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刘吉人 博士    

求学经历

2013.9~2017.6 中国科学技术大学 学士

2017.9~2022.6 浙江大学 硕博连读

研究方向

自由基化学 不对称催化 金属有机化学

联系方式

nitrolexus@zju.edu.cn 1520135343@qq.com

研究成果

As first author and co-first author

Liu, J. –R.; Duan, Y. –Q.; Zhang, S. –Q.; Zhu, L. –J.; Jiang, Y. –Y.; Bi, S.; Hong, X., C–H Acidity and Arene Nucleophilicity as Orthogonal Control of Chemoselectivity in Dual C–H Bond Activation. Org. Lett. 2019, 21, 2360.

Xing, L.; Liu, J. -R.; Hong, X.; Houk, K. N.; Luscombe, C. An Exception to the Carothers Equation Caused by the Accelerated Chain Extension in a Pd/Ag Cocatalyzed Cross Dehydrogenative Coupling Polymerization. J. Am. Chem. Soc. 2022, Accepted. (as co–first author)

Wang, F. -L.; Yang, C. -J.; Liu, J. -R.; Yang, N. -Y.; Dong, X. -Y.; Jiang, R. -Q.; Chang, X. -Y.; Li, Z. -L.; Xu, G. -X.; Yuan, D. -L.; Zhang, Y. -S.; Gu, Q. –S.; Hong, X.; Liu, X. –Y. Mechanism-based Ligand Design for Copper-catalysed Enantioconvergent C(sp3)–C(sp) Cross-coupling of Tertiary Electrophiles with Alkynes. Nat. Chem. 2022, Accepted (as co–first author)

Cheng, Y. –F. ; Liu, J. –R.; Gu, Q. –S.; Yu, Z. –L.; Wang, J.; Li, Z. –L.; Bian, J. –Q.; Wen, H. –T.; Wang, X. –J.; Hong, X.; Liu, X. –Y.; Catalytic Enantioselective Desymmetric Functionalization of Alkyl Radicals via Cu(I)/CPA Cooperative Catalysis. Nat. Catal. 2020, 3, 401. (as co–first author)

Lin, J. –S.; Li, T. –T.; Liu, J. –R.; Jiao, G. –Y.; Gu, Q. –S.; Cheng, J. –T.; Guo, Y. –L.; Hong, X.; Liu, X. –Y., Cu/Chiral Phosphoric Acid-Catalyzed Asymmetric Three-Component Radical-Initiated 1,2-Dicarbofunctionalization of Alkenes. J. Am. Chem. Soc. 2019, 141, 1074. (as co–first author)

Others

Zhang, Y. –Q.; Chen, Y. –B.; Liu, J. –R.; Wu, S. –Q.; Fan, X. –Y.; Zhang, Z. –X.; Hong, X.; Ye, L. –W., Asymmetric Dearomatization Catalysed by Chiral Brønsted Acids via Activation of Ynamides Nat. Chem. 2021, 13, 1093.

Chen, X. –R.; Zhang, S. –Q.; Meyer, T. H.; Yang, C. –H.; Zhang, Q. –H.; Liu, J. –R.; Xu, H. –J.; Cao, F. –H.; Ackermann, L.; Hong, X., Carboxylate Breaks the Arene C–H Bond via a Hydrogen–atom–transfer Mechanism in Electrochemical Cobalt Catalysis  Chem. Sci. 2020, 11, 5790.

Lei, Y.; Shen, L.; Liu, J. –R.; Jiao, T.; Zhang, Y.; Zhang, C.; Tong, L.; Hong, X.; Pan, Y.; Li, H., A Diquat-containing Macrocyclic Anion Acceptor in Pure Water. Chem. Commun. 2019, 55, 8297.

Zheng, X.; Zhang, Y.; Wu, G.; Liu, J. –R.; Cao, N.; Wang, L.; Wang, Y.; Li, X.; Hong, X.;  Yang, C.; Li, H., Temperature-dependent Self-assembly of a Purely Organic Cage in Water. Chem. Commun. 2018, 54, 3138.

Xu, Z. –Y.; Zhang, S. –Q.; Liu, J. –R.; Chen, P. –P.; Li, X.; Yu, H. –Z.; Hong, X.; Fu, Y., Mechanism and Origins of Chemo- and Regioselectivities of Pd–Catalyzed Intermolecular σ–Bond Exchange between Benzocyclobutenones and Silacyclobutanes: A Computational Study. Organometallics 2018, 37, 592.

2019年度浙江省化学会创新奖

2019学年优秀研究生

2019学年新和成奖学金(硕)

“TCI杯 - 浙江大学化学系-高分子系科研成果展PosterShow”优秀奖