Bi₁₉Br₃S₂₇ Nanowires Promotes Metallic Photocatalytic CO₂ Reduction Activity under Near-Infrared Light Irradiation. Journal of the American Chemical Society 2021, 143, 17, 6551-6559. (封面论文)(ESI高被引论文)

20. Jun Li, Baojing Huang, Qiang Guo, Sheng Guo, Zhikun Peng*, Jin Liu, Qingyong Tian, Yongpeng Yang*, Qun Xu* , Zhongyi Liu, Bin Liu*, Van der Waals heteroiunction for selective visible-light-driven photocatalytic CO₂ reduction. Applied Catalysis B: Environmental 2021, 284, 119733. (ESI高被引论文)

19. Sheng Guo, Zhixiong Yang, Huali Zhang, Wei Yang, Jun Li*, Kun Zhou*. Enhanced photocatalytic degradation of organic contaminants over CaFe₂O₄under visible LED light irradiation mediated by peroxymonosulfate. Journal of Materials Science & Technology 2021, 62, 34-43. (ESI高被引论文)

18. Jin Liu*, Sheng Guo, Hongzhang Wu, Xinlei Zhang, Jun Li*, Kun Zhou*, Synergetic effects of Bi⁵⁺ and oxygen vacancies in Bismuth(V)-rich Bi₄O₇ nanosheets for enhanced near-infrared light driven photocatalysis. Journal of Materials Science & Technology 2021, 85, 1-10.

17. Sijia She, Xiaoyue Zhang, Xiaoyong Wu*, Jun Li*, Gaoke Zhang, The fabrication of two-dimensional g-C₃N₄/NaBiO₃·2H₂O heterojunction for improved photocatalytic CO₂ reduction: DFT study and mechanism unveiling. Journal of Colloid and Interface Science 2021, 604, 122-130.

16. Jianhui Liu, Xiangnan Wei, Wanqing Sun, Xinxin Guan*, Xiucheng Zheng, Jun Li*, Fabrication of S-scheme CdS-g-C₃N₄-graphene aerogel heterojunction for enhanced visible light driven. Environmental Research 2021, 197, 111136. (ESI高被引论文)

15. Sheng Guo*, Mengdie Liu, Liming You, Gang Cheng, Jun Li*, Kun Zhou*, Oxygen vacancy induced peroxymonosulfate activation by Mg-doped Fe₂O₃ composites for advanced oxidation of organic pollutants. Chemsphere 2021, 279, 130482.

14. Sheng Guo, Cong Li, Liming You, Wei Yang, Jun Li*, Kun Zhou*. Facile synthesis of AgFeO₂ decorated CaCO₃with enhanced catalytic activity in activation of peroxymonosulfate for efficient degradation of organic pollutants. Advanced Energy and Sustainability Research 2021, 2100038.

2020年

13. Ming Meng*, Lun Yang, Xinglong Wu*, Zhixing Gan, Wenya Pan, Kuili Liu, Chunyang Li, Nan Qin, Jun Li*, Boosted photoelectrochemical performance of In₂O₃ nanowires via modulating oxygen vacancies on crystal facets. Journal of Alloys and Compounds 2020, 584, 156311.

12. Jun-Yang Zhang, Shi-Hao Zhang, Jun Li*, Xiu-Cheng Zheng*, Xin-Xin Guan*, Constructing of 3D graphene aerogel-g-C₃N₄ metal-free heterojunctions with superior purification efficiency for organic dyes. Journal of Molecular Liquids 2020, 310, 113242.

11. Jin Liu, Xingcai Zhang, Qian Zhong, Jun Li*, Hongzhang Wu, Bo Zhang, Lin Jin*, Hua Bing Tao* and Bin Liu*. Electrostatic Self-Assembly of AgI/Bi₂Ga₄O₉ p-n Junction Photocatalyst for Boosting Superoxide Radical Generation. Journal of Materials Chemistry A 2020, 8, 4083-4090.

10. Caiyan Gao, Zhuoqian Li, Haiyang Wang, Yaqi Yang, Baojun Li, Zhikun Peng*, Jun Li*, Zhongyi Liu*. MoS₂ nanosheets coupling Ni2P hollow microspheres as an efficient electrocatalyst for hydrogen generation over a wide pH range mediated by 3D/2D interface. ChemElectroChem 2020, 7, 355.

9. J. H. Lin, Y. T. Yan, T. X. Xu, C. Q. Qu*, J. Li*, J. Cao, J. C. Feng, and J. L. Qi. S doped NiCo₂O₄ nanosheet arrays by Ar plasma: an efficient and bifunctional electrode for overall water splitting. Journal of Colloid and Interface Science 2020, 560, 34-39.

2019年之前

8. Jun Li, Xiaoyong Wu, Gaoke Zhang*, Zhen Wan, Hong Chen, Full spectrum light driven photocatalytic in-situ epitaxy of one-unit-cell Bi₂O₂CO₃ layers on Bi₂O₄ nanocrystals for highly efficient photocatalysis and mechanism unveiling. Applied Catalysis B: Environmental 2019, 243, 667-677. (ESI高被引论文)

7. Jun Li, Yuan Li, Gaoke Zhang*, Hongxia Huang, Xiaoyong Wu, One-dimensional/two-dimensional core-shell structured Bi₂O₄/BiO_2-x heterojunction for highly efficient broad spectrum light driven photocatalysis: Faster interfacial charge transfer and enhanced molecular oxygen activation mechanism. ACS Applied Materials & Interfaces 2019, 11, 7112-7122.

6. Jun Li^#, Chun Xiao^#, Kai Wang, Gaoke Zhang*, Enhanced generation of reactive oxygen species under visible light irradiation by adjusting the exposed facet of FeWO₄ nanosheets to activate oxalic acid for organic pollutant removal and Cr(VI) reduction. Environmental Science & Technology 2019, 53, 11023-11030. (ESI高被引论文)

5. Yuan Li^#, Jun Li^#, Gaoke Zhang*, Kai Wang, Xiaoyong Wu, Selectively photocatalytic oxidation of low concentration methane over graphitic carbon nitride decorated tungsten bronze cesium. ACS Sustainable Chemistry & Engineering 2019, 7, 4382-4389 .

4. Jun Li, Xiaoyong Wu, Wenfeng Pan, Gaoke Zhang,* and Hong Chen,* Vacancy-Rich Monolayer BiO_2-x as a Highly Efficient UV, Visible, and Near-Infrared Responsive Photocatalyst. Angewandte Chemie International Edition 2018, 57, 491-495. (ESI高被引论文、热点论文)

3. Jinlong Wang^#, Jun Li^#, Pengyi Zhang*, Gaoke Zhang*. Understanding the "Seesaw Effect" of interlayered K⁺ with different structure in manganese oxides for the enhanced formaldehyde oxidation. Applied Catalysis B: Environmental 2018, 224, 863-870.

2. Jun Li^#, Wenhui Zhao^#, Jia Wang, Shaoxian Song, Xiaoyong Wu, Gaoke Zhang*, Noble metal-free modified ultrathin carbon nitride with promoted molecular oxygen activation for photocatalytic formaldehyde oxidization and DFT study. Applied Surface Science 2018, 485, 59-69.

1. Jun Li, Jia Wang, Gaoke Zhang*, Yuan Li, Kai Wang. Enhanced molecular oxygen activation of Ni²⁺-doped BiO_2-x nanosheets under UV, visible and near-infrared irradiation: Mechanism and DFT study. Applied Catalysis B: Environmental 2018, 234, 167-177. (ESI高被引论文)