34）Tan, G.*; Ye, S*. Isolable Pseudo-monocoordinate Group 14 to 16 Compounds Supported by Hydrindacenyl Ligands.
Acc. Chem. Res. DOI: 10.1021/acs.accounts.5c00706
33）Jin, Y.‡; Wang, Z.‡; Wang, D.; He, Z.; Xu, L.*; Tan, G.* Stable Thio-, Seleno- and Telluro-Aminyl Radicals Derived from Triplet Nitrene.
Chin. J. Chem. 2026, 44, 343—348
32）Lin, X.#; Zhang, Y.#; Wang, Z.#; He, Z.; Xu, L.*; Tan, G*. Flash Communication: Isolable Stibinidene Chalcogenide Radical Anions.
Organometallics 2025, 44 (22), 2620-2624
31）Wang, Z.; Ding, C.; Chen, Y.; Huang, M.; Wang, D.; Xu, L.; Pan, S.*; Ye, S.*; Tan, G.*; An isolable germa-isonitrile featuring a terminal nitrogen-germanium triple bond.
Nat. Chem. 2025, DOI: 10.1038/s41557-025-01997-4.
Highlighted by Chemistryworld: Bottleable group 14 isonitrile a synthetic first; ScienMag: Isolable Germa-Isonitrile with N≡Ge Triple Bond.
30) Wang, X.; Chen, Y.; Li, X.; Xu, L.; Tan, G.*; Crystalline Aryliminophosphinyl Radical: A Phosphorus Congener of Aryldiazenyl Radicals.
J. Am. Chem. Soc. 2025, 147, 36980−36986
29）Li, X.; Chen, Y.; Zhang Y.; Xu, L.; Tan, G.*; Isolable Arylphosphinidene Chalcogenides and their Radical Anions.
Angew. Chem. Int. Ed. 2025, e202514521
28) Li, X.; Chen, Y.; Dong, S.; Wang, D.; Xu, L.; Zhu, J.; Tan, G.*; Crystalline Arylstibinidene Chalcogenides: Heavier Congeners of Aromatic Nitroso Compounds.
J. Am. Chem. Soc. 2025, 147, 9858−9864
27) Wang, D.; Chen, W.; Sun, R.; Liu, J.-L.; Wang, B.*; Ye, S.*; Tan, G.*; Gao, S. Synthesis and magnetic property of a telluryl radical.
Chem 2025, 11, 102392
26) D, Wang; W, Chen; H, Chen; Y, Chen; S, Ye*; G, Tan*; Isolation and characterization of a triplet nitrene.
Nat. Chem. 2025, 17, 38-43.
Highlighted by ChemistryViews: Stabilizing Triplet Nitrene.
Highlighted by Nature Chemistry: Bottleable triplet nitrenes by Dominik Munz.
25) Y. Chen, P. Su, D. Wang, Z. Ke*, G. Tan*, Molecular-strain induced phosphinidene reactivity of a phosphanorcaradiene
Nat. Commun. 2024, 15, 4579.
24) Chen, H.; Chen, W.; Wang, D.; Chen, Y.; Liu, Z.; Ye, S.*; Tan, G.*; Gao, S. An Isolable One-coordinate Lead(I) Radical with Strong g-Factor Anisotropy.
Angew. Chem. Int. Ed. 2024, n/a, e202402093.
Highlighted by Chemistryviews. Selected as VIP paper.
23) Wang, D.; Chen, H.; He, Y.; Chen, X.*; Zhang, L.*; Tan, G.* An Isolable Phosphinogermylyne as a Synthon of One-Coordinate GeI Radical.
Chin. J. Chem. 2024, 42, 736-742.
Selected as Front Cover.
22) Chen, H.; Chen, Y.; Li, T.; Wang, D.; Xu, L.; Tan, G. Synthesis and Reactivity of N-Heterocyclic Carbene Coordinated Formal Germanimidoyl-Phosphinidenes.
Inorg. Chem. 2023, 62, 20906-20912.
21) Wu, M.; Chen, W.; Wang, D.; Chen, Y.; Ye, S.*; Tan, G.* Triplet Bismuthinidenes Featuring Unprecedented Giant and Positive Zero Field Splittings.
Natl. Sci. Rev. 2023, 10, nwad169.
20) Wu, M.; Li, H.; Chen, W.; Wang, D.; He, Y.; Xu, L.; Ye, S.*; Tan, G.* A triplet stibinidene.
Chem. 2023, 9, 2573-2584.
19) Wang, D.; Chen, W.; Zhai, C.; Zhao, L.*; Ye, S.*; Tan, G.* Monosubstituted Doublet Sn(I) Radical Featuring Substantial Unquenched Orbital Angular Momentum.
J. Am. Chem. Soc. 2023, 145, 6914–6920.
18) Wang, D; Zhai, C; Chen, Y.; He, Y.; Chen, X.; Wang, S.; Zhao, L.*; Frenking, G.*;Wang, X.; Tan, G.*, An isolable germylyne radical with a one-coordinate germanium atom.
Nat. Chem. 2023, 15, 200-205.
被国家基金委网站宣传
17) He, Y.; Dai, C.; Wang, D.; Zhu, J.*; Tan, G.*, Phosphine-Stabilized Germylidenylpnictinidenes as Synthetic Equivalents of Heavier Nitrile and Isocyanide in Cycloaddition Reactions with Alkynes.
J. Am. Chem. Soc. 2022, 144 (11), 5126–5135.
16) Yu, Q.; Zhang, L.; He, Y.; Pan, J.; Li, H.; Bian, G.-q.; Chen, X.; Tan, G.*, A stable tetrazagallole and its radical anion dimer.
Chem. Commun. 2021, 57, 9268-9271.
15) Pan, J.; Zhang, L.; He, Y.; Yu, Q.; Tan, G.*, An Isolable Magnesium(II)-Radical Dianion Complex.
Organometallics. 2021, 40 (20), 3365-3369.
14) Li, H.; He, Y.; Liu, C.; Tan, G.*, A bis(imino)carbazolate pincer ligand stabilized mononuclear gallium(i) compound: synthesis, characterization, and reactivity.
Dalton Trans. 2021, 50 (36), 12674-12680.
13) Liu, J.; Singh, K.; Dutta, S.; Feng, Z.; Koley, D.*; Tan, G.*; Wang, X., Yttrium germole dianion complexes with Y–Ge bonds.
Dalton Trans. 2021, 50 (16), 5552-5556.
12) Chen, Y.; Li, J.; Zhao, Y.; Zhang, L.*; Tan, G.*; Zhu, H.*; Roesky, H. W.*, Stable Radical Cation and Dication of a 1,4-Disilabenzene.
J. Am. Chem. Soc. 2021, 143, 2212-2216.
Selected peer-reviewed papers before 2021.
11) Feng, Z. T.; Fang, Y.; Ruan, H.; Zhao, Y.; Tan, G.*; Wang, X*, Stable Radical Cation and Dication of an N‐Heterocyclic Carbene Stabilized Digallene: Synthesis, Characterization and Reactivity.
Angew. Chem., Int. Ed. 2020, 59, 6769-6774.
10) Mondal, M. K.; Zhang, L.; Feng, Z.; Tang, S.; Feng, R.; Zhao, Y.; Tan, G.*; Ruan, H.*; Wang, X*, Tricoordinate Nontrigonal Pnictogen-Centered Radical Anions: Isolation, Characterization and Reactivity.
Angew. Chem., Int. Ed. 2019, 58, 15829-15833.
9) Feng, R.; Zhang, L.; Ruan, H.; Zhao, Y.; Tan, G.*; Wang, X.*, A Main-Group Element Radical Based One-Dimensional Magnetic Chain.
Angew. Chem. Int. Ed. 2019, 58, 6084.
8) Tan, G.#; Li, J.#; Zhang, L.; Chen, C.; Zhao, Y.; Wang, X.;* Song, Y.;* Zhang, Y.-Q.;* Driess, M.,* The Charge Transfer Approach to Heavier Main-Group Element Radicals in Transition Metal Complexes.
Angew. Chem., Int. Ed. 2017, 56, 12741.
7) Tan, G.; Wang, X.,* Isolable Bis(triarylamine) Dications: Analogues of Thiele’s, Chichibabin’s, and Müller’s Hydrocarbons.
Acc. Chem. Res. 2017, 50, 1997.
6) Wang, L.; Li, J.; Zhang, L.; Fang, Y.; Chen, C.; Zhao, Y.; Song, Y.; Deng, L.; Tan, G.;* Wang, X.;* Power, P. P.,* Isolable Borane-Based Diradical and Triradical Fused by a Diamagnetic Transition Metal Ion.
J. Am. Chem. Soc. 2017, 139, 17723.
5) Li, T.; Wei, H.; Fang, Y.; Wang, L.; Chen, S.; Zhang, Z.; Zhao, Y.; Tan, G.;* Wang, X.,* Elusive Antimony-Centered Radical Cations: Isolation, Characterization, Crystal Structures, and Reactivity Studies.
Angew. Chem., Int. Ed. 2017, 56, 632.
4) Tan, G.; Li, S.; Chen, S.; Sui, Y.; Zhao, Y.; Wang, X.,* Isolable Diphosphorus-Centered Radical Anion and Diradical Dianion.
J. Am. Chem. Soc. 2016, 138, 6735.
3) Tan, G.; Enthaler, S.; Inoue, S.; Blom, B.; Driess, M.,* Synthesis of Mixed Silylene–Carbene Chelate Ligands from N-Heterocyclic Silylcarbenes Mediated by Nickel.
Angew. Chem., Int. Ed. 2015, 54, 2214.
2) Tan, G.; Szilvási, T.; Inoue, S.; Blom, B.; Driess, M.,* An Elusive Hydridoaluminum(I) Complex for Facile C–H and C–O Bond Activation of Ethers and Access to Its Isolable Hydridogallium(I) Analogue: Syntheses, Structures, and Theoretical Studies.
J. Am. Chem. Soc. 2014, 136, 9732.
1) Tan, G.; Yang, Y.; Chu, C.; Zhu, H.;* Roesky, H. W.,* Cu24O24Si8R8: Organic Soluble 56-Membered Copper(I) Siloxane Cage and Its Use in Homogeneous Catalysis.
J. Am. Chem. Soc. 2010, 132, 12231.
