24. Yiyi, Chen+.; Xu, Yi, Xu+.; Shuangquang, Zhang.; Xiaohui, Chen.; Fangqun, Gan.; Xianliang, Tan.; Kun, Feng.; Xiao, Xiao.; Zhong-Yan, Cao*.; Ming Chen*. and Xianqiang, Kong* Electrochemical Dehydroxymethylative Functionalization of Unacti-vated Alcohols via Criegee–Kolbe Radical Relay.
J. Am. Chem. Soc. 2025, 147, DOI: 10.1021/jacs.5c18031.
Highlighted by X-mol, 有机电催化，雁城方法学, 材料化学进展，邃瞳科学云
23. Chen, Zhou+.; Pei-shang, Li+.; and Ming Chen*. Bypassing Sonogashira Coupling: Modular Synthesis of PAHs from Aryl Halides and
Terminal Alkynes via Photoinduced Palladium Catalysis.
Nat. Commun. 2025, 16, 8349. DOI : 10.1038/s41467-025-62466-7.
Article ID : 41467_2025_62466_Article. Manuscript ID : NCOMMS-25-29016.
Highlighted by X-mol，柔谷，科研云资讯，化学身边学，雁城方法学，催化开天地，邃瞳科学云，化学深耕堂，有机那点事，CBG资讯，ChemVibe, NENU微研
22. Yi-bin Wang.; and Ming Chen*. Platinum-Catalyzed C–F Bond Reconstruction via Multi-Unit Insertion for Remote Fluorine Migration.
J. Am. Chem. Soc. 2025, 147, 25061−25071. DOI：10.1021/jacs.5c08669.
Highlighted by X-mol，岳麓化学，有机合成，科学纵横，有机那点事，化学身边学，雁城方法学，搜狐，化学谷，探寻新知，半池清月，CBG资讯
21. Lu-ning Tang, Jia-cheng Miao, and Ming Chen*. Recent advances in Photoinitiated Pd-Catalyzed Desaturation and Heck-Type Reactions via 1,5-Hydrogen Atom Transfer. （Feature Article）
Chem. Commun. 2025, 61, 4621-4629. DOI: 10.1039/D4CC06349J
20. Xu, Cheng-zhi+, Xu, Zhen-yan+, Chen, Yi-feng*, Chen Ming* and Liu, Yuan-hong*. Intermolecular Nitrile 1,2-Difunctionalization via Redox Gold Catalysis.
Chem. Eur. J. 2025, e202404368.
19. Chen, Sheng-yu +, Tang, Lu-ning+*, and Chen, Ming*. Palladium-Catalyzed Double ipso-Defluoroetherification of Allylic gem-Difluorides with Phenols or Alcohols.
Org. Lett. 2024, 26, 9799-9803.
18. Yang, Sen+, Qiu, Chao-Ying+, Hu, Hao, Jiang, Yan* and Chen Ming*. Visible-Light-Driven Synthesis of N-Alkyl α-Amino Acid Derivatives from Unactivated Alkyl Bromides and in situ Generated Imines.
Org. Lett. 2024, 26, 8416−8423. DOI：10.1021/acs.orglett.4c03297.
17. Wang, Huan†.; Wang, Yi-bin†.; Zhan, Yan-fang.; Zhu, Yi-ting.; Jiang, Yan*.; Yang, Sen*.; and Chen, Ming* Copper-Catalyzed Oxidative α-Double Bond Construction in α-Amino Carbonyl Compounds via Homo-Coupling with Arylamine Release.
Org. Lett. 2024, 26, 8128−8133. DOI：10.1021/acs.orglett.4c0304.
16. Sheng, Xia-xin.;† Qiu, Chao-ying.;† Wang, Li-na .;† Du, Yu-jia.; Tang, Lu-ning.; Chen, Jia-ming.; Liu, Guo-ying.; Yang, Sen*, Zheng, Peng-fei*.; and Chen, Ming*. Transition-Metal-Free Radical Relay Cascade Annulation of Amides: Access to Antitumor Active Benzo[b]azepine and Oxindole Derivatives.
Chem. Eur. J. 2024, e202402402. DOI: 10.1002/chem.202402402.
15. Zhan, Yan-fang+.; Jia-ming Chen+.; Sheng, Xia-xin.; Qiu, Chao-ying.; Jiang, Yan*, Yang, Sen*.; and Chen Ming*. Photoinduced Copper Catalyzed Nitrogen-to-Alkyl Radical Relay Sonogashira-type Coupling of o-Alkylbenzamides with Alkynes.
Chem. Commun. 2024, 60, 7906 - 7909. DOI: 10.1039/D4CC02861A.
14. Yang, Sen.;+, Cai, Sha-sha.;+, Li, Jun-hua and Chen Ming.* Photoinduced Palladium-Catalyzed Radical Heck-Type Coupling of Cyclobutanone Oxime Esters with Vinyl Arenes.
J. Org. Chem. 2024, 89, 7243-7254. doi.org/10.1021/acs.joc.4c00703.
13. Liu, Guo-ying +, Tang, Lu-ning+*, Li, Jun-hua, Yang Sen* and Chen Ming *. Palladium-Catalyzed Alkynylation of Allylic gem-Difluorides.
Chem. Commun. 2024, 60, 4471 - 4474. DOI: 10.1039/D4CC01007H.
12. Du, Yu-jia†, Sheng, Xia-xin†, Tang, Lu-ning, Chen, Jia-ming, Liu, Guo-ying, Hu, Hao, Yang, Sen*, Zhu Lei*, and Chen, Ming*. Accessing Benzoazepine Derivatives via Photoinduced Radical Relay Formal [5+2] of Amide/Alkyne Enabled by Palladium Catalysis.
Org. Lett. 2024, 26, 2662-2667. DOI：10.1021/acs.orglett.4c00979.
11. Tang, Lu-ning.; Liu, Guo-ying.; Li, Jun-hua and Chen, Ming.* Palladium-Catalyzed Diversified Synthesis of mono-Fluorinated Alkenes from Allylic gem-Difluorides through Pd-OH intermediate.
10. Yang, Sen.; Hu, Hao.; Li, Jun-hua and Chen, Ming.* Direct Alkylation of Glycine Derivatives via Photoinduced Palladium Catalysis, Utilizing Intermolecular Hydrogen Atom Transfer Mediated by Alkyl Radicals.
ACS Catalysis. 2023, 13, 24, 15652−15662. DOI:10.1021/acscatal.3c04075.
Nat. Commun. 2023,14, 6933. DOI: 10.1038/s41467-023-42699-0.
7. Chen, Jia-ming.; Li, Jun-hua.; Xie, Li-cheng.; Fan, Hui-ke.; Sheng, Xia-xin.; Du, Yu-jia.; Liu, Guo-ying.; Hu, Hao.; Jiang, Yan*.; and Chen, Ming.* Iron-Catalyzed Divergent Approach to Naphthyridinones and Quinolinones: Leveraging Povarov and Carbonyl-Alkyne Metathesis Reactions of Electron Deficient Alkynes.
Org. Chem. Front. 2023, 10, 5505-5511. DOI:10.1039/D3QO01302B.
6. Li, Pei-shang.; Teng, Qiaoqiao*.; and Chen, Ming.* Photoinduced Radical Cascade Domino Heck Coupling of N-Aryl Acrylamide with Vinyl Arenes Enabled by Palladium Catalysis.
Chem. Commun. 2023, 59, 10620-10623. DOI: 10.1039/D3CC03506A.
5. Yang, Sen.; Guo-ying, Liu.; Fan, Huike.; Jun-hua, Li.; Teng, Qiaoqiao*.; and Chen, Ming.* Sodium Hydroxide (NaOH)-Mediated Oxidative Hydroxylation of Arylboronic Acids and Its Applications in C-O Bond Formation.
Eur. J. Org. Chem. 2023, e202300517. DOI: 10.1002/ejoc.202300517. (Dedicated to celebrate the 45th anniversary of Changzhou University)
2. Fan, Huike, Yang, Sen.; Li, Junhua.; Teng, Qiaoqiao*.; and Chen, Ming.* BaO-Catalyzed α-Deuteration of Ketones, Sulfones, Sulfoxides, and Nitriles.
Eur. J. Org. Chem. 2022, e202201218. DOI: 10.1002/ejoc.202201218.
1. Yang, Sen.; Fan, Huike.; Xie, Licheng.; Dong, Guangbin*.; and Chen, Ming.* Photoinduced Desaturation of Amides by Palladium Catalysis.
Org. Lett. 2022, 24, 6460-6465.
1. Chen, M.; Chen, Y.; Sun, N.; Zhao, J.; Liu, Y.* Gold-Catalyzed Oxidative Ring Expansion of 2-Alkynyl-1,2-Dihydropyridines or -quinolines: Highly Efficient Synthesis of Functionalized Azepine or Benzazepine Scaffolds. Angew. Chem. Int. Ed. 2015, 54, 1200.
2. Chen, M.; Dong, G.* Direct Catalytic Desaturation of Lactams Enabled by Soft Enolization.J. Am. Chem. Soc.2017, 139,7757.(Highlighted by Org. Process Res. Dev.2017, 21, 1873.)
3. Chen, M.; Liu, F.; Dong, G.*Direct Palladium-Catalyzed β-Arylation of Lactams. Angew. Chem. Int. Ed. 2018,57, 3815.
4. Chen, M; Rago, A; Dong, G* Platinum-Catalyzed Desaturation of Lactams, Ketones and Lactones.Angew. Chem. Int. Ed.2018, 57, 16205-16209.(Highlighted bySynfacts,2019, 173)
5. Chen, M.; Dong, G.* Copper-Catalyzed Desaturation of Lactones, Lactams and Ketones under pH-Neutral Conditions. J. Am. Chem. Soc. 2019, 141,14889.
6. Chen, M.; Dong, G.*Platinum‐catalyzed α,β‐Desaturation of Cyclic Ketones through Direct Metal‐enolate Formation” Angew. Chem. Int. Ed. 2021, 60(14), 7956-7961.
7. Chen, M.; Chen, Y.; Liu, Y.* Palladium-catalyzed highly efficient synthesis of tetracenes and Pentacenes.Chem. Commun.2012,48, 12189-12191.
8. Chen, M.; Liu, J.; Wang, L.; Zhou, X.; Liu, Y.* Gold-catalyzed cascade cycloisomerization of1,7-diyn-3,6-bis(propargyl carbonate)s: stereoselective synthesis of naphtho[b]cyclobutenes.Chem. Commun.2013,49, 8650-8652. (Highlighted bySynfacts,2014, 144)
9. Chen, M.; Sun, N.; Liu, Y.*Environmentally Benign Synthesis of Indeno[1,2-b]quinolines via an Intramolecular Povarov Reaction.Org.Lett.2013,15, 5574.
10. Chen, M.; Sun, N.; Xu, W.; Zhao, J.; Wang, G.; Liu, Y.* Gold-Catalyzed Ring Expansion ofalkynylheterocycle via 1,2-Migration of an Endocyclic C-Heteroatom Bond. Chem. Eur. J. 2015, 21, 18571.
11. Chen, M†.; Sun, N†.; Chen, H.; Liu, Y.* Dioxazoles, a new mild nitrene transfer reagent in gold catalysis: highly efficient synthesis of functionalized oxazoles. Chem. Commun.2016,52, 6324.
12. Chen, Y.;Chen, M.; Liu, Y.* Gold-Catalyzed Cyclization of 1,6-Diyne-4-en-3-ols: Stannyl Transfer from 2-Tributylstannylfuran Through Au/Sn Transmetalation. Angew. Chem. Int. Ed. 2012, 51, 6181-6186.
13. Chen, Y.;Chen, M.; Liu, Y.* Gold-Catalyzed Cascade Cyclizations of 1,6-Diynyl Carbonates to Benzo[b]fluorenes Involving Arylation of Oxocarbenium Ion Intermediates and Decarboxylative Etherification. Angew. Chem. Int. Ed. 2012, 51, 6493-6497.
14. Sun, N.;Chen, M.; Liu, Y.* Gold-Catalyzed Oxidative Reactions of Propargylic Carbonates Involving 1,2-Carbonate Migration: Stereoselective Synthesis of Functionalized Alkenes. J. Org. Chem. 2014, 79, 4055.
15. Liu, J.;Chen, M.; Zhang, L.; Liu, Y.* Gold(I)-Catalyzed 1,2-Acyloxy Migration/[3+2] Cycloaddition of 1,6-Diynes with an Ynamide Propargyl Ester Moiety: Highly Efficient Synthesis of Functionalized Cyclopenta[b]indoles. Chem. Eur. J.2015,21, 1009.
16. Li, X.; Chen, M.; Xie, X.; Sun, N.; Li, S*.; Liu, Y*. Synthesis of Multiple-Substituted Pyrroles via Gold(I)-Catalyzed Hydroamination/Cyclization Cascade. Org. Lett.2015,17, 2984.
17. Sun, R.;Liu, J.;Yang, S.;Chen, M.; Sun, N.; Chen, H.; Xie, X.; You, X.; Li, S.; Liu, Y.* Cp2TiCl2-Catalyzedcis-Hydroalumination of Propargylic Amines with Red-Al: Stereoselective Synthesis ofZ-Configured Allylic Amines. Chem. Commun. 2015, 51, 6426.
18. Xu, W.; Chen, M.; Sun, N.; Liu, Y.* Gold-catalyzed cyclization of 1,6-diynyl dithioacetals via 1,7-carbene transfer and aromatic C–H functionalization. Chem. Commun. 2016, 52, 11000.
19. Hu, H†.; Hu, X†.;Chen, M.; Sun, N.;* Liu, Y.* Gold-Catalyzed Ring Expansion Reaction: Highly Efficient Synthesis of Functionalized 2,3-Benzodiazepine Scaffolds. Chin. J. Org. Chem. 2018, 38, 190.
