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成果及论文

16.Di Xie, Zhi-Hua Jia, Yan-Li Zhang, Xin-Lei Cai, Long-Nv Liu, Guan-Wen Yang*, Xiaohui Kang*, Xianming ZhangYao-Yao Zhang*. Switchable Polymerization from Monomer Mixtures to Synthesize Oxygen-Rich Block Copolymers with Dual Recyclability and Degradability, Angew. Chem. Int. Ed. 2025, e202424856.https://doi.org/10.1002/anie.202424856

15.Yang, G.-W.; Xie, R; Xu, C-K.; Yao-Yao Zhang; and Wu, G.-P.*, Evolution of Copolymers of Epoxides and CO2: Catalysts, Monomers,Architectures, and Applications. Chem. Rev., 2024, 124, 12305-12380. https://doi.org/10.1021/acs.chemrev.4c0051

14. Yao-Yao Zhang, Guan-Wen Yang, Chenjie Lu, Xiao-Feng Zhu, Yuhui Wang and  Guang-Peng Wu.* Organoboron-mediated polymerizations, Chem. Soc. Rev., 2024,53, 3384-3456.https://doi.org/10.1039/D3CS00115F

13. Mingfu Zheng, Wenjun Peng, Yao-Yao Zhang,* Xianming Zhang,* Wenxing Chen, Synthesis, Characterization, and Application of High-Molecular-Weight Polyethylene-like Polycarbonates: Toward Sustainable and Recyclable Fibers, Macromolecules 2024, 57, 15, 7020–7030.https://doi.org/10.1021/acs.macromol.4c00933

12. Zhang, Y.-Y.; Yang, G.-W.*; R. Xie, Zhu, X.-F.; Wu, G.-P.* Sequence-Reversible Construction of Oxygen-Rich Block Copolymers from Epoxide Mixtures by Organoboron Catalyst, J. Am. Chem. Soc., 2022, 144, 19896–19909.https://doi.org/10.1021/jacs.2c07857

11. Zhang, Y.-Y.; Yang, G.-W.; Xie, R.; Yang, L.; Li, B.; Wu, G.-P.*, Scalable, Durable, and Recyclable Metal-Free Catalysts for Highly Efficient Conversion of CO2 to Cyclic Carbonates. Angew. Chem. Int. Ed. 2020, 59, 23291–23298.https://doi.org/10.1002/anie.202010651

10. Zhang, Y.-Y.; Wu, G.-P.*; Darensbourg, D. J.*, CO2-Based Block Copolymers: Present and Future Designs. Trends Chem. 2020, 2, 750–763.https://doi.org/10.1016/j.trechm.2020.05.002

9. Zhang, Y.-Y.#; Lu, C.#; Yang, G.-W.; Xie, R.; Fang, Y.-B.; Wang, Y.; Wu, G.-P.*, Mechanism-Inspired Upgradation of Phosphonium-Containing Organoboron Catalysts for Epoxide-Involved Copolymerization and Homopolymerization. Macromolecules 2022, 55, 6443-6452.https://doi.org/10.1021/acs.macromol.2c01180

8. Zhang, Y.-Y.; Yang, L.; Xie, R.; Yang, G.-W.; Wu, G.-P.*, Perfectly Alternating Copolymerization of CO and Epoxides to Aliphatic Polyester Oligomers via Cooperative Organoboron–Cobalt Complexes. Macromolecules 2021, 54, 9427-9436. https://doi.org/10.1021/acs.macromol.1c01324

7. Zhang, Y.-Y.; Yang, G.-W.; Wu, G.-P.*, A Bifunctional β-Diiminate Zinc Catalyst with CO2/Epoxides Copolymerization and RAFT Polymerization Capacities for Versatile Block Copolymers Construction. Macromolecules 2018, 51, 3640–3646.https://doi.org/10.1021/acs.macromol.8b00576

6. Zhang, Y.-Y.; Yang, G.-W.; Wang, Y.; Lu, X.-Y.; Wu, G.-P.*; Zhang, Z.-S.; Wang, K.; Zhang, R.-Y.; Nealey, P. F.; Darensbourg, D. J.*; Xu, Z.-K., Synthesis of CO2-Based Block Copolymers via Chain Transfer Polymerization Using Macroinitiators: Activity, Blocking Efficiency, and Nanostructure. Macromolecules 2018, 51, 791–800.https://doi.org/10.1021/acs.macromol.7b02231

5. Yang, G.-W. #; Zhang, Y.-Y.#; Xie, R.; Wu, G.-P.*, High‐Activity Organocatalysts for Polyether Synthesis via Intramolecular Ammonium Cation Assisted SN2 Ring‐Opening Polymerization. Angew. Chem. Int. Ed. 2020, 59, 16910–16917.https://doi.org/10.1002/anie.202002815

4.Xie, R.#; Zhang, Y.-Y.#; Yang, G.-W.; Zhu, X.-F.; Li, B.; Wu, G.-P.*, Record Productivity and Unprecedented Molecular-Weight for Ring-Opening Copolymerization of Epoxides and Cyclic Anhydrides Enabled by Organoboron Catalysts. Angew. Chem. Int. Ed., 2021, 60, 119253–19261.https://doi.org/10.1002/anie.202104981

3. Yang, L. #; Zhang, Y.-Y.#; Yang, G.-W.; Xie, R.; Wu, G.-P.*, Controlled Ring-Opening Polymerization of β-Butyrolactone Via Bifunctional Organoboron Catalysts. Macromolecules. 2021, 54, 5509–5517.https://doi.org/10.1021/acs.macromol.1c00250

2.Yang, G.-W.; Zhang, Y.-Y.; Wu, G.-P.*, Modular Organoboron Catalysts Enable Transformations with Unprecedented Reactivity. Acc. Chem. Res. 202154, 44344448.https://doi.org/10.1021/acs.accounts.1c00620

1.Lu, X.-Y.#; Luo, H.#; Wang, K.#Zhang, Y.-Y.#; Zhu, X.-F.#; Li, D.; Ma, B.; Xiong, S.; Nealey, P. F.*; Li, Q.*; Wu, G.-P.*, CO2-based Dual-Tone Resists for Electron Beam Lithography. Adv. Funct. Mater. 20202007417.https://doi.org/10.1002/adfm.202170086