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成果及论文

2024

♦ Mono- and bis-Pd(ii) complexes of N-confused dithiahexaphyrin(1.1.1.1.1.0) with the absorption and aromaticity modulated by Pd(ii) coordination, macrocycle contraction and ancillary ligands

Meng Sun,  Yongshu Xie,  * Glib Baryshnikov,  Chengjie Li,   Feng Sha,   Xinyan Wu,   Hans Ågren, Shijun Li   and  Qizhao Li  *

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  • Chem. Sci. , 2024, Advance Article

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♦ Syntheses of Thiophene–Thiophene-Linked Corrorin Dimers with Tunable Near-Infrared Absorption and Distinctive Reactivity

Yue Xu, Bin Zhu, Lingfang Zhang, Glib Baryshnikov, Feng Sha, Emiko Nishimoto, Hideaki Takano, Chengjie Li, Xinyan Wu, Hans Ågren, Hiroshi Shinokubo, Yongshu Xie and Qizhao Li

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  • Org. Lett. 2024, 26, 2, 571–576

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    ♦ Syntheses and coordination of linear and macrocyclic pentapyrroles possessing a fused moiety: Confusion modulated structural diversity
      Yanping Huang a, Bin Zhu a, Qizhao Li a,**, Glib Baryshnikov b, Chengjie Li a, Feng Sha a,Xin-Yan Wu a, Hans Ågren c, Yongshu Xie a,* 
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        • Dyes and Pigments 223 (2024) 111948

♦ Panchromatic porphyrin-based dye-sensitized solar cells: from cosensitization to concerted companion dye approaches

Zhemin Li, Qizhao Li, Chengjie Li and Yongshu Xie *

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  • Mater. Chem. Front., 2024, Advance Article

2023

♦ Solar cells based on doubly concerted companion dyes with the efficiencies modulated by inserting an ethynyl group at different positions

Yuqing Wang , Zhemin Li , Qingjun Lu , Qizhao Li , Jiaxin Luo ,Chengjie Li , Yongshu Xie

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  • Chinese Chemical Letters , 2023: 109093  

♦ Conformation Governed Reactivity of Fused Thia-Sapphyrin Dimers Bearing Multiply Fused Heteroaromatic Rings

Qizhao Li1*, Masatoshi Ishida2, Chengjie Li1, Glib Baryshnikov3, Feng Sha1, Bin Zhu1, Xinyan Wu1, Hans Ågren4,Hiroyuki Furuta5,6* & Yongshu Xie1

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  • CCS Chem .2023, 5, 1332–1342  

♦ Synthesis and coordination of a dipyrrin appended N-confused porphyrin

Zhen Yang, Glib Baryshnikov, Feng Sha, Chengjie Li, Xinyan Wu, Hans Ågren, Yongshu Xie, and Qizhao Li

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    • J.Porphyrins Phthalocyanines
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    •  2023; 27: 286-292
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♦ Syntheses and characterization of dithienyl-blocked hexapyrrin and its mononuclear complexes

Yanping Huang, Yating Fu, Bin Zhu, Glib Baryshnikov, Hao-Ling Sun*, Feng Sha, Chengjie Li, Xin-Yan Wu, Hans Ågren, Qizhao Li*, and Yongshu Xie

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    • J.Porphyrins Phthalocyanines
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    • 2023; 27: 1090-1096
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♦ Efficient Solar Cells Based on Porphyrin and Concerted Companion Dyes Featuring Benzo 12-Crown-4 for Suppressing Charge Recombination and Enhancing Dye Loading

  • Jiaxin Luo
  • Qingjun Lu
  • Qizhao Li
  • Zhemin Li
  • Yuqing Wang
  • Xinyan Wu*
  • Chengjie Li*
  • , and 
  • Yongshu Xie 
    •                ACS Applied Materials & Interfaces  2023, 15, 35, 41569–41579


♦ Pyrrolylmethylene Appended Corrorin: Peripheral Coordination and Transformation to Pyridyl Incorporated Hemiporphycene Analogue

  • Yue Xu
  • Bin Zhu
  • Qizhao Li*
  • Feng Sha
  • Glib Baryshnikov
  • Lanka He
  • Yifan Feng
  • Jingxuan Tang
  • Yuan Wei
  • Chengjie Li
  • Xinyan Wu
  • Hans Ågren
  • , and 
  • Yongshu Xie*
  •           Org. Lett. 2023, 25, 10, 1793–1798      
     
       

Solar cells sensitized by donor-linked concerted companion dyes

Jiaxin Luo,a   Yuqing Wang,a   Shaojin Shi,a   Yuankun Wu,a   Taochun Ma,a   Leyao Wang,a   Glib Baryshnikov,b   Xinyan Wu,*a   Chengjie Li*a  and  Yongshu Xie*a 

          J. Mater. Chem. C, 2023,11, 5450-5460

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Antiaromatic Sapphyrin Isomer: Transformation into Contracted Porphyrinoids with Variable Aromaticity 

Qizhao Li,* Masatoshi Ishida, Yunyun Wang, Chengjie Li, Glib Baryshnikov, Bin Zhu, Feng Sha, Xinyan Wu, Hans Ågren, Hiroyuki Furuta,* and Yongshu Xie*

         Angew. Chem. Int. Ed. 2023, 62, e202212174

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2022

Efficient Dye Sensitized Solar Cells Based on a New Class of Doubly Concerted Companion Dyes

Jiazhi Zou a, Yuqing Wang a, Glib Baryshnikov b, Jiaxin Luo a, Xueyan Wang a, Hans Ågren c, Chengjie Li *a, Yongshu Xie *a

         ACS Appl. Mater. Interfaces 2022, 14, 29, 33274–33284       

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Chain Length Modulated Dimerization and Cyclization of Terminal Thienyl-Blocked Oligopyrranes

Yixing He,†,⊥ Bin Zhu,†,⊥ Qizhao Li,*,Glib Baryshnikov, Yu-Hui Fang,# Chengjie Li,Feng Sha, Xin-Yan Wu, Bing-Wu Wang,# Hans Ågren,§ and Yongshu Xie*,

        Org. Lett. 2022, 24, 29, 5428–5432

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  Efficient dye-sensitized solar cells based on concerted companion dyes: Systematic optimization of thiophene units in the organic dye components

Jiaxin Luo, Zhengli Xie, Jiazhi Zou, Xinyan Wu∗, Xueqing Gong∗, Chengjie Li∗,Yongshu Xie

       Chinese Chemical Letters  2022, 33, 4313–4316

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Efficient Solar Cells Sensitized by Organic Concerted Companion Dyes Suitable for Indoor Lamps

Xueyan Wang, Yuqing Wang, Jiazhi Zou, Jiaxin Luo, Chengjie Li,*and Yongshu Xie*

       ChemSusChem 2022, e202201116

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♦ Porphyrins containing a tetraphenylethylene-substituted phenothiazine donor for fabricating efficient dye sensitized solar cells with high photovoltages

Jiazhi Zou‡a,Yunyu Tang,‡b Glib Baryshnikov,c Zhen Yang,a Rui Mao,a Weifang Feng,a Jian Guan,a Chengjie Li*a and Yongshu Xie*a 

       J. Mater. Chem. A, 2022,10, 1320-1328 

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2021

♦ Novel anthracene-based organic dyes as co-sensitizers of porphyrins for developing efficient dye-sensitized solar cells

Yunyu Tang,‡a   Guangxin Yang,‡a   Xiaoyi Lou,a   Chengjie Li,b   Dongmei Huang* and  Yongshu Xie*b  

          New J. Chem., 2021,45, 21881-21887 

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♦ Confusion Approach Modulated Syntheses of Corrorin Parasitized Hexaphyrins(1.1.1.1.1.0) and the Oxidative Ring Cleavage Behavior

Yue Xu, Bin Zhu, Qizhao Li,* Glib Baryshnikov, Mingbo Zhou, Chengjie Li, Feng Sha, Xinyan Wu, Hans Ågren, Jianxin Song, and Yongshu Xie*

           Org. Lett. 2021, 23, 21, 8307–8311   

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Fluorenyl Indoline as an Efficient Electron Donor for Concerted Companion Dyes: Enhanced Light-Harvesting and Photocurrent

Yingying Chen,‡‡ Yunyu Tang,‡‡ Jiazhi Zou, Kaiwen Zeng, Glib Baryshnikov, Chengjie Li,*and Yongshu Xie*

        ACS Appl. Mater. Interfaces 2021, 13, 49828−49839

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♦ Solvent-regulated biomorphs from the intense π,π-mediated assemblies of tetracenequinone fused porphyrin 

Chen Chen,a  Dan Li,a   Guanyue Cao,a   Zhonghe Qin,b   Yi Xu,b   Xiujun Liu,*a   Qizhao Li,a  Yongshu Xiea  and  Chengjie Li  *a  

      CrystEngComm, 2021,23, 7565-7569 

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2020

♦ Twisted-Planar-Twisted expanded porphyrinoid dimer as a rudimentary reaction-based methanol indicator

Qizhao Li, Chengjie Li, Glib Baryshnikov, Yubin Ding, Chengxi Zhao, Tingting Gu, Feng Sha, Xu Liang, Weihua Zhu, Xinyan Wu, Hans Ågren, Jonathan L. Sessler and Yongshu Xie*

         Nat Commun11, 5289 (2020)

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♦ Optimization of porphyrin dyes with a bulky triphenylamine donor for developing efficient dye-sensitized solar cells

YunyuTangaYueqiangWangbQifanYanbKaiwenZengbWeiqiangTangcShuangliangZhaocdCongKongaYongshuXieb

       Dyes and Pigments,187, 2021, 109075

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♦ Light-Absorbing Pyridine Derivative as a New Electrolyte Additive for Developing Efficient Porphyrin Dye-Sensitized Solar Cells

Jiazhi Zou, Qifan Yan, Chengjie Li, Yunyue Lu, Zhangfa Tong, and Yongshu Xie*

      ACS Appl. Mater. Interfaces 2020, 12, 57017-57024

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♦ N-Confused Hexapyrrolic Phlorinoid with NIR Absorption: Synthesis, Fusion, Oxidation, and Copper(II) Coordination

Yu Du, Bin Zhu, Qizhao Li, Glib Baryshnikov, Chuanwan Wei, Yingwu Lin, Guangxian Su, Chengjie Li, Hans Ågren, and Yongshu Xie

        Org. Lett.2020, 22, 24, 9648–9652

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  ♦ Expanded N-Confused Phlorin: A Platform for a Multiply Fused Polycyclic Ring System via Oxidation within the Macrocycle

Chengjie Li, Qizhao Li, Jiewei Shao, Zhangfa Tong, Masatoshi Ishida, Glib Baryshnikov, Hans Ågren, Hiroyuki Furuta*, and Yongshu Xie*

       J. Am. Chem. Soc. 2020, 142, 40, 17195–17205

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♦ Functionalization of BODIPY with enamines and amines through one-step reactions with ethylamines

Guangxian Su, Kaiqi Zhang, Feng Sha, Zhangfa Tong, Jia Ni, Chengjie Li, Qizhao Li, Yu Du, Xiaoming Cao, Xin-Yan Wu, Yongshu Xie

       Dyes and Pigments, 180, 2020, 108504

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♦  Molecular engineering strategies for fabricating efficient porphyrin-based dye-sensitized solar cells

Kaiwen Zeng, Zhangfa Tong, Lin Ma, Wei-Hong Zhu,and Yongshu Xie*

       Energy Environ. SCI.,2020Advance Article

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♦ Efficient Solar Cells based on Concerted Companion Dyes Containing Two Complementary Components: An Alternative Approach for Cosensitization

Kaiwen Zeng, Yingying Chen,Wei-Hong Zhu,He Tian, and Yongshu Xie*

       J. Am. Chem. Soc., 2020, 142, 11, 5154-5161
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Tripyrrin-armed isosmaragdyrins: synthesis, heterodinuclear coordination, and protonation-triggered helical inversion

Chengjie Li, Kai Zhang, Masatoshi Ishida, Qizhao Li, Keito Shimomura, Glib Baryshnikov,  Xin Li, Mathew Savage,  Xin-Yan Wu, Sihai Yang, Hiroyuki Furuta*, and Yongshu Xie*

       Chem. Sci., 2020,11, 2790-2795
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♦ N‐Confused Phlorin‐Prodigiosin Chimera: meso‐Aryl Oxidation and π‐Extension Triggered by Peripheral Coordination

Guangxian Su, Qizhao Li, Masatoshi Ishida, Chengjie Li, Feng Sha, Xin-Yan Wu, Lu Wang, Glib Baryshnikov, Dawei Li, Hans Ågren,Hiroyuki Furuta*and Yongshu Xie*

    Angew. Chem. Int. Ed., 2020, 59(4), 1537-1541
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2019

♦ Regioselectively Halogenated Expanded Porphyrinoids as Building Blocks for Constructing Porphyrin-Porphyrinoid Hetero-Dyads with Tunable Energy Transfer

    Qizhao Li, Chengjie Li, Jinseok Kim, Masatoshi Ishida, Xin Li, Tingting Gu, Xu Liang, Weihua Zhu, Hans Ågren, Dongho Kim*, Hiroyuki Furuta*, and Yongshu Xie*
    J. Am. Chem. Soc., 2019, 141(13), 5294-5302
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♦ Skeletal Rearrangement of Twisted Thia‐Norhexaphyrin: Multiply Annulated Polypyrrolic Aromatic Macrocycles
     Qizhao Li, Masatoshi Ishida, Hiroto Kai, Tingting Gu, Chengjie Li, Xin Li, Glib Baryshnikov, Xu Liang,Weihua Zhu, Hans Ågren,  Hiroyuki Furuta* and Yongshu Xie*

     Angew. Chem. Int. Ed.2019, 58(18), 5925-5929
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♦ Efficient solar cells sensitized by a promising new type of porphyrins: dye-aggregation suppressed by double strapping

     Kaiwen Zeng, Yunyue Lu, Weiqiang Tang, Shuangliang Zhao,  Qingyun Liu, Weihong Zhu, He Tian, and Yongshu Xie*
     Chem. Sci., 2019,10, 2186-2192
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♦ Selective Photocatalysis Approach for Introducing ArS Units into BODIPYs through Thiyl Radicals

     Fangtao Ma, Li Zhou, Qingyun Liu, Chengjie Li*,and Yongshu Xie*
     Org. Lett., 2019, 21, 3, 733-736
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Multiply Wrapped Porphyrin Dyes with a Phenothiazine Donor: A High Efficiency of 11.7% Achieved through a Synergetic Coadsorption and  Cosensitization Approach

     Yunyue Lu, Heli Song, Hans Ågren,Qingyun Liu, Jiwei Zhang, Xuan Zhang*, and Yongshu Xie*
     ACS Appl. Mater. Interfaces, 2019, 11 (5), pp 5046–5054
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Solar Cells Sensitized with Porphyrin Dyes Containing Oligo(Ethylene Glycol) Units: a High Efficiency Beyond 12%

     Yunyue Lu, Qingyun Liu, Jiaxin Luo, Bo Wang, Tong Feng, Xiaoyi Zhou, Xinyu Liu, and Yongshu Xie*
     ChemSusChem, 2019, 12(12), 2802-2809 
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♦ Efficient solar cells based on cosensitizing porphyrin dyes containing a wrapped donor, a wrapped π-framework and a substituted benzothiadiazole unit

     Lu Yunyue, Cheng Yingchun,  Chengjie Li,Jiaxin Luo, Weiqiang Tang, Shuangliang Zhao, Qingyun Liu, and Xie Yongshu*
     SCIENCE CHINA Chemistry, 2019, 62, 994-1000
     
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2018

♦ Organic Sensitizers with Extended Conjugation Frameworks as Cosensitizers of Porphyrins for Developing Efficient Dye-Sensitized Solar Cells

     Yingchun Cheng, Guosheng Yang, Haoran Jiang, Shuangliang Zhao, Qingyun Liu, and Xie Yongshu*
     ACS Appl. Mater. Interfaces, 2018, 10 (45), pp 38880–38891
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2017

♦ Development of Ion Chemosensors Based on Porphyrin Analogues

     Yubin Ding, Wei-Hong Zhu, and Yongshu Xie*
     Chem. Rev., 2017, 117 (4), 2203-2256.
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♦ Neo-N-confused Phlorins and Phlorinone: Rational Synthesis and Tunable Properties

Jiahui Kong, Jiewei Shao, Chengjie Li*, Dongdong Qi, Minzhi Li, Xu Liang, Weihua Zhu, Jianzhuang Jiang, and Yongshu Xie*
Org. Lett., 2017, 19 (3), 650–653
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♦ An AIE and ICT based NIR florescent probe for cysteine and homocysteine
     Lulu Bu, Junqin Chen, Xiaodong Wei, Xin Li, Hans Ågren, Yongshu Xie*
     Dyes and Pigments, 2017, 136, 724-731.
    
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Full color emissions based on intramolecular charge transfer effect modulated by formyl and boron-dipyrromethene moieties
     Xiaodong Wei, Lulu Bu, Xin Li, Hans Ågren, Yongshu Xie*
     Dyes and Pigments,2017, 136, 480-487.
     
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2016

♦ Tetra- and Octapyrroles Synthesized from Confusion and Fusion Approaches
Jiahui Kong, Qiong Zhang, Mathew Savage, Minzhi Li, Xin Li, Sihai Yang, Xu Liang, Weihua Zhu, Hans Ågren, and Yongshu Xie*
Org. Lett., 2016, 18 (19), 5046–5049.
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♦ Macrocyclic Transformations from Norrole to Isonorrole and an N-Confused Corrole with a Fused Hexacyclic Ring  Triggered by a Pyrrole
     Substituent
     Miao Li, Pingchun Wei, Masatoshi Ishida, Xin Li, Mathew Savage, Rui Guo, Zhongping Ou, Sihai Yang, Hiroyuki Furuta,* 
     and Yongshu Xie*
     Angew. Chem. Int. Ed., 2016
, 55(9), 3063-3067.
     
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♦ Rational Syntheses of Helical p-Conjugated Oligopyrrins with a Bipyrrole Linkage: Geometry Control of Bis-Copper(II) Coordination
     Kai Zhang, Mathew Savage, Xin Li, Yu Jiang, Masatoshi Ishida, KokiMitsuno, Satoru Karasawa, Tatsuhisa Kato, Weihua Zhu, 
     Sihai Yang, Hiroyuki Furuta, and 
Yongshu Xie*
     Chem. Commun., 2016
, 52, 5148 – 5151.
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♦ Unprecedentedly targeted customization ofmolecular energy levels with auxiliary-groups inorganic solar cell sensitizers
     Yongshu Xie,Wenjun Wu,Haibo Zhu, Jingchuan Liu, Weiwei Zhang, He Tianand Wei-Hong Zhu*
     Chem. Sci., 2016,7, 544-549.
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♦ Structural Variation in Surface-Supported Synthesisby Adjusting the Stoichiometric Ratio of the Reactants 
     Zhongmiao Gong, Biao Yang, Haiping Lin, Yunyu Tang, Zeyuan Tang, Junjie Zhang, Haiming Zhang, Youyong Li, Yongshu Xie, Qing Li,* and Lifeng Chi*
     ACS Nano, 2016, 10, 42284235.
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2015

♦ Fluorescent and Colorimetric Ion Probes Based on Conjugated Oligopyrroles
     Yubin Ding,Yunyu Tang,Weihong Zhu,and Yongshu Xie*
     Chem. Soc. Rev., 2015, 44 (5), 1101-1112.
    
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♦ Porphyrin Cosensitization for a Photovoltaic Efficiency of 11.5%: a Record for Non-Ruthenium Solar Cells Based on Iodine Electrolyte
     Yongshu Xie*, YunyuTang, Wenjun Wu, Yueqiang Wang, Jingchuan Liu, Xin Li, He Tian, and Wei-Hong Zhu*
     J. Am. Chem. Soc., 2015, 137(44), 14055–14058.
    
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♦ Far-Red and Near-IR AIE-Active Fluorescent Organic Nanoprobes with Enhanced Tumor-Targeting Efficacy: Shape-Specific Effects
     Andong Shao, Yongshu Xie, Shaojia Zhu, Zhiqian Guo,* Shiqin Zhu, Jin Guo, Ping Shi, Tony D.James, He Tian, and Wei-Hong Zhu*
    Angew. Chem. Int. Ed., 2015, 54(25)7275-7280.
    
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♦ Synthesis of a Neo-Confused Octaphyrin and the Formation of ItsMononuclear Complexes
     Kai Zhang,Junda Zhang,Xin Li,Rui Guo,Hans Ågren,Zhongping Ou,Masatoshi Ishida,Hiroyuki Furuta,*and Yongshu Xie*
     Org. Lett. 2015, 17, 4806−4809;
    
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♦ Porphyrins containing a triphenylamine donor and up to eight alkoxychains for dye-sensitized solar cells: a high efficiency of 10.9%
     Yunyu Tang, Yueqiang Wang, Xin Li, Hans Ågren, Wei-Hong Zhu, and Yongshu Xie*
     ACS Appl. Mater. Interfaces, 20157(50), 27976-27985.
    
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♦ Systematic Investigations on the Roles of the Electron Acceptor andNeighboring Ethynylene Moiety in Porphyrins for Dye-SensitizedSolar Cells
      Tiantian
Wei, Xi Sun, Xin Li*, Hans Ågren, and Yongshu Xie*
     ACS Appl. Mater. Interfaces, 2015, 7, 21956 − 21965.
     
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♦ Multicolor Emissions by the Synergism of Intra / Intermolecular Slipped π-π Stackings of Tetraphenylethylene-DiBODIPY conjugate 
     Hai-Tao Feng, Jia-Bin Xiong, Yan-Song Zheng,*, Biao Pan, Chun Zhang,*,Lei Wang, and Yongshu Xie
     Chem. Mater.,2015,27, 7812-7819.
    
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♦ Enantiospecific photoresponse of sterically hindered diarylethenes for chiroptical switches and photomemories
     Wenlong Li, Xin Li, Yongshu Xie, Yue Wu, Mengqi Li, Xin-Yan Wu, Wei-Hong Zhu*, He Tian
     Scientific Reports, 2015, 509186.
    
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♦ Acylation of Dipyrromethanes at the α and β Positionsand Further Development of Fluorescent Zn2+ Probes
     Yunyu Tang, Yubin Ding, Xin Li, Hans Ågren, Tong, Li, Yongshu Xie*
     Sensors and Actuators B: Chemical2015, 206, 291–302.
     
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♦ Concentration-Controlled Reversible Phase Transitions in Self-Assembled Monolayers on HOPG Surfaces
     Xueli Shen,Xiaodong Wei,Pengli Tan,Yingguo Yu,Biao Yang,Zhongmiao Gong,Haiming Zhang,Haiping Lin,Youyong Li,Qing Li,*Yongshu Xie*,Lifeng Chi*
     Small, 2015,11(19), 2284-2290.
    
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♦ Modulation of Photovoltaic Behaviour of Dye-sensitized Solar Cells by Electron Donors of  Porphyrin Dyes and Cosensitization
     Bin Chen, Lu Sun, Yongshu Xie*
     Chin. Chem. Lett.2015, 26, 899-904.
     
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♦ Highly efficient cosensitization of D–A–p–A benzotriazole organic dyes with porphyrin for panchromatic dye-sensitized solar cells
     Jingchuan Liu, Bo Liu, Yunyu Tang, Weiwei Zhang, Wenjun Wu, Yongshu Xie and Wei-Hong Zhu*
     J. Mater. Chem. C, 2015, 3, 11144-11150
     
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2014

♦ Efficient Solar Cells Sensitized by Porphyrins with an Extended Conjugation Framework and a Carbazole Donor: from molecular Design to Cosensitization 
     Yueqiang Wang, Bin Chen, Wenjun Wu, Xin Li, Weihong Zhu, He Tian and Yongshu Xie*
     Angew. Chem. Int. Ed., 2014, 53(40), 10779–10783.
    
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♦ Neo-Fused Hexaphyrin: A Molecular Puzzle Containing an N-Linked Pentaphyrin
     Pingchun Wei, Kai Zhang, Xin Li, Deying Meng, Hans Ågren, Zhongping Ou, Seikweng Ng, Hiroyuki Furuta*, and Yongshu Xie*
     Angew. Chem. Int. Ed., 2014, 53(51)1406914073.
    
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♦ Reversible photoswitching specifically responds tomercury(II) ions: the gated photochromism of bis(dithiazole)ethane

Yue Wu, Weihong Zhu*, Wei Wan, Yongshu Xie, He Tian and Alexander D. Q. Li*

Chem. Commun.2014, 50, 14205-14208.

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♦ Cosensitizers for simultaneous filling up of both absorption valleys of porphyrins: a novel approach for developing efficient panchromatic dye-sensitized solar cells

Xi Sun, Yueqiang Wang, Xin Li, Wenjun Wu, Hans Ågren, Weihong Zhu, He Tian, and Yongshu Xie*

Chem. Commun., 2014 (98),50, 15609 - 15612.

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♦ Oxidative Ring Closure and Metal Triggered Ring Opening: Syntheses of Macrocyclic and Linear Hexapyrroles

Kai Zhang, Pingchun Wei, Xin Li, Hans Ågren, Yongshu Xie*

Org. Lett.,2014, 16(24), 6354–6357.

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♦ Quantitative Photoswitching in Bis(dithiazole)ethene Enables Modulation of Light for Encoding Optical Signals

Yue Wu, Yongshu Xie, Qiong Zhang, He Tian, Weihong Zhu,* and Alexander D. Q. Li*

Angew. Chem. Int. Ed., 2014, 53 (8), 2090–2094.

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♦ Separation of Photoactive Conformers Based on Hindered Diarylethenes: Efficient Modulation in Photocyclization Quantum Yields

Wenlong Li,Changhong Jiao, Xin Li,Yongshu Xie,Keitaro Nakatani,He TianWeihong Zhu*

Angew. Chem. Int. Ed., 2014,53, 4603-4607.

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♦ Coordination polymers of a multipyridyl and pyrazolylligand with conformational flexibility: syntheses, structures and luminescence

Caixia Ding, Xing Rui, Cheng Wang, Yongshu Xie*

Cryst. Eng. Comm., 201416 (6), 1010 – 1019.

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♦ Syntheses of mono- and diacylated bipyrroles with rich substitutionmodes and development of a prodigiosin derivative as a fluorescent Zn(II) probe

Tao Hong, Heli Song, Xin Li, Weibing Zhang and FigureYongshu Xie*

RSC Adv., 2014, 4 (12), 6133 – 6140.

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♦ A novel trigeminal zinc porphyrin and corresponding porphyrin monomers for dye-sensitized solar cells

Bin Chen, Xin Li, Wenjun Wu, Quanzheng Zha, Yongshu Xie*

RSC Adv.,2014, 4, 10439-10449.

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♦ Unexpected but convenient synthesis of solublemeso-tetrakis(3,4-benzoquinone)-substituted porphyrins

Jonathan P. Hill,* Wim Van Rossom, Shinsuke Ishihara, Navaneetha Subbaiyan, Francis D'Souza,* Yongshu Xie, Noelia M. Sanchez-Ballester, Katsuhiko Ariga

J. Porhyrins Phthalocyan.2014, 18(3), 173-181.

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♦ Acceptor-Acceptor Conjugated Copolymers based on Perylenediimide and Benzothiadiazole for All-Polymer Solar Cells

Congwu Ge, Chongyu Mei, Jun Ling, Jintu Wang, Fugang Zhao, Long Liang, Hongjiao Li, Yongshu Xie,* Weishi Li*

J. Polym. Sci., A2014,52, 1200-1215.

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♦ TICT based Fluorescence “turn-on” hydrazine probes

Bin Chen, Xi Sun, Xin Li, Hans Ågren, Yongshu Xie*

Sensors and Actuators B: Chemical, 2014, 199, 93-100.

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♦ 2-Diphenylaminothiophene as the donor of porphyrin sensitizers for dye-sensitized solar cells

Yueqiang Wang, Lu Xu, Xiaodong Wei, Xin Li, Hans Ågren, Wenjun Wu, Yongshu Xie*

New J. Chem., 2014, 38(7), 3227-3235.  

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♦ Diketopyrrolopyrrole-based Acceptor-Acceptor Conjugated Polymers: The Importance of Comonomer on Their Charge Transportation Nature 

Congwu Ge, Chongyu Mei, Jun Ling, Fugang Zhao,Hongjiao Li, Long Liang, Jintu Wang, Jincheng Yu, Wei Shao, Yongshu Xie*, Weishi Li*

J. Polym. Sci., A2014,52(16), 2356–2366.

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♦ Recent Advances in the Design Strategies for Porphyrin-based Coordination Polymers 

Quanzheng Zha, Xing Rui, Tiantian Wei and Yongshu Xie*

CrystEngComm, 2014, 16(32), 7371–7384.

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♦ Acid-Base Switching of Tautomerism in a Dioxoporphyrin as an Intelligent Transformer for Binary Subtraction

Yubin Ding, Xin Li, Jonathan P. Hill, KatsuhikoAriga, Hans Ågren, Joakim Andréasson, Weihong Zhu, He Tian, Yongshu Xie*

Chem. Eur.J., 2014, 20, 12910–12916.

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♦ Syntheses and crystal structures of coordination polymers of a porphyrin ligand bearing two pyridyl and twocarboxyl moieties

Xing Rui, Quanzheng Zha, Tiantian Wei, Yongshu Xie*

Inorg. Chem. Commun., 201448, 111-113.

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2013

♦ From nonconjugationto conjugation: novel meso-OHsubstituted dipyrromethanes as fluorescence turn-on Zn2+probes

Yubin Ding, Tong Li, Xin Li, Weihong Zhu and Yongshu Xie*

Org. Biomol. Chem., 2013, 11 (16),2685 – 2692.

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♦ Self-Assembly Solid-State Enhanced Red Emission of Quinolinemalononitrile: Optical Wave guides and Stimuli Response

CX. Shi, ZQ. Guo, YL. Yan, SQ. Zhu, Y. S. Xie, YS. Zhao,* WH. Zhu,* H. Tian

ACS Appl. Mater.  Interfaces, 2013,5192-198.

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♦ Syntheses and structures of tetranuclear Zn(II) complexes with in situ generated macrocyclic Schiff base ligands: Applications in Zn2+ sensing

Caixia Ding, Changhua He, Yongshu Xie*

Chin. Chem. Lett., 2013, 24 (6), 463-466

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♦ Controlling Porphyrin Nano Architectures at Solid Interfaces
     Jonathan P. Hill,* Yongshu XieMisaho Akada,Yutaka Wakayama, Lok Kumar Shrestha, Qingmin Ji, Katsuhiko Ariga
     Langmuir, 2013,29(24), 7291-7299
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♦ Tailoring zinc porphyrin to the Ag nanostructure substrate: an effective approach for photoelectrochemical studies in the presence of mononucleotides

Farkhondeh Fathi, Cong Kong, Yueqiang Wang, Yongshu Xie, Yi-Tao Long, and Heinz-Bernhard Kraatz*

Analyst, 2013,138(12), 3380-3387

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♦ Polynuclear Complexes with Alkoxo and Phenoxo Bridges from in situ generated Hydroxy-rich Schiff Base Ligands: Syntheses, Structures and Magnetic Properties

Caixia Ding, Chen Gao, Seikweng Ng, Bingwu Wang,* Yongshu Xie*

Chem. Eur. J., 201319 (30), 9961–9972

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♦ α-Monoacylated, α-, α'- and α-, β'- diacylated dipyrrins as highly sensitive fluorescence “turn-on” Zn2+ probes
      Yubin Ding, Xin Li, Tong Li, Weihong Zhu, Yongshu Xie*
      J. Org. Chem., 2013, 78, 5328−5338.
     
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♦ Porphyrins bearing long alkoxyl chains andcarbazolefor dye-sensitized solar cells: tuning cell performance through an ethynylenebridge

Yueqiang Wang, XinLi, Bo Liu, Wenjun Wu, Weihong Zhu,Yongshu Xie*

RSC Adv., 2013, 3(34), 14780 – 14790.

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♦ Syntheses, Structures, and Photoluminescence of Zn(II), Ag(I), Cu(I) and Co(II) Coordination Polymers of a Tetrapyridyl Ligand

Yunyu Tang, Caixia Ding, Seikweng Ng, Yongshu Xie*

RSC Adv., 2013, 3 (39), 18134 –18141.

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♦ Steric hindrance enforced distortion as a general strategy for design of fluorescence “turn-on” cyanide probes

Bin Chen, Yubin Ding, Xin Li, Weihong Zhu, Jonathan P Hill, Katsuhiko Ariga and Yongshu Xie*

Chem. Commun.,2013, 49, 10136-10138.

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Novel Porphyrin Based Ligand Containing Four 4,4'-Dipyridylamine Moieties:Syntheses, Structures, and Luminescent Properties of  Mn(II), Cu(II), Zn(II), and Cd(II) Coordination Polymers
     Quanzheng Zha, Caixia Ding, Xing Rui, Yongshu Xie*
     Cryst. Growth Des.2013, 13 (10), 4583–4590.
     
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♦ Full-colour luminescent compounds based on anthracene and 2,2-dipyridylamine

Bin Chen, Gang Yu, Xin Li, Yubin Ding, Cheng Wang, Zhiwei Liu, and Yongshu Xie*

J. Mater. Chem. C, 2013, 1(44), 7409–7417
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♦ Macrocycle contraction and expansion of a dihydro-sapphyrin isomer

Yongshu Xie*, Pingchun Wei, Xin Li, Tao Hong, Kai Zhang, and Hiroyuki Furuta*

J. Am. Chem. Soc., 2013, 135(51),19119−19122.
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2012

♦ A novel gatedphotochromic reactivity controlled by complexation/ dissociation with BF3

Yue Wu, Shangjun Chen,Yuheng Yang, Qiong Zhang, Yongshu Xie, He Tian, Weihong Zhu*

Chem. Commun.2012,  48, 528-530

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♦ Modulation of energy levels by donors groups: an effective approach for optimizing the efficiency of Zinc-porphyrin based solar cells

Bo Liu, Weihong Zhu, Yueqiang Wang, Wenjun Wu, Xin Li, Baoqin Chen,Yi-Tao Long and Yongshu Xie*

J. Mater. Chem., 2012, 22, 7434-7444

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♦ Polynuclear complexes of ligands containing in situ formed oxazinane and oxazolidine rings with appended alkoxyl and phenol groups

Caixia Ding, Fanhua Zeng, Jia Ni, Bingwu Wang, Yongshu Xie*

Cryst. Growth Des.,2012,12(4), 2089–2096

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♦ Antioxidant-substituted tetrapyrazinoporphyrazine as a fluorescent sensor for basic anions

Jonathan P. Hill,*NavaneethaK.Subbaiyan,Francis D’Souza,*YongshuXie*,SatyajitSahu,Noelia M.Sanchez-Ballester,Gary J. Richards,Toshiyuki Mori andKatsuhiko Ariga

Chem. Commun., 2012, 48, 3951-3953.

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♦ Highly selective colorimetric sensing of cyanidebased on formation of dipyrrin adducts

Yubin Ding, Tong Li, Weihong Zhu,*and Yongshu Xie*

Org. Biomol. Chem.2012, 10(21), 4201- 4207.

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♦ A Binuclear Cu(II) Complex of a Schiff Base Type Polyhydroxyl Ligand with A symmetrical Phenoxo and Methoxo Bridges:  Crystal Structure and Magnetic Properties

Fanhua Zeng,Jia Ni, Caixia Ding, Yongshu Xie*

J. Coord. Chem., 2012, 65(13), 2247–2255

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♦ A Novel Bis(4,4¢-dipyridylamine) Ligand with a Flexible Butadiyne Linker:Syntheses, Structures, and Photoluminescence  ofd10 Metal Coordination Polymers

Caixia Ding,Xing Li,Yubin Ding,Xin Li,Seik Weng Ng,Yongshu Xie*

Cryst. Growth Des.201212(7),3465-3473.

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♦ Mono-, Tetra- and Octanuclear transition metal Complexes of in Situ Generated Schiff Base Ligands containing up to 12 coordinating atoms: Syntheses, Structures and Magnetism

Caixia Ding,Jia Ni, Yuhua Yang,SeikwengNg,Bingwu WangYongshu Xie

CrystEngComm,201214(21), 7312-7319.

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♦ Aromaticity-Controlled Thermal Stability of Photochromic Systems Based on a Six-Membered Ring as Ethene Bridges:  Photochemical and Kinetic Studies

Yuheng Yang, Yongshu Xie, Qiong Zhang, Keitaro Nakatani, He Tian, and Weihong Zhu*

Chem. Eur. J. 201218, 11685-11694

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♦ Selective, sensitive and reversible “turn-on” fluorescent cyanide probes based on 2,2’-dipyridylaminoanthracene-Cu2+ensembles

Yongshu Xie*, Yubin Ding, Xin Li, Cheng Wang, Jonathan P. Hill,* Katsuhiko Ariga, Weibing Zhang, and Weihong Zhu

Chem. Commun., 2012, 48 (94), 11513 – 11515.

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2011

♦ Real time self-assembly and reassembly of molecular nanowires of trigeminal amphiphile porphyrins

Yongshu Xie*J. P. Hill, M. Akada,Q. M. Ji, R.Charvet, K. Ariga*

Chem. Commun., 201147(8), 2285-2287

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♦ A zipper-like double chain coordination polymer constructed from a novel pseudo-macrocyclic binuclear Cu(II) complex

Caixia Ding, Jia Ni, Changhua He, Fanhua Zeng, Weihong Zhu, Yongshu Xie*

Inorg. Chem. Commun.2011, 14(2), 370-373

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♦ Selective and sensitive "turn-on'' fluorescent Zn2+sensors based on di- and tripyrrins with readily modulated emission wavelengths

Yubin Ding, Yongshu Xie,* XinLi, Jonathan P. Hill,* Weibing Zhang, Weihong Zhu
Chem. Commun.
, 2011, 47 (19), 5431–5433
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♦ Absorption and photovoltaic properties of organicsolar cell sensitizers containing fluorene unit as conjunction bridge

Wenqin Li, Yongzhen Wu, XinLi, Yongshu Xie and Weihong Zhu*

Energy Environ. Sci., 2011, 4 (5), 1830 - 1837.

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♦ Novel dyes based on naphthalimide moiety as electron acceptor for efficient dye-sensitized solar cells

Xiaomei Huang, Yi Fang,* Xin Li, Yongshu Xie, Weihong Zhu

Dyes and Pigments,  2011,  90,  297-303.

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♦ (二吡啶胺)配体的二维和三维配位超分子研究

丁彩霞曾凡花汪成倪佳伍锡荣解永树*

高等学校化学学报,2011,32(9)2204-2209.
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♦ Ytterbium pentafluorobenzoate as a novel fluorous Lewis acid catalyst in the synthesis of 2,4-disubstituted quinolines

Jun Tang, Limin Wang,* Dan Mao, Wenbo Wang, Liang Zhang, Shengying Wu, Yongshu Xie

Tetrahedron,2011, 67 (44), 8465-8469.
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♦ 基于DPA识别基团的锌离子荧光传感器

丁煜宾朱为宏,解永树*

化学进201123(12)2478-2488.

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♦ Unprecedented Stability of a Photochromic Bisthienylethene Based on Benzobisthiadiazole as an Ethene Bridge

Weihong Zhu*, Yuheng Yang, RémiMétivier, Qiong Zhang, Régis Guillot, Yongshu Xie, He Tian, Keitaro Nakatani*

Angew.Chem. Int. Ed.201150, 10986–10990

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♦ Color-Tunable Solid-State Emission of 2,2'-Biindenyl-Based Fluorophores

Zhiyun Zhang, Bo Xu,Jianhua Su, Leiping Shen, Yongshu Xie, He Tian*

Angew. Chem. Int. Ed.,2011,50 (49), 11654-11657.

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2010

♦ Bisthienylethenes Containing 2,1,3-Benzothiadiazole Unit as Ethene Bridge: Parallel Conformation in Crystal Phase and Photochromic  Performance Controlled by Substitution Position

Weihong Zhu,* Yuheng Yang, Xianle Meng, QiongZhang, Yongshu Xie, and He Tian*

Chem. Eur. J.,2010, 16, 899906.

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♦ Synthesis, Structures, and Photoluminescence of Zinc(II), Cadmium(II) and Mercury(II) Coordination Polymers Constructed  from Two Novel Tetrapyridyl Ligands

Fanhua Zeng, Jia Ni, Quanguo Wang, Yubin Ding, Seik Weng Ng, Weihong Zhu, Yongshu Xie*

Crystal Growth & Design, 2010, 10, 1611-1622.
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♦ Colorimetric fluoridesensors based on deprotonation of pyrrole-hemiquinone compounds

QuanguoWang,Yongshu Xie,*Yubin Ding,Xin LiWeihong Zhu*

Chem. Commun.,2010, 46, 3669 - 3671

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♦ triple chain coordination polymerconstructed from ZnTPP and a bis(4,4'-dipyridylamine) ligand

QuanguoWang,Yongshu Xie,*Fan-Hua Zeng, Seik-Weng Ng,Wei-Hong Zhu

Inorg. Chem. Commun., 2010, 13, 929-931.

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♦ Hydrothermal Synthesis and Crystal Structure of ZnTPP Axially Coordinated with a Novel Dipyridylamine Ligand

QuanguoWang,Seik Weng Ng, Weihong Zhu,Yongshu Xie*

Chin.J. Struct. Chem.,2010, 29, 1197-1200

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♦ Near-IR Core-Substituted Naphthalenediimide Fluorescent Chemosensors for Zinc Ions: Ligand Effects on PET and ICT Channels

Xinyu Lu, Weihong Zhu,* Yongshu Xie, Xin Li, YuanGao, Fuyou Li, He Tian*

Chem. Eur. J., 201016(28),8355–8364

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2009

♦ Tetra- and Binuclear Complexes of Hydroxy-rich Ligands - Supramolecular Structures, Stabilization of Unusual Water Clusters, and  Magnetic Properties

Yongshu Xie,* Jia Ni, Fakun Zheng, Yong Cui, Quanguo Wang, Seik Weng Ng, Weihong Zhu*

Crystal Growth & Design, 2009, 9, 118-126

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♦ Conveniently synthesized isophorone dyes for high efficiency dye-sensitized solar cells: tuning photovoltaic performance by structural  modification of donor group indonor–π–acceptorsystem

Bo Liu, Weihong Zhu,* Qiong Zhang, Wenjun Wu, MinXu, Zhijun Ning, Yongshu Xie, He Tian,* 

Chem. Commun., 2009, (13)1766-1768

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♦ Triply N-Confused Hexaphyrins: Near-Infrared LuminescentDyes with a Triangular Shape

Yongshu Xie, Keisuke Yamaguchi, Motoki Toganoh, Hidemitsu Uno, Masaaki Suzuki,Shigeki Mori, Shohei Saito, Atsuhiro Osuka,* Hiroyuki Furuta*
Angew. Chem. Int. Ed.,
200948(30)5496-5499
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♦ 异卟啉研究进展

王全国曾凡花解永树,* 朱为宏

化学进展,2009, 21(7/8), 1523-1533.

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♦ Anion-Complexation-Induced Stabilization of Charge Separation

Francis D’Souza,* Navaneetha K.Subbaiyan, Yongshu Xie, Jonathan P. Hill, Katsuhiko Ariga, Kei Ohkubo, and Shunichi Fukuzumi*

J. Am. Chem. Soc., 2009, 131(44), 16138-16146.

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2008

♦ Intramolecular Charge-Transfer Process Based on Dicyanomethylene-4H-pyran Derivative: An Integrated Operation of Half-Subtractor and Comparator

Zhiqian Guo, Ping Zhao, Weihong Zhu, Xiaomei Huang, Yongshu Xie, and He Tian*

J. Phys. Chem. C., 2008112, 7047-7053.

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♦ Twisted, Two-Faced Porphyrins as Hosts for Bispyridyl Fullerenes:Construction and Photophysical Properties

Yongshu Xie, Jonathan P. Hill,*Amy LeaSchumacher, Atula S. D. Sandanayaka, Yasuyuki Araki, Paul A. Karr, Jan Labuta,Francis D’Souza, Osamu Ito, Christopher E. Anson, Annie K. Powell and Katsuhiko Ariga*

J. Phys. Chem. C, 2008, 112, 10559-10572.
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♦ A colorimetric and fluorescent turn-on sensor for pyrophosphate anion based on a dicyanomethylene-4H- chromene framework

Xiaomei Huang, Zhiqian Guo, Weihong Zhu,* Yongshu Xie, He Tian*

Chem. Commun., 2008, 5143–5145.

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2007

♦ Crystal structure and magnetic properties of a 1D mono-m1,3 -NCS- bridged Ni(II) chain complex with N-1,N-3-bis(4-methoxylbenzyl)-diethylenetriamine

   Yongshu Xie, Jonathan P. Hill*, Amy Lea Schumacher, Atula S. D. Sandanayaka, Yasuyuki Araki, Paul A. Karr, Jan Labuta, Francis D’Souza,* Osamu Ito*, Christopher E. Anson, Annie K. Powell, Katsuhiko Ariga.

Synth. React. Inorg. Metal-Org. Nano-Metal Chem., 2007, 37, 301-305.

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♦ Solvent-induced 1-and 2-DCd(II) coordination polymers based on a bent polypyridyl ligand

Kaiju Wei, jia Ni, Yongshu Xie, Qingliang Liu*

Inorg. Chem. Commun.,2007, 10, 279-282.

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♦ Self-assembled hetero-bimetallic coordination cage and cation-clusters with mu(2)-Cl bridgingusing a flexible two-arm ferrocene amide linker

Kaiju Wei, jia Ni, Yongshu Xie, Yangzhong Liu,* Qingliang Liu*

Dalton Trans., 2007, 3390-3397.

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♦ Porphyrin ColorimetricIndicators in Molecular and Nano-Architectures

Yongshu Xie, J. P.Hill,* R. Charvet, K. Ariga

J. Nanosci. Nanotechnol., 2007, 7, 2969-2993.

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♦ Synthesis and crystalstructures of two mixed-ligand Cu(II) complexes of tripyridyldiamine

Min Zhang, Jia Ni, Yongshu Xie,*

J. coord. Chem., 200760, 1173-1182

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♦ TautomerisminNovelOxocorrologens

Yongshu Xie,Jonathan P. Hill,* Amy LeaSchumacher, Paul A. Karr,Francis D’Souza*,Christopher E. Anson, Annie K.Powell,and KatsuhikoAriga

Chem. Eur. J., 2007, 13,9824-9833.

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2006

♦ Synthesis and structure of bis[2,6-bis(2-pyridylamino)pyridinium] tetrachlorocadmiumate(II)

Min Zhang, Yongshu Xie,*Kaiju Wei, Qingliang Liu,* Shieming Peng

Chin. J. Struct. Chem.,2006, 25 (6), 714-718.

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♦ Self-assembly of a 3-D porous solid based on a1-D Ag(I) coordination polymer

Kaiju Wei, Yongshu Xie,*  Jia Ni, Min Zhang, Qingliang Liu*

Inorg. Chem. Commun., 2006, 9(9), 926-930.

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♦ Syntheses, crystal structures, and photoluminescent properties of a series of M(II) coordination polymerscontaining M-X-2-M bridges: From 1-D chains to 2-D networks

Kaiju Wei, Yongshu Xie,* Jia Ni, Min Zhang, Qingliang Liu*

Cryst. Growth & Des., 2006, 6(6), 1341-1350.

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♦ SnIV complexes of N-confused porphyrins and oxoporphyrins - Unique fluorescence "Switch-On" halide receptors

Yongshu Xie, Tatsuki Morimoto, Hiroyuki Furuta*

Angew. Chem. Int. Ed., 2006, 45(41), 6907-6910.

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授权国际专利两项:

  1. YongshuXie, Monomers, Oligomeric complexes, coordination polymers, and methods for their preparation and use, 美国发明专利,申请号:13/030344, 申请日期 2011 年 2 月18 日;公开号:US2012/0214962 A1,公开日期:2012  8  23 日;授权号:US 8653230 B2授权日期:2014  2  18 日;

  

  1. Yongshu Xie, Bin Chen, Cheng Wang, Yubin Ding, Novel luminescent materials, 国际发明专利,申请号:PCT/CN2012/082984,申请日期:2012  10  15 日,公开号: WO 2014/ 059586A1公开日期:2014  4  24 授权号:US 9410081 B2授权日期: 201689