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Oxygen Atom from Carbonyl Group as an Important Binding Agent to the G‐Quadruplex – Study Case of Flavonoids ChemPlusChem (IF 3.4) Pub Date : 2024-05-07 Olga Stężycka, Małgorzata Kasperkowiak, Magdalena Frańska, Damian Nowak, Marcin Hoffmann
In the field of anticancer therapy study it is of great interest to find effective G‐quadruplex ligands which may be of potential use in medical treatment or cancer prevention. Since among the compounds of natural origin, flavonoids have attracted notable attention because of their unique properties and promising therapeutic applications, an interesting question was to identify the flavonoid structural
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Computational and Spectroscopic Studies on the Formation of Halogen‐Bonded Complexes Between Tertiary Amines and CBr4 and Application in the Light‐mediated Amino Acid Coupling ChemPlusChem (IF 3.4) Pub Date : 2024-05-07 E. Alexandros Routsi, Christiana Mantzourani, Marie Rrapi, Olga G. Mountanea, Maroula G. Kokotou, Demeter Tzeli, Christoforos G. Kokotos, George Kokotos
In recent years, halogen‐bonded complexes (XBCs), in solution, have played a pivotal role in inducing photochemical organic reactions. In this work, we explore the ability of various tertiary amines to act as XB acceptors in the presence of the XB donor CBr4 by computational and spectroscopic studies. DFT studies clearly showcase the formation of XBCs between the studied tertiary amines and CBr4. Simultaneously
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Competitive Intramolecular Hydrogen Bonding: Offering Molecules a Choice ChemPlusChem (IF 3.4) Pub Date : 2024-05-07 Yu Sun, Evelyn Morton, Hunaida Bhabha, Ewan Clark, Dejan-Krešimir Bučar, Victoria Barros-Metlova, Jamie A Gould, Abil Aliev, Cally Haynes
The conformational preferences of N‐((6‐methylpyridin‐2‐yl)carbamothioyl)benzamide were studied in solution, the gas phase and the solid state via a combination of NMR, density functional theory (DFT) and single crystal X‐ray techniques. This acyl thiourea derivative can adopt two classes of low energy conformation, each stabilized by a different 6‐membered intramolecular hydrogen bond (IHB) pseudoring
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An NMR Toolkit to Probe Amyloid Oligomer Inhibition in Neurodegenerative Diseases: From Ligand Screening to Dissecting Binding Topology and Mechanisms of Action ChemPlusChem (IF 3.4) Pub Date : 2024-05-07 Alessandro Palmioli, Cristina Airoldi
The aggregation of amyloid peptides and proteins into toxic oligomers is a hallmark of neurodegenerative diseases, such as Alzheimer's disease and Parkinson's disease. Inhibition of amyloid oligomers formation and interactions with biological counterparts, as well as the triggering of non‐toxic amorphous aggregates, are strategies towards preventive interventions against these pathologies. NMR spectroscopy
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Solution Dynamics of Covalent Open‐[60]Fullerene Dimers ChemPlusChem (IF 3.4) Pub Date : 2024-05-07 Shu Okamoto, Yoshifumi Hashikawa, Yasujiro Murata
The translational diffusivity of covalent open‐[60]fullerene dimers in an organic solvent was found to be well describable by a prolate ellipsoid model while a monomeric open‐[60]fullerene behaves like a sphere model. The water association dynamics were examined for two open‐[60]fullerene dimers, showing a higher water affinity for the sp3‐linked dimer relative to sp2‐linked dimer owing to an effective
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Amino‐functionalizing Ce‐based MOF for enhanced CO2 adsorption and selectivity ChemPlusChem (IF 3.4) Pub Date : 2024-05-06 John Senith Ravishan Fernando, Shivani S Asaithambi, Sachin Maruti Chavan
Metal‐organic frameworks (MOF) hold great promise for CO2 adsorption due to their high surface areas, tunable pore sizes, and the ability to modify their chemical properties to enhance CO2 affinity. MOFs tagged with functional groups either at linker or metal sites have shown improved CO2 uptake capacity and selectivity. This study focuses on investigating the potential of selective CO2 adsorption
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Protein Thermodynamic Properties, Crystallisation, and the Hofmeister Series ChemPlusChem (IF 3.4) Pub Date : 2024-05-04 Emmanuel Saridakis, Katerina Donta
The Hofmeister series is a series of ions ordered according to their ability to precipitate proteins. It has also been linked to a host of (bio)chemical phenomena. Several attempts over the years to correlate the series to the varying success of different salts in crystallising proteins have been largely inconclusive. A correlation, based on published data and crystallisation conditions for several
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Cation Dependence of Enniatin B/Membrane‐Interactions Assessed Using Surface‐Enhanced Infrared Absorption (SEIRA) Spectroscopy ChemPlusChem (IF 3.4) Pub Date : 2024-05-03 Barbara Daiana Gonzalez, Enrico Forbrig, Guiyang Yao, Patrycja Kielb, Maria Andrea Mroginski, Peter Hildebrandt, Jacek Kozuch
Enniatins are mycotoxins with well‐known antibacterial, antifungal, antihelmintic and antiviral activity, which have recently come to attention as potential mitochondriotoxic anticancer agents. The cytotoxicity of enniatins is traced back to ionophoric properties, in which the cyclodepsipeptidic structure results in enniatin:cation‐complexes of various stoichiometries proposed as membrane‐active species
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Hydrodeoxygenation of Oxygen‐Containing Aromatic Plastic Wastes into Cycloalkanes and Aromatics ChemPlusChem (IF 3.4) Pub Date : 2024-05-03 Nan Wang, Jieyi Liu, Sibao Liu, Guozhu Liu
Chemical recycling and upcycling offer promising approaches for the management of plastic wastes. Hydrodeoxygenation (HDO) is one of the appealing ways for conversion of oxygen‐containing plastic wastes, including PET, PBT, PC, PPO, and PEEK, into cyclic alkanes and aromatics in high yields under mild reaction conditions. The challenge lies in achieving C‐O activation while preserving C‐C bonds. In
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The Promising Potential of Gallium Based Liquid Metals for Energy Storage ChemPlusChem (IF 3.4) Pub Date : 2024-05-02 Waheed Ur Rehman, Rana Zafar Abbas Manj, Yuanyuan Ma, Jianping Yang
Energy storage devices play a crucial role in various applications, such as powering electronics, power backup for homes and businesses, and support for the integration of renewable energy sources into electrical grid applications. Electrode materials for energy storage devices are preferred to have a flexible nature, conductive, better capacity, and low‐toxicity. Currently, using Gallium based liquid
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Protein Grafting Techniques: From Peptide Epitopes to Lasso‐Grafted Neobiologics ChemPlusChem (IF 3.4) Pub Date : 2024-05-02 Mikio Imai, Kilian Colas, Hiroaki Suga
Protein engineering techniques have vastly expanded their domain of impact, notably following the success of antibodies. Likewise, smaller peptide therapeutics have carved an increasingly significant niche for themselves in the pharmaceutical landscape. The concept of grafting such peptide onto larger protein scaffolds, thus harvesting the advantages of both, has given rise to a variety of protein
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Hydrothiolation of Triisopropylsilyl Acetylene Sulfur Pentafluoride – Charting the Chemical Space of β‐SF5 Vinyl Sulfides ChemPlusChem (IF 3.4) Pub Date : 2024-05-01 Hannes Kucher, Jonas Oliver Wenzel, David Rombach
Recently, we suggested liquid and high‐boiling TIPS‐CΞC‐SF5 (TASP) as a versatile reagent to access so far elusive SF5‐containing building blocks by less specialized laboratories under bench‐top conditions. The synthesis of non‐aromatic SF5 building blocks generally required on‐site fluorination or pentafluorosulfanylation steps employing toxic and/or gaseous reagents. Herein, we underline the versatility
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Critical Aspects and Challenges in the Design of Small Molecules for Electrochemiluminescence (ECL) Application ChemPlusChem (IF 3.4) Pub Date : 2024-04-30 Chiara Alberoni, Giulio Pavan, Thomas Scattolin, Alessandro Aliprandi
Electrochemiluminescence (ECL) has gained renewed interest due to the strong parallel development of luminophores in the field of organic light emitting diodes (OLEDs) with which this technique shares several aspects. In this prospective review we discuss the most relevant advances of the past 15 years in the study of organic and organometallic compounds as ECL emitters, by dividing them in three different
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Photocatalytic Transformation of Organics to Valuable Chemicals – Quo Vadis? ChemPlusChem (IF 3.4) Pub Date : 2024-04-29 Wiktoria Adamowicz, Kasidid Yaemsunthorn, Marcin Kobielusz, Wojciech Macyk
Recent development in photocatalysis is increasingly focused on transforming organic compounds toward producing fine chemicals. Simple, non‐selective oxidation reactions (degradation of pollutants) and very demanding solar‐to‐chemical energy conversion processes (production of solar fuels) face severe economic limitations influenced by still low efficiency and insufficient stability of the systems
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Hydroxyapatite: an Eco‐Friendly Material for Enzyme Immobilization ChemPlusChem (IF 3.4) Pub Date : 2024-04-29 Leonardo Gelati, Marco Rabufetti, Maurizio Benaglia, Sebastiano Campisi, Antonella Gervasini, Giovanna Speranza, Carlo F. Morelli
Biocatalysis has emerged in the last decade as a valuable and eco‐friendly tool in chemical synthesis, allowing in several instances to reduce or eliminate the use of hazardous reagents, environmentally dangerous solvents and harsh reaction conditions. Enzymes are indeed able to catalyse chemical transformations on non‐natural substrates under mild reaction conditions, still maintaining their high
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The Chemistry of Chelation for Built Heritage Cleaning: The Removal of Copper and Iron Stains ChemPlusChem (IF 3.4) Pub Date : 2024-04-29 Carmen Canevali, Antonio Sansonetti, Laura Rampazzi, Damiano Monticelli, Massimiliano D’Arienzo, Barbara Di Credico, Elena Ghezzi, Silvia Mostoni, Roberto Nisticò, Roberto Scotti
Chelators are widely used in conservation treatments to remove metal stains from marble, travertine, and limestone surfaces. In the current review the chemical aspects underlying the use of chelators for the removal of copper and iron stains from built heritage are described and clear criteria for the selection of the most efficient stain removal treatment are given. The main chelator structural features
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Atropisomeric Foldamers ChemPlusChem (IF 3.4) Pub Date : 2024-04-29 Saima Ansari, Peter Clarke Knipe
This concept article explores the emerging role of atropisomerism in foldamer chemistry, a field focussed on oligomers that adopt well‐defined conformations through non‐covalent interactions. Atropisomerism introduces a novel dimension to foldamer design by restricting rotational freedom around single bonds to dictate molecular shape with precision. Despite the prevalence of atropisomeric bonds in
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Evaluating Polyacrylic Acid as a Universal Aqueous Binder for Ni‐rich Cathodes NMC811 and Si Anodes in Full cell Lithium‐ion Batteries ChemPlusChem (IF 3.4) Pub Date : 2024-04-26 Buket Boz, Katja Fröhlich, Lukas Neidhart, Palanivel Molaiyan, Giovanni Bertoni, Marco Ricci, Francesco De Boni, Miljana Vuksanovic, Martina Romio, Karin Whitmore, Marcus Jahn
Silicon (Si) and silicon/graphite (Si/Gr) composite anodes are promising candidates due to their high theoretical capacity, low operating potential and natural abundance for high energy density Li‐ion batteries. Green electrode production, eliminating organic volatile solvents require advancement of aqueous electrodes. Engineering the binder plays a critical role for improving waterborne electrodes
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Carbon‐rich plasma‐deposited silicon oxycarbonitride films derived from 4‐(trimethylsilyl)morpholine as novel single‐source precursor ChemPlusChem (IF 3.4) Pub Date : 2024-04-25 Evgeniya Ermakova, Irina Tsyrendorzhieva, Alexander Mareev, Dmitry Pavlov, Olga Maslova, Vladimir Shayapov, Eugene Maksimovskiy, Irina Yushina, Marina Kosinova
4‐(trimethylsilyl)morpholine O(CH 2CH 2) 2NSi(CH3) 3 (TMSM) was investigated as a single‐source precursor for SiCNO films synthesis. Optical emission spectroscopy of plasma generated from TMSM/He, TMSM/H 2, and TMSM/NH 3 gas mixtures revealed the presence of N 2, CH, H, CN, and CO species. The last two are suggested to be responsible for the lowering of carbon concentration in the films in comparison
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SnO2/Au Microelectromechanical Systems Modified by Oxygen Vacancies for Enhanced Sensing of Dioctyl Phthalate ChemPlusChem (IF 3.4) Pub Date : 2024-04-24 Xue Chen, Danyang Wang, Menghan Xu, Rongrong Jia, Dongqi Yu, Lei Huang
Dioctyl phthalate (DOP) serves as a characteristic gas utilized in early electrical fire detection, its detection offers promising prospects for the prevention of electrical fires. In this study, we employed a modified photodeposition method to prepare Tin dioxide (SnO2) materials co‐modified with Au and oxygen vacancies. Subsequently, microelectromechanical systems (MEMS) gas sensor for DOP detection
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Anodic Reactions in Alkaline Hybrid Water Electrolyzers: Activity versus Selectivity ChemPlusChem (IF 3.4) Pub Date : 2024-04-24 Floris van Lieshout, Dulce M. Morales
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Synthesis of Selenium Derivatives using Organic Selenocyanates as Masked Selenols: Chemical Reduction with Rongalite as a Simpler Tool to give Nucleophilic Selenides ChemPlusChem (IF 3.4) Pub Date : 2024-04-22 Willber Castro-Godoy, adrian A heredia, Lydia M Bouchet, Juan E. Elias Argüello, Adrian A. Heredia, Juan E. Argüello
The chemical reduction within a family of organic selenocyanates, as masked selenols, using reducing agents, such as Rongalite, sodium dithionite, and sodium thiosulfate is investigated. Using Rongalite, the corresponding diselenides were obtained quantitatively and selectively in very good to excellent yields (51-100%) starting from alkyl, aryl, and benzyl selenocyanates. The scope of the reaction
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Spark Discharge Aerosol-generated copper-based nanoparticles: Structural & optical properties; application on the antiviral (SARS-CoV-2) and antibacterial improvement of face masks ChemPlusChem (IF 3.4) Pub Date : 2024-04-22 Konstantinos Giannakopoulos, Michael Lasithiotakis, Charalampos Karakasis, Maria Gini, Spyros Gardelis, Ioannis Karakassiliotis, Nafsika Mouti, Yvonni Xesfyngi, Georgios Manolis, Maria georgoutsou spyridonos, Marios Dimitriou, Kostas Eleftheriadis
Nanoparticle formation by Spark Discharge Aerosol Generation offers low-cost fabrication of nanoparticles, without the use of chemicals or vacuum. It produces aerosol particles of a few nanometers in size with high purity. In this work, copper-based - CuO (tenorite) and Cu- nanoparticles are produced, characterized and used to modify face mask air filters, achieving the introduction of antibacterial
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Smart Sensing of Nerve Agents ChemPlusChem (IF 3.4) Pub Date : 2024-04-22 Roberta Puglisi, Rossella Santonocito, Andrea Pappalardo, Giuseppe Trusso Sfrazzetto
The recent international scenario highlights the importance to protect human health and environmental quality from toxic compounds. In this context, organophosphorous (OP) Nerve Agents (NAs) have received particular attention, due to their use in terrorist attacks. Classical instrumental detection techniques are sensitive and selective, but they cannot be used in real field due to the high cost, specialized
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Retraction: A Naphthalenediimide-Based Fluorescent Sensor for Detecting the pH within the Rough Endoplasmic Reticulum of Living Cells ChemPlusChem (IF 3.4) Pub Date : 2024-04-19
Retraction: Namdev V. Ghule, Rajesh S. Bhosale, Kiran Kharat, Avinash L. Puyad, Sheshanath V. Bhosale, and Sidhanath V. Bhosale, A Naphthalenediimide-Based Fluorescent Sensor for Detecting the pH within the Rough Endoplasmic Reticulum of Living Cells, ChemPlusChem 2014, 80, 485–489 The above article, published online on 20 November 2014 and available in Wiley Online Library (wileyonlinelibrary.com)
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The Transition from Alchemical to Modern Chemical Symbolism: from Bergman and Guiton de Morveau to Hassenfratz and Adet, Higgins, Richter, Dalton, and Berzelius ChemPlusChem (IF 3.4) Pub Date : 2024-04-19 Curt Wentrup
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Reversing the Trend: Deciphering Self‐Assembly of Unconventional Amphiphiles having both Alkyl‐chain and PEG ChemPlusChem (IF 3.4) Pub Date : 2024-04-16 Rita Ghosh, Bharat Singh, Subhadip Basu, Avijit Mondal, Prabal Kumar Maiti, Mrinmoy De
In the field of molecular self‐assembly, the core of an assembly is always made up of hydrophobic moiety like a long alkyl chain, whereas the outer part has always been a hydrophilic moiety such as poly(ethylene glycol) (PEG), or charged species. Hence, reversing the trend to manifest self‐assembled structures with a PEG core and a surface consisting of alkyl chains in aqueous system is incredibly
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Effect of Anchoring Dynamics on Proton‐Coupled Electron Transfer in the Ru(bda) Coordination Oligomer on a Graphitic Surface ChemPlusChem (IF 3.4) Pub Date : 2024-04-16 Dario Calvani, Rick Louwersheimer, Francesco Buda
The oligomeric ruthenium‐based water oxidation catalyst, Ru(bda), is known to be experimentally anchored on graphitic surfaces through CH‐π stacking interactions between the auxiliary bda ([2,2′‐bipyridine]‐6,6′‐dicarboxylate) ligand bonded to ruthenium and the hexagonal rings of the surface. This anchoring provides control over their molecular coverage and enables efficient catalysis of water oxidation
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Formation of Polyimide Membranes via Non‐Solvent Induced Phase Separation: Insight from Molecular Dynamics Simulations ChemPlusChem (IF 3.4) Pub Date : 2024-04-16 George V. Theodorakopoulos, Dionysios S. Karousos, Evangelos P. Favvas, Anastasios Gotzias
Molecular dynamics simulations were applied to investigate the formation of P84 polyimide membranes through the non‐solvent induced phase separation (NIPS) process, considering two scenarios: one using a conventional organic solvent like n‐methyl‐2‐pyrrolidone (NMP) and the other a greener alternative, γ‐butyrolactone (GBL), with water serving as the non‐solvent. Different compositions of polymer solutions
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Combining WO3@AuNPs with Poly(amidoamine) Allows Sensitive Electrochemical Detection of DR1 Based on Dual Signal Amplification ChemPlusChem (IF 3.4) Pub Date : 2024-04-15 Haiyan Wei, Xiaojing Cui, Huaixia Yang, Fuchun Si, Yaping Zhang
Down‐regulator of transcription 1 (DR1) is considered as a biomarker of hashimoto's thyroiditis (HT), which is a risk factor for thyroid cancer. Here, a label‐free electrochemical biosensor for DR1 detection was constructed based on polyamidoamine (PAMAM) polymer and the nanocomposite (WO3@AuNPs) composed of tungsten trioxide (WO3) and gold nanoparticles (AuNPs). WO3@AuNPs was obtained by combining
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Supported Ionic Liquid‐Phase Materials (SILP) as a Multifunctional Group of Highly Stable Modifiers and Hardeners for Carbon and Flax Epoxy Composites ChemPlusChem (IF 3.4) Pub Date : 2024-04-15 Dawid Zielinski, Andrea Szpecht, Rafal Kukawka, Joanna Dzialkowska, Mariusz Pietrowski, Michal Zielinski, Magdalena Palacz, Paulina Nadobna, Marcin Smiglak
This paper introduces a novel approach to enhance epoxy resin formulations by using SILP materials as multifunctional hardeners and fillers in composite structures reinforced with carbon and flax fibers. This study explores the integration of ionic liquids (ILs) onto a silica support structure, presenting various permutations involving silica selection, ionic liquid choice, and concentration. The focus
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Combining Desferriferrioxamine B and 1‐Hydroxy‐2‐Piperidone ((PIPO)H) to Chelate Zirconium. Solution Structure of a Model Complex of the [89Zr]Zr−DFOcyclo*−mAb Radioimmunoconjugate ChemPlusChem (IF 3.4) Pub Date : 2024-04-13 Floriane Mangin, Osian Fonquernie, Pawel Jewula, Stéphane Brandès, Marie‐José Penouilh, Quentin Bonnin, Bruno Vincent, Enrique Espinosa, Emmanuel Aubert, Michel Meyer, Jean‐Claude Chambron
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Hollow Polyethyleneimine Nanoparticles with Drug Loaded DNA for Chemotherapeutic Applications ChemPlusChem (IF 3.4) Pub Date : 2024-04-11 Brendan Rucci, Brian Boyle, Mark Edward Byrne
The next generation of anticancer agents are emerging from rationally designed nanostructured materials. This work involved the synthesis and characterization of novel hollow DNA‐conjugated gold nanoparticles (DNA‐AuNPs) for controlled drug delivery. Polyethyleneimine (PEI) was bound to AuNPs, forming polymer‐shell nanoparticles. Dissolution of the gold core via iodine formed hollow core polymeric
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CHARMM‐GUI Membrane Builder for Lipid Droplet Modeling and Simulation ChemPlusChem (IF 3.4) Pub Date : 2024-04-11 Stephen Gee, Kerney Jebrell Glover, Nathan J. Wittenberg, Wonpil Im
Lipid droplets (LDs) are organelles that are necessary for eukaryotic and prokaryotic metabolism and energy storage. They have a unique structure consisting of a spherical phospholipid monolayer encasing neutral lipids such as triacylglycerol (TAG). LDs have garnered increased interest for their implications in disease and for drug delivery applications. Consequently, there is an increased need for
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Direct Conjugation of Gallium(III)‐Corroles to Short Interfering RNA (siRNA) Providing Real‐Time siRNA Imaging and Gene Silencing ChemPlusChem (IF 3.4) Pub Date : 2024-04-11 Ifrodet Giorgees, Vanessa Affe, Islah Williams, Jean‐Paul Desaulniers
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The Heptazine-Based Materials through Intrinsically Modification for the Cycloaddition of CO2 and Bisepoxides ChemPlusChem (IF 3.4) Pub Date : 2024-04-10 Hongguang Liang, Xiaoyun Li, Junwei Wang, Qifeng Li, Yuelan Feng, Maoqing Kang, Yingan Zhang
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Conformational Analysis of Conjugated Organic Materials: What Are My Heteroatoms Really Doing? ChemPlusChem (IF 3.4) Pub Date : 2024-04-10 Karl J. Thorley, Christian B. Nielsen
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Transparent Conductive Titanium and Fluorine Co-doped Zinc Oxide Films ChemPlusChem (IF 3.4) Pub Date : 2024-04-09 Iqra Ramzan, Joanna Borowiec, Ivan P. Parkin, Claire J. Carmalt
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Post-Assembly Polymerization of Discrete Anion-Coordinated Triple Helicate ChemPlusChem (IF 3.4) Pub Date : 2024-04-09 Jie Zhao, Ruying Lv, Fen Zhao, Dong Yang
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Chiral Heterometallic Cu8Ln4 Complexes with Enantiopure Schiff Base Ligands: Synthesis, Structural, Spectroscopic and Magnetic Studies ChemPlusChem (IF 3.4) Pub Date : 2024-04-09 Despina Dermitzaki, Angeliki Panagiotopoulou, Michael Pissas, Vassilis Psycharis, Catherine P. Raptopoulou
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Tungsten Oxide Dispersed on Silica as Robust and Readily Available Oxo/Imido Heterometathesis Catalyst ChemPlusChem (IF 3.4) Pub Date : 2024-04-08 Nikolai S. Bushkov, Andrey V. Rumyantsev, Anton A. Zhizhin, Tatyana V. Strelkova, Roman A. Novikov, Evgenii I. Gutsul, Rina U. Takazova, Dinara K. Kitaeva, Nikolai A. Ustynyuk, Pavel A. Zhizhko, Dmitry N. Zarubin
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Supramolecular Synthesis of Star Polymers ChemPlusChem (IF 3.4) Pub Date : 2024-04-08 Takeharu Haino, Natsumi Nitta
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Bifunctional Metal-Organic Nanoballs Featuring Lewis Acidic and Basic Sites as a New Platform for One-Pot Tandem Catalysis ChemPlusChem (IF 3.4) Pub Date : 2024-04-05 Gaurav Verma, Sanjay Kumar, Elliott R. Slaughter, Harsh Vardhan, Thamraa M. Alshahrani, Zheng Niu, Wen-Yang Gao, Lukasz Wojtas, Yu-Sheng Chen, Shengqian Ma
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Composite System of Lauryl Glucoside and Lauryl Glycoside Sulfosuccinate: Properties and Applications in Vitamin E Nanoemulsions ChemPlusChem (IF 3.4) Pub Date : 2024-04-05 Yunqin Qi, Zhihui Zhang, Zhiyu Wu, Ziyu Qin, Yuan Zhou, Xiuquan Yang
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A novel collagen aerogel with features relevant for topical biomedical applications ChemPlusChem (IF 3.4) Pub Date : 2024-04-05 Miguel P. Batista, Baldur Schroeter, Naiara Fernández, Frédéric Bustos Gaspar, Maria do Rosário Bronze, Ana Rita Cruz Duarte, Pavel Gurikov
Collagen‐based aerogels have great potential for topical biomedical applications. Collagen's natural affinity with skin, biodegradability, and gelling behavior are compelling properties to combine with the structural integrity of highly porous matrices in the dry form (aerogels). This work aimed to produce a novel collagen‐based aerogel and to perform the material's solid‐state and physicochemical
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Cyclodextrins-Based Polyrotaxanes: From Functional Polymers to Applications in Electronics and Energy Storage Materials ChemPlusChem (IF 3.4) Pub Date : 2024-04-03 Ruichun Du, Tianwei Bao, Deshuo Kong, Qiuhong Zhang, Xudong Jia
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L→S Coordination Complexes Containing Benzothiazol-2-ylidene Ligand: Quantum Chemical Analysis and Synthesis ChemPlusChem (IF 3.4) Pub Date : 2024-03-30 Joy Mukhopadhyay, Srikant Bhagat, Subash C. Sahoo, Prasad V. Bharatam
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Tellurium Containing Long Lived Emissive Fluorophore for Selective and Visual Detection of Picric Acid through Photo-Induced Electron Transfer ChemPlusChem (IF 3.4) Pub Date : 2024-03-29 Bhaskar Banerjee, Afsar Ali, Sandeep Kumar, Rajaneesh Kumar Verma, Vinay Kumar Verma, Ram Chandra Singh
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Stimuli-Induced Controls of Magnetic and Photophysical Properties Using Liquescent Open-Shell Ionic Molecular Systems ChemPlusChem (IF 3.4) Pub Date : 2024-03-28 Shuichi Suzuki, Ritsuki Tanaka, Ruifeng Shu, Takeshi Naota
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Continuous-Flow Catalysis Using Phosphine-Metal Complexes on Porous Polymers: Designing Ligands, Pores, and Reactors ChemPlusChem (IF 3.4) Pub Date : 2024-03-28 Hikaru Matsumoto, Tomohiro Iwai, Masaya Sawamura, Yoshiko Miura
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Effects of Cyclic Glycopolymers Molecular Mobility on their Interactions with Lectins ChemPlusChem (IF 3.4) Pub Date : 2024-03-27 Wenkang Jin, Masanori Nagao, Yusuke Kumon, Hikaru Matsumoto, Yu Hoshino, Yoshiko Miura
Cyclic polymers, which are found in the field of biopolymers, exhibit unique physical properties such as suppressed molecular mobility. Considering thermodynamics, the suppressed molecular mobility of cyclic polymers is expected to prevent unfavorable entropy loss in molecular interactions. In this study, we synthesized cyclic glycopolymers carrying galactose units and investigated the effects of their
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Concept and Development of Algebraic Topological Framework Nucleic Acids ChemPlusChem (IF 3.4) Pub Date : 2024-03-26 Lu Song, Xiaolei Zuo, Min Li
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Aryl Sulfoxides: A Traceless Directing Group for Catalytic C−H Activation of Arenes ChemPlusChem (IF 3.4) Pub Date : 2024-03-26 Pablo Simón Marqués, Claire Kammerer
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Photon Management Enabled by Opal and Inverse Opal Photonic Crystals: from Photocatalysis to Photoluminescence Regulation ChemPlusChem (IF 3.4) Pub Date : 2024-03-25 Hui Wang, Yiyan Cheng, Jintao Zhu, Lianbin Zhang
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Supramolecular Handshakes: Characterization of Urea-Carboxylate Interactions Within Calixarene Frameworks ChemPlusChem (IF 3.4) Pub Date : 2024-03-25 M. Cvetnić, N. Cindro, E. Topić, N. Bregović, V. Tomišić
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Probing the Dynamic Landscape: From Static to Time-Resolved X-Ray Absorption Spectroscopy to Investigate Copper Redox Chemistry in Neurodegenerative Disorders ChemPlusChem (IF 3.4) Pub Date : 2024-03-25 Emiliano De Santis, Stefania Alleva, Velia Minicozzi, Silvia Morante, Francesco Stellato
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Perylene Diimide-Based Dimeric Electron Acceptors with Molecular Conformations for Perovskite Solar Cells ChemPlusChem (IF 3.4) Pub Date : 2024-03-25 Gözde Murat Saltan, Tamer Yeşil, Aysun Albayrak Ötken, Ceylan Zafer, Haluk Dinçalp
Indoloquinoxaline and cibalackrot subunits covalently attached to perylene diimide dimers decorated with long-alkyl chains used as ETM are coated on the MAPbI2Br perovskite surface to manufacture solar cells. Attaching groups improve the charge transfer capability of the material depending on their molecular conformation, which plays important role in adjusting the energy level between the perovskite
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Synthesis of PtNi Nanoparticles to Accelerate the Oxygen Reduction Reaction ChemPlusChem (IF 3.4) Pub Date : 2024-03-24 Gerard M. Leteba, Sarah L. George, David R. G. Mitchell, Pieter B. J. Levecque, Eric van Steen, Lebohang Macheli, Candace I. Lang
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Immobilization of Silver(I) Ions on Amino-Functionalized Chromium(III) Terephthalate with Organophosphine and its C−H Carboxylation of a Heteroaromatic Compound ChemPlusChem (IF 3.4) Pub Date : 2024-03-24 Mijung Lee, Kyung-Ryul Oh, Ga-Young Cha, Se-Min Jeong, Su-Kyung Lee, Young Kyu Hwang
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Self-Promoted Glycosylation of Carbamoylated Peptides on Solid Phase ChemPlusChem (IF 3.4) Pub Date : 2024-03-24 Niklas H. Fischer, Benedicte N. Vævest, Andreas K. Dam, Frederik Diness, Christian M. Pedersen