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成果及论文

近年主要代表性科研项目

20. 【基金委】CeO2基催化剂上糠醛-丙酮加合物合成生物基功能单体呋喃基丁二烯的研究

19.【中科院先导专项】仿生橡胶合成及工程化

18.【国家项目】橡胶合成技术研究

17.【吉林省人才开发项目】高性能仿生合成橡胶全链条产业化技术开发

16.吉林省重点专项气固下行循环流化床一步法合成异戊二烯的研究

15.【吉林省重点专项】高寒地带先进轨道交通用橡胶制品的研制开发 

14. 【省院合作】碳四碳五产业链高值化综合利用-异戊二烯单体流化床反应器关键技术开发 

13. 【中阿合作】高性能绿色轮胎合成橡胶系列产品研发

12. 【基金委】新型仿生合成橡胶的制备及其性能研究  

11. 【长春应化所重点】10万吨级异戊二烯单体产业化技术 

10. 【中科院】王宽诚-产研人才扶持计划 

9. 【中科院】XX计划 

8. 【吉林省专项】人工合成天然橡胶-稀土异戊橡胶”关键凝聚后处理反应设备的研制开发

7. 【吉林省专项】吉林省高性能合成橡胶工程研究中心创新能力建设 

6. 【中科院重点专项】合成天然橡胶及其单体成套产业化技术-单体合成技术  

5. 【吉林省重点专项】高性能绿色轮胎合成橡胶制备及应用技术  

4. 【吉林省重点专项】新型可控长链支化三元乙丙橡胶关键技术研发  

3.【国家科技部】国家科技支撑计划项目课题-稀土异戊橡胶溶液聚合工艺工程研究 

2. 【基金委】新型仿生合成橡胶的制备及其性能研究 

1. 【基金委】配位双烯烃聚合微观结构控制机理研究 



近五年代表性学术论文

26. Thermally stable vanadium complexes supported by the iminophenyl oxazolinylphenylamines ligands: Synthesis, characterization and application for ethylene (co-)polymerizationDalton Trans., 2021, DOI: 10.1039/D1DT03004C

25.Catalyst-free Vitrimer Cross-linked By Biomass-derived Compounds with Mechanical Robustness, Reprocessability and Multi-shape Memory Effects. Macromol. Rapid Comm., 2021, DOI: 10.1002/marc.202100432

24. Multifunctional Ce/ZrSi Catalyst Synergistically Converting 1,4-Pentanediol Derived from Levulinic Acids to Renewable PentadieneACS Sustainable Chem. Eng. 2021, DOI: 10.1021/acssuschemeng.1c03507

23. Recyclable, robust and shape memory vitrified polyisoprene composite prepared through a green methodology. Polymer, 2020, DOI: 10.1016/j.polymer.2021.123864

22. An In-situ Self-regeneration Catalyst for the Production of Renewable 1,3-pentadieneChem. Eur. J, 2021, DOI:10.1002/chem.202100613

21. Boron nitride and hyperbranched polyamide assembled recyclable polyisoprene vitrimer with robust mechanical properties, high thermal conductivity and remoldability. Polymer, 2020, 10.1016/j.polymer.2020.122964

20Converting formaldehyde-methylethylketone adduct to a nonlinear C5 1,3-diol over Pt-ceria catalysts for isoprene production. Appl. Catal. A. 2020, 603, 117745

19. Efficient synthesis of a nonlinear C5 1,3-diol from butanone and formalin under mild conditions for isoprene production. ACS Sustainable Chem. Eng. 2020, 8, 28, 10323–10329

18. Assembling of reprocessable polybutadiene-based vitrimers with high-strength and shape-memory via catalyst-free imine-coordinated boroxine. ACS Appl. Mater. Inter. 2020, 12, 29, 33305–33314

17. Production of a renewable functionalized 1,3-diene from furfural–acetone adduct over supported heteropolyacid catalysts. ACS Sustainable Chem. Eng. 2020, 8, 7214

16. Depositing Different Carbon Species on MoP to Enhance Its Activity for Isoprene Production in Different Ways. Ind. Eng. Chem. Res., 2020, 59, 5491

15. Selectively creating oxygen vacancies on PrCe/SiO2 catalysts for the transformation of furfural–acetone adduct into a functionalized 1,3-diene. Catal. Sci. Technol., 20199, 6875

14. Neodymium Organic Sulfonate Complexes: Tunable Electronegativity/Steric Hindrance and Application in Controlled Cis-1,4-polymerization of Butadiene. Chinese J. Polym. Sci. 2019, 37, 208.

13. Fabrication of β-cyclodextrin-crosslinked epoxy polybutadiene/hydroxylated boron nitride nanocomposites with improved mechanical and thermal-conducting properties.  J. Mater Res Technol., 2019, 8, 5853

12. Controllable synthesis of silver anchored N-doped yolk-shell carbon@mSiO2 spheres and their application for the catalytic reduction of 4-nitrophenol. Appl. Surf. Sci., 2019, 493, 1013 

11. Production of a renewable 1,3–diene containing a functional group from furfural–acetone adduct in a fixed–bed reactor.  Green Chem., 2019, 21, 3911-3919

10. High Tg and thermostable phytic Acid?Cured polynorbornene-based polymer by a Palladium(Ⅱ) complex bearing iminophenyl oxazolinylphenylamines ligand.Polymer 2019, 172, 196-204

9. Fabrication of boron nitride nanosheet/polymer composites with tunable thermal insulating propertiesNew J. Chem., 2019,43, 4878-4885 

8. Synthesis of 1,3-Butadiene and Its 2-Substituted Monomers for Synthetic RubbersCatalysts 2019, 9, 97

7. Facile synthesis of hierarchically porous carbonaceous materials derived from olefin/ aldehyde precursors using silica as templatesRSC Adv. 20188, 11462-11468

6. High cis-1,4-copolymerization of myrcene and butadiene with a neodymium-based catalystChina Synthetic Rubber Industry, 2018, 1, 65-65

5. Insight into performance of lactam-based Bronsted-acidic catalysts for Prins condensation and their self-separation in water.Molecular Catalysis 2018, 445, 80-86

4. Development a facile way to restore reactivity of deactivated phosphate catalysts for Prins reaction with the assistance of carbon deposition.Catal. Commun. 2018106, 11-15

3. Regulation of the cis-1,4-and trans-1,4-Polybutadiene Multiblock Copolymers via Chain Shuttling Polymerization Using a Ternary Neodymium Organic Sulfonate CatalystMacromolecules 2017, 50,7887-7894

2. Assembly line synthesis of isoprene from formaldehyde and isobutene over SiO2-supported MoP catalysts with active deposited carbonRSC Adv., 2017, 7, 37392-37401

1. Iminopyridine-Based Cobalt(II) and Nickel(II) Complexes: Synthesis, Characterization, and Their Catalytic Behaviors for 1,3-Butadiene PolymerizationPolymers 2016, 8, 12


近五年代表性专利

29 白晨曦,祁彦龙,代全权,崔龙 一种催化糠醛及其衍生物转化合成2-乙烯基呋喃的方法 CN202110171660.6

28 白晨曦,祁彦龙,代全权,崔龙 一种催化糠醇/甲醇转化两步法合成呋喃乙烯类功能单体及催化剂应用 CN202011519333.7

27 白晨曦,祁彦龙,代全权,崔龙 一种基于糠醇/甲醇催化转化合成生物质基功能单体的方法及催化剂应用 CN202011521421.0

26 白晨曦,祁彦龙,刘士俊,代全权,崔龙 一种戊二醇的合成方法、一种乙酰丙酸及其衍生物转化制生物质基间戊二烯的合成方法 CN202011608874.7

25 白晨曦,祁彦龙,冯瑞林,代全权,崔龙 一种戊二醇的合成方法以及一种基于乳酸转化制备生物质基线性戊二烯的合成方法 CN202011608887.4

24 白晨曦,祁彦龙,代全权,崔龙 一种支化度可控的EVA合成的调控方法及合成方法、一种EVOH树脂及其合成方法 CN202011626512.0

23 白晨曦,祁彦龙,代全权,崔龙. 一种自由基可控释放的合成EVA的调控方法及合成方法、一种EVOH树脂及其合成方法 CN202011626536.6

22 代全权, 白晨曦, 崔龙, 祁彦龙, 董巍. 稀土配合物、催化剂及其制备方法和双烯烃聚合物的制备方法 ZL201910418499.0

21 代全权, 白晨曦, 崔龙, 祁彦龙, 董巍. 一种稀土催化剂的制备方法及其在双烯烃聚合和共聚合中的应用. ZL201910418514.1

20 祁彦龙, 白晨曦, 崔龙, 代全权, 董巍. 一种利用催化剂积碳的甲基叔丁基醚和甲醛制备异戊二烯的生产方法及生产系统. ZL201910655900

19  祁彦龙, 白晨曦, 崔龙, 代全权, 董巍. 一种用于烯(醚)醛气相法合成异戊二烯的抗积碳与废水、废热综合利用的生产系统及方法. ZL201910655856

18. 祁彦龙, 白晨曦, 崔龙, 代全权, 董巍. 一种基于生物质化学品合成功能化1,3-丁二烯的方法. CN201910044171.7

17. 祁彦龙, 白晨曦, 崔龙, 代全权, 董巍. 一种基于醛酮缩合反应合成二烯烃类化合物的方法. CN201910044174.0

16. 白晨曦, 贺剑云, 代全权, 祁彦龙, 崔龙. 一种氟硅异戊橡胶及其制备方法、宽温域高强度航空轮胎橡胶材料及其制备方法. ZL201810354409

15. 白晨曦, 贺剑云, 代全权, 祁彦龙, 崔龙. 一种改性氟硅异戊橡胶及其制备方法、高强度航空轮胎橡胶材料及其制备方法. ZL201810355068

14. 白晨曦, 贺剑云, 代全权, 祁彦龙, 崔龙. 一种改性氟硅异戊橡胶及其制备方法、仿生型航空轮胎橡胶材料及其制备方法. CN201810353778

13. 白晨曦, 祁彦龙, 崔龙, 代全权. 一种改性的钙铁矿型催化剂及其制备方法、在催化合成异戊二烯中的应用. ZL201711189767.3

12. 白晨曦, 祁彦龙, 崔龙, 代全权. 一种碳层包覆的复合型催化剂及其制备方法、在催化合成异戊二烯中的应用. CN201711190785.3

11. 白晨曦, 祁彦龙, 崔龙, 代全权. 烯醛气相法合成异戊二烯产生的积碳催化剂的处理方法. CN201711431016.8

10. 白晨曦, 祁彦龙, 崔龙, 代全权.一种失活催化剂的再利用方法和复合催化剂. ZL201711417187.5

9. 白晨曦, 祁彦龙, 崔龙, 代全权. 一种烯醛气相法合成异戊二烯反应废气的处理方法. ZL201711430139.X

8. 白晨曦, 曾尚景, 刘士俊, 代全权, 崔龙. 一种自支撑金属改性ZSM-5分子筛的制备方法及其在合成异戊二烯中的应用, ZL201711189770.5

7. 白晨曦, 曾尚景, 刘士俊, 代全权, 崔龙. 一种自支撑金属改性Beta分子筛的制备方法及其在合成异戊二烯中的应用. ZL201711190821.6

6. 白晨曦, 张梦辉, 张学全, 张春雨. 一种用于烯醛一步法合成异戊二烯的催化剂及其制备方法. ZL201610161038.6

5. 张春雨, 白晨曦, 张学全. 一种用于合成异戊二烯的催化剂及其制备方法. ZL201610944377.1

4. 代全权, 张学全, 白晨曦, 胡雁鸣, 张春雨. 一种含有不饱和长链烷基的烷基铝的制备方法. ZL201610348816.2

3. 代全权, 张学全, 白晨曦, 胡雁鸣, 张春雨, 毕吉福, 那丽华. 一种双烯烃聚合物及其制备方法. ZL201610348812.4,

2. 代全权, 张学全, 白晨曦, 胡雁鸣, 张春雨, 毕吉福, 那丽华. 一种阳离子稀土中心催化体系、其制备方法及双烯烃聚合物的制备方法. ZL201610348792.0

1. 代全权, 白晨曦, 崔龙, 贺剑云, 张倩. 一种顺‑1,4‑反‑1,4多嵌段聚丁二烯的制备方法. ZL201710780263.2